CN103225746B - A kind of chemical photic device - Google Patents
A kind of chemical photic device Download PDFInfo
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- CN103225746B CN103225746B CN201210021367.2A CN201210021367A CN103225746B CN 103225746 B CN103225746 B CN 103225746B CN 201210021367 A CN201210021367 A CN 201210021367A CN 103225746 B CN103225746 B CN 103225746B
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Abstract
The invention discloses a kind of chemical photic devices, technical solution includes one or more cavitys (2) that a light transmission closure (1) surrounds, cavity (2) inner containment has chemiluminescence medicament (3), the cavity (2) to be internally provided with image device (4).The purpose of the present invention is to provide a kind of chemical photic device, it can make chemiluminescence and image shows perfect adaptation that colored or well-bedded image device lower is fully showed in chemiluminescent irradiation and setting off.
Description
Technical field
The present invention relates to a kind of chemical photic devices.
Background technology
In general, it is by chemistry such as substituted-phenyl oxalate ester, fluorescer, oxidant, catalyst, solvents that civilian chemical, which shines,
The medicament that shines generated chemical reaction after mixing.We are containing substituted-phenyl oxalate ester (abbreviation oxalate ester)
Component be called luminous agent component, the component of the oxidant containing peroxide is called oxidant component or activator, usually
The peroxide used is hydrogen peroxide or carbamide peroxide.Fluorescer is in the component containing oxalate ester under normal circumstances
In, and catalyst is in the oxidant constituents containing peroxide, but this is nor absolute, containing glimmering in oxidant component
Photo etching containing catalyst is also feasible in oxalate ester component.The use of solvent be also in this way, oxidant component and
The component of oxalate ester can be dissolved with solvent, can also only one of which component use solvent.Under various circumstances, may be used
Even to achieve the effect that high viscosity or solid luminescence without using solvent by using different solvent or dispersant.Usual
In the case of most popular substituted-phenyl oxalate ester refer to bis- (2,4,5- tri- chloro-salicylic acid's n-pentyl ester) oxalates (CPPO)
Or bis- (2,4,5- trichlorine isoamyl salicylate) oxalates (CIPO).
Light source of the chemiluminescence product as patterned display, common application are the printing figures on the outside of chemical photic device
Case, or stick the transparent non-setting adhesive with printed patterns shows pattern classes through chemical photic device from inside to outside luminous
As method also have such as Chinese patent：As 201507790U descriptions, equipped with chemistry in the packaging bag for having hollowed printing
Light-emitting device.The common feature of this kind of luminous showing device is that silhouette effect shines, and the contour feature of pattern is clear, but
Be pattern color rendition effect and contrast level effect it is excessively poor, due to light from inside appear, if completely black
The level and color of the image that can not differentiate appearance at all are used under environment.
Invention content
The invention aims to provide a kind of new chemical light-emitting device.Chemiluminescence can be made perfect with image shows
Lower fully show in chemiluminescent irradiation and setting off in conjunction with colored or well-bedded image device is made.
Include to reach the technical solution that the purpose of the present invention is taken：Surround one of one light transmission closure 1
Or multiple cavities 2,2 inner containment of the cavity have chemiluminescence medicament 3, which is characterized in that the cavity 2 is internally provided with image
Device 4.
In above-mentioned chemical photic device, the image device 4 be one or more pieces carry by printing or printing and dyeing or
It engraves or folds or watermark or the paper or high molecular material or non-woven fabrics or fiber of piecing or weave or spin or embroider obtained image together
Material.These described materials be a kind of material in single layer or these materials MULTILAYER COMPOSITE or these materials in it is different
The MULTILAYER COMPOSITE that material is constituted, the fibrous material is inorganic material or organic material, and wherein inorganic material is glass fibre, is had
Machine material is fibrous material made of cotton fiber or high molecular polymer.
In above-mentioned chemical photic device, the image device 4 is that one or more pieces carry the figure obtained by printing
The paper or/and macromolecule member material of picture, the macromolecule member material are polypropylene or polyethylene or polyvinyl chloride or gather to benzene
Naphthalate or they therein at least two the double-deck composite material to multilayer, the paper and macromolecule member material
Refer to the composite material of paper and macromolecule member material, when image device 4 is composite material, the image printing is in composite wood
The surface of material or the inner surface of composite intermediate layer.
In above-mentioned chemical photic device, cavity 2 that the closure 1 surrounds is that the material of light transmission is the soft of light transmission
The bag that property macromolecule resin material or the macromolecule member material of light transmission surround.The macromolecule member material is polypropylene or poly- second
Alkene or nylon or polyvinyl chloride or polyethylene terephthalate or PVAC polyvinylalcohol or Vingon or high-barrier MA-
In PVDC or ethylene/vinyl alcohol copolymer EVOH or poly- naphthalene ester PEN or these materials two or more it is double-deck at most
The composite material of layer.
In above-mentioned chemical photic device, the chemiluminescence medicament 3 refers to the component 3-A containing oxalate ester and contains
There are the component 3-B of oxidant, at least their one of which to be loaded into the sealing container 5 that can be crushed.
In above-mentioned chemical photic device, the material of the sealing container 5 being crushed is glass or macromolecule membrane
Or aluminium foil composite polymer material；The high molecular material is polyfluorinated ethylene propylene FEP or Meltability polytetrafluorethyletubular PFA or gathers
Propylene or polyethylene or nylon or polyvinyl chloride or polyethylene terephthalate or PVAC polyvinylalcohol or Vingon or
Two or more in high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or poly- naphthalene ester PEN or these materials
Bilayer or multilayer composite material.
In above-mentioned chemical photic device, the image of the macromolecule membrane or paper that are printed with image is placed in the bag
Device 4, while also separated in bag thering is the transparent polymer thin-film material for sealing the 3-A of the component containing oxalate ester to enclose
At the sealing container 5 that can be crushed of independence and seal the transparent polymer thin-film material of the component 3-B containing oxidant and surround
The sealing container 5 that can be crushed of independence.
In above-mentioned chemical photic device, the bag inside points placed the macromolecule member material for being printed with image in region
Or the image device 4 of paper, wherein be placed at least adjacent to the region on a side of bag in remaining subregion seal containing
The sealing that the independence that the high molecular film material or aluminium foil composite polymer material of the component 3-A of oxalate ester surrounds can be crushed is held
Device 5；Seal the sealing container 5 that the independence that the transparent polymer thin-film material of the component 3-B containing oxidant surrounds can be crushed
Overlay the region of image device 4.
In above-mentioned chemical photic device, the sealing being crushed for sealing the component 3-A containing oxalate ester
When container 5 is transparent polymer thin-film material, it is placed on the region close to a side, the appearance bread in the region in the bag
It is cased with the exhausted water bag 6 of the aluminium foil composite polymer material of one end open, with dissoluble sealed separation device 7 by the exhausted water bag 6
The opening in outside compressed with the outer surface of the bag and will seal the sealing being crushed of the component 3-A containing oxalate ester and hold
Device 5 is sealed in exhausted water bag 6.
In above-mentioned chemical photic device, the sealing being crushed for sealing the component 3-A containing oxalate ester
Container 5 is placed on the region close to a side in the bag, the outer clad aluminum foil of macromolecule member material of the closure 1 in the region
Exhausted water layer constitutes exhausted water bag 6, and being crushed for the component 3-B containing oxidant is sealed close to placement at the edge of the exhausted water bag 6
Sealing container 5 region side outside or inside be equipped with dissoluble sealed separation device 7.
In above-mentioned chemical photic device, at least one sideband of the bag has supporting adn fixing device 8.
In above-mentioned chemical photic device, cavity 2 that the shell 1 surrounds is transparent or semitransparent macromolecule membrane material
When expecting the bag surrounded, cavity 2 is divided into two or more areas by one or more than one segmentation hot pressing lines 9
Domain, it is interregional to communicate or be not communicated with.When the image device 4 is the papery with image, it is divided and is placed on relatively
In the region answered.When the image device 4 is high molecular material or non-woven fabrics, divide hot pressing line 9 by the height of itself and shell 1
The hot pressing of molecule membrane material is together.
In above-mentioned chemical photic device, the shape of above-mentioned chemical photic device is flag.
In above-mentioned chemical photic device, the cavity 2 that the shell 1 surrounds is the cavity 2 being evacuated.
The present invention provides a kind of chemical photic devices, and chemiluminescence can be made to make colour with image shows perfect adaptation
Or well-bedded image device lower fully show in chemiluminescent irradiation and setting off.
Description of the drawings
Fig. 1 is the structural schematic diagram of the chemical photic device of a cylindrical shell；
Fig. 2 is the structural schematic diagram of the chemical photic device of a film shell；
Sectional view when Fig. 3 is the use of light-emitting device shown in Fig. 2 and Fig. 5；
Fig. 4 is a kind of structural schematic diagram of the chemical photic device with segmentation hot pressing line；
Fig. 5 is a kind of structural schematic diagram of flag-shaped chemical photic device；
Fig. 6 is the structural schematic diagram with the tubulose clamp to crack；
Fig. 7 is the structural schematic diagram that tubulose clamp seals flag-shaped chemical photic device and exhausted water bag；
Fig. 8 is the structural schematic diagram with the tubulose clamp to crack of stock；
Fig. 9 is use state diagram of the stock tubulose clamp as flagpole；
Figure 10 is the structural schematic diagram of the flag-shaped chemical photic device with supporting adn fixing device；
Figure 11 is a kind of structural schematic diagram of flag-shaped chemical photic device using glass ampere bottle；
Figure 12 is a kind of structural schematic diagram for the M shape image device pieced together.
Specific embodiment
It is closed by material of high-pressure polypropylene as shown in Figure 1, the chemical photic device of a light transmission cylindrical shell is one
The hollow cavity 2 that surrounds of cylindrical shell 1,2 inside of cavity is equipped with chemiluminescence medicament 3.It is also placed with image simultaneously in cavity 2
Device 4.Image device 4 is the thin plate of a polyethylene for engraving alphabetical " A B C ", and thin plate can be that polyethylene is translucent
Primary colors pigments or dyes it is dyed still maintain translucent or opaque.Here chemiluminescence medicament 3 is
Refer to the luminous chemiluminescence for being mixed with oxalate ester, fluorescer, hydrogen peroxide, sodium salicylate catalyst, solvent
Liquid.Also there is luminescent solution inside luminal fluid, or even the hollow out position of alphabetical " A B C " due to having before and after image device 4
Body, so being totally different from from the effect of 1 external vision image shows of shell by image printing or being attached to institute on the outside of light-emitting device
The silhouette effect brought.The illumination of luminal fluid is much better than the prior art on 4 surface of image device to the performance of its material texture
Effect.When the thin plate of image device 4 is dyed with pigments or dyes, no matter it is translucent or opaque, works as hair
When light liquid selects white light, the color rendition degree to 4 material of image device is also good.The material of shell 1 be glass or
When the high grades of transparency material such as polycarbonate, the bandwagon effect of image device 4 is more preferably perfect.
Other than high molecular material can make image device 4, material can also be paper or non-woven fabrics or undulation degree
Material braiding, can also be a kind of MULTILAYER COMPOSITE of material in these materials or the MULTILAYER COMPOSITE that a variety of different materials are constituted.
Wherein fibrous material can be：Inorganic material or organic material, inorganic material can be glass fibres, and organic material can be cotton
Fibrous material made of fiber or high molecular polymer.Other than to image device 4 engrave and to form its pattern, when its material
We can also pass through the side of the density of the subregion of change image device 4 whens matter selects paper or non-woven fabrics or fibrous material etc.
Method forms pattern on image device 4, such as the pattern or hot pressing non-woven fabrics or high score of digital watermark acquisition are utilized on paper
The pattern that subbundle material obtains.Or it by the way of high pressure punch die or folding or the modes such as pieces together and makes shape in pattern means 4
At three-dimensional pattern, in this way when using the present apparatus, light reflects shell 1 from three-dimensional image device 4 and forms luminescent image
Effect.When using fibrous material, image device 4 can also be to be woven or spun or embroidered by the fiber of different colours to obtain
's.
In the present embodiment, shell 1 is that have certain thickness, we can also carve the inner surface of shell 1
It carves or printing forms image device 4, light is radiated on shell when chemiluminescence medicament shines, and sheathing material is formed a small amount of
Identical effect can also be reached by scattering the reflective printing layer or the sunk area of engraving of can also illuminating.
As shown in Fig. 2, the chemical photic device of a film shell：The closed shell of one light transmission 1 surrounds cavity 2, with Fig. 1
Described in unlike embodiment, shell 1 is the bag that macromolecule polypropylene (PP) membrane material of light transmission surrounds.2 inside of cavity is close
The component 3-A containing oxalate ester and the component 3-B containing oxidant for having sealed separated liquid, wherein containing oxidant
Component 3-B be loaded into the sealing container 5 that can be crushed, the component 3-A containing oxalate ester is directly placed into cavity 2 and can break
The material of broken sealing container 5 is that high molecular polythene (PE) thin-film material surrounds capsule made of simultaneously sealing welding edge fit, thickness
In 0.001mm-0.006mm or so, it is easy to be squeezed and be ruptured by external force.Image device 4 is also sealed in the bag that shell 1 surrounds,
Here image device 4 is that the Biaxially oriented polypropylene of the pattern of the flower for the printing chromatic colour that a piece of expansion is placed in cavity 2 is thin
Film (i.e. BOPP film) composite polyethylene (PE) film, the pattern of colored flower are printed in BOPP film again compound upper polyethylene
(PE) film.The thickness of BOPP film and polyethylene (PE) film is 0.004mm.When in use, it is only necessary to which racking can be crushed
Sealing container 5, allow the component 3-A that the component 3-B outflow of oxidant encounters oxalate ester to generate chemiluminescence, while shining
The both sides that liquid rapidly flows to image device 4 are submerged.The component 3-A of oxalate ester in this embodiment contains fluorescence
Agent is the chemiluminescence that the green mixing fluorescer of blue reddish yellow generates white.As shown in figure 3, when Fig. 3 is the use of above-described embodiment
Sectional view is immersed in by the image device 4 of carrier of laminated film in luminous medicament 3, at this time image device entirely as can be seen from Figure 3
The white light that the pattern of colored flower on 4 will be sent out by chemiluminescent fluid illuminates, and passes through the table for the bag that shell 1 surrounds
Surface launching comes out, at the same tow sides it can be seen that luminous colored flower image.
The image device 4 can also be the high molecular film material other than material mentioned in above-described embodiment, it
Can also be polypropylene or polyethylene or polyvinyl chloride or polyester (polyethylene terephtalate) or they are therein
At least two double-deck composite material to multilayer.It is printed with the paper of image or the composite material or nothing of paper and macromolecule member material
Woven fabric or cloth glass fabric are also feasible as image device 4.With the glass fabric or nylon for weaving or being embroidered with image
Image device 4 made of web or polyester material is also that luminescent image effect is very outstanding.
The material of shell 1 is can also be in addition to macromolecule polypropylene (PP) in the high molecular material of light transmission in the present embodiment
Polyethylene (PE) or nylon (PA) or polyvinyl chloride (PVC) or polyethylene terephthalate (polyester PET) or polyethylene
Alcohol (PVA) or Vingon (PVDC) or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer (EVOH) or poly- naphthalene ester
(PEN) or the composite material of their two or more bilayer or multilayers therein.
In the present embodiment, the material for the sealing container 5 that can be crushed can also be other high other than polyethylene (PE)
Molecular film material, they can be polyfluorinated ethylene propylene (FEP) or Meltability polytetrafluorethyletubular (PFA) or polypropylene (PP) or
Nylon (PA) or polyvinyl chloride (PVC) or polyester (PET) or polyvinyl alcohol (PVA) or Vingon (PVDC) or high-barrier
MA-PVDC or ethylene/vinyl alcohol copolymer (EVOH) or poly- naphthalene ester (PEN) or their two or more bilayers therein
To the composite material of multilayer.Aluminium foil composite polymer material, and the good selection for the sealing container 5 that can be crushed is made, only
It is easy the region shading in image device 4.The overall thickness when use of above-mentioned material is between 0.0001mm-0.1mm.
In the present embodiment, the component 3-A containing oxalate ester can also be also sealed in another sealing being crushed
In container 5.It is more conducive to the extension of product shelf life in this way, while multiple and different color chemiluminescence medicaments 3 can be placed
5 one side of sealing container being crushed can enrich color performance can also by several times using extend fluorescent lifetime.
As shown in figure 4, a kind of chemical photic device with segmentation hot pressing line：The closed shell of one light transmission 1 surrounds chamber
Body 2, shell 1 are the bags that high molecular polythene (PE) membrane material of light transmission surrounds.One point has been pressed the centre position of shell 1 is horizontal
It cuts hot pressing line 9 and the cavity 2 that shell 1 surrounds is divided into two parts up and down, a vertical edge on the right side and shell 1 of segmentation hot pressing line 9
Fusion, left side do not fuse, and there are channels, and the chamber 2 that upper and lower two divided hot pressing lines 9 are divided is made to communicate.Image device 4 is two
Piece is placed in the chamber 2 that two divided hot pressing lines 9 are divided up and down in shell 1 and is printed with rabbit or more two parts pattern respectively
60g/ square metres of 100% wood pulp paper of white, the pattern of rabbit are combined into jointly by upper and lower two panels.Two up and down of cavity 2
The right side divided is placed there are two the sealing container 5 being crushed for sealing the component 3-B containing oxidant, and the left side of cavity 2 is put
The sealing container 5 of the component 3-A containing oxalate ester being crushed, the material for the sealing container 5 that can be crushed are sealed there are two setting
Matter is that macromolecule polypropylene (PP) thin-film material surrounds capsule made of simultaneously sealing welding edge fit, and thickness is in 0.002mm.It is using
When, it is only necessary to all sealing containers 5 being crushed are racked, the component 3-B outflows of oxidant is allowed to encounter the oxalate ester of outflow
Component 3-A generate chemiluminescence, and map out the pattern of rabbit.What it is different from embodiment described in Fig. 2 is the present embodiment tool
The segmentation hot pressing line 9 played the role of is when hand-held light-emitting device left side vertical picks up entire light-emitting device, under right side meeting is slight
Pendant is divided hot pressing line 9 and intercepts when luminal fluid being caused to drop so that most will not flow to the last cell of light-emitting device and
Influence the illumination effect of global pattern, the left side of segmentation hot pressing line 9, which does not fuse, makes up and down that there are channels in order to abundant for two chambers
Mixed luminescence liquid can not also make device become two completely self-contained cavitys up and down there are channel if necessary.With point
The light-emitting device for cutting hot pressing line 9 is suitable for more large area and needs to erect the light-emitting device for the case where using.If using more
The effect that light-emitting device is divided into more horizontal chambers to prevent liquid dirty by segmentation hot pressing line 9 is then more obvious, but paper image
Device will be divided into more pieces, to influence overall effect.
If image device 4 uses the figuratum high molecular film material of printing or macromolecule non-woven fabrics in above-described embodiment
Or two-sided composite polymer film material paper when, entire pattern need not be divided into multi-disc and be put again such as multiple cavities 2, but can will be upper
The material for stating image device 4 is directly placed into the bag that high molecular material surrounds, then from the direct transverse direction on the two sides in the outside of bag
Hot pressing can equally play the work for being partitioned into multiple cavities 2 to prevent chemiluminescent fluid from dropping to form segmentation hot pressing line 9
With.
As shown in figure 5, a kind of flag form chemical photic device：The closed shell of one light transmission 1 surrounds cavity 2, and shell 1 is
It is rectangular that the internal layer that the overall thickness of light is 0.02mm is that high molecular polythene (PE) complex polyester (PET) membrane material (outer layer) surrounds
Shape bag.The image that papery double-sided symmetrical is printed on the flag pattern of star is placed with out of the right side of bag to the left the area of 80-90%
Device 4.The sealing container 5 being crushed for sealing the component 3-B containing oxidant overlays the lower right corner of image device 4, such as
There are one seal to contain for the place placement on figure close left side of the vacant position of remaining 10-20% areas on the left of rectangle bag
There is the sealing container 5 of the component 3-A of oxalate ester being crushed, the material for the sealing container 5 that can be crushed is high molecular polythene
(PE) thin-film material surrounds capsule made of simultaneously sealing welding edge fit, and thickness is in 0.002mm.It is put into paper in position as described above
Matter double-sided symmetrical, which is printed on the image device 4 of the flag pattern of star and seals the component 3-B containing oxidant, to be contained with sealing
After having two capsules of the component 3-A of oxalate ester, when carrying out last pressurizing window, can using vacuum air suction sealing machine come into
Row sealing, to exclude the air in cavity 2 as possible.In the left side of rectangle bag after the completion of sealing, that is, there are one close for placement
The aluminium foil composite polymer material of one three side sealing mouth of outer surface cover of the side of the capsule of the component 3-A containing oxalate ester is sealed
Exhausted water bag 6, the length of exhausted water bag 6 place the region of the capsule for sealing the component 3-A containing oxalate ester again can wrap
It is slightly long, then use dissoluble sealed separation device 7 as shown in FIG. 6 --- with crack 10 tubulose clamp, such as
Cracking for clamp will be inserted into after 6 reflexed of rectangle bag and exhausted water bag as shown in Figure 7 10 to be sealed.Such as Fig. 8 can also be applied
Shown in stock dissoluble sealed separation device 7 it is shown in fig. 6 with the clamp to crack to substitute, shown in practical figure 8 above
Dissoluble sealed separation device 7 be lengthening with the tubulose clamp to crack, and in the front end cracked with one
Section lead-in groove 11.Chemical photic device using when remove tubulose clamp and exhausted water bag 6, then rack and seal containing oxalate ester
Component 3-A and the capsule for sealing the component 3-B containing oxidant, and shine after so that chemiluminescence medicament is mixed, after shining uniformly
Obtaining one side can be with the flag of double-side.Then the left side of bag can not be had into image device 4 as shown in Fig. 9 as
Part roll by lead-in groove 11 be inserted into stock with crack 10 clamp in, part that bar lengthens is taken as hand-held or solid
Surely flagpole is used.It can also be set on the left of the rectangle bag that shell 1 surrounds as chemical photic device shown in Fig. 10
There is supporting adn fixing device 8, supporting adn fixing device 8 is a thin stick of the sealing in the leftmost side of rectangle bag herein, this
Sample can easily be rolled the part of the no image device in the left side of bag 4 using thin stick as axis, then be inserted into the band of stock
Have crack 10 clamp in.In addition upper iron wire or plastics are fixed in other frames of the rectangle bag surrounded in shell 1 or surface
The supporting objects such as stick or bamboo pole, to reinforce the non-deformability of film shell.Iron wire or other shapes memory material can also make
Flag-shaped light-emitting device keeps the shape of certain specific needs.
Water is really isolated in the effect of the exhausted water bag 6 of aluminium foil composite polymer material and dissoluble sealed separation device 7
The effect of vapour, to extend the shelf-life of the component 3-A containing oxalate ester.So if above-mentioned chemical photic device uses aluminium foil
Sealing container 5 that the independence that composite polymer material surrounds can be crushed can seal the component 3-A containing oxalate ester
The outer exhausted water layer of direct combination aluminium foil of the macromolecule member material of the closure 1 of the placement region of broken sealing container 5 constitutes exhausted
Water bag 6, at the edge of exhausted water bag 6 close to the area for placing the sealing container 5 being crushed for sealing the component 3-B containing oxidant
The outside or inside of the side in domain is equipped with dissoluble sealed separation device 7, here the internal dissoluble sealed separation being equipped with
Device 7 can be the engaged strip of paper used for sealing of channel-shaped for being welded on 1 inner surface of shell in the position.Also may be used by both above-mentioned modes
To reach the effect for the shelf-life for extending the component 3-A containing oxalate ester, while reaching the use purpose of the device.If
There are the vacant positions of certain area in the left side for the rectangle bag that shell 1 surrounds, and directly place and seal containing double oxalic acid
For the sealing container 5 of the component 3-A of ester being crushed in the region of image device 4, the material for the sealing container 5 that can be crushed is transparent
Luminescent image effect is equally very good when high molecular film material, but if being broken using what aluminium foil composite polymer material surrounded
Broken sealing container 5 is covered when there is luminous caused by aluminium foil is opaque, so as to cause chemiluminescence image device
There is shade.
Its sectional view is identical as Fig. 3 when the flag-shaped chemical photic device described in Fig. 5 uses vertically, as can be seen from Figure 3 paper
Matter double-sided symmetrical is printed on being immersed in entirely in luminous medicament 3 of the image device 4 of the flag pattern of star, the pattern of star and entire flag
The illumination that face is sent out by chemiluminescent agent is bright, and the surface emitting of the bag surrounded by shell 1 comes out, while tow sides all may be used
To see the image of Luminous flag.It is used since flag is nearly all straightened, so to prevent luminal fluid to be snapped down to bag
Lower part be very necessary.There are several factors to ensure that luminal fluid can reduce downslide to the greatest extent herein, first, luminal fluid
The adsorption layer formed between paper image device 4 has adsorbed a part of liquid；Second is that the intensity of of shell 1 itself has held one
Part luminal fluid；Third, since the bag surrounded in shell 1 has used vacuum seal technology in sealing, eliminate internal most
Number air, has on the one hand compressed the bag that shell 1 surrounds using atmospheric pressure, and luminal fluid is on the other hand allow to be full of in bag as possible
Portion space.
As shown in figure 11, another flag-shaped chemical photic device：The closed shell of one light transmission 1 surrounds cavity 2, shell 1
The internal layer that the overall thickness for being light transmission is 0.016mm is macromolecule ethylene/vinyl alcohol copolymer EVOH composite nylons (PA) membrane material
The rectangle bag that (outer layer) surrounds.The image device that papery double-sided symmetrical is printed on the flag pattern of star is placed on the right side of bag
4.The sealing being crushed for sealing the component 3-B for having oxidant containing liquid and sealing the component 3-A containing oxalate ester
Container 5 is two glass ampere bottles sealed respectively, they are in the protection tube 12 of a tube wall belt hole, this plastics
Pipe is fixed on the leftmost side for the rectangle bag that shell 1 surrounds by intermittent segmentation hot pressing line 9.Across protection tube 12 when use
It breaks two glass ampere bottles release chemiluminescence medicament 3-A and 3-B into pieces with one's fingers, liquid was got rid of into intermittent segmentation hot pressing after mixed luminescence
Line 9 obtains the Luminous flag of double-side to 4 region of image device.In protection pipe 12 can also only place 1 seal containing
The glass ampere bottle of the component 3-A of oxalate ester, and the component 3-B containing oxidant is then directly loadable into cavity 2 and protection pipe 12
Interior vacant position.
The glass disintegrating slag that protection tube 12 is mainly used for the glass ampere bottle that protection is broken into pieces with one's fingers cannot pierce through thin-film material
The bag surrounded can simultaneously serve as the fixing device of fixed flagpole.Protection tube 12 can also directly be extended, you can to increase
The region of glass ampere bottle is placed to increase the dose of luminous liquid, its own can also be used as flagpole.
The image device 4 for the rice word flag pattern pieced together as shown in figure 12 for three colors, respectively red, white from top to bottom,
The polyester PET thin film of blue 3 layers of transparent dyeing of multi-disc pieces composition together.They can be placed on one it is above-mentioned as described in Fig. 5 or Figure 11
The closed of light transmission surrounded in cavity 2 by light transmission film shell 1.Three layers can also be divided to be distributed in three by light transmission film shell
In 1 cavity 2 surrounded, folded fall together of final three light transmission film shells 1 collectively forms luminescent image.When image device 4 divides
Three layers when being distributed in the cavity 2 that three shells 1 surround, the color of the chemiluminescence medicament of each intracavitary can it is respectively red, white,
Lan Sanse, the image device 4 of each layer can be the paper material of white at this time, can also similarly obtain gorgeous rice word flag
Effect.
It should be noted last that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although ginseng
It is described the invention in detail according to preferred embodiment, it will be understood by those of ordinary skill in the art that, it can be to the present invention
Technical solution be modified or replaced equivalently, without departing from the spirit of the technical scheme of the invention and range, should all cover
In the scope of the claims of the present invention.
Claims (9)
1. a kind of chemical photic device, including one or more cavitys (2) that a light transmission closure (1) surrounds, the chamber
Body (2) inner containment has chemiluminescence medicament (3), it is characterised in that：The cavity (2) is internally provided with image device (4), and institute
Image device (4) is stated to be impregnated in the chemiluminescence medicament (3)；
The image device (4) be one or more pieces carry by printing printing and dyeing or engrave or fold watermark or piece together or
The paper or high molecular material or non-woven fabrics or fibrous material for the image that braiding or spinning or embroidery obtain；These described materials are single layers
Or a kind of material in these materials MULTILAYER COMPOSITE or these materials in different materials constitute MULTILAYER COMPOSITE, the fibre
It is inorganic material or organic material to tie up material, and wherein inorganic material is glass fibre, and organic material is cotton fiber or polyphosphazene polymer
Close fibrous material made of object；
The cavity (2) that the light transmission closure (1) surrounds is the flexible macromolecule resin material of light transmission or the high score of light transmission
The bag that sub- membrane material surrounds；The macromolecule member material is polypropylene or polyethylene or nylon or polyvinyl chloride or gathers to benzene two
Formic acid glycol ester or PVAC polyvinylalcohol or Vingon or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or
The composite material of poly- naphthalene ester PEN or two or more the multilayer in these materials；
The chemiluminescence medicament (3) refers to the component (3-A) containing oxalate ester and the component (3-B) containing oxidant,
At least their one of which are loaded into the sealing container (5) that can be crushed；
The material of the sealing container (5) being crushed is glass or macromolecule membrane or aluminium foil composite polymer material；Institute
Stating high molecular material is polyfluorinated ethylene propylene FEP or Meltability polytetrafluorethyletubular PFA or polypropylene or polyethylene or nylon or gathers
Vinyl chloride or polyethylene terephthalate or PVAC polyvinylalcohol or Vingon or high-barrier MA-PVDC or ethylene/second
The composite material of enol copolymer EVOH or poly- naphthalene ester PEN or two or more the multilayer in these materials.
2. chemical photic device according to claim 1, it is characterised in that：The image device (4) is a piece of or more
Piece carries the paper or/and macromolecule member material of the image obtained by printing, and the macromolecule member material is polypropylene or gathers
Ethylene or polyvinyl chloride or polyethylene terephthalate or they therein at least two multilayer composite material, it is described
Paper and macromolecule member material refer to the composite material of paper and macromolecule member material, described when image device (4) is composite material
Image printing in the surface of composite material or the inner surface of composite intermediate layer.
3. chemical photic device according to claim 1 or 2, it is characterised in that：It placed in the bag and be printed with figure
The macromolecule membrane of picture or the image device (4) of paper, at the same in bag also it is separated have seal the group containing oxalate ester
Divide the sealing container (5) and seal containing oxidant that the independence that the transparent polymer thin-film material of (3-A) surrounds can be crushed
The sealing container (5) that the independence that the transparent polymer thin-film material of component (3-B) surrounds can be crushed；Or in the bag internal zone dividing
The image device (4) that placed the macromolecule member material or paper that are printed with image in domain, wherein in remaining subregion at least
Region close to a side of bag is placed with the high molecular film material or aluminium foil for sealing the component containing oxalate ester (3-A)
The sealing container (5) that the independence that composite polymer material surrounds can be crushed；Seal the transparent of the component (3-B) containing oxidant
The sealing container (5) that the independence that high molecular film material surrounds can be crushed overlays the region of image device (4).
4. chemical photic device according to claim 3, it is characterised in that：Described seals the group containing oxalate ester
When the sealing container (5) being crushed of point (3-A) is transparent polymer thin-film material, it is placed in the bag close to a side
Region, the outer surface in the region is sheathed with the exhausted water bag (6) of the aluminium foil composite polymer material of one end open, and use is dissoluble
The outer surface of the opening in the outside of the exhausted water bag (6) and the bag is compressed and will be sealed containing double grass by sealed separation device (7)
The sealing container (5) of the component (3-A) of acid esters being crushed is sealed in exhausted water bag (6).
5. chemical photic device according to claim 4, it is characterised in that：Described seals the group containing oxalate ester
The sealing container (5) being crushed of (3-A) is divided to be placed on the region in the bag close to a side, the light transmission closing in the region is outer
The outer exhausted water layer of clad aluminum foil of the macromolecule member material of shell (1) constitutes exhausted water bag (6), at the edge of the exhausted water bag (6) close to placement
The outside or inside of the region side for the sealing container (5) of the component (3-B) containing oxidant being crushed is sealed equipped with can
The sealed separation device (7) of releasing.
6. chemical photic device according to claim 5, it is characterised in that：At least one sideband of the bag has support
Fixing device (8).
7. chemical photic device according to claim 6, it is characterised in that：What the light transmission closure (1) surrounded
When cavity (2) is the bag that transparent or semitransparent macromolecule member material surrounds, cavity (2) is by one or more than one segmentations warm
Crimping (9) is divided into two or more regions, interregional to communicate or be not communicated with；When the image device (4)
For papery with image when, be divided and be placed in corresponding region；When the image device (4) is macromolecule material
When material or non-woven fabrics, segmentation hot pressing line (9) is by it together with the macromolecule member material hot pressing of light transmission closure (1).
8. chemical photic device according to claim 7, it is characterised in that：The shape of the chemical photic device is one side
Flag.
9. chemical photic device according to claim 8, it is characterised in that：What the light transmission closure (1) surrounded
Cavity (2) is the cavity (2) being evacuated.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210021367.2A CN103225746B (en) | 2012-01-31 | 2012-01-31 | A kind of chemical photic device |
| US14/118,164 US9488319B2 (en) | 2011-05-17 | 2012-05-16 | Film chemiluminescent device |
| PCT/CN2012/000676 WO2012155537A1 (en) | 2011-05-17 | 2012-05-16 | A film chemiluminescent device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210021367.2A CN103225746B (en) | 2012-01-31 | 2012-01-31 | A kind of chemical photic device |
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| Publication Number | Publication Date |
|---|---|
| CN103225746A CN103225746A (en) | 2013-07-31 |
| CN103225746B true CN103225746B (en) | 2018-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210021367.2A Active CN103225746B (en) | 2011-05-17 | 2012-01-31 | A kind of chemical photic device |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726226A (en) * | 2013-12-10 | 2014-04-16 | 吴江市品信纺织科技有限公司 | Thickened non-woven fabric |
| CN105355801B (en) * | 2015-11-05 | 2017-06-16 | 武汉大学 | One kind is repeatable to utilize flexible organic electroluminescent device |
| CN105228283B (en) * | 2015-11-05 | 2017-07-25 | 武汉大学 | One kind is repeatable to utilize flexible inorganic electroluminescent device |
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| US5190367A (en) * | 1990-12-17 | 1993-03-02 | High Performance Chemical Co., Ltd. | Luminous display board |
| WO2003023275A1 (en) * | 2001-09-07 | 2003-03-20 | Omniglow Corporation | Chemiluminescent lighting element |
| CN2560815Y (en) * | 2002-03-19 | 2003-07-16 | 张树忠 | Light-emitting stick |
| CN2606838Y (en) * | 2002-12-13 | 2004-03-17 | 金朝阳 | Luminous device |
| CN101173735A (en) * | 2007-11-30 | 2008-05-07 | 金朝阳 | Chemiluminescence medicament storage device with protection casing and its use |
| CN201507790U (en) * | 2007-12-14 | 2010-06-16 | 金朝阳 | Chemical light-emitting device |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202519194U (en) * | 2012-01-31 | 2012-11-07 | 金朝阳 | Chemiluminescence device |
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2012
- 2012-01-31 CN CN201210021367.2A patent/CN103225746B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5190367A (en) * | 1990-12-17 | 1993-03-02 | High Performance Chemical Co., Ltd. | Luminous display board |
| WO2003023275A1 (en) * | 2001-09-07 | 2003-03-20 | Omniglow Corporation | Chemiluminescent lighting element |
| CN2560815Y (en) * | 2002-03-19 | 2003-07-16 | 张树忠 | Light-emitting stick |
| CN2606838Y (en) * | 2002-12-13 | 2004-03-17 | 金朝阳 | Luminous device |
| CN101173735A (en) * | 2007-11-30 | 2008-05-07 | 金朝阳 | Chemiluminescence medicament storage device with protection casing and its use |
| CN201507790U (en) * | 2007-12-14 | 2010-06-16 | 金朝阳 | Chemical light-emitting device |
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| CN103225746A (en) | 2013-07-31 |
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Effective date of registration: 20180329 Address after: 102205 Beijing city Changping District Yangfang Town West Village Ma Applicant after: BEIJING WENHAIYANG INDUSTRY AND TRADE CO., LTD. Address before: 102205 Beijing City, Changping District Beijing paper company Haiyang Yangfang town Applicant before: Jin Chaoyang |
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