CN103232813B - Slushing oil of a kind of salt spray resistance and preparation method thereof - Google Patents
Slushing oil of a kind of salt spray resistance and preparation method thereof Download PDFInfo
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- CN103232813B CN103232813B CN201310136170.8A CN201310136170A CN103232813B CN 103232813 B CN103232813 B CN 103232813B CN 201310136170 A CN201310136170 A CN 201310136170A CN 103232813 B CN103232813 B CN 103232813B
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- 150000003839 salts Chemical class 0.000 title claims abstract description 14
- 239000007921 spray Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000003921 oil Substances 0.000 claims abstract description 31
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000004581 coalescence Methods 0.000 claims abstract description 12
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims abstract description 8
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims abstract description 7
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- 239000003208 petroleum Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229940035048 sorbitan monostearate Drugs 0.000 claims abstract description 7
- 235000011076 sorbitan monostearate Nutrition 0.000 claims abstract description 7
- 239000001587 sorbitan monostearate Substances 0.000 claims abstract description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 9
- HMVCFZCJPVUFQG-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)(=O)N.C(CCCCCCCCCCCCCCCCC)(=O)N.OCCC=C Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)N.C(CCCCCCCCCCCCCCCCC)(=O)N.OCCC=C HMVCFZCJPVUFQG-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert-Butyl hydroperoxide Substances CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000003595 mist Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 238000003892 spreading Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Abstract
The invention discloses a kind of slushing oil of salt spray resistance, 75SN base oil 60-65,32# machinery oil 15-20 that it is made up of the raw material of following weight parts, petroleum sodium sulfonate 1-2, zinc naphthenate 4-5, dodecenylsuccinic acid half ester 3-4, sorbitan monostearate 1-2, fatty alcohol-polyoxyethylene ether 1-2, the tertiary butyl are to biphenol 2-3, dimeracid 2-5, film coalescence aid 2-4, dialkyl diphenylamine 1-2, N-phenyl-2-naphthylamine 1-2, aerosil 2-3; The slushing oil that the present invention produces is not easy to change; not oxidizable, do not affect the outward appearance of workpiece, excellent combination property; there are high salt fog resistance, humidity resistance, ageing resistance etc.; performance capable of washing is good, by the film coalescence aid added, improves the surface tension of oil film; make spraying evenly; good at surface of workpiece spreading property, the oil film of formation is uniform and stable, improves the provide protection kept metal.
Description
Technical field
The present invention relates generally to a kind of oil, particularly relates to slushing oil of a kind of salt spray resistance and preparation method thereof.
Background technology
Along with present national defence, developing rapidly of the industries such as automobile making, increasing to the demand of sheet metal, also more and more higher to the surface quality requirements of sheet material, because how anticorrosion, be lowered into product, transport, the loss of storage cost is the most important thing, at present, prevent generally cooking of metallic corrosion from being that workpiece surface is coated with last layer slushing oil, the large multicomponent of slushing oil traditional is at present simple, certain or several specific in performance pretty good, but over-all properties is bad, some slushing oil rust-proof lifes are short, some salt fog resistance ability, some paint films are unstable, be difficult to meet antirust demand.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides slushing oil of a kind of salt spray resistance and preparation method thereof.
The present invention is achieved by the following technical solutions:
A slushing oil for salt spray resistance, it is made up of the raw material of following weight parts:
75SN base oil 60-65,32# machinery oil 15-20, petroleum sodium sulfonate 1-2, zinc naphthenate 4-5, dodecenylsuccinic acid half ester 3-4, sorbitan monostearate 1-2, fatty alcohol-polyoxyethylene ether 1-2, the tertiary butyl are to biphenol 2-3, dimeracid 2-5, film coalescence aid 2-4, dialkyl diphenylamine 1-2, N-phenyl-2-naphthylamine 1-2, aerosil 2-3;
Described film coalescence aid is made up of the raw material of following weight parts:
Chloroprene rubber CR12150-60, eva resin 20-30, dimethylbenzene 30-40, polyvinyl alcohol 8-10, hydroxyethyl ethylene bis stearamide 1-2, Kathon 3-4, methyl benzotriazazole 2-3, Union carbide A-162 1-2, alkylpolyoxyethylene 2-3, dicumyl peroxide 1-2,2,5-dimethyl-2,5-bis-(tert-butyl hydroperoxide) hexane 0.8-1;
The preparation of described film coalescence aid comprises the following steps:
Add in Banbury mixer by above-mentioned chloroprene rubber CR121, plasticate separately 10-20 minute at temperature is 70-80 DEG C, and then discharging is cooled to normal temperature;
By above-mentioned eva resin, hydroxyethyl ethylene bis stearamide, Kathon, methyl benzotriazazole, alkylpolyoxyethylene mixing, 1-2 hour is reacted at 90-100 DEG C, add the chloroprene rubber after above-mentioned plasticating, reduction temperature is 80-90 DEG C, continue reaction 40-50 minute, add each raw material of residue again, at temperature is 60-70 DEG C, reacts 4-5 hour.
A preparation method for the slushing oil of salt spray resistance, comprises the following steps:
(1) above-mentioned 75SN base oil, 32# machinery oil are joined in reactor, stir, be heated to 110-120 DEG C;
(2) add above-mentioned petroleum sodium sulfonate, heated and stirred makes it dissolve;
(3) add above-mentioned zinc naphthenate, dodecenylsuccinic acid half ester, dimeracid, N-phenyl-2-naphthylamine, continuously dehydrating 1-1.5 hour, lower the temperature as 55-60 DEG C;
(4) the above-mentioned tertiary butyl is added to biphenol, sorbitan monostearate, insulated and stirred 3-4 hour at 55-60 DEG C;
(5) add each raw material of residue, fully stir, reduce temperature to 35-38 DEG C, filter discharging.
Advantage of the present invention is:
The slushing oil that the present invention produces is not easy to change; not oxidizable, do not affect the outward appearance of workpiece, excellent combination property; there are high salt fog resistance, humidity resistance, ageing resistance etc.; performance capable of washing is good, by the film coalescence aid added, improves the surface tension of oil film; make spraying evenly; good at surface of workpiece spreading property, the oil film of formation is uniform and stable, improves the provide protection kept metal.
Embodiment
Embodiment 1
A slushing oil for salt spray resistance, it is made up of the raw material of following weight parts (kilogram):
75SN base oil 65,32# machinery oil 20, petroleum sodium sulfonate 2, zinc naphthenate 5, dodecenylsuccinic acid half ester 4, sorbitan monostearate 2, fatty alcohol-polyoxyethylene ether 2, the tertiary butyl are to biphenol 3, dimeracid 2-5, film coalescence aid 4, dialkyl diphenylamine 1-2, N-phenyl-2-naphthylamine 2, aerosil 3;
Described film coalescence aid is made up of the raw material of following weight parts:
Chloroprene rubber CR12160, eva resin (VA content 28) 30, dimethylbenzene 40, polyvinyl alcohol 10, hydroxyethyl ethylene bis stearamide 1, Kathon 4, methyl benzotriazazole 3, Union carbide A-162 2, alkylpolyoxyethylene 3, dicumyl peroxide 2,2,5-dimethyl-2,5-bis-(tert-butyl hydroperoxide) hexane 0.8;
The preparation of described film coalescence aid comprises the following steps:
Add in Banbury mixer by above-mentioned chloroprene rubber CR121, plasticate separately at temperature is 80 DEG C 20 minutes, then discharging is cooled to normal temperature;
By above-mentioned eva resin, hydroxyethyl ethylene bis stearamide, Kathon, methyl benzotriazazole, alkylpolyoxyethylene mixing, react 2 hours at 100 DEG C, add the chloroprene rubber after above-mentioned plasticating, reducing temperature is 90 DEG C, continue reaction 50 minutes, add each raw material of residue again, react 5 hours at temperature is 70 DEG C.
A preparation method for the slushing oil of salt spray resistance, comprises the following steps:
(1) above-mentioned 75SN base oil, 32# machinery oil are joined in reactor, stir, be heated to 120 DEG C;
(2) add above-mentioned petroleum sodium sulfonate, heated and stirred makes it dissolve;
(3) add above-mentioned zinc naphthenate, dodecenylsuccinic acid half ester, dimeracid, N-phenyl-2-naphthylamine, continuously dehydrating 1 hour, lower the temperature as 60 DEG C;
(4) the above-mentioned tertiary butyl is added to biphenol, sorbitan monostearate, insulated and stirred 4 hours at 60 DEG C;
(5) add each raw material of residue, fully stir, reduce temperature to 38 DEG C, filter discharging.
Performance test:
Apparent: without precipitation, to separate out without layering, nodeless mesh thing;
Salt spray resistance is tested: 36 DEG C, 170 hours, corrosion-free;
Wet-heat resisting is tested: 50 DEG C, 700 hours, corrosion-free;
Weathering resistance is tested: experiment workpiece is 100 blocks of 45# steel, size is 200mm*200mm*10mm, surface non-corroding, wherein traditional slushing oil used by 50 pieces of workpiece, and slushing oil of the present invention used by 50 pieces of workpiece, as for same indoor, experimental period 2 years, after tested, use the workpiece corrosion degree of slushing oil of the present invention the highest be 1.2%, what extent of corrosion was minimum is 0.7%, and average corrosion rate is 0.84%; Use the workpiece corrosion degree of traditional slushing oil the highest be 4.1%, what extent of corrosion was minimum is 3.3%, and average corrosion rate is 3.66%.
Claims (2)
1. a slushing oil for salt spray resistance, is characterized in that what it was made up of the raw material of following weight parts: 75SN base oil 60-65,32# machinery oil 15-20, petroleum sodium sulfonate 1-2, zinc naphthenate 4-5, dodecenylsuccinic acid half ester 3-4, sorbitan monostearate 1-2, fatty alcohol-polyoxyethylene ether 1-2, the tertiary butyl are to biphenol 2-3, dimeracid 2-5, film coalescence aid 2-4, dialkyl diphenylamine 1-2, N-phenyl-2-naphthylamine 1-2, aerosil 2-3; Described film coalescence aid is prepared from by the raw material of following weight parts: chloroprene rubber CR12150-60, eva resin 20-30, dimethylbenzene 30-40, polyvinyl alcohol 8-10, hydroxyethyl ethylene bis stearamide 1-2, Kathon 3-4, methyl benzotriazazole 2-3, Union carbide A-162 1-2, alkylpolyoxyethylene 2-3, dicumyl peroxide 1-2,2,5-dimethyl-2,5-bis-(tert-butyl hydroperoxide) hexane 0.8-1; The preparation of described film coalescence aid comprises the following steps: add in Banbury mixer by above-mentioned chloroprene rubber CR121, and plasticate separately 10-20 minute at temperature is 70-80 DEG C, and then discharging is cooled to normal temperature; By above-mentioned eva resin, hydroxyethyl ethylene bis stearamide, Kathon, methyl benzotriazazole, alkylpolyoxyethylene mixing, 1-2 hour is reacted at 90-100 DEG C, add the chloroprene rubber after above-mentioned plasticating, reduction temperature is 80-90 DEG C, continue reaction 40-50 minute, add each raw material of residue again, at temperature is 60-70 DEG C, reacts 4-5 hour.
2. a preparation method for Anti-salt mist anti-rust oil as claimed in claim 1, is characterized in that comprising the following steps: above-mentioned 75SN base oil, 32# machinery oil join in reactor by (1), stirs, is heated to 110-120 DEG C; (2) add above-mentioned petroleum sodium sulfonate, heated and stirred makes it dissolve; (3) add above-mentioned zinc naphthenate, dodecenylsuccinic acid half ester, dimeracid, N-phenyl-2-naphthylamine, continuously dehydrating 1-1.5 hour, lower the temperature as 55-60 DEG C; (4) the above-mentioned tertiary butyl is added to biphenol, sorbitan monostearate, insulated and stirred 3-4 hour at 55-60 DEG C; (5) add each raw material of residue, fully stir, reduce temperature to 35-38 DEG C, filter discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310136170.8A CN103232813B (en) | 2013-04-18 | 2013-04-18 | Slushing oil of a kind of salt spray resistance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310136170.8A CN103232813B (en) | 2013-04-18 | 2013-04-18 | Slushing oil of a kind of salt spray resistance and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103232813A CN103232813A (en) | 2013-08-07 |
| CN103232813B true CN103232813B (en) | 2016-03-30 |
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| CN201310136170.8A Active CN103232813B (en) | 2013-04-18 | 2013-04-18 | Slushing oil of a kind of salt spray resistance and preparation method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666272A (en) * | 2013-12-09 | 2014-03-26 | 常熟市大康汽车座垫有限责任公司 | Antirust emulsified wax for metal products |
| CN106635265A (en) * | 2015-11-02 | 2017-05-10 | 中昊(大连)化工研究设计院有限公司 | Method for increasing adhesion and anti-hydraulic pressure of shield tail sealing grease |
| CN105713708A (en) * | 2016-02-02 | 2016-06-29 | 宁波美代进出口有限公司 | Anti-rust lubricating canola oil for door lock and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0282079A2 (en) * | 1987-03-12 | 1988-09-14 | Nippon Oil And Fats Company, Limited | Coating composition with improved rust-preventing properties for use in preparing lubricated steel products |
| CN102977981A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ferrocene gas-phase slow-release rust preventive oil and preparation method thereof |
| CN102977982A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ammonium benzoate gas-phase slow-release rust preventive oil and preparation method thereof |
-
2013
- 2013-04-18 CN CN201310136170.8A patent/CN103232813B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0282079A2 (en) * | 1987-03-12 | 1988-09-14 | Nippon Oil And Fats Company, Limited | Coating composition with improved rust-preventing properties for use in preparing lubricated steel products |
| CN102977981A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ferrocene gas-phase slow-release rust preventive oil and preparation method thereof |
| CN102977982A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ammonium benzoate gas-phase slow-release rust preventive oil and preparation method thereof |
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| CN103232813A (en) | 2013-08-07 |
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Effective date of registration: 20160226 Address after: 244100 new road, West Lake Town Development Zone, lion mountain, Tongling, Anhui Applicant after: Anhui Mingzhu Pigment Technology Co., Ltd. Address before: Wu Song Zhen Tongling County of Anhui province Tongling 244100 Union City Village Applicant before: Anhui Mingzhu Pigment Technology Co., Ltd. |
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Effective date of registration: 20191012 Address after: 314000 floor 3, building 8-1, Gaoqiao Street Industrial Zone, Tongxiang City, Jiaxing City, Zhejiang Province Patentee after: Tongxiang Shuangma Machinery Co., Ltd. Address before: 211112 No. 3 Fengyi Road, Jiling Street, Jiangning District, Nanjing City, Jiangsu Province Patentee before: Ni Shu Jun |
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