CN202519194U

CN202519194U - Chemiluminescence device

Info

Publication number: CN202519194U
Application number: CN2012200306545U
Authority: CN
Inventors: 金朝阳
Original assignee: Individual
Current assignee: BEIJING WENHAIYANG INDUSTRY AND TRADE Co Ltd
Priority date: 2012-01-31
Filing date: 2012-01-31
Publication date: 2012-11-07
Anticipated expiration: 2022-01-31

Abstract

The utility model discloses a chemiluminescence device. According to the technical scheme, the chemiluminescence device comprises one or more chambers (2) formed by a transparent sealed shell (1), wherein the one or more chambers (2) contains/contain a chemiluminescence reagent (3), and an image device (4) is arranged in the one or more chambers (2). The utility model aims to provide a chemiluminescence device capable of perfectly combining chemiluminescence and image display, so that the colored or image device can sufficiently display under the irradiation and contrast of chemiluminescence.

Description

A kind of chemical photic device

Technical field

The utility model relates to a kind of chemical photic device.

Background technology

Usually, civilian chemoluminescence is to be come by the chemical reaction that is produced after the mixing of chemiluminescence medicaments such as substituted-phenyl oxalate ester, fluorescent agent, oxygenant, catalyzer, solvent.We are called the luminous agent component to the component that contains substituted-phenyl oxalate ester (abbreviation oxalate ester), are called oxygenant component or activator to the component that contains the peroxy oxygen agent, and normally used superoxide is a hydrogen peroxide, or carbamide peroxide.Fluorescent agent is to contain in the component of oxalate ester generally speaking; And catalyzer is containing in the peroxy oxygen agent component; But this neither be absolute, in the oxygenant component, contains fluorescent agent, and it also is fully feasible in the oxalate ester component, containing catalyzer.The use of solvent also is like this, and the component of oxygenant component and oxalate ester can be used dissolution with solvents, also can have only one of them component to use solvent.Under varying environment, can even not use solvent to reach the effect of HV or solid luminescence through using different solvents or dispersion agent.Most popular under normal conditions substituted-phenyl oxalate ester is meant two (2,4,5-three chloro-salicylic acid's n-pentyl esters) barkites (CPPO) or two (2,4,5-trichlorine Salicylate Isomyl) barkite (CIPO).

The chemoluminescence product is as the light source of patterned display; Common application is printed patterns in the chemical photic device outside; Or stick the transparent non-setting adhesive that has printed patterns; See through from inside to outside luminous of chemical photic device and come showing pattern. similarly method also has for example Chinese patent: as described in the 201507790U, in the packing bag that hollowed printing is arranged, chemical photic device is housed.The common feature of this type luminous showing device is; Silhouette effect luminous; The contour feature of pattern is clear; But the non-constant of effect of the color rendition effect of pattern and contrast level is because light appears internally, if use can't be differentiated the level and the color of the image of appearance under total darkness environment at all.

Summary of the invention

The purpose of the utility model is that a kind of new chemical light-emitting device will be provided.Can make chemoluminescence and image shows perfect adaptation make chromatic or well-bedded image device fully represent in chemiluminescent irradiation with under setting off.

The technical scheme of taking for the purpose that reaches the utility model comprises: the one or more cavitys 2 that printing opacity sealing shell 1 surrounds, and said cavity 2 inside accommodate chemiluminescence medicament 3, it is characterized in that, and said cavity 2 inside are provided with image device 4.

In the above-mentioned chemical photic device, described image device 4 is that one or more pieces have through printing or printing and dyeing or engrave or folding or watermark or piece or weave or spin or embroider paper or macromolecular material or the non-woven fabrics or the filamentary material of the image that obtains together.Said these materials be individual layer or these materials in a kind of MULTILAYER COMPOSITE of material; Or the MULTILAYER COMPOSITE that differing materials constitutes in these materials; Said filamentary material is inorganic materials or organic materials; Wherein inorganic materials is a spun glass, and organic materials is the filamentary material that cotton fibre or high molecular polymer are processed.

In the above-mentioned chemical photic device; Described image device 4 is that one or more pieces paper that have the image that obtains through printing are or/and macromolecule member material; Described macromolecule member material is Vestolen PP 7052 or Vilaterm or SE or polyethylene terephthalate or their at least two kinds bilayer to multiwalled matrix materials wherein; Said paper and macromolecule member material are meant the matrix material of paper and macromolecule member material; When image device 4 was matrix material, described image printing was on the surface of matrix material or the internal surface of composite intermediate layer.

In the above-mentioned chemical photic device, the cavity 2 that described sealing shell 1 surrounds is that the material of printing opacity is the bag that the macromolecule member material of flexible macromolecule resin material or the printing opacity of printing opacity surrounds.Described macromolecule member material is Vestolen PP 7052 or Vilaterm or nylon or SE or polyethylene terephthalate or PVAC polyvinylalcohol or polyvinylidene chloride or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or gathers naphthalene ester PEN, or two or more bilayer to the multiwalled matrix material in these materials.

In the above-mentioned chemical photic device, described chemiluminescence medicament 3 is meant the component 3-A that contains oxalate ester and the component 3-B that contains oxygenant, at least they wherein a kind of be loaded into can broken sealed vessel 5 in.

In the above-mentioned chemical photic device, the material of described sealed vessel 5 that can be broken is glass or macromolecule membrane or aluminium foil composite high-molecular material; Said macromolecular material is perfluoroethylene third rare FEP or Meltability polytetrafluorethyletubular PFA or Vestolen PP 7052 or Vilaterm or nylon or SE or polyethylene terephthalate or PVAC polyvinylalcohol or polyvinylidene chloride or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or gathers naphthalene ester PEN, or two or more bilayer or the multiwalled matrix material in these materials.

In the above-mentioned chemical photic device; The macromolecule membrane that is printed with image or the image device 4 of paper have been placed in the described bag, the sealed vessel 5 that the independence that the sealed vessel 5 that the independence that has the transparent polymer thin-film material that sealed the component 3-A that contains oxalate ester to surround also placed apart can be broken in bag simultaneously and the transparent polymer thin-film material that has sealed the component 3-B that contains oxygenant surround can fragmentation.

In the above-mentioned chemical photic device; Placed the macromolecule member material that is printed with image or the image device 4 of paper in the said bag internal zone dividing territory, wherein being placed with independence that the high molecular film material that sealed the component 3-A that contains oxalate ester or aluminium foil composite high-molecular material surround near the zone on a limit of bag at least in the rest parts zone can broken sealed vessel 5; Sealed the zone that independence that the transparent polymer thin-film material of the component 3-B that contains oxygenant surrounds can broken sealed vessel 5 overlays image device 4.

In the above-mentioned chemical photic device; Described sealed the component 3-A that contains oxalate ester can be broken sealed vessel 5 during for the transparent polymer thin-film material; It is placed on the interior zone near a limit of said bag; This regional outside surface is sheathed with the exhausted water bag 6 of the aluminium foil composite high-molecular material of an end opening, and the outside surface of opening and said bag that will cut off the outside of water bag 6 with dissoluble sealed separation device 7 compresses having sealed can being sealed in the exhausted water bag 6 by broken sealed vessel 5 of the component 3-A that contains oxalate ester.

In the above-mentioned chemical photic device; The described zone that can broken sealed vessel 5 be placed in the said bag that has sealed the component 3-A that contains oxalate ester near a limit; The exhausted water layer of the outer clad aluminum foil of the macromolecule member material of the sealing shell 1 in this zone constitutes exhausted water bag 6, sealed near placement at the edge of this exhausted water bag 6 the component 3-B that contains oxygenant can be broken the outside or the inside of zone one side of sealed vessel 5 dissoluble sealed separation device 7 is housed.

In the above-mentioned chemical photic device, at least one sideband of described bag has supporting adn fixing device 8.

In the above-mentioned chemical photic device; The cavity 2 that described shell 1 surrounds is whens bag that transparent or semitransparent macromolecule member material surrounds; Cavity 2 is divided into two or more zones by the hot pressing line 9 of cutting apart more than or, interregionally communicates or does not communicate.When described image device 4 is that it is cut apart is placed in the corresponding zone when having the papery of image.When described image device 4 is macromolecular material or non-woven fabrics, cut apart hot pressing line 9 together with the macromolecule member material hot pressing of itself and shell 1.

In the above-mentioned chemical photic device, the profile of above-mentioned chemical photic device is Yi Mianqi.

In the above-mentioned chemical photic device, the cavity 2 that the cavity 2 that described shell 1 surrounds is vacuumized.

The utility model provides a kind of chemical photic device, can make chemoluminescence and image shows perfect adaptation make chromatic or well-bedded image device fully represent in chemiluminescent irradiation with under setting off.

Description of drawings

Fig. 1 is the structural representation of the chemical photic device of a cylindrical shell;

Fig. 2 is the structural representation of the chemical photic device of a film shell;

Sectional view when Fig. 3 is the use of Fig. 2 and light-emitting device shown in Figure 5;

Fig. 4 is a kind of structural representation that has the chemical photic device of cutting apart the hot pressing line;

Fig. 5 is a kind of structural representation of flag-shaped chemical photic device;

Fig. 6 is the structural representation that has the tubulose clamp that cracks;

Fig. 7 is the structural representation of tubulose clamp sealing flag-shaped chemical photic device and exhausted water bag;

Fig. 8 is the structural representation that has the tubulose clamp that cracks of stock;

Fig. 9 is the user mode synoptic diagram of stock tubulose clamp as flagpole;

Figure 10 is the structural representation that has the flag-shaped chemical photic device of supporting adn fixing device;

Figure 11 is a kind of structural representation that uses the flag-shaped chemical photic device of glass ampere bottle;

Figure 12 is a kind of structural representation of the M shape image device of piecing together.

Specific embodiment

As shown in Figure 1, it is the hollow cavity 2 that the cylindrical shell 1 of material sealing surrounds with the high-pressure polypropylene that the chemical photic device of a printing opacity cylindrical shell is one, and chemiluminescence medicament 3 is equipped with in cavity 2 inside.Also be placed with image device 4 in the cavity 2 simultaneously.Image device 4 is poly thin plates of engraving letter " A B C ", and thin plate can be the translucent primary colors of Vilaterm or to dye the still maintenance of look with pigment or dyestuff translucent or opaque.The chemiluminescence medicament 3 here is meant the luminous chemiluminescent fluid of having mixed oxalate ester, fluorescent agent, hydrogen peroxide, SS catalyzer, solvent.Owing to luminal fluid is all arranged in the front and back of image device 4; Even also there is luminal fluid the hollow out position the inside of letter " A B C ", so be different from image printing fully or be attached to the silhouette effect that the light-emitting device outside is brought from the effect of shell 1 viewed image shows.The illumination of luminal fluid is much better than the effect of prior art to the performance of its material texture on image device 4 surfaces.When the thin plate of image device 4 is that no matter it was translucent or opaque when dying look with pigment or dyestuff, when luminal fluid is selected white light for use, also be good to the color rendition degree of image device 4 materials.When the material of shell 1 is high-clarity materials such as glass or polycarbonate, the better perfection of the bandwagon effect of image device 4.

Except macromolecular material can be made image device 4, its material can also be paper or non-woven fabrics or filamentary material braiding, also can be the MULTILAYER COMPOSITE of a kind of material in these materials or the MULTILAYER COMPOSITE that multiple differing materials constitutes.Wherein filamentary material can be: inorganic materials or organic materials, inorganic materials can be spun glass, and organic materials can be the filamentary material that cotton fibre or high molecular polymer are processed.Except being engraved, image device 4 forms it pattern; The method of the density of the subregion that we can also be through changing image device 4 when its material is selected paper or non-woven fabrics or filamentary material etc. for use forms pattern on image device 4; The pattern that for example on paper, utilizes digital watermark to obtain, or the pattern of hot pressing non-woven fabrics or polymer fiber material acquisition.Or the mode or the folding or mode such as piece together that adopt the high pressure punch die make and form the spatial pattern on the pattern means 4, and when using this device, light reflects the effect of shell 1 formation luminescent image from spatial image device 4 like this.When using filamentary material, image device 4 also can be that the fiber through different colours weaves or spins or embroider and obtains.

In the middle of present embodiment; Shell 1 be have certain thickness; We can also carve or print and form image device 4 internal surface of shell 1; Light is radiated on the shell when chemiluminescence medicament is luminous, and the reflective sunk area that also can illuminate printed layers or engraving of very small amount of scattered that sheating material forms also can reach identical effect.

As shown in Figure 2, the chemical photic device of a film shell: the shell 1 of a printing opacity sealing surrounds cavity 2, and different with embodiment described in Fig. 1 is that shell 1 is the bag that macromolecule polypropylene (PP) mould material of printing opacity surrounds.Cavity 2 seal insides the component 3-A that contains oxalate ester and the component 3-B that contains oxygenant of liquid placed apart; The component 3-B that wherein contains oxygenant be loaded into can broken sealed vessel 5 in; The component 3-A that contains oxalate ester directly puts into cavity 2. and the material of sealed vessel 5 that can be broken is capsules that high-molecular polythene (PE) thin-film material surrounds and the sealing weld edge fit forms; Its thickness is easy to receive the external force extruding to break about 0.001mm-0.006mm.Image device 4 also is sealed in the bag that shell 1 surrounds; Here image device 4 is BiOriented Polypropylene Films (being the BOPP film) composite polyethylene (PE) films that a slice launches to be placed on the pattern that is printed with chromatic flower in the cavity 2, and the pattern of chromatic flower is printed on compound again Vilaterm (PE) film of going up on the BOPP film.The thickness of BOPP film and Vilaterm (PE) film is 0.004mm.In use, only need to squeeze broken can broken sealed vessel 5, let the component 3-B of oxygenant flow out the component 3-A that runs into oxalate ester and produce chemoluminescence, simultaneously luminous liquid flow to image device 4 rapidly both sides with its submergence.It is the chemoluminescence that the green mixing fluorescent agent of blue reddish yellow produces white that the component 3-A of the oxalate ester among this embodiment contains fluorescent agent.As shown in Figure 3; Sectional view when Fig. 3 is the use of the foregoing description; The image device 4 that as can beappreciated from fig. 3 with the laminated film is carrier is immersed in the luminous medicament 3 entirely; This moment, the pattern of the chromatic flower on the image device 4 will be illuminated by the white light that chemiluminescent fluid is sent, and the surface emitting of the bag that surrounds through shell 1 is come out, and tow sides can be seen the image of luminous chromatic flower simultaneously.

Described image device 4 can also be the high molecular film material beyond the mentioned material in the foregoing description, and they can also be Vestolen PP 7052 or Vilaterm or SE or polyester (polyethylene terephtalate) or their at least two kinds bilayer to multiwalled matrix materials wherein.Matrix material or the non-woven fabrics or the cloth glasscloth that are printed with paper or the paper and the macromolecule member material of image also are feasible as image device 4.With braiding or be embroidered with glasscloth or the nylon fiber net of image or image device 4 that polyester material is processed also is that the luminescent image effect is very outstanding.

The material of shell 1 can also be Vilaterm (PE) or nylon (PA) or SE (PVC) or polyethylene terephthalate (polyester PET) or Z 150PH (PVA) or polyvinylidene chloride (PVDC) or high-barrier MA-PVDC or the ethylene/vinyl alcohol copolymer (EVOH) in the macromolecular material of printing opacity except macromolecule polypropylene (PP) or gather naphthalene ester (PEN) or their two or more bilayer or multiwalled matrix materials wherein in the present embodiment.

In the middle of present embodiment; The material of sealed vessel 5 that can be broken can also be Vilaterm (PE) other high molecular film material in addition, and they can be perfluoroethylene third rare (FEP) or Meltability polytetrafluorethyletubular (PFA) or Vestolen PP 7052 (PP) or nylon (PA) or SE (PVC) or polyester (PET) or Z 150PH (PVA) or polyvinylidene chloride (PVDC) or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer (EVOH) or gather naphthalene ester (PEN) or their two or more bilayer to multiwalled matrix materials wherein.The aluminium foil composite high-molecular material also is the good selection of making sealed vessel 5 that can be broken, and just it is easily at the regional shading of image device 4.Total thickness during the use of above-mentioned materials is between 0.0001mm-0.1mm.

In the middle of present embodiment, also can the component 3-A that contain oxalate ester also be sealed in the sealed vessel 5 that another can be broken.Help the prolongation of product shelf life so more, can place simultaneously a plurality of different colours chemiluminescence medicaments 3 can be broken sealed vessel 5 can enrich the color performance on the one hand and can also gradation use and prolong fluorescent lifetime.

As shown in Figure 4, a kind of chemical photic device of cutting apart the hot pressing line that has: the shell 1 of a printing opacity sealing surrounds cavity 2, and shell 1 is the bag that high-molecular polythene (PE) mould material of printing opacity surrounds.Horizontally in the mid-way of shell 1 pressed one to cut apart the cavity 2 that hot pressing line 9 surrounds shell 1 and be divided into two portions up and down; Cut apart the right side of hot pressing line 9 and a vertical edge fusion of shell 1; The left side is fusion not, leaves passage, makes up and down two quilts cut apart the chamber 2 that hot pressing line 9 cuts apart and communicates.Image device 4 is two and is placed in the shell 1 up and down two quilts and cuts apart in the chamber 2 that hot pressing line 9 cuts apart and be printed with rabbit 60g/ square metre white 100% wood pulp paper of two portions pattern up and down respectively, the pattern of rabbit by up and down two be combined into jointly.The up and down two-part right side of cavity 2 be placed with two sealed the component 3-B that contains oxygenant can broken sealed vessel 5; The left side of cavity 2 be placed with two sealed the component 3-A that contains oxalate ester can broken sealed vessel 5; The material of sealed vessel 5 that can be broken is capsules that macromolecule polypropylene (PP) thin-film material surrounds and the sealing weld edge fit forms, and its thickness is at 0.002mm.In use, only need to squeeze broken all can broken sealed vessel 5, let the component 3-B of oxygenant flow out the component 3-A that runs into effusive oxalate ester and promptly produce chemoluminescence, and shine upon the pattern of rabbit.What be different from the said embodiment of Fig. 2 is that the effect of cutting apart hot pressing line 9 that present embodiment has is when whole light-emitting device is vertically picked up in hand-held light-emitting device left side; The right side can slightly drop; Cut apart 9 interceptions of hot pressing line when causing the luminal fluid tenesmus; Influence the illumination effect of global pattern to such an extent as to can most not flow to the last cell of light-emitting device; The left side of cutting apart hot pressing line 9 not fusion does not make up and down two chambeies not leave passage so that the thorough mixing luminal fluid also can not leave passage if desired, makes device become up and down two fully independently cavitys.Have the light-emitting device of cutting apart hot pressing line 9 and be suitable for the light-emitting device that big area more and needs are erect situation about using.If use and to cut apart more that hot pressing line 9 is divided into effect that more horizontal chamber prevents that liquid is dirty with light-emitting device then more obvious, but the papery image device will be divided into more sheet, thereby can influence whole structure.

When if image device 4 uses the paper of the figuratum high molecular film material of printing or polymer non-woven fabrics or two-sided composite high-molecular mould material in the foregoing description; Whole pattern needn't be divided into multi-disc and put like a plurality of cavitys 2 again; But can the material of above-mentioned image device 4 directly be put into the bag that macromolecular material surrounds; Then from the two sides in the outside of bag directly laterally hot pressing form and cut apart hot pressing line 9, can play the effect that a plurality of cavitys 2 prevent the chemiluminescent fluid tenesmus that is partitioned into equally.

As shown in Figure 5, a kind of flag form chemical photic device: the shell 1 of printing opacity sealing surrounds cavity 2, and shell 1 is that the total thickness of printing opacity is that the internal layer of 0.02mm is the rectangle bag that high-molecular polythene (PE) complex polyester (PET) mould material (skin) surrounds.Be placed with the image device 4 that the two-sided symmetry of papery is printed on the flag pattern of star in the area of 80-90% left from the right side of bag.Sealed the lower right corner that can broken sealed vessel 5 overlays image device 4 of the component 3-B that contains oxygenant; As the place near the left side of figure vacant position of remaining 10-20% area in rectangle bag left side be placed with one sealed the component 3-A that contains oxalate ester can broken sealed vessel 5; The material of sealed vessel 5 that can be broken is capsules that high-molecular polythene (PE) thin-film material surrounds and the sealing weld edge fit forms, and its thickness is at 0.002mm.Put into by the position of foregoing description the two-sided symmetry of papery be printed on star the flag pattern image device 4 with sealed the component 3-B that contains oxygenant and sealed two capsules of the component 3-A that contains oxalate ester after; When carrying out last pressurizing window; Can use the vacuum suction sealing machine to seal, to get rid of the air in the cavity 2 as far as possible.Seal after accomplishing left side at the rectangle bag; Just be placed with the exhausted water bag 6 of aluminium foil composite high-molecular material of a three side sealing mouth of outside cover of a side of a capsule that has sealed the component 3-A that contains oxalate ester; The zone of placing the capsule that has sealed the component 3-A that contains oxalate ester is long slightly again to get final product the length of exhausted water bag 6 wrapping; Use dissoluble sealed separation device 7 as shown in Figure 6 then---have 10 the tubulose clamp of cracking, that kind as shown in Figure 7 10 seals inserting cracking of clamp behind rectangle bag and exhausted water bag 6 reflexeds.The dissoluble sealed separation device 7 that also can use stock as shown in Figure 8 substitutes the clamp that shown in Figure 6 having cracked; In fact dissoluble sealed separation device 7 shown in Figure 8 is the tubulose clamps that crack having of a lengthening, and has one section lead-in groove 11 at the front end that cracks.Chemical photic device removes tubulose clamp and exhausted water bag 6 when using; Squeezing decodes has again sealed component 3-A that contains oxalate ester and the capsule that has sealed the component 3-B that contains oxygenant; And it is luminous to make chemiluminescence medicament mix the back, the luminous flag that obtains one side after evenly can double-side.Shown in then can image pattern 9 with that kind, do not have the part of image device 4 to roll in the left side of bag and insert in 10 the clamp of cracking having of stocks through lead-in groove 11, the part of bar lengthening be taken as hand-held or fixedly the flagpole of usefulness be used.Chemical photic device shown in all right image pattern 10; The left side of the rectangle bag that surrounds at shell 1 is provided with supporting adn fixing device 8; Here supporting adn fixing device 8 is a sealing thin rods in the leftmost side of rectangle bag; Like this can be easily the left side of bag not being had the part of image device 4 serves as that axle is rolled with thin rod, and then inserts in 10 the clamp of cracking having of stock.In addition on other frame or surface of rectangle bag that shell 1 surrounds fixing on iron wire or supporting objects such as sticking plaster or bamboo pole, to add the non-deformability of strong film shell.Iron wire or other shape-memory materials can also make the flag-shaped light-emitting device keep the shape of certain specific needs.

The exhausted water bag 6 of aluminium foil composite high-molecular material and the effect of dissoluble sealed separation device 7 are actual to be the effect of isolating steam, contains the quality guaranteed period of the component 3-A of oxalate ester with prolongation.If so the sealed vessel 5 that the independence that above-mentioned chemical photic device uses the aluminium foil composite high-molecular material to surround can be broken or sealed the component 3-A that contains oxalate ester can be broken the exhausted water layer of the outer directly clad aluminum foil of macromolecule member material of sealing shell 1 of put area of sealed vessel 5 constitute and cut off water bag 6; Sealed near placement at the edge of exhausted water bag 6 the component 3-B that contains oxygenant can be broken the outside or the inside of a side in zone of sealed vessel 5 dissoluble sealed separation device 7 is housed, the inner here dissoluble sealed separation device 7 that is equipped with can be the engaged strip of paper used for sealing of groove shape that is welded on shell 1 internal surface in this position.Also can reach the effect of the quality guaranteed period that prolongs the component 3-A contain oxalate ester by above-mentioned this dual mode, reach the application target of this device simultaneously.If the vacant position of certain area is not left in the left side of the rectangle bag that surrounds at shell 1; And directly place sealed the component 3-A that contains oxalate ester can be broken sealed vessel 5 in the zone of image device 4; The luminescent image effect was very good equally when the material of sealed vessel 5 that can be broken was the transparent polymer thin-film material; If but use that the aluminium foil composite high-molecular material surrounds can be broken covering of causing owing to aluminium foil is light tight when luminous with regard to existing of sealed vessel 5, thereby cause the chemoluminescence image device shade to occur.

Its sectional view is identical with Fig. 3 when the said flag-shaped chemical photic device of Fig. 5 vertically uses; As can beappreciated from fig. 3 the two-sided symmetry of papery is printed on being immersed in entirely in the luminous medicament 3 of image device 4 of the flag pattern of star; The illumination that the pattern of star and whole flag face are sent by the chemoluminescence agent is bright; The surface emitting of the bag that surrounds through shell 1 is come out, and simultaneously tow sides can be seen the image of luminous flag.Because flag nearly all is straightened use, be very necessary so will prevent to slide under the luminal fluid bottom of bag.There are several kinds of factors to guarantee that luminal fluid can reduce downslide as far as possible here, the one, the adsorption layer that forms between luminal fluid and the papery image device 4 has adsorbed a part of liquid; The 2nd, shell 1 intensity own adds has held a part of luminal fluid; The 3rd, because the bag that surrounds at shell 1 has used the vacuum seal technology when sealing, got rid of inner most of air, utilize normal atmosphere to compress the bag that shell 1 surrounds on the one hand, make luminal fluid can be full of a bag internal space on the other hand as far as possible.

Shown in figure 11; Another kind of flag-shaped chemical photic device: the shell 1 of a printing opacity sealing surrounds cavity 2, and shell 1 is that the total thickness of printing opacity is that the internal layer of 0.016mm is the rectangle bag that polymer ethylene/vinyl alcohol copolymer EVOH composite nylon (PA) mould material (skin) surrounds.Be placed with the image device 4 that the two-sided symmetry of papery is printed on the flag pattern of star from the right side of bag.Sealed that to contain component 3-B that liquid has an oxygenant can broken sealed vessel 5 be two sealed glass ampere bottles respectively with what sealed the component 3-A that contains oxalate ester; They are contained in the protection tube 12 in an arm cornice hole, and this plastics tubing is interrupted cuts apart the leftmost side that hot pressing line 9 is fixed on the rectangle bag that shell 1 surrounds.Break two glass ampere bottles into pieces with one's fingers across protection tube 12 during use and discharge chemiluminescence medicament 3-A and 3-B, behind the mixed luminescence with soup got rid of be interrupted cut apart hot pressing line 9 to image device 4 zones, obtain the luminous flag of double-side.Also can only place 1 glass ampere bottle that has sealed the component 3-A that contains oxalate ester in the protective tube 12, the component 3-B that the contains oxygenant vacant position in cavity 2 and the protective tube 12 of then directly packing into.

Protection tube 12 mainly is to be used to protect the glass disintegrating slag of the glass ampere bottle that breaks into pieces with one's fingers can not pierce through the bag that thin-film material surrounds, and can be used as the fixedly stationary installation of flagpole simultaneously.Also can directly prolong protection tube 12, the zone that promptly can increase placement glass ampere bottle also can be used himself being used as flagpole to increase the dose of luminous soup.

Shown in figure 12 is the image device 4 of the rice word flag pattern pieced together of one three look, is respectively red, white, blue 3 layers of transparent painted polyester PET thin film of multi-disc from top to bottom and pieces formation together.They can be placed on being surrounded in the cavity 2 by light transmission film shell 1 of an above-mentioned sealing like Fig. 5 or the described printing opacity of Figure 11.Also can divide three layers to be distributed in three cavitys 2 that surrounded by light transmission film shell 1, final three light transmission film shells, 1 folded dropping on constitutes luminescent image together jointly.In the time of in three layers of image devices 4 minutes are distributed in the cavity 2 that three shells 1 surround; The color of the chemiluminescence medicament in each chamber can be respectively red, white, Lan Sanse; The image device of each layer can be the paper material of white 4 this moments, the same effect that also can obtain gorgeous rice word flag.

It should be noted last that; Above embodiment is only unrestricted in order to the technical scheme of explanation the utility model; Although with reference to preferred embodiment the utility model is specified, those of ordinary skill in the art should be appreciated that and can make amendment or be equal to replacement the technical scheme of the utility model; And not breaking away from the spirit and the scope of the technical scheme of the utility model, it all should be encompassed in the middle of the claim scope of the utility model.

Claims

1. a chemical photic device comprises one or more cavitys (2) that a printing opacity sealing shell (1) surrounds, and said cavity (2) inside accommodates chemiluminescence medicament (3), it is characterized in that, said cavity (2) inside is provided with image device (4).

2. chemical photic device according to claim 1; It is characterized in that described image device (4) is that one or more pieces have through printing and dyeing or engrave or folding or watermark or piece or weave or spin or embroider paper or macromolecular material or the non-woven fabrics or the filamentary material of the image that obtains together; Said these materials be individual layer or these materials in a kind of MULTILAYER COMPOSITE of material; Or the MULTILAYER COMPOSITE that differing materials constitutes in these materials; Said filamentary material is inorganic materials or organic materials; Wherein inorganic materials is a spun glass, and organic materials is the filamentary material that cotton fibre or high molecular polymer are processed.

3. chemical photic device according to claim 2; It is characterized in that; Described image device (4) is that one or more pieces paper that have the image that obtains through printing are or/and macromolecule member material; Described macromolecule member material is Vestolen PP 7052 or Vilaterm or SE or polyethylene terephthalate or their at least two kinds bilayer to multiwalled matrix materials wherein; Said paper and macromolecule member material are meant the matrix material of paper and macromolecule member material, and when image device (4) was matrix material, described image printing was on the surface of matrix material or the internal surface of composite intermediate layer.

4. according to claim 1 or 2 or 3 described chemical photic devices, it is characterized in that the cavity (2) that described sealing shell (1) surrounds is that the material of printing opacity is the bag that the macromolecule member material of flexible macromolecule resin material or the printing opacity of printing opacity surrounds; Described macromolecule member material is Vestolen PP 7052 or Vilaterm or nylon or SE or polyethylene terephthalate or PVAC polyvinylalcohol or polyvinylidene chloride or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or gathers naphthalene ester PEN, or two or more bilayer to the multiwalled matrix material in these materials.

5. according to claim 1 or 2 or 3 or 4 described chemical photic devices, it is characterized in that described chemiluminescence medicament (3) is meant luminous agent (3-A) and oxygenant (3-B), at least they wherein a kind of be loaded into can be broken sealed vessel (5) in.

6. chemical photic device according to claim 5 is characterized in that, the material of described sealed vessel (5) that can be broken is glass or macromolecule membrane or aluminium foil composite high-molecular material; Said macromolecular material is perfluoroethylene third rare FEP or Meltability polytetrafluorethyletubular PFA or Vestolen PP 7052 or Vilaterm or nylon or SE or polyethylene terephthalate or PVAC polyvinylalcohol or polyvinylidene chloride or high-barrier MA-PVDC or ethylene/vinyl alcohol copolymer EVOH or gathers naphthalene ester PEN, or two or more bilayer or the multiwalled matrix material in these materials.

7. chemical photic device according to claim 4; It is characterized in that; The macromolecule membrane that is printed with image or the image device (4) of paper have been placed in the described bag, the sealed vessel (5) that the independence that has the transparent polymer thin-film material that sealed luminous agent (3-A) to surround also placed apart can be broken in bag simultaneously and sealed the sealed vessel (5) that independence that the transparent polymer thin-film material of oxygenant (3-B) surrounds can fragmentation; Or in said bag internal zone dividing territory, placed the macromolecule member material that is printed with image or the image device (4) of paper, wherein being placed with the high molecular film material that has sealed luminous agent (3-A) or the independence that the aluminium foil composite high-molecular material surrounds near the zone on a limit of bag at least in the rest parts zone can broken sealed vessel (5); Sealed the zone that independence that the transparent polymer thin-film material of oxygenant (3-B) surrounds can broken sealed vessel (5) overlays image device (4).

8. chemical photic device according to claim 7; It is characterized in that; Described sealed luminous agent (3-A) can be broken sealed vessel (5) during for the transparent polymer thin-film material; It is placed on the interior zone near a limit of said bag; This regional outside surface is sheathed with the exhausted water bag (6) of the aluminium foil composite high-molecular material of an end opening, and opening and the outside surface of said bag that will cut off the outside of water bag (6) with dissoluble sealed separation device (7) compress having sealed can being sealed in the exhausted water bag (6) by broken sealed vessel (5) of luminous agent (3-A).

9. chemical photic device according to claim 7; It is characterized in that; The described zone that can broken sealed vessel (5) be placed in the said bag that has sealed luminous agent (3-A) near a limit; The exhausted water layer of the outer clad aluminum foil of the macromolecule member material of the sealing shell (1) in this zone constitutes exhausted water bag (6), at the edge of this exhausted water bag (6) near placement sealed oxygenant (3-B) can be broken the outside or the inside of zone one side of sealed vessel (5) dissoluble sealed separation device (7) is housed.

10. according to claim 4 or 7 or 8 or 9 described chemical photic devices, it is characterized in that at least one sideband of described bag has supporting adn fixing device (8).

11. according to claim 4 or 7 or 8 or 9 described chemical photic devices; The cavity (2) that described shell (1) surrounds is when bag that transparent or semitransparent macromolecule member material surrounds; Cavity (2) is divided into two or more zones by the hot pressing line (9) of cutting apart more than or, interregionally communicates or does not communicate; When described image device (4) when having the papery of image, it is cut apart is placed in the corresponding zone; When described image device (4) is macromolecular material or non-woven fabrics, cut apart hot pressing line (9) together with the macromolecule member material hot pressing of itself and shell (1).

12. chemical photic device according to claim 10; The cavity (2) that described shell (1) surrounds is when bag that transparent or semitransparent macromolecule member material surrounds; Cavity (2) is divided into two or more zones by the hot pressing line (9) of cutting apart more than or, interregionally communicates or does not communicate; When described image device (4) when having the papery of image, it is cut apart is placed in the corresponding zone; When described image device (4) is macromolecular material or non-woven fabrics, cut apart hot pressing line (9) together with the macromolecule member material hot pressing of itself and shell (1).

13., it is characterized in that the profile of above-mentioned chemical photic device is Yi Mianqi according to claim 4 or 7 or 8 or 9 described chemical photic devices.

14. chemical photic device according to claim 10 is characterized in that, the profile of above-mentioned chemical photic device is Yi Mianqi.

15. chemical photic device according to claim 11 is characterized in that, the profile of above-mentioned chemical photic device is Yi Mianqi.

16. chemical photic device according to claim 12 is characterized in that, the profile of above-mentioned chemical photic device is Yi Mianqi.

17., it is characterized in that the cavity (2) that the cavity (2) that described shell (1) surrounds is vacuumized according to claim 1 or 2 or 3 or 4 or 7 or 8 or 9 described chemical photic devices.

18. chemical photic device according to claim 10 is characterized in that, the cavity (2) that the cavity (2) that described shell (1) surrounds is vacuumized.

19. chemical photic device according to claim 11 is characterized in that, the cavity (2) that the cavity (2) that described shell (1) surrounds is vacuumized.

20. chemical photic device according to claim 12 is characterized in that, the cavity (2) that the cavity (2) that described shell (1) surrounds is vacuumized.

21. chemical photic device according to claim 13 is characterized in that, the cavity (2) that the cavity (2) that described shell (1) surrounds is vacuumized.