CN103184695A - Resin-formed flexible puncture-proof fabric and preparation method thereof - Google Patents

Resin-formed flexible puncture-proof fabric and preparation method thereof Download PDF

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CN103184695A
CN103184695A CN2013101344149A CN201310134414A CN103184695A CN 103184695 A CN103184695 A CN 103184695A CN 2013101344149 A CN2013101344149 A CN 2013101344149A CN 201310134414 A CN201310134414 A CN 201310134414A CN 103184695 A CN103184695 A CN 103184695A
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resin
fabric
mesh
web plate
flexible anti
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CN103184695B (en
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王新厚
马飞飞
谢正权
杨静茹
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SHANGHAI SHENGJIA SAFETY PROTECTION TECHNOLOGY Co Ltd
Donghua University
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SHANGHAI SHENGJIA SAFETY PROTECTION TECHNOLOGY Co Ltd
Donghua University
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Abstract

The invention relates to a resin-formed flexible puncture-proof fabric and a preparation method of the resin-formed flexible puncture-proof fabric. The fabric consists of garment fabric and thermosetting resin condensates, wherein a gap exists between the thermosetting resin condensates. The preparation method comprises the following steps of: uniformly dispersing the thermosetting resin in each mesh of a screen plate so that each mesh is filled with resin; scraping residual resin on the surface of the screen plate; spreading the garment fabric on the screen plate filled with resin; applying pressure to the garment fabric, and drying; solidifying the thermosetting resin condensate on the surface of the garment fabric; and finally removing the thermosetting resin condensate from the screen plate to obtain the resin-formed flexible puncture-proof fabric. According to the invention, the thermosetting resin is a good binder before solidification, has a good binding effect with the garment fabric and relatively high strength and hardness after solidification, and can resist the puncture of a conventional tool needle tube; and the shortcomings and defects of the prior art are overcome, and the needs of the military field and civil field are met.

Description

A kind of resin forming flexible anti stabbing lining and preparation method thereof
Technical field
The invention belongs to protective fabric and preparation field thereof, particularly a kind of resin forming flexible anti stabbing lining and preparation method thereof.
Background technology
Even at peace the age, violent conflict also constantly takes place in countries in the world.In order to ensure numerous public security cadres and police when executing the task, the injury that the main organs position is not subjected to or is subjected to less common sharp devices such as dagger to cause, numerous public security cadres and police and Security Personnel are necessary to be equipped with protective gear, and stab-resistance body armor is exactly a kind of important protective articles wherein.And along with people to the raising that the clothes barrier propterty requires, press for that hidden performance is good, comfortable ventilating, light, cheap novel anti-stabbing lining flexibly.In addition, anti-stabbing lining can also be used to making stabproof vest, Anti-cut Gloves, armlet, endurable thorn suitcase etc.
Mainly contain hard, semi-rigid and flexible three kinds of stab-resistance body armors in the market.The hard stab-resistance body armor be a kind of hard thorn protecting plate with definite shape and curved surface as the anti-stab armor of anti-stab plate, its antipricking layer all is made up of metals such as special steel, aluminium alloys.Chinese patent (CN2625838) discloses a kind of stab-resistance body armor, and antipricking layer is spliced to form by the sheet metal phase lap embedding in twos that the several piece edge has butt hook, does not stay the slit between each piece sheet metal.Because there is butt hook at each piece sheet metal edge, do not stay the slit so take embedding mutually, overcome blade effectively and slipped into the slit and locate the injury that brings to the protection people, have good anti-stab effect.But there is preponderance in this stab-resistance body armor, and very flexible is worn shortcomings such as uncomfortable, difficult folding preservation.The semi-rigid stab-resistance body armor by which floor antipricking layer is composited, and there are one deck or which floor special sheet metal or metal sandwich in the centre, and certain pliability is arranged.A kind of stab-resistance body armor of herringbone structure of metal wire knitted is disclosed in the Chinese patent (CN2163361).This kind stab-resistance body armor has certain elasticity, but lays particular stress on through showing slightly on one's body, is difficult for all kinds of actions of performance, and flexibility is bad.
Flexible stab-resistance body armor is to be shaped by woven, knitting, non-weaving method such as knit by other flexible fibers such as high-performance fibers basically, layer with layer between be connected by heat bonding or suture way.In world patent (WO97-21334), a kind of anti-stab protective clothing that scribbles thermoplastic resin at fragrant acid amides fabric face is disclosed.This stab-resistance body armor has certain flexibility, better performances, but thickness is thicker, and gas permeability is poor.United States Patent (USP) (US6280546) discloses and has a kind ofly adopted thermoplastic film and contain the stab-resistance body armor that 25% above aramid fiber, the woven fabric of UHMWPE high-performance fiber are bonded under tension force necessarily, the stab-resistance body armor of this method manufacturing has good anti-shearing, puncture resistance, just gas permeability is very poor, and the wearer has tangible sense of discomfort.Chinese patent (CN101543318) discloses a kind of antipricking layer that is become with the anti-stab felt of aramid fiber by soft band coating kevlar fabric.This stab-resistance body armor has certain flexibility, but thickness is thicker, wears uncomfortable, and airtight substantially.Chinese patent (CN1727178) discloses a kind of coating machine fabric that is become by ultrahigh molecular weight polyethylene, nonwoven fabric, no latitude cloth crossing stack and the anti-stabbing lining that forms.This anti-stabbing lining has anti-stab performance preferably, but manufacturing technique is various, and processing cost is higher.Chinese patent (CN201088147) discloses a kind of for the protection body that is bonded with sheet metal of making stab-resistance body armor, is made up of ready-made clothes sheet material, binding agent and sheet metal.That this stab-resistance body armor has is easy to break, lightweight, high-strength performance, but processed complex, a stab-resistance body armor needs the 3000-4000 sheet metal, and dress is also uncomfortable, is unfavorable for the action performance.
Summary of the invention
Technical problem to be solved by this invention provides a kind of resin forming flexible anti stabbing lining and preparation method thereof, the resin forming flexible anti stabbing lining of this invention preparation can be made and be convenient to various technique and tactics action performances, and stab-resistance body armor comfortable and easy to wear, disguised strong also can be made the products for civilian use such as armlet, Anti-thorn gloves, the suitcase of anti-the cutting.The needs of military domain and civil area are satisfied in this invention and then remedy the deficiencies in the prior art and defective.
A kind of resin forming flexible anti stabbing lining of the present invention, described fabric is made up of ready-made clothes fabric and thermosetting resin cured matter; The resin cured matter that has the certain rule pattern by the web plate moulding process at ready-made clothes fabric surface cure; Wherein to be of a size of the distance of any point-to-point transmission be 1-30mm to the horizontal plane of resin cured matter, and thickness is 0.1-5mm; Gap between resin cured matter and the resin cured matter is 0.1-5mm.
Described ready-made clothes fabric is one or more fibers in chemical fibre, high-performance fiber, cotton, hair, silk, the fiber crops, the fabric that yarn is made.
Described fabric is wovenly, knitting, non-to knit or weave.
Described thermosetting resin is one or more in epoxy resin, thermosetting acrylic resin, amino resins, phenolic resins, Lauxite, unsaturated polyester (UP), the silicon ether resin.
Described thermosetting resin adds one or more in diluent, flexibilizer, defoamer, fire retardant, look grain, the curing agent, strengthening the cohesive force on thermosetting resin and ready-made clothes fabric surface, and the performance indications such as viscosity, hardness, color that change thermosetting resin.
The quality proportioning of resin and curing agent is 1:0.9-3:1.
The preparation method of a kind of resin forming flexible anti stabbing lining of the present invention comprises:
Web plate moulding process: thermosetting resin is evenly dispersed in each mesh of web plate and (adopts the mode of blade coating), make each mesh fill up resin, scrape off the unnecessary resin in web plate surface, then the ready-made clothes fabric is tiled on the web plate of filling full resin, the ready-made clothes fabric is exerted pressure, and drying, thermosetting resin cured matter are cemented in ready-made clothes fabric surface, at last thermosetting resin cured matter is taken off from web plate, namely obtained the flexible anti stabbing lining.
Described web plate length and width is arbitrary dimension, and web plate thickness is 0.1-5mm; The distance that the horizontal plane of each mesh is of a size of any point-to-point transmission is 1-30mm, and mesh runs through on web plate fully; Gap between adjacent two mesh is 0.1-5mm; Mesh is shaped as in circle, triangle, quadrangle, pentagon, the polygon one or more on the web plate; The mesh shape is arranged according to the many Size Formula of matrix form, dislocation type, Suresh Kumar, many Size Formula or Suresh Kumar; The web plate material is metal material or nonmetallic materials; Mesh inner surface and outer surface plated film or spraying releasing agent.
Described metal material is aluminium alloy or stainless steel, and nonmetallic materials are ceramic material.
Described film is poly tetrafluoroethylene, also can be to be convenient to other material that thermosetting resin cured matter breaks away from from web plate.
Described drying temperature is 10-120 ℃, and criteria thus the drying time is 15min-24h.
All inner surfaces of described mesh and outer surface spraying releasing agent are convenient to thermosetting resin cured matter and are broken away from from web plate.
In the present invention, the shape of resin cured matter is determined by web plate mesh shape.Thermosetting resin breaks away from from web plate after overcuring reaches working strength.
Referring to shown in Figure 1, the present invention is a kind of for the resin forming flexible anti stabbing lining of making stab-resistance body armor, is made up of ready-made clothes fabric 3 and thermosetting resin cured matter 1.Process route by the web plate curing molding, obtain the flexible anti stabbing lining, this thermosetting resin can have good wettability with ready-made clothes fabric 3 surfaces before curing, play the effect of binding agent, again can be after curing, thermosetting resin cured matter 1 relies on excellent mechanical property to play the effect of opposing cutter puncture.Simultaneously, there is gap 2 between the thermosetting resin cured matter 1, makes this flexible anti stabbing lining have the characteristics of gas permeability and flexibility.
Referring to shown in Figure 2, the web plate mesh pattern is constituted by equilateral triangle 5 and inversion equilateral triangle 6.
Referring to shown in Figure 3, the web plate mesh pattern is made of square 7, and this pattern can be revised a little and become other similar fitgures, and for example square 7 can change other suitable quadrangles such as rectangle, rhombus into.
Referring to shown in Figure 4, the web plate mesh pattern is constituted with parallelogram 10 by pentagon 8 and inversion pentagon 9 onesize, diverse location, and wherein per four pentagons are closely around a parallelogram.
Referring to shown in Figure 5, the web plate mesh pattern by left pentagon 11, the right pentagon 12 of onesize, diverse location, go up pentagon 13, pentagon 14 constitutes with another square 15 down, around one of them square closely around 8 equal regular pentagons.
Referring to shown in Figure 6, the web plate mesh pattern has shown a typical cellular figure by the figure that a plurality of hexagons 16 are staggered and constitute among the figure.
In the present invention, 2-8 layer single-layer resin moulding flexible anti stabbing lining according to the certain angle cross laminates, is hidden the slit between adjacent two resin cured matters as far as possible, sew up by conventional stitching process between layer and the layer.The pattern on layer and layer flexible anti stabbing lining surface can be identical, also can be different, and be to make the resin forming flexible compound anti-stabbing lining after this stitching as far as possible both keep air permeability and good and flexibility after all, also have good anti-stab performance.
The difform thermosetting resin cured matter of above-mentioned introduction generally all is to adopt the technology mode of web plate moulding to be cemented in ready-made clothes fabric surface, forms resin forming flexible anti stabbing lining.Make several layers of individual layer anti-stabbing lining according to the certain angle cross laminates at last, adopt conventional stitching process to make then, be processed into protection body (anti-stab inner bag), and then manufacture protective articless such as stabproof vest, armlet, trousers, gloves, perhaps the product for civilian use such as suitcase of anti-the cutting.
Beneficial effect
(1) product of the present invention's preparation is compared with the stab-resistance body armor of present existence, this flexibility stab-resistance body armor mainly can adopt common chemical fibre class such as chemical fibre class ready-made clothes fabrics such as terylene, polyamide fibre as base cloth, unit price has been saved manufacturing cost greatly than low about 10 times of aramid fiber, the contour performance fibers of UHMWPE.Certainly, the fabric that resin forming flexible anti stabbing lining of the present invention also can adopt the contour performance fibers of aramid fiber to be made into can make the stab-resistance body armor number of plies significantly reduce like this, and thickness further lowers, and the class of safety protection that can reach is higher;
(2) the present invention adopts the web plate moulding process, and technological process is short, and speed of production is fast, formation highly effective;
(3) thermosetting resin is good binding agent before not having curing among the present invention, can good cementation be arranged with the ready-made clothes fabric, and higher intensity and hardness are arranged after the curing, can resist the puncture of conventional cutter needle tubing;
(4) slit between resin cured matter and resin cured matter is very little among the present invention, can eliminate the slit after superimposed with the anti-stabbing lining of multilayer cured resin is staggered, makes stab-resistance body armor have good anti-stab performance; Simultaneously, the slit between the resin cured matter can make stab-resistance body armor possess certain gas permeability and flexibility;
(5) kind of resin cured matter, size, color, profile and compound mode can design according to concrete purposes and degree of protection among the present invention, make the stab-resistance body armor of using anti-stabbing lining making of the present invention can satisfy the requirement of shelter under the various conditions;
(6) the resin forming flexible anti stabbing lining of the present invention's preparation both can have been made the military use products such as stab-resistance body armor of high standard, also can make the common grade stab-resistance body armor, for field personnel such as security personnel, municipal administration, glass processing industry workman dress, can also make the products for civilian use such as Anti-thorn gloves, the suitcase of anti-the cutting;
(7) use under identical protection level, the stab-resistance body armor that anti-stabbing lining of the present invention is made has that weight significantly alleviates, thickness obviously reduces, and is comfortable and easy to wear, light flexibly, characteristics such as disguised height;
(8) the present invention remedies the deficiencies in the prior art and defective, satisfies the needs of military domain and civil area.
Description of drawings
Fig. 1 is the cross-sectional view of flexible anti stabbing lining of the present invention;
Fig. 2 is the combination pattern schematic diagram of positive and negative equilateral triangle web plate mesh;
Fig. 3 is the pattern schematic diagram of square web plate mesh;
Fig. 4 is the combination pattern schematic diagram of positive and negative pentagon and parallelogram web plate mesh;
Fig. 5 is the combination pattern schematic diagram of onesize, diverse location pentagon and square web plate mesh;
Fig. 6 is the combination pattern schematic diagram of the cellular web plate mesh that is combined into of regular hexagon;
Among the figure: 1. the 3. ready-made clothes fabrics of the gap between resin cured matter 2. resin cured matters and the resin cured matter, 4. web plates, 5. equilateral triangles 6. are inverted equilateral triangle 7. square 8. pentagons 9. and are inverted 14. times pentagons of pentagon, 15. another square 16. regular hexagons on the pentagon 10. parallelogram 11. left pentagon 12. right pentagons 13..
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used for explanation the present invention and be not used in and limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
This flexible anti stabbing lining adopts polyamide fibre plain weave fabric as base cloth, and surface density is 180g/m 2, thread count is 308 * 316(root/10cm).E44 epoxy resin and 650 polyamide curing agent, the quality proportioning is 1:0.9, the dioctyl phthalate flexibilizer of interpolation resin quality 8%, 5% epoxide diluent (SM-90) and 5% look grain.The manufacture process of this anti-stabbing lining is as follows: a at first mixes epoxy resin and curing agent and auxiliary agent; B, this example adopts the web plate of Fig. 6 honeycomb-like pattern, hexagon mesh length of side 4mm in the web plate, gap between mesh and the mesh is 1mm, mesh height is 1.0mm, this resin compound is evenly dispersed in each mesh of web plate, makes each mesh fill up resin, then use scraper to scrape off the unnecessary resin in web plate surface; C is tiled in the polyamide fibre fabric on the web plate of filling full resin, applies the iron plate of a same size, surfacing at the polyamide fibre fabric; D, under 90 ℃ of conditions, drying 30min makes epoxy resin reach working strength, and epoxy resin cured product is cemented in polyamide fibre fabric surface; E separates web plate with the ready-made clothes fabric, obtain the flexible anti stabbing lining.
Adopt 7 layers of this polyamide fibre flexible anti stabbing lining to intersect and spread layer (namely single-layer fabric hides the slit between resin cured matter each other through dislocation up and down), stitching mutually between each layer edge then through cutting, is made protection body (anti-stab inner bag).The stab-resistance body armor gross weight of making specification 175cm, 90A with this protection body is 2.3kg, and thickness is 10.8mm.
The stab-resistance body armor that makes adopts the public safety industry newest standards GA68-2008 of the People's Republic of China (PRC) to test, the result shows that this stab-resistance body armor meets the specification requirement of defined in this standard fully, and can reach NIJ0115.00 high-energy level degree of protection one-level.
Embodiment 2
This flexible anti stabbing lining adopts terylene plain weave fabric as base cloth, and surface density is 210g/m 2, thread count is 160 * 166(root/10cm).E44 epoxy resin and 650 polyamide curing agent, the quality proportioning is 1:1, the dioctyl phthalate flexibilizer of interpolation resin quality 10%, 5% epoxide diluent (SM-90) and 5% look grain.The manufacture process of this anti-stabbing lining is as follows: a at first mixes epoxy resin and curing agent and auxiliary agent; B, this example adopts the identical pentagon of Fig. 5 size around the web plate of square pattern, pentagon mesh length of side 3mm in the web plate, square mesh length of side 5mm, gap between mesh and the mesh is 0.8mm, and mesh height is 0.9mm, this resin compound is evenly dispersed in each mesh of web plate, make each mesh fill up resin, then use scraper to scrape off the unnecessary resin in web plate surface; C is tiled in polyester fabric on the web plate of filling full resin, applies the iron plate of a same size, surfacing at polyester fabric; D, under 80 ℃ of conditions, drying 40min makes epoxy resin reach working strength, and epoxy resin cured product is cemented in the polyester fabric surface; E separates web plate with polyester fabric, obtain the flexible anti stabbing lining.
Adopt 8 layers of this terylene flexible anti stabbing lining to intersect and spread layer (namely single-layer fabric hides the slit between resin cured matter each other through dislocation up and down), stitching mutually between each layer edge then through cutting, is made protection body (anti-stab inner bag).The stab-resistance body armor gross weight of making specification 175cm, 90A with this protection body is 2.5kg, and thickness is 10.3mm.
The stab-resistance body armor that makes adopts the public safety industry newest standards GA68-2008 of the People's Republic of China (PRC) to test, the result shows that this stab-resistance body armor meets the specification requirement of defined in this standard fully, and can reach NIJ0115.00 high-energy level degree of protection one-level.
Embodiment 3
This flexible anti stabbing lining adopts terylene plain weave fabric as base cloth, and surface density is 245g/m 2, thread count is 280 * 298(root/10cm).Thermosetting acrylic resin (BS-965), isocyanate curing agent (740D), quality proportioning 3:1, the neck benzene dibutyl ester flexibilizer of interpolation resin quality 10%.The manufacture process of this anti-stabbing lining is as follows: a at first mixes this thermosetting acrylic resin and curing agent, auxiliary agent; B, this example adopts the web plate of the identical square mutual dislocation Pareto diagram of Fig. 3 size, square mesh length of side 3mm in the web plate, gap between mesh and the mesh is 0.8mm, mesh height is 1.1mm, this resin compound is evenly dispersed in each mesh of web plate, makes each mesh fill up resin, then use scraper to scrape off the unnecessary resin in web plate surface; C is tiled in polyester fabric on the web plate of filling full resin, applies the iron plate of a same size, surfacing at polyester fabric; D solidifies 2h under 80 ℃ of conditions, make acrylic resin reach working strength, and the acrylic resin solidfied material is cemented in the polyester fabric surface; E separates web plate with the ready-made clothes fabric, obtain the flexible anti stabbing lining.
Adopt 7 layers of this terylene flexible anti stabbing lining to intersect and spread layer (namely single-layer fabric hides the slit between resin cured matter each other through dislocation up and down), stitching mutually between each layer edge then through cutting, is made protection body (anti-stab inner bag).The stab-resistance body armor gross weight of making specification 175cm, 90A with this protection body is 2.7kg, and thickness is 11.2mm.
The stab-resistance body armor that makes adopts the public safety industry newest standards GA68-2008 of the People's Republic of China (PRC) to test, the result shows that this stab-resistance body armor meets the specification requirement of defined in this standard fully, and can reach NIJ0115.00 high-energy level degree of protection one-level.
Embodiment 4
This flexible anti stabbing lining adopts aramid fiber plain weave fabric as base cloth, and surface density is 207g/m 2, thread count is 93 * 95(root/10cm).E44 epoxy resin and 650 polyamide curing agent, the quality proportioning is 1:1, the dioctyl phthalate flexibilizer of interpolation resin quality 8%, 5% epoxide diluent (SM-90) and 5% look grain.The manufacture process of this anti-stabbing lining is as follows: a at first mixes epoxy resin and curing agent and auxiliary agent; B, this example still adopts the web plate of Fig. 6 honeycomb-like pattern, hexagon mesh length of side 4mm in the web plate, gap between mesh and the mesh is 1mm, mesh height is 1.0mm, this resin compound is evenly dispersed in each mesh of web plate, makes each mesh fill up resin, then use scraper to scrape off the unnecessary resin in web plate surface; C is tiled in the aramid fiber fabric on the web plate of filling full resin, applies the iron plate of a same size, surfacing at the aramid fiber fabric; D, under 90 ℃ of conditions, drying 30min makes epoxy resin reach working strength, and epoxy resin cured product is cemented in aramid fiber fabric surface; E separates web plate with the ready-made clothes fabric, obtain the flexible anti stabbing lining.
Adopt 5 layers of this aramid fiber flexible anti stabbing lining to intersect and spread layer (namely single-layer fabric hides the slit between resin cured matter each other through dislocation up and down), stitching mutually between each layer edge then through cutting, is made protection body (anti-stab inner bag).The stab-resistance body armor gross weight of making specification 175cm, 90A with this protection body is 1.8kg, and thickness is 8.4mm.
The stab-resistance body armor that makes adopts the public safety industry newest standards GA68-2008 of the People's Republic of China (PRC) to test, the result shows that this stab-resistance body armor meets the specification requirement of defined in this standard fully, and can reach NIJ0115.00 high-energy level degree of protection one-level.
The flexible anti stabbing lining of embodiment 1-4 mainly adopts common chemical fibre as base cloth, the kevlar fabric of employing is also arranged as base cloth, utilize the setting of web plate molding mode, the stab-resistance body armor weight of making is at 1.8-2.7kg, thickness is at 8.4-11.2mm, the number of plies meets every specification requirement of GB GA68-2008 at the 5-8 layer, also can reach NIJ0115.00 high-energy level degree of protection one-level.The stab-resistance body armor that this flexible anti stabbing lining is made is compared with the stab-resistance body armor of the anti-stab grade of domestic same specification, and weight obviously alleviates, and thickness significantly descends, and is with low cost, and comfortable ventilating shows that the present invention has good market prospects.

Claims (10)

1. resin forming flexible anti stabbing lining, it is characterized in that: described fabric is made up of ready-made clothes fabric and thermosetting resin cured matter, has the gap between the thermosetting resin cured matter; Wherein to be of a size of the distance of any point-to-point transmission be 1-30mm to the horizontal plane of resin cured matter, and thickness is 0.1-5mm; Gap between resin cured matter and the resin cured matter is 0.1-5mm.
2. a kind of resin forming flexible anti stabbing lining according to claim 1, it is characterized in that: described ready-made clothes fabric is one or more fibers in chemical fibre, high-performance fiber, cotton, hair, silk, the fiber crops, the fabric that yarn is made.
3. a kind of resin forming flexible anti stabbing lining according to claim 2 is characterized in that: described fabric is wovenly, knitting, non-to knit or weave.
4. a kind of resin forming flexible anti stabbing lining according to claim 1, it is characterized in that: described thermosetting resin is one or more in epoxy resin, thermosetting acrylic resin, amino resins, phenolic resins, Lauxite, unsaturated polyester (UP), the silicon ether resin.
5. according to claim 1 or 4 described a kind of resin forming flexible anti stabbing linings, it is characterized in that: described thermosetting resin adds one or more in diluent, flexibilizer, defoamer, fire retardant, look grain, the curing agent.
6. according to claim 1 and 4 described a kind of resin forming flexible anti stabbing linings, it is characterized in that: the quality proportioning of described resin and curing agent is 1:0.9-3:1.
7. the preparation method of a resin forming flexible anti stabbing lining comprises:
Thermosetting resin is evenly dispersed in each mesh of web plate, make each mesh fill up resin, scrape off the unnecessary resin in web plate surface, then the ready-made clothes fabric is tiled on the web plate of filling full resin, the ready-made clothes fabric is exerted pressure, and drying, thermosetting resin cured matter are cemented in ready-made clothes fabric surface, at last thermosetting resin cured matter is taken off from web plate, namely obtained the flexible anti stabbing lining.
8. the preparation method of a kind of resin forming flexible anti stabbing lining according to claim 6, it is characterized in that: web plate thickness is 0.1-5mm; The distance that the horizontal plane of each mesh is of a size of any point-to-point transmission is 1-30mm, and mesh runs through on web plate fully; Gap between adjacent two mesh is 0.1-5mm; Mesh is shaped as in circle, triangle, quadrangle, pentagon, the polygon one or more on the web plate; The mesh shape is arranged according to the many Size Formula of matrix form, dislocation type, Suresh Kumar, many Size Formula or Suresh Kumar; The web plate material is metal material or nonmetallic materials; Mesh inner surface and outer surface plated film or spraying releasing agent.
9. the preparation method of a kind of resin forming flexible anti stabbing lining according to claim 7, it is characterized in that: described metal material is aluminium alloy or stainless steel, nonmetallic materials are ceramic material; Film is poly tetrafluoroethylene.
10. the preparation method of a kind of resin forming flexible anti stabbing lining according to claim 7, it is characterized in that: the preparation method of a kind of resin forming flexible anti stabbing lining according to claim 6, it is characterized in that: described drying temperature is 10-120 ℃, and criteria thus the drying time is 15min-24h.
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CN104501659A (en) * 2014-12-01 2015-04-08 上海圣甲安全防护科技有限公司 Composite material for preparing flexible stab-resistant material and preparation method of stab-resistant material
CN103791778B (en) * 2014-01-20 2015-11-18 上海圣甲安全防护科技有限公司 The molding bonded method of flexible puncture-proof material, stab-proof body
CN105258567A (en) * 2015-09-07 2016-01-20 苏州高甲防护科技有限公司 Flexible stab-resistant material and preparation method thereof
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CN109297358A (en) * 2018-10-22 2019-02-01 北京理工大学 A kind of anti-puncturing chip and anti-stab equipment
CN110834440A (en) * 2019-11-13 2020-02-25 嘉兴泓盾服饰有限公司 Production process of high-molecular nano composite stab-resistant fabric
CN110978541A (en) * 2019-12-26 2020-04-10 上海固甲新材料科技有限公司 Protective material formed by bonding discrete resin and preparation method thereof
CN112220135A (en) * 2020-10-19 2021-01-15 无锡市第五人民医院 Medical puncture-proof gloves with warp knitting three-dimensional structure
CN112220136A (en) * 2020-10-19 2021-01-15 无锡市第五人民医院 Medical stab-resistant glove
CN114687214A (en) * 2020-12-28 2022-07-01 北京同益中新材料科技股份有限公司 High-strength light-weight stab-resistant material and preparation method thereof
CN114703678A (en) * 2022-03-23 2022-07-05 南通大学 Wear-resistant and scratch-resistant fabric and forming method thereof
CN114858002A (en) * 2022-05-06 2022-08-05 东华大学 Anti-stab fabric with porous buffer structure and preparation method thereof
CN115572456A (en) * 2021-07-06 2023-01-06 南通大学 Puncture-proof, cutting-proof, comfortable and breathable composite material and preparation method thereof

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CN103791778B (en) * 2014-01-20 2015-11-18 上海圣甲安全防护科技有限公司 The molding bonded method of flexible puncture-proof material, stab-proof body
CN104329990A (en) * 2014-09-05 2015-02-04 上海圣甲安全防护科技有限公司 Double-side formation grid anti-piercing material and manufacturing process thereof
CN104329990B (en) * 2014-09-05 2016-02-10 上海圣甲安全防护科技有限公司 A kind of double-faced forming grid stab-resistant material and manufacturing process thereof
CN104501659A (en) * 2014-12-01 2015-04-08 上海圣甲安全防护科技有限公司 Composite material for preparing flexible stab-resistant material and preparation method of stab-resistant material
CN105258567A (en) * 2015-09-07 2016-01-20 苏州高甲防护科技有限公司 Flexible stab-resistant material and preparation method thereof
CN106343637A (en) * 2016-08-25 2017-01-25 湖州环球手套有限公司 Glove for oil-well operation
CN107323061A (en) * 2017-06-30 2017-11-07 常州市瑞泰物资有限公司 A kind of preparation method of thorn-proof composite material
CN108467569A (en) * 2018-04-03 2018-08-31 安徽农业大学 A kind of preparation method of civilian local compliance thorn-proof composite material
CN109297358A (en) * 2018-10-22 2019-02-01 北京理工大学 A kind of anti-puncturing chip and anti-stab equipment
CN109297358B (en) * 2018-10-22 2024-05-24 北京理工大学 Anti-prick chip and anti-prick device
CN110834440A (en) * 2019-11-13 2020-02-25 嘉兴泓盾服饰有限公司 Production process of high-molecular nano composite stab-resistant fabric
CN110978541A (en) * 2019-12-26 2020-04-10 上海固甲新材料科技有限公司 Protective material formed by bonding discrete resin and preparation method thereof
CN112220135A (en) * 2020-10-19 2021-01-15 无锡市第五人民医院 Medical puncture-proof gloves with warp knitting three-dimensional structure
CN112220136A (en) * 2020-10-19 2021-01-15 无锡市第五人民医院 Medical stab-resistant glove
CN114687214A (en) * 2020-12-28 2022-07-01 北京同益中新材料科技股份有限公司 High-strength light-weight stab-resistant material and preparation method thereof
CN115572456A (en) * 2021-07-06 2023-01-06 南通大学 Puncture-proof, cutting-proof, comfortable and breathable composite material and preparation method thereof
CN114703678A (en) * 2022-03-23 2022-07-05 南通大学 Wear-resistant and scratch-resistant fabric and forming method thereof
CN114703678B (en) * 2022-03-23 2024-04-26 南通大学 Wear-resistant and scratch-resistant fabric and forming method thereof
CN114858002A (en) * 2022-05-06 2022-08-05 东华大学 Anti-stab fabric with porous buffer structure and preparation method thereof

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