CN103173992B - Bleaching liquid and bleaching method for soybean protein fiber fabric - Google Patents
Bleaching liquid and bleaching method for soybean protein fiber fabric Download PDFInfo
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- CN103173992B CN103173992B CN201310051907.6A CN201310051907A CN103173992B CN 103173992 B CN103173992 B CN 103173992B CN 201310051907 A CN201310051907 A CN 201310051907A CN 103173992 B CN103173992 B CN 103173992B
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- 238000004061 bleaching Methods 0.000 title claims abstract description 70
- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 239000000835 fiber Substances 0.000 title claims abstract description 42
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 22
- 108010073771 Soybean Proteins Proteins 0.000 title abstract 3
- 235000019710 soybean protein Nutrition 0.000 title abstract 3
- 235000010469 Glycine max Nutrition 0.000 claims description 33
- 244000068988 Glycine max Species 0.000 claims description 33
- 238000005406 washing Methods 0.000 claims description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 9
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract description 2
- BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 abstract 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 14
- 239000007844 bleaching agent Substances 0.000 description 11
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 4
- 229940120146 EDTMP Drugs 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 3
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 3
- 229960002218 sodium chlorite Drugs 0.000 description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001919 chlorite Inorganic materials 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- -1 peracid compound Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- PEYVWSJAZONVQK-UHFFFAOYSA-N hydroperoxy(oxo)borane Chemical compound OOB=O PEYVWSJAZONVQK-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000009898 sodium hypochlorite bleaching Methods 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910021655 trace metal ion Inorganic materials 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Abstract
The invention discloses a bleaching liquid and a bleaching method for a soybean protein fiber fabric. The bleaching liquid comprises the following components in parts by weight: 0.2 to 0.6 part of ammonium borate, 0.5 to 1.5 parts of ethylenediamine (tetramethylene phosphonate) hexasodium salt, 0.5 to 1.5 parts of acrylic acid maleic acid copolymer, 0.5 to 1.5 parts of 1, 5-anhydrous glucitol, 1 to 3 parts of 4-(2-nonanoyl acyloxy ethyoxyl carbonyl oxygroup) sodium benzene sulfonate, 0.2 to 0.6 part of tetra acetyl ethylene diamine, 1.5 to 7.5 parts of sodium hydroxide, 2 to 8 parts of hydrogen peroxide and 1000 parts of water. When the bleaching liquid is used for bleaching the soybean protein fiber fabric, the bleaching process is simple, so that the bleaching liquid is suitable for mass production. The bleaching liquid is less in fabric strength damage and good in bleaching effect, and can be used for effectively inhibiting the fabric from being broken.
Description
Technical field
The present invention relates to the method for bleaching of a kind of fabric bleaching liquid and fabric, particularly relate to a kind of soybean fiber fabric bleaching liquid and soybean fiber fabric method for bleaching.
Background technology
In weave dyeing and finishing technique, fabric is after kiering, and on fabric, the natural and artificial impurity of major part removes, and capillary effect significantly improves, and can meet the processing request of some kinds.But to light figured cloth, the painting cloth class of white goods and lovely luster, also need to improve whiteness, therefore need to remove the pigment on fabric further, make fabric pure whiter.Though fabric is through kiering besides, especially normal pressure decatize kiering, still have partial impurities such as cotton seed hulls to fail entirely to remove, by the effect of bleaching agent, these impurity can remove completely.
Cotton dyeing factory widely uses the oxidative bleaches such as hypochlorite, hydrogen peroxide.To cotton and cotton fabric bleaching, peracid compound as perboric acid receive, peracetic acid, sodium percarbonate etc. are also even application, sodium chlorite is used for the bleaching of synthetic fibers and blend fabric thereof.Usually floated referred to as chlorine by hypochlorite bleaching, hydrogen peroxide bleaching is referred to as oxygen bleaching, and chlorite bleaching floats referred to as Asia.
(1) hypochlorite bleaching
Conventional hypochlorite has bleaching powder and clorox two kinds.Bleaching powder is that chlorine and calcium hydroxide effect form, and if logical chlorine is in milk of lime, can obtain the bleaching powder doubled containing active ingredient; Logical chlorine in soda bath, then can obtain clorox.In bleaching powder and bleaching powder, active ingredient is calcium hypochlorite, and total effect is not as clorox.Cotton dyeing factory larger is at present normal oneself manufactures clorox, or buys clorox for bleaching to neighbouring chemical plant, and bleaching powder is difficult to obtain the small-sized printing and dyeing mill in area of clorox for small city or rural area.Bleaching powder price is more expensive, uses less.
Sodium hypochlorite bleaching technology and equipment is comparatively simple, is used for bafta and victoria blended spinning fabric bleaching, sometimes also bleaches for polyester cotton.But the bleaching of the protein fibre such as silk, wool can not be used for, because clorox has destruction to protein fibre, and make fiber yellowing.
(2) hydrogen peroxide bleaching
Hydrogen peroxide also claims hydrogen peroxide.Better with the fabric whiteness of hydrogen peroxide bleaching, pure color light, not easily yellowing during storage, is widely used in the bleaching of cotton fabric.Oxygen bleaching has larger adaptability than chlorine drift.
(3) chlorite bleaching
The great advantage that sodium chlorate is used for when bafta is bleached is under the condition not damaging fiber, can destroy pigment and impurity.Sodium chlorite is again the good bleaching agent of chemical fibre, and the retention of whiteness of white goods is better than the fabric of chlorine drift and oxygen bleaching, but sodium chlorite price is more expensive, strong to metal protection, by titanium or titanium alloy etc materials, and need produce poisonous ClO in sub-drift process
2gas, equipment need have good sealing, therefore in use, is subject to a definite limitation.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of soybean fiber fabric bleaching liquid and soybean fiber fabric method for bleaching.The method flow process is simple, is suitable for large production; Less to fabric strength damage, environmental protection.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of soybean fiber fabric bleaching liquid, is made up of following components in mass portion:
Ammonium borate 0.2-0.6 part;
EDTMP six sodium salt 0.5-1.5 part;
Acrylic acid maleic acid 0.5-1.5 part;
1,5-anhydrous grape sugar alcohol 0.5-1.5 part;
4-(2-oyloxyethoxy in ninth of the ten Heavenly Stems ketonic oxygen base) benzene sulfonic acid sodium salt 1-3 part;
Tetraacetyl ethylene diamine 0.2-0.6 part;
NaOH 1.5-7.5 part;
Hydrogen peroxide 2-8 part;
1000 parts, water.
Adopt the method that this area is general, above-mentioned each raw material is dissolved in the water, mixes and can obtain this soybean fiber fabric bleaching liquid.
Here is the basic introduction of part material of the present invention, for the NaOH of this area routine, hydrogen peroxide and water, does not obviously need to be explained further again.
Ammonium borate, CAS accession number: 12228-87-4.
EDTMP six sodium salt, No. CAS: 15142-96-8.Molecular structural formula, as follows:
Acrylic acid maleic acid, is called for short AA/MA, No. CAS: 26677-99-6.
1,5-anhydrous grape sugar alcohol, another name: 1,5-acid anhydride-D-D-sorbite, CAS accession number: 154-58-5, English name: D-Glucitol.
4-(2-oyloxyethoxy in ninth of the ten Heavenly Stems ketonic oxygen base) benzene sulfonic acid sodium salt, molecular structural formula is as follows:
4-(2-oyloxyethoxy in ninth of the ten Heavenly Stems ketonic oxygen base) benzene sulfonic acid sodium salt, molecule is made up of two parts, and its one end is a longer nonpolar hydrocarbon chain, i.e. hydrophobic group; The other end is shorter polar group, i.e. a hydrophilic group, is a kind of surfactant of benzenesulfonates.
Tetraacetyl ethylene diamine, No. CAS: 10543-57-4, No. EC: 234-123-8, be called for short NOBS, English name: N, N, N', N'-Tetraacety lethy lenediamine.
Boron compound ammonium borate and chelating agent EDTMP six sodium salt, acrylic acid maleic acid, 1, the synergies such as 5-anhydrous grape sugar alcohol, can act in hydrogen peroxide and free metal, catch trace metal ion, improve hydrogen peroxide stability in the solution in bleaching process, thus bleaching effect of the present invention can be improved to a greater degree.Amazingly be, bleach-activating 4-(2-oyloxyethoxy in ninth of the ten Heavenly Stems ketonic oxygen base) benzene sulfonic acid sodium salt in the present invention, the composite use of tetraacetyl ethylene diamine, bleaching effect can be improved further, and can effectively suppress the breakage of fabric and fade.
Soybean fiber fabric bleaching liquid of the present invention, can adopt the conventional method of this area to bleach fabric, as filling-steaming process, pressurization boiling process, and the similar approach such as the infusion process within the scope of 60-100 DEG C.
Further,
Present invention also offers a kind of method for bleaching of soybean fiber fabric, comprise and pad bleaching liquor, decatize and water-washing step,
Wherein, the bleaching liquor padded described in bleaching liquor step adopts above-mentioned soybean fiber fabric bleaching liquid.
Preferably,
At room temperature, pad bleaching liquor, at 95-100 DEG C of decatize 45-60min, then wash 20-60min.
The advantage of technical solution of the present invention is mainly reflected in:
Adopt bleaching liquid of the present invention to bleach soybean fiber fabric, bleaching process is simple, can be suitable for large production, and less to fabric strength damage, bleaching effect is good, and effectively can suppress the breakage of fabric.
Detailed description of the invention
Embodiment 1
The preparation of soybean fiber fabric bleaching liquid
Table 1: soybean fiber fabric bleaching liquid formula table unit: kilogram
By the data corresponding to table 1, take each raw material.Under room temperature, by ammonium borate, EDTMP six sodium salt, acrylic acid maleic acid, 1,5-anhydrous grape sugar alcohol, 4-(2-oyloxyethoxy in ninth of the ten Heavenly Stems ketonic oxygen base) benzene sulfonic acid sodium salt and tetraacetyl ethylene diamine are dissolved in the water, add NaOH and hydrogen peroxide again, mix, described soybean fiber fabric bleaching liquid can be obtained.
Comparative example 1
By the data corresponding to table 1, take each raw material, be uniformly mixed, soybean fiber fabric bleaching liquid can be obtained.
Comparative example 2
By the data corresponding to table 1, take each raw material, be uniformly mixed, soybean fiber fabric bleaching liquid can be obtained.
Comparative example 3
By the data corresponding to table 1, take each raw material, be uniformly mixed, soybean fiber fabric bleaching liquid can be obtained.
Embodiment 2
The method for bleaching of soybean fiber fabric
Under room temperature, soybean fiber fabric bleaching liquid obtained for embodiment 1 is padded soybean fiber fabric, and with ironer mangle to 100% pick-up, then at 100 DEG C of decatize 50min, last normal temperature washes 30 minutes, dry.
Comparative example 4
Under room temperature, soybean fiber fabric bleaching liquid obtained for comparative example 1 is padded soybean fiber fabric, and with ironer mangle to 100% pick-up, then at 100 DEG C of decatize 50min, last normal temperature washes 30 minutes, dry.
Comparative example 5
Under room temperature, soybean fiber fabric bleaching liquid obtained for comparative example 2 is padded soybean fiber fabric, and with ironer mangle to 100% pick-up, then at 100 DEG C of decatize 50min, last normal temperature washes 30 minutes, dry.
Comparative example 6
Under room temperature, soybean fiber fabric bleaching liquid obtained for comparative example 3 is padded soybean fiber fabric, and with ironer mangle to 100% pick-up, then at 100 DEG C of decatize 50min, last normal temperature washes 30 minutes, dry.
Test case
To the embodiment 2 after bleaching and the soybean fiber fabric of comparative example 4-6, carry out whiteness and tearing strength test.
Concrete method of testing is as follows:
Whiteness is detected according to FZ/T50013-2008 " cellulose chemistry fibre whiteness test method ".
By Elmendorf Tear tester test tearing strength, the test sample two ends clamping of 6.5cm × 10cm is of a size of by one, the otch of a 2cm is vertically cut at position therebetween, tearing to the maximum grams shown by this point of 4.5cm place measurement, measure 3 times, average, and with the measured value of this mean value divided by undressed sample, its quotient is tearing strength.Tearing strength is larger, and illustrate that the intensity of fabric keeps better, the damage of bleaching process to fabric is less.
Test data, sees the following form 2.
Table 2: test data table
| Test event | Embodiment 2 | Comparative example 4 | Comparative example 5 | Comparative example 6 |
| Whiteness, % | 89 | 68 | 66 | 79 |
| Tearing strength, % | 94.2 | 84.3 | 81.7 | 88.5 |
The soybean fiber fabric adopted in the present invention, before bleaching, whiteness is 53%.
Compared by table 2 data, can obviously draw, bleaching effect and the tearing strength of embodiment 2 are obviously better than comparative example 4-6.
Claims (3)
1. a soybean fiber fabric bleaching liquid, is characterized in that, is made up of following components in mass portion:
2. a method for bleaching for soybean fiber fabric, comprises and pads bleaching liquor, decatize and water-washing step, it is characterized in that: described in the bleaching liquor padded in bleaching liquor step adopt soybean fiber fabric bleaching liquid according to claim 1.
3. the method for bleaching of soybean fiber fabric as claimed in claim 2, is characterized in that: at room temperature pad bleaching liquor, at 95-100 DEG C of decatize 45-60min, then washes 20-60min.
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| CN201310051907.6A CN103173992B (en) | 2013-02-14 | 2013-02-14 | Bleaching liquid and bleaching method for soybean protein fiber fabric |
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| CN201310051907.6A CN103173992B (en) | 2013-02-14 | 2013-02-14 | Bleaching liquid and bleaching method for soybean protein fiber fabric |
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| CN103173992B true CN103173992B (en) | 2015-04-29 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341241A (en) * | 2005-12-28 | 2009-01-07 | 花王株式会社 | Liquid detergent |
| JP2012188525A (en) * | 2011-03-10 | 2012-10-04 | Kao Corp | Method for producing liquid bleaching agent composition |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341241A (en) * | 2005-12-28 | 2009-01-07 | 花王株式会社 | Liquid detergent |
| JP2012188525A (en) * | 2011-03-10 | 2012-10-04 | Kao Corp | Method for producing liquid bleaching agent composition |
Non-Patent Citations (2)
| Title |
|---|
| "新型过氧化氢漂白活化剂4-(2-壬酰氧基乙氧基羰基氧基)苯磺酸钠的合成";孔祥文等;《中华纸业》;20121231;第33卷(第12期);第9-12页 * |
| 梁亮."氧漂稳定剂"、"漂白活化剂".《精细化工配方原理与剖析》.化学工业出版社,2007,(第1版),第100页. * |
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