CN103151568A - Battery repairing method - Google Patents

Battery repairing method Download PDF

Info

Publication number
CN103151568A
CN103151568A CN2013100834583A CN201310083458A CN103151568A CN 103151568 A CN103151568 A CN 103151568A CN 2013100834583 A CN2013100834583 A CN 2013100834583A CN 201310083458 A CN201310083458 A CN 201310083458A CN 103151568 A CN103151568 A CN 103151568A
Authority
CN
China
Prior art keywords
storage battery
battery
liquid
charging
electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013100834583A
Other languages
Chinese (zh)
Inventor
方亚琴
蒋菊生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN2013100834583A priority Critical patent/CN103151568A/en
Priority to CN201310228011.0A priority patent/CN103311588B/en
Priority to CN201410774862.XA priority patent/CN104409786B/en
Priority to CN201410774812.1A priority patent/CN104485487B/en
Publication of CN103151568A publication Critical patent/CN103151568A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/446Initial charging measures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/443Methods for charging or discharging in response to temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Filling, Topping-Up Batteries (AREA)

Abstract

The invention belongs to the technical field of batteries and particularly relates to a battery repairing method. The battery repairing method is characterized by comprising the steps of: initial charging, treating the original electrolyte, adding repairing liquid, recovering charging, adding electrolyte, charging and the like. The battery repairing method mainly solves the problem of repairing waste batteries. The battery repairing method has the main beneficial effects of convenience in battery recovery, high success rate, small input, quickness of effect realization, environmental protection, and sustainable development.

Description

A kind of battery restorative procedure
Technical field
The invention belongs to the battery technology field, especially relate to the recovery technique of a kind of automobile, motorcycle, battery vehicle, electric vehicle battery.
Background technology
Along with the development of new energy technology, battery vehicle, electric motor car, motorcycle and electric automobile promote the popularization use day by day.Yet using can not charge because of the lead sulfate salinization after 1~2 year, scraps by the storage battery that assembles on this class car.Owing to containing poisonous and hazardous element and heavy metal compound in useless battery, can cause great pollution for environment, for this reason, reclaiming or repair battery becomes the problem that Social Expectation solves.
Summary of the invention
In order to address the above problem, the present invention discloses a kind of battery restorative procedure, and it can realize the regeneration of most of battery, can economize on resources widely, makes environment safer, and the present invention realizes by the following technical solutions.
A kind of battery restorative procedure is characterized in that it includes following steps:
The first step: initial charge: first get the storage battery that to repair, again the nut on storage battery is all backed out, then storage battery is placed on the place of ventilation and the flames of anger, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post and fluid injection aperture at any time, when in the time of in temperature rises to 40 ℃~45 ℃ scopes or fluid injection aperture steams bubble, stop immediately charging;
Second step: process original electrolyte: adopt the cooling or air-cooled mode of nature to make storage battery cooling, when electrolysis temperature in storage battery is down to 20 ℃, electrolyte and the presumable sediment of bottom of storage battery are poured out together, then recover accumulator positive facing up;
The 3rd step: add recovery liquid: will recover liquid and join in storage battery, addition is as the criterion to flood battery polar plate, adds to recover to soak 6-12 hour after liquid;
The 4th step: recover charging: the place that is placed on ventilation and the flames of anger for the storage battery in the 3rd step, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post at any time, in the time of in temperature rises to 30 ℃~40 ℃ scopes, stop immediately charging; Then the battery filling-hole nut is tightened again, storage battery is sidelong on the ground, with hand hammer tapped bottom, the lead powder that comes off in the bottom is sunk to a side, then storage battery was fallen, beat the side that lead powder sinks, lead powder is sunk to the liquid injection hole direction; Then turning on nut will recover liquid and all be poured in clean plastic containers again;
The 5th step: repeatedly the 3rd to the 4th step, until in the recovery liquid of pouring out, naked eyes do not see that any solid impurity is arranged, obtained the initial storage battery of repairing;
The 6th step: add electrolyte and charging: adding commercially available density in the initial storage battery of the reparation that obtains in going on foot the 5th is 1.25~1.3g/cm 3Electrolyte; Be added to exceed baffle 10~15cm till; Then, adopt normal battery charger to charge, charge parameter arranges according to the original parameter of storage battery, charge and stop charging after 5-8 hour, the liquid injection hole nut is tightened, measuring battery voltage with storage battery Special pressure measuring table after to charging, when the pressure gauge pointer reaches the nominal value of battery tension, the explanation electric weight is sufficient, has obtained the storage battery of repairing.
A kind of battery restorative procedure described above, the power that it is characterized in that the high-power charger described in the first step are 60 watts~1000 watts; Charging current is 5 amperes~40 amperes, and charging voltage is 12 volts~25 volts.
A kind of battery restorative procedure described above is characterized in that the recovery liquid described in the 3rd step, is that 70%~85% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and form by commercially available concentration; Wherein, 70%~85% the concentrated sulfuric acid and the volume ratio of distilled water are 1:14~1:11, in mass ratio, and sodium sulphate: (70%~85% the concentrated sulfuric acid and distilled water)=(1:390)~(1:210); The density of described recovery liquid is 1.05~1.15g/cm 3
A kind of battery restorative procedure described above is characterized in that described recovery liquid, is that 75% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and form by commercially available concentration; Wherein, 75% the concentrated sulfuric acid and the volume ratio of distilled water are 1:12, in mass ratio, and sodium sulphate: (75% the concentrated sulfuric acid and distilled water)=1:275; The density of described recovery liquid is 1.1g/cm 3
Adopt method of the present invention to repair battery, only need to use several industrial chemicals of easily purchasing to be made into recovery liquid, can repair the old and useless battery more than 95%, repair 4~10 yuan of the cost of material of a battery that is worth 400 yuan of left and right, and, prove through a large amount of uses after reparation, can continue at least to use 2 years; Therefore the cost of repairing is relatively very low, and market is very huge.
In addition, only need during reparation that nonmetal resistance to acid attack container is some, resistance to acid attack rubber gloves, hand hammer, glass bar, handsaw, measuring cup, graduated cylinder are some, funnel, thermometer, balance, battery Special pressure measuring table, large power high efficiency quick charger, motorcycle electric electrolytic battery charger, etc. equipment, fund input is relatively seldom.
In addition, the poisonous and harmful substance that contains in the recovery liquid of pouring out in the 4th step can be processed by centralized recovery, and is more effective for environmental protection; Carry out separately adding sodium sulphate and distilled water after impurity separates for the recovery liquid that obtains, transfer to density and be; 1.05~1.15g/cm 3In time, recycle, and effectively saved resource.
Therefore, the present invention has following main beneficial effect: battery recovery is convenient, and success rate is high, less investment, instant effect, more environmental protection, more sustainable development.
Embodiment
For the public is had a better understanding for the present invention, now elaborate for execution mode.
Embodiment 1
A kind of battery restorative procedure is characterized in that it includes following steps:
The first step: initial charge: first get the storage battery that to repair, again the nut on storage battery is all backed out, then storage battery is placed on the place of ventilation and the flames of anger, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post and fluid injection aperture at any time, when in the time of in temperature rises to 40 ℃~45 ℃ scopes or fluid injection aperture steams bubble, stop immediately charging; The power of described high-power charger is 60 watts~1000 watts; Charging current is 5 amperes~40 amperes, and charging voltage is 12 volts~25 volts;
Second step: process original electrolyte: adopt the cooling or air-cooled mode of nature to make storage battery cooling, when electrolysis temperature in storage battery is down to 20 ℃, electrolyte and the presumable sediment of bottom of storage battery are poured out together, then recover accumulator positive facing up;
The 3rd step: add recovery liquid: will recover liquid and join in storage battery, addition is as the criterion to flood battery polar plate, adds to recover to soak 6-12 hour after liquid; Described recovery liquid is that 75% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and form by commercially available concentration; Wherein, 75% the concentrated sulfuric acid and the volume ratio of distilled water are 1:12, in mass ratio, and sodium sulphate: (75% the concentrated sulfuric acid and distilled water)=1:275; The density of described recovery liquid is 1.1g/cm 3
The 4th step: recover charging: the place that is placed on ventilation and the flames of anger for the storage battery in the 3rd step, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post at any time, in the time of in temperature rises to 30 ℃~40 ℃ scopes, stop immediately charging; Then the battery filling-hole nut is tightened again, storage battery is sidelong on the ground, with hand hammer tapped bottom, the lead powder that comes off in the bottom is sunk to a side, then storage battery was fallen, beat the side that lead powder sinks, lead powder is sunk to the liquid injection hole direction; Then turning on nut will recover liquid and all be poured in clean plastic containers again;
The 5th step: repeatedly the 3rd to the 4th step, until in the recovery liquid of pouring out, naked eyes do not see that any solid impurity is arranged, obtained the initial storage battery of repairing;
The 6th step: add electrolyte and charging: adding commercially available density in the initial storage battery of the reparation that obtains in going on foot the 5th is 1.25~1.3g/cm 3Electrolyte; Be added to exceed baffle 10~15cm till; Then, adopt normal battery charger to charge, charge parameter arranges according to the original parameter of storage battery, charge and stop charging after 5-8 hour, the liquid injection hole nut is tightened, measuring battery voltage with storage battery Special pressure measuring table after to charging, when the pressure gauge pointer reaches the nominal value of battery tension, the explanation electric weight is sufficient, has obtained the storage battery of repairing.
Embodiment 2
A kind of battery restorative procedure is characterized in that it includes following steps:
The first step: initial charge: first get the storage battery that to repair, again the nut on storage battery is all backed out, then storage battery is placed on the place of ventilation and the flames of anger, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post and fluid injection aperture at any time, when in the time of in temperature rises to 40 ℃~45 ℃ scopes or fluid injection aperture steams bubble, stop immediately charging; The power of described high-power charger is 60 watts~1000 watts; Charging current is 5 amperes~40 amperes, and charging voltage is 12 volts~25 volts;
Second step: process original electrolyte: adopt the cooling or air-cooled mode of nature to make storage battery cooling, when electrolysis temperature in storage battery is down to 20 ℃, electrolyte and the presumable sediment of bottom of storage battery are poured out together, then recover accumulator positive facing up;
The 3rd step: add recovery liquid: will recover liquid and join in storage battery, addition is as the criterion to flood battery polar plate, adds to recover to soak 6-12 hour after liquid; Described recovery liquid is that 70% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and form by commercially available concentration; Wherein, 70% the concentrated sulfuric acid and the volume ratio of distilled water are 1:11, in mass ratio, and sodium sulphate: (75% the concentrated sulfuric acid and distilled water)=1:390; The density of described recovery liquid is 1.05g/cm 3
The 4th step: recover charging: the place that is placed on ventilation and the flames of anger for the storage battery in the 3rd step, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post at any time, in the time of in temperature rises to 30 ℃~40 ℃ scopes, stop immediately charging; Then the battery filling-hole nut is tightened again, storage battery is sidelong on the ground, with hand hammer tapped bottom, the lead powder that comes off in the bottom is sunk to a side, then storage battery was fallen, beat the side that lead powder sinks, lead powder is sunk to the liquid injection hole direction; Then turning on nut will recover liquid and all be poured in clean plastic containers again;
The 5th step: repeatedly the 3rd to the 4th step, until in the recovery liquid of pouring out, naked eyes do not see that any solid impurity is arranged, obtained the initial storage battery of repairing;
The 6th step: add electrolyte and charging: adding commercially available density in the initial storage battery of the reparation that obtains in going on foot the 5th is 1.25~1.3g/cm 3Electrolyte; Be added to exceed baffle 10~15cm till; Then, adopt normal battery charger to charge, charge parameter arranges according to the original parameter of storage battery, charge and stop charging after 5-8 hour, the liquid injection hole nut is tightened, measuring battery voltage with storage battery Special pressure measuring table after to charging, when the pressure gauge pointer reaches the nominal value of battery tension, the explanation electric weight is sufficient, has obtained the storage battery of repairing.
Embodiment 3
A kind of battery restorative procedure is characterized in that it includes following steps:
The first step: initial charge: first get the storage battery that to repair, again the nut on storage battery is all backed out, then storage battery is placed on the place of ventilation and the flames of anger, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post and fluid injection aperture at any time, when in the time of in temperature rises to 40 ℃~45 ℃ scopes or fluid injection aperture steams bubble, stop immediately charging; The power of described high-power charger is 60 watts~1000 watts; Charging current is 5 amperes~40 amperes, and charging voltage is 12 volts~25 volts;
Second step: process original electrolyte: adopt the cooling or air-cooled mode of nature to make storage battery cooling, when electrolysis temperature in storage battery is down to 20 ℃, electrolyte and the presumable sediment of bottom of storage battery are poured out together, then recover accumulator positive facing up;
The 3rd step: add recovery liquid: will recover liquid and join in storage battery, addition is as the criterion to flood battery polar plate, adds to recover to soak 6-12 hour after liquid; Described recovery liquid is that 85% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and form by commercially available concentration; Wherein, 85% the concentrated sulfuric acid and the volume ratio of distilled water are 1:14, in mass ratio, and sodium sulphate: (85% the concentrated sulfuric acid and distilled water)=1:210; The density of described recovery liquid is 1.15g/cm 3
The 4th step: recover charging: the place that is placed on ventilation and the flames of anger for the storage battery in the 3rd step, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post at any time, in the time of in temperature rises to 30 ℃~40 ℃ scopes, stop immediately charging; Then the battery filling-hole nut is tightened again, storage battery is sidelong on the ground, with hand hammer tapped bottom, the lead powder that comes off in the bottom is sunk to a side, then storage battery was fallen, beat the side that lead powder sinks, lead powder is sunk to the liquid injection hole direction; Then turning on nut will recover liquid and all be poured in clean plastic containers again;
The 5th step: repeatedly the 3rd to the 4th step, until in the recovery liquid of pouring out, naked eyes do not see that any solid impurity is arranged, obtained the initial storage battery of repairing;
The 6th step: add electrolyte and charging: adding commercially available density in the initial storage battery of the reparation that obtains in going on foot the 5th is 1.25~1.3g/cm 3Electrolyte; Be added to exceed baffle 10~15cm till; Then, adopt normal battery charger to charge, charge parameter arranges according to the original parameter of storage battery, charge and stop charging after 5-8 hour, the liquid injection hole nut is tightened, measuring battery voltage with storage battery Special pressure measuring table after to charging, when the pressure gauge pointer reaches the nominal value of battery tension, the explanation electric weight is sufficient, has obtained the storage battery of repairing.
By applicant's repeated tests, the applicant finds, the recovery liquid described in above-mentioned arbitrary embodiment is that 70%~85% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and forms by commercially available concentration; Wherein, 70%~85% the concentrated sulfuric acid and the volume ratio of distilled water are 1:14~1:11, in mass ratio, and sodium sulphate: (70%~85% the concentrated sulfuric acid and distilled water)=(1:390)~(1:210); The density of described recovery liquid is 1.05~1.15g/cm 3The time, can reach the purpose of using in the present invention.
Adopt method of the present invention to repair battery, only need to use several industrial chemicals of easily purchasing to be made into recovery liquid, can repair the old and useless battery more than 95%, repair 4~10 yuan of the cost of material of a battery that is worth 400 yuan of left and right, and, prove through a large amount of uses after reparation, can continue at least to use 2 years; Therefore the cost of repairing is relatively very low, and market is very huge.
In addition, only need during reparation that nonmetal resistance to acid attack container is some, resistance to acid attack rubber gloves, hand hammer, glass bar, handsaw, measuring cup, graduated cylinder are some, funnel, thermometer, balance, battery Special pressure measuring table, large power high efficiency quick charger, motorcycle electric electrolytic battery charger, etc. equipment, fund input is relatively seldom.
In addition, the poisonous and harmful substance that contains in the recovery liquid of pouring out in the 4th step can be processed by centralized recovery, and is more effective for environmental protection; Carry out separately adding sodium sulphate and distilled water after impurity separates for the recovery liquid that obtains, transfer to density and be; 1.05~1.15g/cm 3In time, recycle, and effectively saved resource.
Therefore, the present invention has following main beneficial effect: battery recovery is convenient, and success rate is high, less investment, instant effect, more environmental protection, more sustainable development.
The present invention is not limited to above-mentioned preferred forms, should be appreciated that design of the present invention can be by other various forms enforcement utilizations, and they drop in protection scope of the present invention equally.

Claims (4)

1. battery restorative procedure is characterized in that it includes following steps:
The first step: initial charge: first get the storage battery that to repair, again the nut on storage battery is all backed out, then storage battery is placed on the place of ventilation and the flames of anger, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post and fluid injection aperture at any time, when in the time of in temperature rises to 40 ℃~45 ℃ scopes or fluid injection aperture steams bubble, stop immediately charging;
Second step: process original electrolyte: adopt the cooling or air-cooled mode of nature to make storage battery cooling, when electrolysis temperature in storage battery is down to 20 ℃, electrolyte and the presumable sediment of bottom of storage battery are poured out together, then recover accumulator positive facing up;
The 3rd step: add recovery liquid: will recover liquid and join in storage battery, addition is as the criterion to flood battery polar plate, adds to recover to soak 6-12 hour after liquid;
The 4th step: recover charging: the place that is placed on ventilation and the flames of anger for the storage battery in the 3rd step, then temperature-measuring range being not less than the thermometer of 80 degree or the detecting head of temperature probe or remote control temperature measuring equipment stretches in the electrolyte of storage battery, then storage battery is charged with high-power charger again, then the temperature value surveyed of observation post at any time, in the time of in temperature rises to 30 ℃~40 ℃ scopes, stop immediately charging; Then the battery filling-hole nut is tightened again, storage battery is sidelong on the ground, with hand hammer tapped bottom, the lead powder that comes off in the bottom is sunk to a side, then storage battery was fallen, beat the side that lead powder sinks, lead powder is sunk to the liquid injection hole direction; Then turning on nut will recover liquid and all be poured in clean plastic containers again;
The 5th step: repeatedly the 3rd to the 4th step, until in the recovery liquid of pouring out, naked eyes do not see that any solid impurity is arranged, obtained the initial storage battery of repairing;
The 6th step: add electrolyte and charging: adding commercially available density in the initial storage battery of the reparation that obtains in going on foot the 5th is 1.25~1.3g/cm 3Electrolyte; Be added to exceed baffle 10~15cm till; Then, adopt normal battery charger to charge, charge parameter arranges according to the original parameter of storage battery, charge and stop charging after 5-8 hour, the liquid injection hole nut is tightened, measuring battery voltage with storage battery Special pressure measuring table after to charging, when the pressure gauge pointer reaches the nominal value of battery tension, the explanation electric weight is sufficient, has obtained the storage battery of repairing.
2. a kind of battery restorative procedure according to claim 1, the power that it is characterized in that the high-power charger described in the first step is 60 watts~1000 watts; Charging current is 5 amperes~40 amperes, and charging voltage is 12 volts~25 volts.
3. according to claim 1 or a kind of battery restorative procedure claimed in claim 2, it is characterized in that the recovery liquid described in the 3rd step is that 70%~85% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and forms by commercially available concentration; Wherein, 70%~85% the concentrated sulfuric acid and the volume ratio of distilled water are 1:14~1:11, in mass ratio, and sodium sulphate: (70%~85% the concentrated sulfuric acid and distilled water)=(1:390)~(1:210); The density of described recovery liquid is 1.05~1.15g/cm 3
4. a kind of battery restorative procedure according to claim 3 is characterized in that described recovery liquid is that 75% the concentrated sulfuric acid, distilled water, sodium sulphate mix the liquid that forms and forms by commercially available concentration; Wherein, 75% the concentrated sulfuric acid and the volume ratio of distilled water are 1:12, in mass ratio, and sodium sulphate: (75% the concentrated sulfuric acid and distilled water)=1:275; The density of described recovery liquid is 1.1g/cm 3
CN2013100834583A 2013-03-16 2013-03-16 Battery repairing method Pending CN103151568A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2013100834583A CN103151568A (en) 2013-03-16 2013-03-16 Battery repairing method
CN201310228011.0A CN103311588B (en) 2013-03-16 2013-06-08 Battery repairing method
CN201410774862.XA CN104409786B (en) 2013-03-16 2013-06-08 A kind of battery restorative procedure
CN201410774812.1A CN104485487B (en) 2013-03-16 2013-06-08 A kind of battery recovery liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013100834583A CN103151568A (en) 2013-03-16 2013-03-16 Battery repairing method

Publications (1)

Publication Number Publication Date
CN103151568A true CN103151568A (en) 2013-06-12

Family

ID=48549514

Family Applications (4)

Application Number Title Priority Date Filing Date
CN2013100834583A Pending CN103151568A (en) 2013-03-16 2013-03-16 Battery repairing method
CN201410774812.1A Expired - Fee Related CN104485487B (en) 2013-03-16 2013-06-08 A kind of battery recovery liquid
CN201310228011.0A Active CN103311588B (en) 2013-03-16 2013-06-08 Battery repairing method
CN201410774862.XA Expired - Fee Related CN104409786B (en) 2013-03-16 2013-06-08 A kind of battery restorative procedure

Family Applications After (3)

Application Number Title Priority Date Filing Date
CN201410774812.1A Expired - Fee Related CN104485487B (en) 2013-03-16 2013-06-08 A kind of battery recovery liquid
CN201310228011.0A Active CN103311588B (en) 2013-03-16 2013-06-08 Battery repairing method
CN201410774862.XA Expired - Fee Related CN104409786B (en) 2013-03-16 2013-06-08 A kind of battery restorative procedure

Country Status (1)

Country Link
CN (4) CN103151568A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103311591A (en) * 2013-06-28 2013-09-18 江苏玖宇实业有限公司 Repair method of lead-acid storage batteries
CN106329016A (en) * 2016-10-25 2017-01-11 梁振华 Lead-acid storage battery active compatibilizer and preparation and use method thereof
CN106785117A (en) * 2016-12-23 2017-05-31 安徽国威电动车制造有限公司 A kind of electric motor car lead-acid battery method for supplementing water
CN109103524A (en) * 2018-09-29 2018-12-28 溧阳中科海钠科技有限责任公司 A kind of restorative procedure of waste and old sodium-ion battery
CN111342149A (en) * 2020-02-26 2020-06-26 天能电池集团股份有限公司 Lead storage battery cathode devulcanization repairing method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108631018B (en) * 2018-04-27 2020-01-10 贵州中伟资源循环产业发展有限公司 Method for preparing lithium ion battery by utilizing recovered resources
CN110635189B (en) * 2019-10-16 2022-06-07 湖南科霸汽车动力电池有限责任公司 Battery module maintenance frock that charges

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1198799A (en) * 1966-11-09 1970-07-15 Norman William Cooper Improvements in or relating to Lead Acid Batteries
PL1611626T3 (en) * 2003-03-10 2011-06-30 Akuros S R O Method of regenerating battery cells and regenerative agent for lead batteries
CN1481048A (en) * 2003-06-26 2004-03-10 原建锋 Liquid for beneficiating and renovating lead and acid battery
CN101022181A (en) * 2006-02-15 2007-08-22 王一锋 Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method
CN101252211A (en) * 2008-03-12 2008-08-27 邢纪国 Lead acid batteries restoring system and method
CN101752615B (en) * 2008-12-12 2014-04-02 成都鑫元帝科技有限公司 Desulphurized high-frequency pulse activating instrument for battery recovery, activating agent and recovery process
CN102376985A (en) * 2010-08-16 2012-03-14 芜湖大江电源有限公司 Novel electrolyte
CN102683758B (en) * 2011-03-08 2015-01-07 依安县鲍德发电瓶电器修理部 Method for repairing discarded lead-acid storage batteries with imbalanced electrolyte specific gravity
CN102290609A (en) * 2011-07-22 2011-12-21 浙江天能电池(江苏)有限公司 Electrolyte for energy-storing lead-acid storage batteries and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103311591A (en) * 2013-06-28 2013-09-18 江苏玖宇实业有限公司 Repair method of lead-acid storage batteries
CN106329016A (en) * 2016-10-25 2017-01-11 梁振华 Lead-acid storage battery active compatibilizer and preparation and use method thereof
CN106785117A (en) * 2016-12-23 2017-05-31 安徽国威电动车制造有限公司 A kind of electric motor car lead-acid battery method for supplementing water
CN106785117B (en) * 2016-12-23 2019-08-23 安徽国威电动车制造有限公司 A kind of electric vehicle lead-acid battery method for supplementing water
CN109103524A (en) * 2018-09-29 2018-12-28 溧阳中科海钠科技有限责任公司 A kind of restorative procedure of waste and old sodium-ion battery
CN111342149A (en) * 2020-02-26 2020-06-26 天能电池集团股份有限公司 Lead storage battery cathode devulcanization repairing method
CN111342149B (en) * 2020-02-26 2021-06-01 天能电池集团股份有限公司 Lead storage battery cathode devulcanization repairing method

Also Published As

Publication number Publication date
CN104409786B (en) 2016-08-24
CN104485487B (en) 2016-09-28
CN104485487A (en) 2015-04-01
CN103311588B (en) 2015-05-20
CN104409786A (en) 2015-03-11
CN103311588A (en) 2013-09-18

Similar Documents

Publication Publication Date Title
CN103311588B (en) Battery repairing method
CN101431170B (en) Lead acid accumulator renovation system and method thereof
CN105024103B (en) The restorative procedure of waste and old lead acid accumulator
CN104882646B (en) A kind of highly effective and safe charging method of waste and old lithium ion battery
CN103985919B (en) The method of graphite and Copper Foil is reclaimed from scrap lithium ion battery negative plate
Zhang The current status on the recycling of lead-acid batteries in China
CN104393290A (en) Aluminum-ion battery using MoS2 as positive electrode material and preparation method of battery
CN101022181A (en) Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method
CN105098280B (en) A kind of method that collector is reclaimed from waste and old lithium ion battery
CN102881949B (en) Electrolyte used for ion state mixed crystal salt storage battery
CN104868179B (en) One kind can discharge and recharge aluminium ion molten salt battery and preparation method thereof
CN104485492B (en) A kind of separating waste, worn lithium ion battery electrode material and the method for collector
CN101397175A (en) Innocent treatment process and device for waste and old lithium ionic cell electrolyte
CN110276925B (en) Lithium battery short circuit thermal runaway fire detection and early warning method
CN101312262A (en) Environment-friendly type accumulator rehabilitation liquor manufacture method
CN104046998A (en) Oriented reinforced concrete chloride ion absorption device convenient to install and change and method
CN202928657U (en) Automatic alarming device for over-low liquid level of automobile storage battery electrolyte
CN104518248A (en) Nano carbon sol lead-acid storage battery devulcanization repairing liquid
CN101281982A (en) Colloidal electrolyte accumulator and production method
CN101083346A (en) Lead acid accumulator recovery technique
CN101192685A (en) Regenerated lead acid batteries and method
CN106252780A (en) A kind of lithium-ion-power cell disassembles the processing method producing waste water
CN207091545U (en) One kindization throws acid solution reclaimer
CN203674320U (en) Electrolyte storage tank for redox flow cell
CN117438682B (en) Method for completely discharging waste lithium ion battery

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20130612