CN103161095A - Antistatic and photodegradable environment-friendly synthetic paper - Google Patents
Antistatic and photodegradable environment-friendly synthetic paper Download PDFInfo
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- CN103161095A CN103161095A CN 201110406968 CN201110406968A CN103161095A CN 103161095 A CN103161095 A CN 103161095A CN 201110406968 CN201110406968 CN 201110406968 CN 201110406968 A CN201110406968 A CN 201110406968A CN 103161095 A CN103161095 A CN 103161095A
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Abstract
The invention discloses an antistatic and photodegradable environment-friendly synthetic paper, and belongs to the technical field of functional high-polymer materials. The antistatic and photodegradable environment-friendly synthetic paper comprises the components in the following proportioning ratios by mass: 100-130 parts of modified high-polymer resin, 20-30 parts of starch filler, 10-20 parts of wood fibres, 5-15 parts of superfine calcium carbonate, 2-5 parts of phenol antioxidant, 1-4 parts of silane coupling agent, 0.5-3 parts of acrylic toughening agent, 1-2 parts of aliphatic amide lubricant, and 10-15 parts of the mixture of nano-silica and titanium dioxide. The synthetic paper disclosed by the invention is high in tensile resistance, water resistance and heat resistance, capable of effectively preventing the generation of static electricity during a printing process and a binding process, photodegradable, and free from generating substances harm to environment after being degraded.
Description
Technical field
The present invention relates to antistatic light degradation environmental protection synthetic paper, belong to the functional high molecule material technical field.
Background technology
Synthetic paper, it is emerging in recent years a kind of material, to utilize chemical raw material such as olefines to add again some additives to be made, have the quality softness, stretching resistance is strong, WATER RESISTANCE is high, fast light cold-hot, and can resist the corrosion of chemical substance, is widely used in the printing of the senior art work, map, picture album, high-grade books and periodicals etc.China's synthetic paper is started late, and market development is inadequate, and domestic only have several enterprises to produce, second-rate, also unstable, and present annual consumption is ten thousand tons of 3-4, is mainly import, and basic is the PP synthetic paper entirely.The history of external existing three more than ten years, development is very fast, and quality is better.Although synthetic paper has plurality of advantages, and development in recent years is swift and violent, but undeniable is the shortcoming that synthetic paper also has self, it is because synthetic paper itself is exactly some characteristics with plastics, to be difficult for degraded be distinct issues to plastics, now white plastic pollute allowed a lot of people with attention mobility on this problem of degraded, and synthetic paper is as the subject that has just risen in recent years, the recycling of synthetic paper or be degraded into the focus of present research.
Summary of the invention
Defective in view of prior art exists the purpose of this invention is to provide a kind of other advantages that not only have synthetic paper, and antistatic and carry out not producing after light degradation antistatic light degradation environmental protection synthetic paper to environmentally hazardous substance.
for achieving the above object, the technology used in the present invention solution is: antistatic light degradation environmental protection synthetic paper, comprise the modified high-molecular resin, starch fillers, wood fibre, calcium carbonate superfine powder, phenol antioxidant, silane coupler, esters of acrylic acid flexibilizer, the aliphatic amide series lubricant agent, the mixture of nano silicon and titanium dioxide, wherein each component is 100 ~ 130 parts of modified high-molecular resins by the quality proportioning, 20 ~ 30 parts of starch fillers, 10 ~ 20 parts of wood fibres, 5 ~ 15 parts of calcium carbonate superfine powders, 2 ~ 5 parts of phenol antioxidant, 1 ~ 4 part of silane coupler, 0.5 ~ 3 part of esters of acrylic acid flexibilizer, 1 ~ 2 part of aliphatic amide series lubricant agent, 10 ~ 15 parts, the mixture of nano silicon and titanium dioxide.
A kind of in polyethylene, polypropylene, polystyrene, polyvinyl chloride and polyethylene terephthalate that described modified high-molecular resin is the carbon nano modification.
Described starch fillers is ultra-fine Oxidized Starch Filler.
Described wood fibre is bamboo and arbor fiber.
Described phenol antioxidant is a kind of in three grades of butyl of 2,6--4-methylphenol, two (three grades of butyl of 3,5--4-hydroxy phenyl) thioether.
Described silane coupler is APTES, γ-glycidyl ether oxygen propyl trimethoxy silicane, N-(β one aminoethyl)-a kind of in γ-aminopropyl front three (second) TMOS.
Described esters of acrylic acid flexibilizer is methyl methacrylate-ethyl acrylate high polymer.
Described aliphatic amide series lubricant agent is a kind of in dimethyl formamide and para Toluic Acid's acetamide.
In the mixture of described nano silicon and titanium dioxide, proportioning is 5:2.
The synthetic paper of gained of the present invention not only has higher stretching resistance, WATER RESISTANCE and heat resistance, has effectively prevented the generation of static simultaneously in printing process and forwarding, can carry out light degradation simultaneously, can not produce environmentally harmful material after degraded.
The specific embodiment
Embodiment 1
Antistatic light degradation environmental protection synthetic paper, comprise 5 parts of 100 parts of the polyvinyl resins of carbon nano modification, 20 parts of ultra-fine Oxidized Starch Fillers, 10 parts of willow fibers, calcium carbonate superfine powder, 2,10 parts, the mixture of three grades of butyl of 6--2 parts of 4-methylphenol antioxidants, 1 ~ 4 part of APTES coupling agent, methyl methacrylate-0.5 part of ethyl acrylate high polymer flexibilizer, 1 part of dimethyl formamide lubricant, nano silicon and titanium dioxide, the made synthetic paper of this formula can be used for wall advertisement.
Embodiment 2
antistatic light degradation environmental protection synthetic paper, 120 parts of acrylic resins that comprise the carbon nano modification, 25 parts of ultra-fine Oxidized Starch Fillers, 15 parts of willow fibers, 10 parts of calcium carbonate superfine powders, two (3, three grades of butyl of 5--4-hydroxy phenyl) the thioether antioxidant is 4 parts, γ-3 parts of glycidyl ether oxygen propyl trimethoxy silicane coupling agents, methyl methacrylate-1.5 parts of ethyl acrylate high polymer flexibilizer, 1.5 parts of para Toluic Acid's acetamide lubricants, 12 parts, the mixture of nano silicon and titanium dioxide, this made synthetic paper toughness of filling a prescription is larger, intensity is also larger, be suitable for map, picture album and billboard.
Embodiment 3
antistatic light degradation environmental protection synthetic paper, 130 parts of polystyrene resins that comprise the carbon nano modification, 30 parts of ultra-fine Oxidized Starch Fillers, 20 parts of bamboo fibers, 15 parts of calcium carbonate superfine powders, 2, three grades of butyl of 6--5 parts of 4-methylphenols, N-(β one aminoethyl)-γ-4 parts of aminopropyl front three (second) TMOS coupling agents, methyl methacrylate-2 parts of ethyl acrylate high polymer flexibilizer, 2 parts of para Toluic Acid's acetamide lubricants, 15 parts, the mixture of nano silicon and titanium dioxide, this made synthetic paper toughness of filling a prescription is large, intensity is high, can in all case use.
Claims (9)
1. antistatic light degradation environmental protection synthetic paper, it is characterized in that comprising the modified high-molecular resin, starch fillers, wood fibre, calcium carbonate superfine powder, phenol antioxidant, silane coupler, esters of acrylic acid flexibilizer, the aliphatic amide series lubricant agent, wherein each component is 100 ~ 130 parts of modified high-molecular resins by the quality proportioning, 20 ~ 30 parts of starch fillers, 10 ~ 20 parts of wood fibres, 5 ~ 15 parts of calcium carbonate superfine powders, 2 ~ 5 parts of phenol antioxidant, 1 ~ 4 part of silane coupler, 0.5 ~ 3 part of esters of acrylic acid flexibilizer, 1 ~ 2 part of aliphatic amide series lubricant agent, 10 ~ 15 parts, the mixture of nano silicon and titanium dioxide.
2. antistatic light degradation environmental protection synthetic paper according to claim 1 is characterized in that described modified high-molecular resin is a kind of in the polyethylene of carbon nano modification, polypropylene, polystyrene, polyvinyl chloride and polyethylene terephthalate.
3. antistatic light degradation environmental protection synthetic paper according to claim 1, is characterized in that described starch fillers is ultra-fine Oxidized Starch Filler.
4. antistatic light degradation environmental protection synthetic paper according to claim 1, is characterized in that described wood fibre is bamboo and arbor fiber.
5. antistatic light degradation environmental protection synthetic paper according to claim 1 is characterized in that described phenol antioxidant is a kind of in three grades of butyl of 2,6--4-methylphenol, two (three grades of butyl of 3,5--4-hydroxy phenyl) thioether.
6. antistatic light degradation environmental protection synthetic paper according to claim 1, is characterized in that described silane coupler is APTES, γ-glycidyl ether oxygen propyl trimethoxy silicane, N-(β one aminoethyl)-a kind of in γ-aminopropyl front three (second) TMOS.
7. antistatic light degradation environmental protection synthetic paper according to claim 1, is characterized in that described esters of acrylic acid flexibilizer is methyl methacrylate-ethyl acrylate high polymer.
8. antistatic light degradation environmental protection synthetic paper according to claim 1 is characterized in that described aliphatic amide series lubricant agent is a kind of in dimethyl formamide and para Toluic Acid's acetamide.
9. antistatic light degradation environmental protection synthetic paper according to claim 1 is characterized in that in the mixture of described nano silicon and titanium dioxide, proportioning is 5:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110406968 CN103161095A (en) | 2011-12-09 | 2011-12-09 | Antistatic and photodegradable environment-friendly synthetic paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110406968 CN103161095A (en) | 2011-12-09 | 2011-12-09 | Antistatic and photodegradable environment-friendly synthetic paper |
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| CN103161095A true CN103161095A (en) | 2013-06-19 |
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| CN 201110406968 Pending CN103161095A (en) | 2011-12-09 | 2011-12-09 | Antistatic and photodegradable environment-friendly synthetic paper |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603070A (en) * | 2017-10-16 | 2018-01-19 | 河北凯成包装股份有限公司 | The processing technology of Polymer Synthesizing paper |
| CN109263080A (en) * | 2018-08-30 | 2019-01-25 | 杨仲辉 | With the artificial composite synthetic paper and preparation method for improving printing performance |
-
2011
- 2011-12-09 CN CN 201110406968 patent/CN103161095A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603070A (en) * | 2017-10-16 | 2018-01-19 | 河北凯成包装股份有限公司 | The processing technology of Polymer Synthesizing paper |
| CN109263080A (en) * | 2018-08-30 | 2019-01-25 | 杨仲辉 | With the artificial composite synthetic paper and preparation method for improving printing performance |
| CN109263080B (en) * | 2018-08-30 | 2022-01-07 | 湖北金三峡印务有限公司 | Artificial composite synthetic paper with improved printing performance and preparation method thereof |
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Application publication date: 20130619 |