CN103168788A - Indoxacarb and dimilin insecticide composition - Google Patents
Indoxacarb and dimilin insecticide composition Download PDFInfo
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- CN103168788A CN103168788A CN2013100917270A CN201310091727A CN103168788A CN 103168788 A CN103168788 A CN 103168788A CN 2013100917270 A CN2013100917270 A CN 2013100917270A CN 201310091727 A CN201310091727 A CN 201310091727A CN 103168788 A CN103168788 A CN 103168788A
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- China
- Prior art keywords
- indoxacarb
- dimilin
- days
- medicine
- young urea
- Prior art date
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Links
- 239000005907 Indoxacarb Substances 0.000 title claims abstract description 70
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 title claims abstract description 70
- 239000002917 insecticide Substances 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 title claims abstract description 7
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000375 suspending agent Substances 0.000 claims abstract description 8
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 5
- 239000008187 granular material Substances 0.000 claims abstract description 4
- 238000009472 formulation Methods 0.000 claims abstract description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 43
- 239000004202 carbamide Substances 0.000 claims description 42
- 239000000843 powder Substances 0.000 claims description 15
- 238000009736 wetting Methods 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 13
- 241000238631 Hexapoda Species 0.000 abstract description 12
- 230000002195 synergetic effect Effects 0.000 abstract description 12
- 239000002270 dispersing agent Substances 0.000 abstract description 7
- 235000013311 vegetables Nutrition 0.000 abstract description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 abstract description 4
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000000575 pesticide Substances 0.000 abstract description 4
- 239000000945 filler Substances 0.000 abstract description 3
- 240000007594 Oryza sativa Species 0.000 abstract description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 2
- 244000061456 Solanum tuberosum Species 0.000 abstract description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract description 2
- 235000009566 rice Nutrition 0.000 abstract description 2
- 239000000080 wetting agent Substances 0.000 abstract description 2
- 240000007124 Brassica oleracea Species 0.000 abstract 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 abstract 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 abstract 1
- 244000141359 Malus pumila Species 0.000 abstract 1
- 235000021016 apples Nutrition 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 235000012015 potatoes Nutrition 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 39
- YPSCQJTUAKNUNF-UHFFFAOYSA-N 2-chloro-n-[(4-chlorophenyl)carbamoyl]benzamide Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl YPSCQJTUAKNUNF-UHFFFAOYSA-N 0.000 description 17
- 239000002131 composite material Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- -1 fatty acid salts Chemical class 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000007900 aqueous suspension Substances 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 235000018927 edible plant Nutrition 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- XYFMGGWVGACNEC-UHFFFAOYSA-N n-carbamoyl-n-phenylbenzamide Chemical compound C=1C=CC=CC=1N(C(=O)N)C(=O)C1=CC=CC=C1 XYFMGGWVGACNEC-UHFFFAOYSA-N 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 238000005507 spraying Methods 0.000 description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 9
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 241000985245 Spodoptera litura Species 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 4
- 229920002101 Chitin Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 244000068988 Glycine max Species 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- 241000255969 Pieris brassicae Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 description 4
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 4
- 210000003491 skin Anatomy 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 238000001238 wet grinding Methods 0.000 description 4
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- 241001674939 Caulanthus Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 3
- 241000256247 Spodoptera exigua Species 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 2
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 2
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000201 insect hormone Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 241001046947 Ectropis obliqua Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241001531327 Hyphantria cunea Species 0.000 description 1
- 241001325860 Lacanobia oleracea Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 102000003960 Ligases Human genes 0.000 description 1
- 108090000364 Ligases Proteins 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241001581015 Lyonetia clerkella Species 0.000 description 1
- 241000409991 Mythimna separata Species 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 108010052164 Sodium Channels Proteins 0.000 description 1
- 102000018674 Sodium Channels Human genes 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- MVPPADPHJFYWMZ-IDEBNGHGSA-N chlorobenzene Chemical group Cl[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 MVPPADPHJFYWMZ-IDEBNGHGSA-N 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 239000005515 coenzyme Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000013020 embryo development Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 230000000422 nocturnal effect Effects 0.000 description 1
- 239000002777 nucleoside Substances 0.000 description 1
- 125000003835 nucleoside group Chemical group 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000026267 regulation of growth Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of pesticide, and relates to pesticide combination technology. The invention relates to an indoxacarb and dimilin insecticide composition; the weight ratio between indoxacarb and dimilin is within the range of 1: 1-1: 10; and the weight percent of the indoxacarb to the dimilin is within the range of 20-80%. The indoxacarb and dimilin insecticide composition can be processed into formulations such as suspending agent, wettable powder, granules and water dispersible granules; and in the binary complex, the auxiliary component comprises acceptable dispersing agent, wetting agent, penetrating agent, filler and the like. The composition is used for controlling multiple insect pests on vegetables and crops such as cabbages, apples, rice, brassicaceous vegetables, cotton, potatoes and the like by compounding, and is remarkable in synergistic effect.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the agriculture chemical compounding technology, particularly the binary built technology take indoxacarb as active component.
Background technology
Indoxacarb:
Chemical name: 7-chloro-2,3,4a, 5-tetrahydrochysene-2-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester molecular formula: C
22H
17ClF
3N
3O
7
Relative molecular weight: 527.83;
Structural formula:
Young urea goes out:
Trade name: mieyotmiao No.3, flutter that moth pellet, moth kill spirit, strength is killed the children
The adjacent chlorobenzene formacyl of chemical name: 1-()-3-(4-chlorphenyl) urea;
Molecular weight: 308.0;
Molecular structural formula: C
14H
10N
2C
l2O
2
Fusing point: 199 ℃-201 ℃;
Structural formula:
Indoxacarb as a kind of brand-new insecticide, is mainly the sodium channel in blocking-up insect nerve cell, causes target pest to coordinate poor, paralysis, and is final dead.Medicament enters polypide by tagging and ingesting, and the behavior of insect changes rapidly, causes insect to stop rapidly ingesting, thus fabulous protection the target crop.Test shows with other insecticide without cross resistance.The young urea that goes out is on-steroidal Novel insect growth regulation type, is the insect hormone insecticides of up-to-date research and development.The young urea that goes out belongs to the benzoyl area kind Chitin synthesis inhibitor, is insect hormone.By suppressing the activity of insect cuticle chitin synthetase and urine nucleosides coenzyme, thereby suppress that insect chitin is synthetic causes insect normally not cast off a skin and dead.Affect respiratory metabolism and the DNA in embryo development procedure and the proteometabolism of ovum, make larva shortage chitin in ovum and death immediately after can not hatching or hatch; Use in larval phase, the new epidermis of insect is formed be obstructed, delayed development, or lack hardness can not normally be casted off a skin and caused death or form lopsided pupa dead.Abnormal insect, particularly lepidopterous larvae are shown as good insecticidal activity.Main manifestations is stomach poison function.Lepidopterous larvae is shown as good insecticidal activity.Almost harmless to the hymenopterans such as beneficial insect and honeybee and Forest birds.But influential to oophagous trichogrammae.Such medicament is used for the lepidoptera pests such as control peach leaf miner, the black poison moth of tea, tea geometrid, cabbage caterpillar, tomato moth, wheat mythimna separata, corn borer and poison moth class, nocturnal moth class by large tracts of land.Simultaneously, also find with No. 3 1000 times of liquid pouring green onions of young urea of going out, garlic kind of vegetable roots section, can effectively kill maggot; Larvae to control lavatory fly maggot, stagnant water gulf also has special efficacy.They are all single dose uses or mixed with other products, cause the generation of resistance due to every factor, and control efficiency is undesirable; Indoxacarb and the composite rear desinsection of young urea that goes out are general wider, and activity is higher.More being conducive to alleviate present Irrational Use of Drugs causes resistance to promote very fast problem.
Summary of the invention
The object of the present invention is to provide a kind of indoxacarb and the young urea that goes out is the composite a kind of binary desinsection compound that forms of main active ingredient.
The object of the present invention is achieved like this, characteristic based on indoxacarb and the young urea that goes out is further studied, and finds and proves take indoxacarb and go out young urea as being mixed that effective ingredient is carried out, and can produce obvious synergistic effect, and enlarged the control spectrum, reduced use cost.
The indoxacarb that the present invention relates to and the young urea insecticides that goes out, indoxacarb and go out young urea weight ratio between 1:1～1:10, weight percent content is between 20～80%.
The indoxacarb that the present invention relates to and the young urea insecticides that goes out, indoxacarb and go out young urea weight ratio between 1:2～1:6, weight percent content is between 20～80%.
The indoxacarb that the present invention relates to and the young urea insecticides that goes out, formulation are a kind of in wetting powder, suspending agent, granule, water-dispersible granules.
The indoxacarb that the present invention relates to and the young urea insecticides that goes out, auxiliary element comprises acceptable dispersant, wetting agent, bleeding agent, filler etc.; Surfactant has anion surfactant, the fatty acid salts such as alkylbenzenesulfonate, lignin sulfonate, alkyl sulfate, Alkyl ethoxy carboxylate acid salt also have one or more in phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, sulfonate and formaldehyde condensation product etc.; Cationic surfactant has amine salt, quaternary amine, amine oxide etc.; Amphoteric surfactant has one or more in betain, imidazoline type, Amino acid, phosphine ester etc.; Non-ionic surface active agent has the alkoxides such as fatty alcohol ether, alkyl phenol ether, alkyl ether amine, polyethers; Also have the aliphatic alcohol esters such as glyceride, polyol ester; Also have fatty acid alkane ester, alkylamide etc.; The mixed surfactant that also has alcohol ether type.Other auxiliary element is drawn together xanthans, the thickeners such as sodium carboxymethyl starch, the antifreezing agents such as ethylene glycol, glycerine, urea; The fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and one or more in the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.
the concrete dosage form of Recompounded pesticide of the present invention, can indoxacarb and the young urea that goes out be main active ingredient from above-mentioned listed each auxiliary element in one or several be mixed with according to a conventional method different preparations, can be mixed with the wetting powder of different content, suspending agent, granule, water-dispersible granules etc., be used for preventing and treating wild cabbage, apple, paddy rice, brassicaceous vegetable, cotton, various pests on the vegetables such as potato and crop, as: diamond-back moth, beet armyworm, cabbage caterpillar, prodenia litura, striped rice borer, paddy stem borer, cotton bollworm, the various plants insects such as fall webworm, have efficient, low toxicity, low-residual, insecticidal spectrum is wide, synergistic effect significantly and reduce the characteristics such as use cost, its high efficiency particularly, low toxicity, low-residual, be particularly advantageous in the production of pollution-free food.
Four, embodiment
Below in conjunction with embodiment, the technical scheme that invention relates to is further illustrated, in order to help understanding of the present invention, but not as the restriction to technical scheme, except mentioning especially, component ratio is part by weight.
Embodiment one
20% indoxacarb Chlorbenzuron deflocculant
Raw material consists of: the 10% former medicine of indoxacarb, and 10% benzoylphenyl urea original medicine, 1.2% pulls open powder, 1% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% calcium dodecyl benzene sulfonate, 2.5% triphen ethyl-phenol APEO, phenethyl phenol mela mine-formaldehyde resin APEO 1%, 1.2% white carbon, aluminium-magnesium silicate 1.5%, 0.15% xanthans, 5% glycerine, all the other waters are supplied, suspending agent mode of production preparation routinely.
This embodiment is used for control wild cabbage diamond-back moth, and 1500 times of 20% indoxacarb Chlorbenzuron deflocculants are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 88.9% and 95.7%.600 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 78.9%, 79.5% and 88.8% and 90.1%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of wild cabbage diamond-back moth is better than single dose.
Embodiment two
30% indoxacarb Chlorbenzuron deflocculant
Raw material consists of: the 10% former medicine of indoxacarb, and 20% benzoylphenyl urea original medicine, 1.2% pulls open powder, 1% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% calcium dodecyl benzene sulfonate, 2.5% triphen ethyl-phenol APEO, phenethyl phenol mela mine-formaldehyde resin APEO 1%, 1% white carbon, aluminium-magnesium silicate 1.5%, 0.12% xanthans, 5% glycerine, all the other waters are supplied, suspending agent mode of production preparation routinely.
This embodiment is used for preventing and treating large greenish brown hawk moth, and 1500 times of 30% indoxacarb Chlorbenzuron deflocculants are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 87.8% and 94.9%.600 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 79.5%, 77.7% and 89.1% and 90.3%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of large greenish brown hawk moth is better than single dose.
Embodiment three
36% indoxacarb Chlorbenzuron deflocculant
Raw material consists of: the 9% former medicine of indoxacarb, and 27% benzoylphenyl urea original medicine, 1.2% pulls open powder, 1% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% calcium dodecyl benzene sulfonate, 2.5% triphen ethyl-phenol APEO, phenethyl phenol mela mine-formaldehyde resin APEO 1%, 0.8% white carbon, aluminium-magnesium silicate 1.2%, 0.12% xanthans, 5% glycerine, all the other waters are supplied, suspending agent mode of production preparation routinely.
This embodiment is used for control peanut prodenia litura, and 1500 times of 36% indoxacarb Chlorbenzuron deflocculants are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 89.1% and 96.9%.800 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 76.1%, 78.9% and 85.7% and 86.3%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of peanut prodenia litura is better than single dose.
Embodiment four
The 50% indoxacarb young urea wetting powder that goes out
Raw material consists of the 10% former medicine of indoxacarb, 40% benzoylphenyl urea original medicine, and 10% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% polycarboxylate salt dispersant, 2% lauryl sodium sulfate, 6% calcium lignosulfonate, all the other are supplied with kaolin.But wet-milling mode of production preparation routinely.
This embodiment is used for control soybean bridging worm, and go out 2000 times of young urea wetting powders of 50% indoxacarb are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 90.1% and 96.7%.800 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 81.5%, 79.9% and 87.5% and 88.9%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of soybean bridging worm is better than single dose.
Embodiment five
24% indoxacarb Chlorbenzuron deflocculant
Raw material consists of: the 4% former medicine of indoxacarb, and 20% benzoylphenyl urea original medicine, 1.2% pulls open powder, 1% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% calcium dodecyl benzene sulfonate, 2.5% triphen ethyl-phenol APEO, phenethyl phenol mela mine-formaldehyde resin APEO 1%, 1% white carbon, aluminium-magnesium silicate 1.5%, 0.15% xanthans, 5% glycerine, all the other waters are supplied, suspending agent mode of production preparation routinely.
This embodiment is used for the control of maize prodenia litura, and 1000 times of 24% indoxacarb Chlorbenzuron deflocculants are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 88.7% and 94.8%.800 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 76.8%, 78.4% and 84.6% and 85.9%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of corn prodenia litura is better than single dose.
Embodiment six
The 70% indoxacarb young urea wetting powder that goes out
Raw material consists of the 10% former medicine of indoxacarb, 60% benzoylphenyl urea original medicine, and 10% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% polycarboxylate salt dispersant, 3% lauryl sodium sulfate, 5% calcium lignosulfonate, all the other are supplied with kaolin.But wet-milling mode of production preparation routinely.
This embodiment is used for control cotton cotton bollworm, and go out 2000 times of young urea wetting powders of 70% indoxacarb are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 87.1% and 94.2%.800 times of 20% 600 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 76.1%, 77.5% and 82.4% and 84.5%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of cotton cotton bollworm is better than single dose.
Embodiment seven
The 54% indoxacarb young urea wetting powder that goes out
Raw material forms: the 6% former medicine of indoxacarb, 48% benzoylphenyl urea original medicine; 8% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% polycarboxylate salt dispersant, 2% lauryl sodium sulfate, 10% calcium lignosulfonate, all the other are supplied with kaolin.But wet-milling mode of production preparation routinely.
This embodiment is used for control Chinese cabbage cabbage caterpillar, and go out 2000 times of young urea wetting powders of 54% indoxacarb are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 91.7% and 96.8%.1000 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 80.3%, 81.7% and 90.1% and 92.2%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of Chinese cabbage cabbage caterpillar is better than single dose.
Embodiment eight
The 80% indoxacarb young urea wetting powder that goes out
Raw material consists of the 8% former medicine of indoxacarb, 72% benzoylphenyl urea original medicine, and 8% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% polycarboxylate salt dispersant, 2% lauryl sodium sulfate, 4% calcium lignosulfonate, all the other are supplied with kaolin.But wet-milling mode of production preparation routinely.
This embodiment is used for the control apple skin worm, and go out 3000 times of young urea wetting powders of 80% indoxacarb are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 89.8% and 94.6%.800 times of 20% 800 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 80.2%, 78.6% and 85.3% and 85.5%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of apple skin worm is better than single dose.
Embodiment nine
The 66% indoxacarb young urea WDG that goes out
Raw material forms: the 6% former medicine of indoxacarb, 60% benzoylphenyl urea original medicine; 1% calcium dodecyl benzene sulfonate, 5% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 3% naphthalenesulfonate formaldehyde condensation compound, 5% polycarboxylate salt dispersant, 10% sodium carboxymethyl starch, all the other are supplied with ammonium sulfate, and the extruder grain mode is prepared routinely.
This embodiment is used for control soybean beet armyworm, and go out 2000 times of young urea water-dispersible granules of 66% indoxacarb are watered the dilution spraying, and after medicine, the control efficiency of 7 days and 15 days is respectively 90.1% and 95.9%.600 times of 20% 600 times of Chlorbenzuron deflocculants and 5% indoxacarb aqueous suspension agents, the use that uses the same method, after medicine, the preventive effect of 7 days and 15 days is respectively 77.2%, 80.6% and 82.3% and 86.5%; The composite rear synergistic effect of young urea and indoxacarb of going out is obvious, and the control efficiency of soybean beet armyworm is better than single dose.
Claims (3)
1. a described indoxacarb and the young urea insecticides that goes out, indoxacarb and go out young urea weight ratio between 1:1～1:10, weight percent content is between 20～80%.
2. indoxacarb according to claim 1 and the young urea insecticides that goes out, indoxacarb and go out young urea weight ratio between 1:2～1:6, weight percent content is between 20～80%.
3. indoxacarb according to claim 1 and the young urea insecticides that goes out, formulation are a kind of in wetting powder, suspending agent, granule, water-dispersible granules.
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| CN2013100917270A CN103168788A (en) | 2013-03-21 | 2013-03-21 | Indoxacarb and dimilin insecticide composition |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6232489B1 (en) * | 1994-04-20 | 2001-05-15 | E. I. Du Pont De Nemours And Company | Preparation of arthropodicidal oxadiazines |
| CN101480191A (en) * | 2009-02-13 | 2009-07-15 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6232489B1 (en) * | 1994-04-20 | 2001-05-15 | E. I. Du Pont De Nemours And Company | Preparation of arthropodicidal oxadiazines |
| CN101480191A (en) * | 2009-02-13 | 2009-07-15 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
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Application publication date: 20130626 |