CN103172132A - Seawater desalting device and method of off-grid type photovoltaic photo-thermal coupled heat pump - Google Patents

Seawater desalting device and method of off-grid type photovoltaic photo-thermal coupled heat pump Download PDF

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Publication number
CN103172132A
CN103172132A CN2013100784438A CN201310078443A CN103172132A CN 103172132 A CN103172132 A CN 103172132A CN 2013100784438 A CN2013100784438 A CN 2013100784438A CN 201310078443 A CN201310078443 A CN 201310078443A CN 103172132 A CN103172132 A CN 103172132A
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magnetic valve
vaporizer
photovoltaic
tank
photothermal
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CN2013100784438A
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CN103172132B (en
Inventor
任建波
王金燕
苗超
张铭
冯厚军
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Tianjin Institute of Seawater Desalination and Multipurpose Utilization SOA
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Tianjin Institute of Seawater Desalination and Multipurpose Utilization SOA
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Publication of CN103172132A publication Critical patent/CN103172132A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Abstract

The invention discloses a sweater desalting device of an off-grid type photovoltaic photo-thermal coupled heat pump. The sweater desalting device of the off-grid type photovoltaic photo-thermal coupled heat pump comprises a direct-expansion type solar heat pump system, a material water tank, a heat storage water tank, a flash tank and a master controller, wherein the direct-expansion type solar heat pump system comprises a photovoltaic photo-thermal evaporator; the photovoltaic photo-thermal evaporator is connected with a second tee joint, a gas-liquid separator, a compressor, a condenser, a liquid storage device, a drying filter, a visual liquid lens, a throttling device and a first tee joint by a pipeline in sequence; and the first tee joint is connected with a first solenoid valve, a regenerative heat evaporator, a condensing evaporator, a second solenoid valve and the second tee joint by a pipeline in sequence. The invention further discloses a method for desalting the sweater by utilizing the seawater desalting device of the off-grid type photovoltaic photo-thermal coupled heat pump. According to the seawater desalting device and the seawater desalting method of off-grid type photovoltaic photo-thermal coupled heat pump disclosed by the invention, the renewable energy sources can be sufficiently utilized and the energy utilization efficiency is improved, so that the off-grid operation of the sweater desalting device in remote areas including an island without power supply and the like is realized.

Description

A kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant and method
Technical field
The invention belongs to solar photovoltaic photothermal technique and field of sea water desalting technology, relate to a kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant and utilize it to carry out the method for seawater or brackish water desalination.
Technical background
Water is the source of all life.Along with the industrial or agricultural development, population fast growth, the demand of fresh water will sharply increase, and shortage of fresh water is the serious problems that many countries will face future.Especially in some island and remote area, saltwater lake, water resources is mostly seawater or brackish water, the fresh water famine, power supply simultaneously is also more difficult, but solar energy resources is abundant, therefore utilizing sun power to carry out seawater or brackish water desalination, is the important channel that solves these regional shortage of fresh water problems.The water production rate of tradition passive type solar energy distiller unit daylighting area is too low, is only 4-8kg/m 2d, limited its range of application greatly.Increase although be equipped with the water production rate of the active solar energy Distallation systm unit daylighting area of solar energy collector, because the heat-collecting temperature of solar energy heat collector is higher, cause collecting efficiency lower; Simultaneously, the active solar energy collecting system generally needs the fluid drive apparatus such as water pump, and the application external electrical network provides electric power for system, in the island or the remote districts that lack supply of electric power, does not possess practicality.
The Chinese invention patent that publication number is CN101316080B discloses a kind of electric energy and heat energy that utilizes the solar photovoltaic spot light generating to produce, after promoting by heat pump, as the vapor flash device thermal source of low-temperature multi-effect seawater desalination device, utilize renewable energy source to realize the device of sea water desaltination.Mainly there is the problem of following three aspects in this device: the complexity of system of having utilized condensing tracking device to increase; Do not utilize the condensation latent heat of secondary steam; Because converging of sunlight may make vaporization temperature higher, cause the lubricant in compressor charing, cause system not run well.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant.
Second purpose of the present invention is to provide a kind of method that utilization is carried out sea water desaltination from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant.
Technical scheme of the present invention is summarized as follows:
A kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant, comprise direct expanding solar heating pump system, raw material water tank 18, hot water storage tank 17, flash tank 20 and primary controller;
The direct expanding solar heating pump system comprises photovoltaic and photothermal vaporizer 12, and the outlet 1 of photovoltaic and photothermal vaporizer is connected with the entrance 11 of the second threeway 2, gas-liquid separator 3, compressor 4, condenser 5, reservoir 6, device for drying and filtering 7, liquid-sighting glass 8, throttling set 9, the first threeway 10, photovoltaic and photothermal vaporizer successively by pipeline; Solar Total Irradiance Monitor and the first temperature sensor be arranged on photovoltaic and photothermal vaporizer 12 the surface or near; The first threeway 10 is connected with the second threeway 2 with the first magnetic valve 13, backheat vaporizer 14, condenser/evaporator 15, the second magnetic valve 16 successively by pipeline; Condenser 5 is arranged at the inside of hot water storage tank 17; Be provided with refrigeration agent in described direct expanding solar heating pump system; Photovoltaic and photothermal vaporizer 12 is connected with controller 33, invertor 35 successively by circuit, and controller 33 is connected by circuit is two-way with store battery 34;
The outlet of raw material water tank 18 is connected with the entrance on hot water storage tank 17 tops with the 3rd magnetic valve 19 successively by pipeline;
The top of hot water storage tank 17 is connected with the 4th magnetic valve 22, flash tank 20 successively by pipeline; Be provided with the second temperature sensor in hot water storage tank 17 inside;
Flash tank 20 bottoms are connected with the first check valve 23, sea water circulating pump 24, the 3rd threeway 25 and hot water storage tank 17 bottoms successively by pipeline; The 3rd threeway 25 is connected with the strong brine entrance 27 of the 5th magnetic valve 26, backheat vaporizer 14 successively by pipeline, and the strong brine outlet 28 of backheat vaporizer 14 is connected with the strong brine delivery pipe; Condenser/evaporator 15 is arranged on the top of flash tank 20 inside, is provided with water-collecting tray 21 below condenser/evaporator 15; The top of flash tank 20 is provided with product water outlet 32, and product water outlet 32 is connected with water-collecting tray 21, and product water outlet 32 is connected with the water-in on product water tank 29 tops by pipeline, and the bottom of product water tank 29 is provided with the product water feed water inlet; The top of product water tank 29 is connected with the second check valve 30, vacuum pumping pump 31 successively by pipeline;
Described primary controller is electrically connected to the first magnetic valve 13, the second magnetic valve 16, the 3rd magnetic valve 19, the 4th magnetic valve 22, the 5th magnetic valve 26, sea water circulating pump 24, vacuum pumping pump 31, compressor 4, Solar Total Irradiance Monitor, the first temperature sensor, the second temperature sensor and invertor 35 respectively.
Photovoltaic and photothermal vaporizer 12 is comprised of solar energy collector and the photovoltaic cell that is arranged on described solar energy collector surface.
Flat plate collector or the vacuum tube collector of the preferred flat plate collector of solar energy collector, cover plate.
The preferred monocrystalline silicon battery of photovoltaic cell, polycrystal silicon cell, amorphous silicon battery or hull cell.
Flash tank 20 preferred body Flash Type flash tanks or spray Flash Type flash tank.
The preferred plate-type heat exchanger of backheat vaporizer 14, tube and shell heat exchanger or double-pipe exchanger.
The preferred straight tubular heat exchanger of condenser/evaporator 15, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The preferred straight tubular heat exchanger of condenser 5, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The bottom of water-collecting tray 21 preferably is provided with catches the foam net.
A kind of method of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant, carrying out sea water desaltination of utilizing, comprise the steps:
When the photovoltaic cell surface shined upon on photovoltaic and photothermal vaporizer 12 is arranged, the electric energy that photovoltaic cell produces is by control accumulators 34 chargings of controller 33, and store battery 34 provides electric energy by controller 33 and invertor 35 for sea water desaltination;
The solar irradiance recorded when Solar Total Irradiance Monitor is greater than 200W/m 2or first envrionment temperature that record of temperature sensor during higher than 5 ℃, primary controller is controlled compressor 4 and is automatically opened, refrigeration agent is subject to thermal evaporation in photovoltaic and photothermal vaporizer 12, becoming low-pressure gas flows out by the outlet 1 of photovoltaic and photothermal vaporizer, second threeway 2 of flowing through arrives in gas-liquid separator 3 carries out gas-liquid separation, becoming high temperature and high pressure gas after 4 compressions of the compressed machine of low-pressure gas after separation enters in condenser 5 and discharges latent heat and become highly pressurised liquid after to the seawater in hot water storage tank 17, the highly pressurised liquid reservoir 6 of flowing through, device for drying and filtering 7 and liquid-sighting glass 8, become the saturated air of low-temp low-pressure and the mixture of saturated solution after throttling set 9 throttlings, by the first threeway 10, entrance 11 through the photovoltaic and photothermal vaporizer is got back to photovoltaic and photothermal vaporizer 12, complete a circulation,
When the second temperature sensor records seawater temperature in hot water storage tank 17 higher than 60 ℃, primary controller is controlled vacuum pumping pump 31 and is opened, and the gas in flash tank 20 and product water tank 29 is discharged by the second check valve 30 and vacuum pumping pump 31; The interior formation negative pressure of flash tank 20,3-10 minute after vacuum pumping pump 31 is opened, the 4th magnetic valve 22 controlled by primary controller and sea water circulating pump 24 is opened, seawater in hot water storage tank 17 flow into flash tank 20 by pipeline through the 4th magnetic valve 22, and the strong brine after flash distillation is got back to hot water storage tank 17 by pipeline through the first check valve 23, sea water circulating pump 24, the 3rd threeway 25;
Seawater forms water vapor in the interior flash distillation of flash tank 20,1-2 minute after sea water circulating pump 24 is opened, primary controller is controlled the first magnetic valve 13, the second magnetic valve 16, the 3rd magnetic valve 19 and the 5th magnetic valve 26 and is opened, a strong brine part through the 3rd threeway 25 flows back to hot water storage tank 17, another part strong brine enters into backheat vaporizer 14 by pipeline through the 5th magnetic valve 26, strong brine entrance 27, and the strong brine after heat exchange is discharged from the strong brine delivery pipe through strong brine outlet 28; Refrigeration agent after throttling set 9 throttlings is by first threeway 10 parts, first magnetic valve 13 of flowing through, in backheat vaporizer 14 with the strong brine heat exchange, after heat exchange, enter in condenser/evaporator 15, with the water vapor heat exchange, heat exchange is got back to the second threeway 2 by the second magnetic valve 16, the water droplet formed after water vapor condensation enters into product water tank 29 by the road by product water outlet 32 after being collected by water-collecting tray 21, and another part of refrigeration agent flow back into photovoltaic and photothermal vaporizer 12 by pipeline; Raw material water tank 18 is that hot water storage tank 17 is mended raw material seawater by the 3rd magnetic valve 19 by the road;
Seawater temperature in the second temperature sensor records hot water storage tank 17 is during lower than 60 ℃, primary controller controls the 3rd magnetic valve 19, the 4th magnetic valve 22, the 5th magnetic valve 26 and sea water circulating pump 24 and cuts out, 1-2 minute, primary controller controls the first magnetic valve 13, the second magnetic valve 16 and vacuum pumping pump 31 and cuts out;
When recording the solar irradiance that seawater temperature in hot water storage tank 17 records lower than 60 ℃, Solar Total Irradiance Monitor, the second temperature sensor is less than 200W/m 2the envrionment temperature recorded with the first temperature sensor is during lower than 5 ℃, and primary controller controls compressor 4 and automatically cuts out.
Photovoltaic and photothermal vaporizer 12 is comprised of solar energy collector and the photovoltaic cell that is arranged on described solar energy collector surface.
Flat plate collector or the vacuum tube collector of the preferred flat plate collector of solar energy collector, cover plate.
The preferred monocrystalline silicon battery of photovoltaic cell, polycrystal silicon cell, amorphous silicon battery or hull cell.
Flash tank 20 preferred body Flash Type flash tanks or spray Flash Type flash tank.
The preferred plate-type heat exchanger of backheat vaporizer 14, tube and shell heat exchanger or double-pipe exchanger.
The preferred straight tubular heat exchanger of condenser/evaporator 15, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The preferred straight tubular heat exchanger of condenser 5, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The bottom of water-collecting tray 21 preferably is provided with catches the foam net.
The present invention has following positively effect:
Device of the present invention can take full advantage of sun power and ambient air heat energy, photovoltaic cell is combined to the temperature that has reduced photovoltaic cell with evaporator with heat pump, has improved the generating efficiency of photovoltaic cell; A part using the interchanger in sea water desalinating plant as evaporator with heat pump, the sensible heat of the sensible heat of the condensation latent heat of recovered steam, condensation fresh water and discharge strong brine, improve the efficiency of energy utilization of device to greatest extent.Whole device can realize the remote areas such as island that there is no supply of electric power from network operation, have that floor space is little, movability is strong simultaneously, convenient for installation and maintenance and without characteristics such as staff on duty, can meet the remote regional seawater such as island and brackish water and process user's demand, there is good society and economic benefit.
The accompanying drawing explanation
Fig. 1 is of the present invention a kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant schematic diagram.
In figure: the outlet 1 of photovoltaic and photothermal vaporizer; The second threeway 2; Gas-liquid separator 3; Compressor 4; Condenser 5; Reservoir 6; Device for drying and filtering 7; Liquid-sighting glass 8; Throttling set 9; The first threeway 10; The entrance 11 of photovoltaic and photothermal vaporizer; Photovoltaic and photothermal vaporizer 12; The first magnetic valve 13; Backheat vaporizer 14; Condenser/evaporator 15; The second magnetic valve 16; Hot water storage tank 17; Raw material water tank 18; The 3rd magnetic valve 19; Flash tank 20; Water-collecting tray 21; The 4th magnetic valve 22; The first check valve 23; Sea water circulating pump 24; The 3rd threeway 25; The 5th magnetic valve 26; Strong brine entrance 27; Strong brine outlet 28; Product water tank 29; The second check valve 30; Vacuum pumping pump 31; Product water outlet 32; Controller 33; Store battery 34; Invertor 35.
Embodiment
Below in conjunction with accompanying drawing, the present invention is further illustrated.Of the present invention is in order to enable those skilled in the art to understand better the present invention for example, but the present invention is not imposed any restrictions.
See Fig. 1.
A kind of from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant, comprise direct expanding solar heating pump system, raw material water tank 18, hot water storage tank 17, flash tank 20 and PLC primary controller;
The direct expanding solar heating pump system comprises photovoltaic and photothermal vaporizer 12, and the outlet 1 of photovoltaic and photothermal vaporizer is connected with the entrance 11 of the second threeway 2, gas-liquid separator 3, compressor 4, condenser 5, reservoir 6, device for drying and filtering 7, liquid-sighting glass 8, throttling set 9, the first threeway 10, photovoltaic and photothermal vaporizer successively by pipeline; Solar Total Irradiance Monitor and the first temperature sensor are arranged near surface or (within 1 meter, the photovoltaic and photothermal vaporizer) of photovoltaic and photothermal vaporizer 12; The first threeway 10 is connected with the second threeway 2 with the first magnetic valve 13, backheat vaporizer 14, condenser/evaporator 15, the second magnetic valve 16 successively by pipeline; Condenser 5 is arranged at the inside (condenser 5 also can adopt the seawater cycle heat exchange in external mode and hot water storage tank 17) of hot water storage tank 17; Be provided with refrigeration agent in the direct expanding solar heating pump system; Refrigeration agent can select mineral compound, as water, ammonia, carbonic acid gas; The halogenide of stable hydrocarbon, as R12, R22, R134a; Hydrocarbon compound, as propane, Trimethylmethane; Azeotrope refrigerant, as R502; Non-azeotropic refrigerant, as R407C etc.; Photovoltaic and photothermal vaporizer 12 is connected with controller 33, invertor 35 successively by circuit, and controller 33 is connected by circuit is two-way with store battery 34;
The outlet of raw material water tank 18 is connected with the entrance on hot water storage tank 17 tops with the 3rd magnetic valve 19 successively by pipeline;
The top of hot water storage tank 17 is connected with the 4th magnetic valve 22, flash tank 20 successively by pipeline; Be provided with the second temperature sensor in hot water storage tank 17 inside;
Flash tank 20 bottoms are connected with the first check valve 23, sea water circulating pump 24, the 3rd threeway 25 and hot water storage tank 17 bottoms successively by pipeline; The 3rd threeway 25 is connected with the strong brine entrance 27 of the 5th magnetic valve 26, backheat vaporizer 14 successively by pipeline, and the strong brine outlet 28 of backheat vaporizer 14 is connected with the strong brine delivery pipe; Condenser/evaporator 15 is arranged on the top of flash tank 20 inside, is provided with water-collecting tray 21 below condenser/evaporator 15; The top of flash tank 20 is provided with product water outlet 32, and product water outlet 32 is connected with water-collecting tray 21, and product water outlet 32 is connected with the water-in on product water tank 29 tops by pipeline, and the bottom of product water tank 29 is provided with the product water feed water inlet; The top of product water tank 29 is connected with the second check valve 30, vacuum pumping pump 31 successively by pipeline;
The PLC primary controller is electrically connected to the first magnetic valve 13, the second magnetic valve 16, the 3rd magnetic valve 19, the 4th magnetic valve 22, the 5th magnetic valve 26, sea water circulating pump 24, vacuum pumping pump 31, compressor 4, Solar Total Irradiance Monitor, the first temperature sensor, the second temperature sensor and invertor 35 respectively.
Photovoltaic and photothermal vaporizer 12 is comprised of solar energy collector and the photovoltaic cell that is arranged on described solar energy collector surface.
Flat plate collector or the vacuum tube collector of the preferred flat plate collector of solar energy collector, cover plate.
The preferred monocrystalline silicon battery of photovoltaic cell, polycrystal silicon cell, amorphous silicon battery or hull cell.
Flash tank 20 preferred body Flash Type flash tanks or spray Flash Type flash tank.
The preferred plate-type heat exchanger of backheat vaporizer 14, tube and shell heat exchanger or double-pipe exchanger.
The preferred straight tubular heat exchanger of condenser/evaporator 15, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The preferred straight tubular heat exchanger of condenser 5, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
The bottom of water-collecting tray 21 preferably is provided with catches the foam net.
The components and parts that the present invention adopts can be chosen as required from the market, and the PLC primary controller can be purchased, as siemens S7-200CPU224XP.
Device of the present invention, when flash tank 20 for spray Flash Type flash tank, photovoltaic and photothermal vaporizer 12(by solar energy collector and be arranged on its surperficial photovoltaic cell and form) solar energy collector be that flat plate collector, photovoltaic cell are that monocrystalline silicon battery, backheat vaporizer 14 are tube exchanger for tube and shell heat exchanger, condenser/evaporator 15 for spiral tube heat exchanger, condenser 5, when refrigeration agent is R134a, in solar irradiance, be 700W/m 2, under the condition that ambient air temp is 25 ℃, the fresh water yield of this device is about 40kg/m 2the fresh water yield of d(and existing general traditional passive type solar energy distiller is at 4-8kg/m 2the d left and right).
The method of seawater (or brackish water) desalination is carried out in utilization from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant, comprise the steps:
When the photovoltaic cell surface shined upon on photovoltaic and photothermal vaporizer 12 is arranged, the electric energy that photovoltaic cell produces is by control accumulators 34 chargings of controller 33, and store battery 34 provides electric energy by controller 33 and invertor 35 for whole device;
The solar irradiance recorded when Solar Total Irradiance Monitor is greater than 200W/m 2or first envrionment temperature that record of temperature sensor during higher than 5 ℃, the PLC primary controller is controlled compressor 4 and is automatically opened, the refrigeration agent of low-temp low-pressure absorbs solar radiant energy and ambient air heat energy and evaporates in the solar energy collector of photovoltaic and photothermal vaporizer 12, becoming low-pressure gas flows out by the outlet 1 of photovoltaic and photothermal vaporizer, second threeway 2 of flowing through arrives in gas-liquid separator 3 carries out gas-liquid separation, becoming high temperature and high pressure gas after 4 compressions of the compressed machine of low-pressure gas after separation enters in condenser 5 and discharges latent heat and become highly pressurised liquid after to the seawater (or brackish water) in hot water storage tank 17, the highly pressurised liquid reservoir 6 of flowing through, device for drying and filtering 7 and liquid-sighting glass 8, become the saturated air of low-temp low-pressure and the mixture of saturated solution after throttling set 9 throttlings, by the first threeway 10, entrance 11 through the photovoltaic and photothermal vaporizer is got back to photovoltaic and photothermal vaporizer 12, complete a circulation,
When the second temperature sensor records seawater temperature in hot water storage tank 17 higher than 60 ℃, the PLC primary controller is controlled vacuum pumping pump 31 and is opened, and the gas in flash tank 20 and product water tank 29 is discharged by the second check valve 30 and vacuum pumping pump 31; The interior formation negative pressure of flash tank 20, after opening, vacuum pumping pump 31 (also can be set as 5 minutes according to size and the flash tank size of vacuum pumping pump in 3 minutes, or 10 minutes), the 4th magnetic valve 22 controlled by the PLC primary controller and sea water circulating pump 24 is opened, seawater in hot water storage tank 17 flow into flash tank 20 by pipeline through the 4th magnetic valve 22, and the strong brine after flash distillation is got back to hot water storage tank 17 by pipeline through the first check valve 23, sea water circulating pump 24, the 3rd threeway 25;
Seawater forms water vapor in the interior flash distillation of flash tank 20, after sea water circulating pump 24 is opened 1 minute (also can be set as 2 minutes according to seawater temperature and flash tank size), the PLC primary controller is controlled the first magnetic valve 13, the second magnetic valve 16, the 3rd magnetic valve 19 and the 5th magnetic valve 26 and is opened, a strong brine part through the 3rd threeway 25 flows back to hot water storage tank 17, another part strong brine enters into backheat vaporizer 14 by pipeline through the 5th magnetic valve 26, strong brine entrance 27, and the strong brine after heat exchange is discharged from the strong brine delivery pipe through strong brine outlet 28; Refrigeration agent after throttling set 9 throttlings is by first threeway 10 parts, first magnetic valve 13 of flowing through, in backheat vaporizer 14 with strong brine heat exchange the sensible heat of strong brine (absorb), after heat exchange, enter in condenser/evaporator 15, with water vapor heat exchange (absorbing latent heat and the water of condensation sensible heat of water vapor), heat exchange is got back to the second threeway 2 by the second magnetic valve 16, the water droplet formed after water vapor condensation enters into product water tank 29 by the road by product water outlet 32 after being collected by water-collecting tray 21, and another part of refrigeration agent flow back into photovoltaic and photothermal vaporizer 12 by pipeline; Raw material water tank 18 is that hot water storage tank 17 is mended raw material seawater by the 3rd magnetic valve 19 by the road;
Seawater temperature in the second temperature sensor records hot water storage tank 17 is during lower than 60 ℃, the PLC primary controller controls the 3rd magnetic valve 19, the 4th magnetic valve 22, the 5th magnetic valve 26 and sea water circulating pump 24 and cuts out, and 1 minute (also can be set as 2 minutes according to seawater temperature and flash tank size) rear PLC primary controller controls the first magnetic valve 13, the second magnetic valve 16 and vacuum pumping pump 31 and cuts out;
When recording the solar irradiance that seawater temperature in hot water storage tank 17 records lower than 60 ℃, Solar Total Irradiance Monitor, the second temperature sensor is less than 200W/m 2the envrionment temperature recorded with the first temperature sensor is during lower than 5 ℃, and the PLC primary controller controls compressor 4 and automatically cuts out.
The parcel such as pipeline, hot water storage tank and flash tank thermal insulation material, prevent the loss of heat.
The above; be only preferably embodiment of the present invention, but protection scope of the present invention is not limited to this, in the technical scope that any those of ordinary skill in the art disclose in the present invention; the variation that can expect easily or replacement, within all should being encompassed in the protection domain of this aspect.

Claims (10)

1. one kind from net type photovoltaic and photothermal coupling heat pump sea water desalinating plant, comprises direct expanding solar heating pump system, raw material water tank (18), hot water storage tank (17), flash tank (20) and primary controller;
Described direct expanding solar heating pump system comprises photovoltaic and photothermal vaporizer (12), and the outlet of photovoltaic and photothermal vaporizer (1) is connected with the entrance (11) of the second threeway (2), gas-liquid separator (3), compressor (4), condenser (5), reservoir (6), device for drying and filtering (7), liquid-sighting glass (8), throttling set (9), the first threeway (10), photovoltaic and photothermal vaporizer successively by pipeline; Solar Total Irradiance Monitor and the first temperature sensor be arranged on photovoltaic and photothermal vaporizer (12) the surface or near; The first threeway (10) is connected with the first magnetic valve (13), backheat vaporizer (14), condenser/evaporator (15), the second magnetic valve (16) and the second threeway (2) successively by pipeline; Condenser (5) is arranged at the inside of hot water storage tank (17); Be provided with refrigeration agent in described direct expanding solar heating pump system; Photovoltaic and photothermal vaporizer (12) is connected with controller (33), invertor (35) successively by circuit, and controller (33) is connected by circuit is two-way with store battery (34);
The outlet of raw material water tank (18) is connected with the entrance on hot water storage tank (17) top with the 3rd magnetic valve (19) successively by pipeline;
The top of hot water storage tank (17) is connected with the 4th magnetic valve (22), flash tank (20) successively by pipeline; Be provided with the second temperature sensor in hot water storage tank (17) inside;
Flash tank (20) bottom is connected with the first check valve (23), sea water circulating pump (24), the 3rd threeway (25) and hot water storage tank (17) bottom successively by pipeline; The 3rd threeway (25) is connected with the strong brine entrance (27) of the 5th magnetic valve (26), backheat vaporizer (14) successively by pipeline, and the strong brine outlet (28) of backheat vaporizer (14) is connected with the strong brine delivery pipe; Condenser/evaporator (15) is arranged on the inner top of flash tank (20), in condenser/evaporator (15) below, is provided with water-collecting tray (21); The top of described flash tank (20) is provided with product water outlet (32), product water outlet (32) is connected with water-collecting tray (21), product water outlet (32) is connected with the water-in on product water tank (29) top by pipeline, and the bottom of product water tank (29) is provided with the product water feed water inlet; The top of product water tank (29) is connected with the second check valve (30), vacuum pumping pump (31) successively by pipeline;
Described primary controller is electrically connected to the first magnetic valve (13), the second magnetic valve (16), the 3rd magnetic valve (19), the 4th magnetic valve (22), the 5th magnetic valve (26), sea water circulating pump (24), vacuum pumping pump (31), compressor (4), Solar Total Irradiance Monitor, the first temperature sensor, the second temperature sensor and invertor (35) respectively.
2. device according to claim 1 is characterized in that: described photovoltaic and photothermal vaporizer (12) is comprised of solar energy collector and the photovoltaic cell that is arranged on described solar energy collector surface.
3. device according to claim 2, is characterized in that: the flat plate collector that described solar energy collector is flat plate collector, cover plate or vacuum tube collector; Described photovoltaic cell is monocrystalline silicon battery, polycrystal silicon cell, amorphous silicon battery or hull cell.
4. device according to claim 1 is characterized in that: described flash tank (20) is body Flash Type flash tank or spray Flash Type flash tank; Described backheat vaporizer (14) is plate-type heat exchanger, tube and shell heat exchanger or double-pipe exchanger; Described condenser/evaporator (15) is straight tubular heat exchanger, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger; Described condenser (5) is straight tubular heat exchanger, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
5. device according to claim 1 is characterized in that: the bottom of described water-collecting tray (21) arranges catches the foam net.
6. a method of utilizing the described device of claim 1 to carry out sea water desaltination, comprise the steps:
When the photovoltaic cell surface shined upon on photovoltaic and photothermal vaporizer (12) is arranged, the electric energy that photovoltaic cell produces is by control accumulators (34) charging of controller (33), and store battery (34) provides electric energy by controller (33) and invertor (35) for sea water desaltination;
The solar irradiance recorded when Solar Total Irradiance Monitor is greater than 200W/m 2or first envrionment temperature that record of temperature sensor during higher than 5 ℃, primary controller is controlled compressor (4) and is automatically opened, refrigeration agent is subject to thermal evaporation in photovoltaic and photothermal vaporizer (12), becoming low-pressure gas flows out by the outlet (1) of photovoltaic and photothermal vaporizer, the second threeway (2) of flowing through arrives in gas-liquid separator (3) carries out gas-liquid separation, become after the compressed machine of low-pressure gas after separation (4) compression after high temperature and high pressure gas enters the middle release of condenser (5) the latent heat seawater interior to hot water storage tank (17) and become highly pressurised liquid, the highly pressurised liquid reservoir (6) of flowing through, device for drying and filtering (7) and liquid-sighting glass (8), become the saturated air of low-temp low-pressure and the mixture of saturated solution after throttling set (9) throttling, by the first threeway (10), entrance (11) through the photovoltaic and photothermal vaporizer is got back to photovoltaic and photothermal vaporizer (12), complete a circulation,
When the second temperature sensor records seawater temperature in hot water storage tank (17) higher than 60 ℃, primary controller is controlled vacuum pumping pump (31) and is opened, and the gas in flash tank (20) and product water tank (29) is discharged by the second check valve (30) and vacuum pumping pump (31); Form negative pressure in flash tank (20), 3-10 minute after vacuum pumping pump (31) is opened, the 4th magnetic valve (22) controlled by primary controller and sea water circulating pump (24) is opened, seawater in hot water storage tank (17) flow into flash tank (20) by pipeline through the 4th magnetic valve (22), and the strong brine after flash distillation is got back to hot water storage tank (17) by pipeline through the first check valve (23), sea water circulating pump (24), the 3rd threeway (25);
Seawater flash distillation in flash tank (20) forms water vapor, 1-2 minute after sea water circulating pump (24) is opened, primary controller is controlled the first magnetic valve (13), the second magnetic valve (16), the 3rd magnetic valve (19) and the 5th magnetic valve (26) and is opened, a strong brine part through the 3rd threeway (25) flows back to hot water storage tank (17), another part strong brine enters into backheat vaporizer (14) by pipeline through the 5th magnetic valve (26), strong brine entrance (27), and the strong brine after heat exchange is discharged from the strong brine delivery pipe through strong brine outlet (28); Refrigeration agent after throttling set (9) throttling is by the first threeway (10) part the first magnetic valve (13) of flowing through, in backheat vaporizer (14) with the strong brine heat exchange, after heat exchange, enter in condenser/evaporator (15), with the water vapor heat exchange, heat exchange is got back to the second threeway (2) by the second magnetic valve (16), the water droplet formed after water vapor condensation enters into product water tank (29) by the road by product water outlet (32) after being collected by water-collecting tray (21), and another part of refrigeration agent flow back into photovoltaic and photothermal vaporizer (12) by pipeline; Raw material water tank (18) is that hot water storage tank (17) is mended raw material seawater by the 3rd magnetic valve (19) by the road;
Seawater temperature in the second temperature sensor records hot water storage tank (17) is during lower than 60 ℃, primary controller controls the 3rd magnetic valve (19), the 4th magnetic valve (22), the 5th magnetic valve (26) and sea water circulating pump (24) and cuts out, 1-2 minute, primary controller controls the first magnetic valve (13), the second magnetic valve (16) and vacuum pumping pump (31) and cuts out;
When recording the solar irradiance that seawater temperature in hot water storage tank (17) records lower than 60 ℃, Solar Total Irradiance Monitor, the second temperature sensor is less than 200W/m 2the envrionment temperature recorded with the first temperature sensor is during lower than 5 ℃, and primary controller controls compressor (4) and automatically cuts out.
7. method according to claim 6 is characterized in that: described photovoltaic and photothermal vaporizer (12) is comprised of solar energy collector and the photovoltaic cell that is arranged on described solar energy collector surface.
8. method according to claim 7, is characterized in that: the flat plate collector that described solar energy collector is flat plate collector, cover plate or vacuum tube collector; Described photovoltaic cell is monocrystalline silicon battery, polycrystal silicon cell, amorphous silicon battery or hull cell.
9. method according to claim 6 is characterized in that: described flash tank (20) is body Flash Type flash tank or spray Flash Type flash tank; Described backheat vaporizer (14) is plate-type heat exchanger, tube and shell heat exchanger or double-pipe exchanger; Described condenser/evaporator (15) is straight tubular heat exchanger, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger; Described condenser (5) is straight tubular heat exchanger, coiled interchanger, U-shaped tubular heat exchanger, tube exchanger or spiral tube heat exchanger.
10. method according to claim 6 is characterized in that: the bottom of described water-collecting tray (21) arranges catches the foam net.
CN201310078443.8A 2013-03-12 2013-03-12 Seawater desalting device and method of off-grid type photovoltaic photo-thermal coupled heat pump Expired - Fee Related CN103172132B (en)

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CN106395950A (en) * 2016-10-31 2017-02-15 国家海洋局天津海水淡化与综合利用研究所 Sea water desalination method adopting low-temperature multi-effect distillation for producing fresh water through efficient use of heat energy
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