CN103173989B - Bleaching liquid and bleaching method for polyvinyl alcohol cotton blended fabric - Google Patents
Bleaching liquid and bleaching method for polyvinyl alcohol cotton blended fabric Download PDFInfo
- Publication number
- CN103173989B CN103173989B CN201310051886.8A CN201310051886A CN103173989B CN 103173989 B CN103173989 B CN 103173989B CN 201310051886 A CN201310051886 A CN 201310051886A CN 103173989 B CN103173989 B CN 103173989B
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- Prior art keywords
- bleaching
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- fabric
- liquid
- bleaching liquid
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- 238000004061 bleaching Methods 0.000 title claims abstract description 70
- 239000004744 fabric Substances 0.000 title claims abstract description 65
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 22
- 229920000742 Cotton Polymers 0.000 title abstract description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 title abstract 3
- 229920002451 polyvinyl alcohol Polymers 0.000 title abstract 3
- 238000009987 spinning Methods 0.000 claims description 34
- 238000005406 washing Methods 0.000 claims description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 9
- 230000006378 damage Effects 0.000 abstract description 5
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract description 2
- DERCTHYVTQKCLG-UHFFFAOYSA-N CP(O)(O)=O.NC1=NC(N(C=C1)CC(CO)[O])=O Chemical compound CP(O)(O)=O.NC1=NC(N(C=C1)CC(CO)[O])=O DERCTHYVTQKCLG-UHFFFAOYSA-N 0.000 abstract 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 abstract 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 abstract 1
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 15
- 239000007844 bleaching agent Substances 0.000 description 11
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 3
- HAKFWHINKUNSIR-UHFFFAOYSA-N CP(O)(O)=O.[O] Chemical compound CP(O)(O)=O.[O] HAKFWHINKUNSIR-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 3
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 3
- 229960002218 sodium chlorite Drugs 0.000 description 3
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001919 chlorite Inorganic materials 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 peracid compound Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- PEYVWSJAZONVQK-UHFFFAOYSA-N hydroperoxy(oxo)borane Chemical compound OOB=O PEYVWSJAZONVQK-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000009898 sodium hypochlorite bleaching Methods 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910021655 trace metal ion Inorganic materials 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Abstract
Description
Test event | Embodiment 2 | Comparative example 4 | Comparative example 5 | Comparative example 6 |
Whiteness, % | 82 | 71 | 66 | 75 |
Tearing strength, % | 94.1 | 87.6 | 84.8 | 90.2 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310051886.8A CN103173989B (en) | 2013-02-14 | 2013-02-14 | Bleaching liquid and bleaching method for polyvinyl alcohol cotton blended fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310051886.8A CN103173989B (en) | 2013-02-14 | 2013-02-14 | Bleaching liquid and bleaching method for polyvinyl alcohol cotton blended fabric |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103173989A CN103173989A (en) | 2013-06-26 |
CN103173989B true CN103173989B (en) | 2015-03-11 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201310051886.8A Active CN103173989B (en) | 2013-02-14 | 2013-02-14 | Bleaching liquid and bleaching method for polyvinyl alcohol cotton blended fabric |
Country Status (1)
Country | Link |
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CN (1) | CN103173989B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104233775B (en) * | 2014-09-15 | 2016-07-06 | 河南工程学院 | A kind of cold bleaching method of cotton textiles or cotton-containing fabrics |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101341241A (en) * | 2005-12-28 | 2009-01-07 | 花王株式会社 | Liquid detergent |
-
2013
- 2013-02-14 CN CN201310051886.8A patent/CN103173989B/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101341241A (en) * | 2005-12-28 | 2009-01-07 | 花王株式会社 | Liquid detergent |
Non-Patent Citations (2)
Title |
---|
"新型过氧化氢漂白活化剂4-(2-壬酰氧基乙氧基羰基氧基)苯磺酸钠的合成;孔祥文等;《中华纸业》;20121231;第33卷(第12期);9-12 * |
梁亮."氧漂稳定剂"、"漂白活化剂".《精细化工配方原理与剖析》.化学工业出版社,2007,100. * |
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Publication number | Publication date |
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CN103173989A (en) | 2013-06-26 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Sun Xia Inventor after: Guo Chi Inventor after: Huang Meirong Inventor before: Huang Meirong |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: HUANG MEIRONG TO: SUN XIA GUO CHI HUANG MEIRONG |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181016 Address after: 215228 217, 23 building, 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee after: SUZHOU HUAZONG TEXTILE NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 201111 room 271, thirtieth building, 280 Shuguang Road, Minhang District, Shanghai. Patentee before: SHANGHAI QIUCHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181026 Address after: 313000 Zhang Jia Dai village, eight Li Dian Town, Wuxing District, Huzhou, Zhejiang Patentee after: HUZHOU HYUNDAI TEXTILE MACHINERY Co.,Ltd. Address before: 201111 room 271, thirtieth building, 280 Shuguang Road, Minhang District, Shanghai. Patentee before: SHANGHAI QIUCHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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TR01 | Transfer of patent right | ||
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Effective date of registration: 20211123 Address after: 510000 building B1, No. 1 Yiheng, Shixia Road, Xiamao, Baiyun Lake Street, Baiyun District, Guangzhou, Guangdong Patentee after: Shosha Address before: 313000 Zhang Jia Dai village, eight Li Dian Town, Wuxing District, Huzhou, Zhejiang Patentee before: HUZHOU HYUNDAI TEXTILE MACHINERY Co.,Ltd. |
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Effective date of registration: 20230808 Address after: 710061 Room 5112, Building 21, Dongbali Community, Changming Road, Yanta District, Xi'an City, Shaanxi Province Patentee after: Xi'an Hengpu Dake Industry and Trade Co.,Ltd. Address before: 510000 building B1, No. 1 Yiheng, Shixia Road, Xiamao, Baiyun Lake Street, Baiyun District, Guangzhou, Guangdong Patentee before: Xiao Xia |