CN102376985A - Novel electrolyte - Google Patents

Novel electrolyte Download PDF

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Publication number
CN102376985A
CN102376985A CN2010102540824A CN201010254082A CN102376985A CN 102376985 A CN102376985 A CN 102376985A CN 2010102540824 A CN2010102540824 A CN 2010102540824A CN 201010254082 A CN201010254082 A CN 201010254082A CN 102376985 A CN102376985 A CN 102376985A
Authority
CN
China
Prior art keywords
electrolyte
sulfuric acid
pure water
sodium sulfate
anhydrous sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010102540824A
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Chinese (zh)
Inventor
何国海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU DAJIANG POWER CO Ltd
Original Assignee
WUHU DAJIANG POWER CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU DAJIANG POWER CO Ltd filed Critical WUHU DAJIANG POWER CO Ltd
Priority to CN2010102540824A priority Critical patent/CN102376985A/en
Publication of CN102376985A publication Critical patent/CN102376985A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Secondary Cells (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

The invention, belonging to an electrolyte, particularly discloses a novel electrolyte as a medium for a chemical battery or an electrolytic capacitor. The electrolyte comprises 53-57 weight portions of pure water, 42-46 weight portions of sulfuric acid, and 0.8-1.2 weight portions of anhydrous sodium sulfate. According to the invention, the problems that easy volatilization and seepage and large influence to service life and stability in a high temperature environment, and possible instant vaporization under high temperature high pressure, explosion caused by volume increasing, and low conductivity of the ionic conduction method used by the electrolyte existing in the electrolyte in the prior art are solved.

Description

Novel electrolyte
Technical field
The present invention relates to electrolyte, be specifically related to the electrolyte that a kind of chemical cell or electrochemical capacitor are used as medium.
Background technology
Electrolyte is the most traditional electrolyte, and electrolyte adds salt of weak acid electric capacity matter by organic solvent and obtains through heating.The negative electrode of the alminium electrolytic condenser on the common meaning all is this electrolyte.Electrolyte is the medium (certain corrosivity is arranged) of uses such as chemical cell, electrochemical capacitor, and for their operate as normal provides ion, and the chemical reaction that takes place in the assurance work is reversible.Use electrolyte to do negative electrode many benefits are arranged.The contact area that at first is liquid and medium is bigger, and is helpful to promoting capacitance like this.The electrochemical capacitor that next is to use electrolyte to make, the high temperature of the highest ability 260 degree so just can be through wave-soldering (wave-soldering be one important procedure that the SMT paster is installed), resistance to pressure is also more intense simultaneously.In addition, use electrolyte to do the electrochemical capacitor of negative electrode, after medium was breakdown, as long as breakdown current does not continue, electric capacity can self-healing so.But existing electrolyte also has its weak point.At first be volatilization, seepage easily under hot environment, very big to life-span and stability influence, electrolyte also might instant vaporization under HTHP, and volume increases and set off an explosion (be exactly us the normal quick-fried slurry of saying); Next is that its conductance of ion guide electrical method of adopting of electrolyte is very low, has only 0.01S (conductivity, the inverse of ohm)/CM, and this causes the ESR value (equivalent series resistance) of electric capacity high especially.
The electrolyte of storage battery by special-purpose sulfuric acid and the formulated by a certain percentage density of distilled water generally be 1.24-1.30g/cm cube.Proportion 12.75-1.285G/CM3 sulfuric acid adds pure water, if water consumption in the battery use adds the pure water charging and gets final product.
Summary of the invention
The purpose of this invention is to provide novel electrolyte; The invention solves the volatilization easily under hot environment of existing electrolyte, seepage, very big to life-span and stability influence; And the also possible instant vaporization of electrolyte under HTHP; The volume increase sets off an explosion the very low problem of its conductance of ion guide electrical method that electrolyte adopted.
Novel electrolyte of the present invention is made up of following raw materials by weight percent: pure water 53-57, sulfuric acid 42-46, anhydrous sodium sulfate 0.8-1.2.
Further, novel electrolyte of the present invention also has following characteristics, is made up of following raw materials by weight percent: pure water 54-56, sulfuric acid 43-45, anhydrous sodium sulfate 0.9-1.1.
Further, novel electrolyte of the present invention also has following characteristics, pure water 53-56, sulfuric acid 43-45, anhydrous sodium sulfate 0.8-1.1.
Further, novel electrolyte of the present invention also has following characteristics, is made up of following raw materials by weight percent: pure water 53-56, sulfuric acid 43-46, anhydrous sodium sulfate 0.9-1.2.
The concentration of above-mentioned sulfuric acid is 98%.
Electrolyte of the present invention has the volatilization of under hot environment, being not easy, seepage, long service life, and stable performance, electrolyte can instant vaporization under HTHP, and is safe in utilization, the advantage that conductivity is good.Electrolyte of the present invention is particularly suitable in storage battery, acting on.
Embodiment
With illustrated embodiments the present invention is done detailed explanation below.
Embodiment one
Novel electrolyte is made up of following raw materials by weight percent: pure water 53, sulfuric acid 46, anhydrous sodium sulfate 1.The concentration of above-mentioned sulfuric acid is 98%.
Embodiment two
Novel electrolyte is made up of following raw materials by weight percent: pure water 54.8, sulfuric acid 44, anhydrous sodium sulfate 1.2.The concentration of above-mentioned sulfuric acid is 98%.
Embodiment three
Novel electrolyte is made up of following raw materials by weight percent: pure water 55, sulfuric acid 44.2, anhydrous sodium sulfate 0.8.The concentration of above-mentioned sulfuric acid is 98%.
Embodiment four
Novel electrolyte is made up of following raw materials by weight percent: pure water 55, sulfuric acid 44, anhydrous sodium sulfate 1.The concentration of above-mentioned sulfuric acid is 98%.
The density that above-mentioned electrolyte quota is accomplished is 1.345 ± 0.0002g/cm 3(25 ℃).
Above embodiment is respectively more preferably embodiment a kind of of the present invention, and common variation that those skilled in the art carry out in present technique scheme scope and replacement should be included in protection scope of the present invention.

Claims (5)

1. novel electrolyte is characterized in that, is made up of following raw materials by weight percent: pure water 53-57, sulfuric acid 42-46, anhydrous sodium sulfate 0.8-1.2.
2. novel electrolyte according to claim 1 is characterized in that, is made up of following raw materials by weight percent: pure water 54-56, sulfuric acid 43-45, anhydrous sodium sulfate 0.9-1.1.
3. novel electrolyte according to claim 1 is characterized in that, is made up of following raw materials by weight percent: pure water 53-56, sulfuric acid 43-45, anhydrous sodium sulfate 0.8-1.1.
4. novel electrolyte according to claim 1 is characterized in that, is made up of following raw materials by weight percent: pure water 53-56, sulfuric acid 43-46, anhydrous sodium sulfate 0.9-1.2.
5. novel electrolyte according to claim 1 is characterized in that the concentration of said sulfuric acid is 98%.
CN2010102540824A 2010-08-16 2010-08-16 Novel electrolyte Pending CN102376985A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102540824A CN102376985A (en) 2010-08-16 2010-08-16 Novel electrolyte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102540824A CN102376985A (en) 2010-08-16 2010-08-16 Novel electrolyte

Publications (1)

Publication Number Publication Date
CN102376985A true CN102376985A (en) 2012-03-14

Family

ID=45795212

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010102540824A Pending CN102376985A (en) 2010-08-16 2010-08-16 Novel electrolyte

Country Status (1)

Country Link
CN (1) CN102376985A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104485487A (en) * 2013-03-16 2015-04-01 方秀琴 Battery recovery solution
CN111477978A (en) * 2020-04-15 2020-07-31 天能电池(芜湖)有限公司 Colloidal electrolyte suitable for partial charge state

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104485487A (en) * 2013-03-16 2015-04-01 方秀琴 Battery recovery solution
CN104485487B (en) * 2013-03-16 2016-09-28 宁波江东甬风工业设计有限公司 A kind of battery recovery liquid
CN111477978A (en) * 2020-04-15 2020-07-31 天能电池(芜湖)有限公司 Colloidal electrolyte suitable for partial charge state

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Application publication date: 20120314