CN103148646B - A kind of cold power circulating refrigerating device - Google Patents

A kind of cold power circulating refrigerating device Download PDF

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CN103148646B
CN103148646B CN201310029677.3A CN201310029677A CN103148646B CN 103148646 B CN103148646 B CN 103148646B CN 201310029677 A CN201310029677 A CN 201310029677A CN 103148646 B CN103148646 B CN 103148646B
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refrigerant
recooler
storage tank
throttle valve
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CN103148646A (en
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王海波
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Nanjing Reclaimer Environmental Technology Co Ltd
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Abstract

本发明涉及一种冷力循环制冷装置,采用低温液态制冷剂经液态循环泵增压的方法补充冷量,经回冷器升高温度后,进入用冷单元提供冷量,出来的制冷剂经节流阀降低压力、温度后,返回制冷剂贮罐,为降低传冷过程的不可逆损失,设置必要数量的回冷器以减少冷量可用能的损失。本发明无需传统蒸汽压缩式制冷装置中的循环冷却水系统,维修及运行成本下降较多,相同制冷量的机组,节能率较传统提高30%以上,经济、社会、环保效益显著。

The invention relates to a cold cycle refrigeration device, which uses a low-temperature liquid refrigerant to supplement the cooling capacity through a liquid circulation pump pressurization method, and after the temperature is raised by a recooler, it enters a cooling unit to provide cooling capacity, and the refrigerant that comes out is passed through After the throttle valve lowers the pressure and temperature, it returns to the refrigerant storage tank. In order to reduce the irreversible loss in the cooling process, a necessary number of recoolers are installed to reduce the loss of cooling energy. The invention does not need the circulating cooling water system in the traditional vapor compression refrigeration device, the maintenance and operation costs are greatly reduced, the energy saving rate of the unit with the same cooling capacity is increased by more than 30% compared with the traditional one, and the economic, social and environmental benefits are remarkable.

Description

一种冷力循环制冷装置A cold cycle refrigeration device

技术领域technical field

本发明涉及一种冷力循环制冷装置,具体属制冷技术领域。The invention relates to a cold cycle refrigeration device, specifically belonging to the technical field of refrigeration.

背景技术Background technique

现代制冷技术作为一门科学,是十九世纪中期和后期发展起来的,在此之前,追溯到人类的祖先,人们很早就懂得冷的利用和简单的人工制冷了:用地窖作冷贮室,用泉水冷却贮藏室已有5000年之久的历史。Modern refrigeration technology, as a science, was developed in the middle and late nineteenth century. Before that, back to the ancestors of mankind, people knew the use of cold and simple artificial refrigeration very early: using the cellar as a cold storage room , has used spring water to cool storerooms for 5,000 years.

二十世纪后,制冷技术有了更大的发展:1910年家用冰箱问世,1917年在美国开始作为商品投放市场。1930年,氟利昂制冷工质的出现和氟利昂制冷机的使用给制冷技术带来新的变革。二十世纪七十年代,人们对混合工质进行了大量的研究,并开始使用共沸混合工质,为蒸汽压缩式制冷机的发展开辟了新的道路。制冷技术发展到今天,已经从保存食品和调节一定空间的温度,扩展、渗透到国民经济的各个部门,并与人们的日常生活有了更加紧密的联系:After the twentieth century, refrigeration technology has made greater development: in 1910, the domestic refrigerator came out, and in 1917 it began to be put on the market as a commodity in the United States. In 1930, the emergence of freon refrigerants and the use of freon refrigerators brought new changes to refrigeration technology. In the 1970s, people conducted a lot of research on mixed working fluids, and began to use azeotropic mixed working fluids, which opened up a new path for the development of vapor compression refrigerators. With the development of refrigeration technology today, it has expanded and penetrated into various sectors of the national economy from preserving food and adjusting the temperature of a certain space, and has a closer relationship with people's daily life:

1、商业1. Business

制冷技术在商业上的应用主要是对易腐食品(如鱼、肉、蛋、果类、蔬菜等)进行冷加工、冷藏及冷藏运输,以减少生产和分配中的食品耗损,保证各个季节市场的合理销售。现代化的食品工业,从食品生产、贮运到销售已经形成一条完整的冷链。所采用的制冷装置有冷库、冷藏汽车、冷藏船以及冷藏列车等。另外还有供食品零售商店、食堂、餐厅等用的商品冷藏柜、各类冷饮设备和各种带有制冷设备的商品陈列柜。The commercial application of refrigeration technology is mainly for cold processing, refrigeration and refrigerated transportation of perishable foods (such as fish, meat, eggs, fruits, vegetables, etc.) Reasonable sales. The modern food industry has formed a complete cold chain from food production, storage and transportation to sales. The refrigeration devices used include cold storage, refrigerated cars, refrigerated ships, and refrigerated trains. In addition, there are commodity refrigerators for food retail stores, canteens, restaurants, etc., various cold drink equipment and various commodity display cabinets with refrigeration equipment.

2、降温和空气调节2. Cooling and air conditioning

为生活用的舒适性空调,例如宾馆、剧场、地下地铁、大型公共建筑、汽车、飞机座舱、办公室。居民住宅等的空调设备,为人们提供了适宜的生活和工作环境,不仅有益于身心健康,而且可以提高生产和工作效率。Comfortable air conditioners for daily use, such as hotels, theaters, underground subways, large public buildings, automobiles, aircraft cockpits, and offices. Air-conditioning equipment in residential buildings provides people with a suitable living and working environment, which is not only beneficial to physical and mental health, but also improves production and work efficiency.

3、工业生产3. Industrial production

机械制造中,对钢进行低温处理(-70℃~-90℃),可以改变其金相组织,使奥氏体变成马氏体,提高钢的硬度和强度;在机器的装配过程中,利用低温能方便实现过盈配合。化学工业中,借助于制冷,可以使气体液化,混合气分离,带走化学反应中的反应热。盐类结晶、润滑油脱脂需要制冷;石油裂解、合成橡胶、合成树脂、燃料、化肥的生产需要制冷,天然气液化、贮运也需要制冷。在钢铁工业中,高炉鼓风需要用制冷的方法先将其除湿,然后再送入高炉,以降低焦化比,保证铁水质量,一般大型高炉需几千千瓦冷量。In mechanical manufacturing, low-temperature treatment of steel (-70℃~-90℃) can change its metallographic structure, make austenite into martensite, and improve the hardness and strength of steel; during the assembly process of the machine, Low temperature can be used to facilitate interference fit. In the chemical industry, with the help of refrigeration, the gas can be liquefied, the mixed gas can be separated, and the heat of reaction in the chemical reaction can be taken away. Refrigeration is required for salt crystallization and degreasing of lubricating oil; refrigeration is required for petroleum cracking, production of synthetic rubber, synthetic resin, fuel, and fertilizer, as well as natural gas liquefaction, storage and transportation. In the iron and steel industry, the blast furnace blast needs to be dehumidified by refrigeration first, and then sent to the blast furnace to reduce the coking ratio and ensure the quality of molten iron. Generally, a large blast furnace requires thousands of kilowatts of cooling capacity.

4、农牧业4. Agriculture and animal husbandry

利用制冷对农作物种子进行低温处理,创造人工气候室育秧,保存良种精液以便进行人工配种等等。Use refrigeration to treat crop seeds at low temperature, create artificial climate chambers to raise seedlings, preserve fine seed semen for artificial breeding, etc.

5、建筑工程5. Construction

利用制冷可实现冻土法开采土方。在挖掘矿井、隧道、建筑江河堤坝时,或在泥沼、砂水处掘进时,可采用冻土法使工作面不坍塌,保证施工安全。拌合混凝土时,用冰代替水,借冰的熔化热补偿水泥的固化反应热,可以制出大型的独柱混凝土构件,可有效地避免大型构件因得不到充分散热而产生内应力和裂缝等缺陷。The use of refrigeration can realize the mining of earthwork by frozen soil method. When excavating mines, tunnels, building river embankments, or excavating in mud, sand and water, the frozen soil method can be used to prevent the working face from collapsing and ensure construction safety. When mixing concrete, use ice instead of water, and use the melting heat of ice to compensate the solidification reaction heat of cement, so that large-scale single-column concrete components can be produced, which can effectively avoid internal stress and cracks caused by large-scale components due to insufficient heat dissipation and other defects.

6、国防工业6. Defense industry

高寒条件下工作的发动机、汽车、坦克、大炮等常规武器的性能需作环境模拟实验;航空仪表、火箭、导弹中的控制仪表,也需要地面模拟高空低温条件进行性能实验,所有这些都需要制冷为其提供实验的环境条件。原子能反应堆的控制也需要制冷。The performance of conventional weapons such as engines, automobiles, tanks, and cannons working under extreme cold conditions requires environmental simulation experiments; the control instruments in aviation instruments, rockets, and missiles also need to simulate high-altitude and low-temperature conditions on the ground for performance experiments, all of which require refrigeration. Provide the environmental conditions for the experiment. The control of atomic power reactors also requires refrigeration.

7、医疗卫生7. Medical and health care

冷冻手术,如心脏、外科、肿瘤、白内障、扁桃体的切除,皮肤和眼球的移植手术及低温麻醉等,均需要制冷技术。除了低温保存疫苗、药品外,医药中还用冻结真空干燥法保存血液及皮肤。Cryosurgery, such as heart, surgery, tumor, cataract, tonsillectomy, skin and eye transplantation and cryogenic anesthesia, all require refrigeration technology. In addition to low-temperature preservation of vaccines and medicines, blood and skin are also preserved by freeze-drying in medicine.

此外,在微电子技术、能源、新型原材料、宇宙开发、生物技术这些尖端科学领域中,制冷技术也有重要的应用。In addition, refrigeration technology also has important applications in cutting-edge scientific fields such as microelectronics technology, energy, new raw materials, space development, and biotechnology.

各种制冷方法,概括起来,可分为两大类:输入功实现制冷和输入热量实现制冷。蒸汽压缩式制冷、热电制冷属于输入功制冷,吸收式制冷、蒸汽喷射式制冷、吸附式制冷属于输入热量实现制冷。Various refrigeration methods can be summarized into two categories: cooling by inputting work and cooling by inputting heat. Vapor compression refrigeration and thermoelectric refrigeration belong to input work refrigeration, and absorption refrigeration, steam injection refrigeration, and adsorption refrigeration belong to input heat to achieve refrigeration.

传统制冷技术的研究内容可概括为以下三个方面:The research content of traditional refrigeration technology can be summarized into the following three aspects:

1)研究获得低温的方法和有关的机理以及相应的制冷循环,并对制冷循环进行热力学的分析和计算。1) Study the method of obtaining low temperature and the related mechanism and the corresponding refrigeration cycle, and conduct thermodynamic analysis and calculation of the refrigeration cycle.

2)研究制冷剂的性质,从而为制冷机提供性能满意的工质。机械制冷要通过制冷剂热力状态的变化才能实现,所以,制冷剂的热物理性质是进行循环分析和计算的基础。此外,为了使制冷剂能实际应用,还必须掌握它们的一般物理化学性质。2) Study the properties of the refrigerant, so as to provide a working fluid with satisfactory performance for the refrigerator. Mechanical refrigeration can only be realized through the change of the thermodynamic state of the refrigerant, so the thermophysical properties of the refrigerant are the basis for cycle analysis and calculation. In addition, in order for refrigerants to be used in practice, their general physical and chemical properties must also be mastered.

3)研究实现制冷循环所必须的各种机械和技术设备,它们的工作原理、性能分析、结构设计计算以及各种制冷装置的流程组织、系统配套计算。此外,还有热绝缘问题、制冷设备的自动化问题,等等。3) Study various mechanical and technical equipment necessary to realize the refrigeration cycle, their working principle, performance analysis, structural design calculation, process organization and system matching calculation of various refrigeration devices. In addition, there are thermal insulation issues, automation of refrigeration equipment, and so on.

上述前两个方面构成制冷的理论基础,即传统的制冷原理的研究内容,第三方面涉及到具体的机器、设备和装置。The first two aspects above constitute the theoretical basis of refrigeration, that is, the research content of traditional refrigeration principles, and the third aspect involves specific machines, equipment and devices.

传统制冷理论的主要基础是热力学,即采用同温差的卡诺逆循环分析制冷循环过程,制冷循环的经济性指标是制冷系数,就是得到的收益和耗费的代价之比值,并且以大气环境温度T0与温度为TC低温热源(如冷库)之间的一切制冷循环,以逆向卡诺循环的制冷系数为最高:The main basis of the traditional refrigeration theory is thermodynamics, that is, the Carnot reverse cycle with the same temperature difference is used to analyze the refrigeration cycle process. The economic index of the refrigeration cycle is the refrigeration coefficient, which is the ratio of the income obtained to the cost of the consumption, and the ambient temperature T For all refrigeration cycles between 0 and T C low-temperature heat sources (such as cold storage), the refrigeration coefficient of the reverse Carnot cycle is the highest:

ϵϵ cc == (( COPCOP )) RR ,, CC == qq 22 ww 00 == TT cc TT 00 -- TT cc -- -- -- (( 11 ))

上式中的εc为制冷系数,q2为循环的制冷量,w0为循环所消耗的净功。In the above formula, ε c is the refrigeration coefficient, q 2 is the cooling capacity of the cycle, and w 0 is the net work consumed by the cycle.

实际上,卡诺在“关于热动力的见解”的论文中,得出的结论为:“在两个不同温度的恒温热源之间工作的所有热机,以可逆热机的效率为最高。”即被后人称之为卡诺定理,按理想气体状态方程进行整理得出的卡诺循环的热效率为:In fact, in Carnot's paper "Insights on Thermodynamics", he concluded that: "Of all heat engines working between two constant temperature heat sources at different temperatures, the efficiency of the reversible heat engine is the highest." That is to say, Later generations call it Carnot's theorem. According to the ideal gas state equation, the thermal efficiency of the Carnot cycle is:

ηη cc == 11 -- TT 22 TT 11 -- -- -- (( 22 ))

公式(2)中的高温热源的温度T1与低温热源的温度为T2均高于大气环境温度T0,并可以得出以下几点重要结论:The temperature T 1 of the high-temperature heat source and the temperature T 2 of the low-temperature heat source in formula (2) are both higher than the ambient temperature T 0 of the atmosphere, and the following important conclusions can be drawn:

1)卡诺循环的热效率只决定于高温热源和低温热源的温度,也就是工质吸热和放热时的温度,提高T1和T2,可以提高热效率。1) The thermal efficiency of the Carnot cycle is only determined by the temperature of the high-temperature heat source and the low-temperature heat source, that is, the temperature when the working medium absorbs heat and releases heat. Increasing T 1 and T 2 can improve thermal efficiency.

2)卡诺循环的热效率只能小于1,绝不能等于1,因为T1=∞或T2=0都不可能实现。这就是说,在循环发动机中即使在理想情况下,也不可能将热能全部转化为机械能,热效率当然更不可能大于1。2) The thermal efficiency of the Carnot cycle can only be less than 1, and must not be equal to 1, because neither T 1 =∞ nor T 2 =0 can be realized. That is to say, in a cycle engine, even under ideal conditions, it is impossible to convert all heat energy into mechanical energy, and it is certainly impossible for the thermal efficiency to be greater than 1.

3)当T1=T2时,循环热效率等于0,它表明,在温度平衡的体系中,热能不可能转化为机械能,热能产生动力一定要有温度差作为热力学条件,从而验证了借助单一热源连续做功的机器是制造不出的,或第二类永动机是不存在的。3) When T 1 =T 2 , the thermal efficiency of the cycle is equal to 0, which shows that in a temperature-balanced system, heat energy cannot be converted into mechanical energy, and the power generated by heat energy must have a temperature difference as a thermodynamic condition, thus verifying the use of a single heat source A machine that does work continuously cannot be manufactured, or the second type of perpetual motion machine does not exist.

4)卡诺循环及其热效率公式在热力学的发展上具有重大意义。首先,它奠定了热力学第二定律的理论基础;其次,卡诺循环的研究为提高各种热动力机热效率指出了方向,近可能提高工质的吸热温度和尽可能降低工质的放热温度,使放热在接近可自然得到的最低温度即大气温度时进行。卡诺循环中所提出的利用绝热压缩以提高气体吸热温度的方法,至今在以气体为工质的热动力机中仍普遍采用。4) The Carnot cycle and its thermal efficiency formula are of great significance in the development of thermodynamics. First of all, it laid the theoretical foundation for the second law of thermodynamics; secondly, the study of the Carnot cycle pointed out the direction for improving the thermal efficiency of various thermodynamic engines, and it is possible to increase the endothermic temperature of the working medium and reduce the exothermic temperature of the working medium as much as possible , so that the exotherm takes place near the lowest naturally obtainable temperature, that is, atmospheric temperature. The method proposed in the Carnot cycle to use adiabatic compression to increase the gas absorption temperature is still commonly used in thermodynamic engines using gas as the working medium.

5)卡诺循环的极限点是大气环境温度,对低于环境温度的制冷过程循环,卡诺循环并没有给出明确的答案。5) The limit point of the Carnot cycle is the atmospheric ambient temperature, and the Carnot cycle does not give a clear answer to the refrigeration process cycle below the ambient temperature.

由于制冷系数的不完善性,国内外众多的学者对其进行研究,并提出了完善建议。马一太等在《制冷与热泵产品的能效标准研究和循环热力学完善度的分析》中结合Curzon和Ahlborn把有温差传热这个不可逆过程引入热力循环的分析,以及由此创建的有限时间热力学的启发,结合CA循环效率,提出了CA正循环的热力学完善度,使制冷和热泵产品的能效研究有了一定程度的进展。Due to the imperfection of the refrigeration coefficient, many scholars at home and abroad have studied it and put forward suggestions for improvement. In "Research on Energy Efficiency Standards of Refrigeration and Heat Pump Products and Analysis of Cycle Thermodynamics Perfection", Ma Yitai combined Curzon and Ahlborn to introduce the irreversible process of heat transfer with temperature difference into the analysis of thermodynamic cycles, and the finite time thermodynamics created thereby. Inspired by the CA cycle efficiency, the thermodynamic perfection of the CA positive cycle was proposed, which made a certain degree of progress in the energy efficiency research of refrigeration and heat pump products.

但是运用热力学的基本理论并不能对制冷循环做出简洁、明了、直观的解释。爱因斯坦曾对经典热力学做过评价:“一种理论,其前提越简单,所涉及的事物越多,其适应范围愈广泛,它给人们的印象就越深刻。”对制冷领域的理论解释,也应继承和发扬这个优点。However, using the basic theory of thermodynamics cannot give a concise, clear and intuitive explanation to the refrigeration cycle. Einstein once commented on classical thermodynamics: "The simpler the premise of a theory, the more things it involves, and the wider its scope of application, the more impressive it will be to people." Theoretical explanations in the field of refrigeration , should also inherit and carry forward this advantage.

因此如何对制冷循环进行研究,真正找到制冷循环的理论基础,并在此理论基础上提出新的制冷循环装置应用于实际中,并有效减低能源的消耗,成为制冷技术领域研究的难点。Therefore, how to study the refrigeration cycle, truly find the theoretical basis of the refrigeration cycle, and propose a new refrigeration cycle device based on this theory to be applied in practice and effectively reduce energy consumption has become a difficult point in the field of refrigeration technology research.

发明内容Contents of the invention

本发明的目的就是为解决卡诺定理应用于制冷装置及制冷循环理论分析的不完善性,提出对应于热力学理论的新的制冷理论即冷力学理论,对于低于大气环境温度的环境称之为冷源,相对于高于环境温度的热源;相应于热能、热量,提出对应的冷能、冷量概念。所述的制冷装置,是指消耗机械功来实现冷能从大气环境向低温冷源或者从低温冷源向更低温冷源的转移。在实现冷能转换时,均需要某些物质作为制冷装置的工作物质,称为制冷工质。所述的制冷工质,是指在标准状态下沸点小于-10℃的单一组分的低沸点工质,或以标准状态下沸点小于-10℃的低沸点工质为制冷剂为主的混合制冷工质。The purpose of the present invention is to solve the incompleteness of Carnot's theorem applied to refrigeration equipment and refrigeration cycle theory analysis, to propose a new refrigeration theory corresponding to thermodynamic theory, that is, cold dynamics theory, which is called cold dynamics theory for the environment lower than the ambient temperature of the atmosphere. The cold source is relative to the heat source higher than the ambient temperature; corresponding to heat energy and heat, the corresponding concepts of cold energy and cold quantity are proposed. The refrigeration device refers to the consumption of mechanical work to realize the transfer of cold energy from the atmospheric environment to a low-temperature cold source or from a low-temperature cold source to a lower-temperature cold source. When realizing the conversion of cold energy, certain substances are required as the working substance of the refrigeration device, which is called the refrigerant. The refrigerant refers to a single-component low-boiling refrigerant with a boiling point of less than -10°C under standard conditions, or a mixture of low-boiling refrigerants with a boiling point of less than -10°C under standard conditions as the main refrigerant. Refrigeration medium.

制冷过程中冷能的传递遵循能量转化和守恒定律。The transfer of cold energy in the refrigeration process follows the law of energy conversion and conservation.

为描述制冷过程中冷量传递的方向、条件和限度,提出冷力学第二定律:冷力学第二定律的实质跟热力学第二定律的实质是一样的,同样遵循“能质衰贬原理”,即不同形式的冷能,在转换成功量的能力上是有“质”的差别的;即使是同一种形式的冷能,其存在状态不同时,它的转换能力也不同的。一切冷能传递的实际过程,总是朝着能质下降的方向进行,一切冷能总会自发向大气环境方向转换。冷能能质的提高过程不可能自动、单独地进行,一个能质的提高的过程必然伴随着另一个能质的下降的过程同时发生,这个能质下降的过程就是实现能质升高过程的必要的补偿条件,即以能质下降为代价、作为补偿来推动能质升高过程的实现。在实际过程中,作为代价的能质下降过程,必须足以补偿能质升高的过程,以满足总的能质必定下降的普遍规律。因此,在一定的能质下降的补偿条件下,能质升高的过程必然有一个最高的理论限度。只有在完全可逆的理想条件下,才能达到这个理论限度,这时,能质升高值正好等于能质下降的补偿值,使总的能质保持不变。可见,可逆过程是纯理想化的能质守恒过程;在不可逆过程中总的能质必然下降;在任何情况下都不可能实现使孤立系统总的能质升高的过程。这就是能质衰贬原理的物理内涵,是冷力学第二定律的实质,也是热力学第二定律的实质,它揭示了一切宏观过程必须遵循的、有关过程进行方向、条件及限度的客观规律。In order to describe the direction, conditions and limits of cold energy transfer in the refrigeration process, the second law of cold dynamics is proposed: the essence of the second law of cold dynamics is the same as that of the second law of thermodynamics, and it also follows the "principle of energy and mass decay". That is to say, different forms of cold energy have "qualitative" differences in their ability to convert into energy; even the same form of cold energy has different conversion capabilities when they exist in different states. The actual process of all cold energy transfer is always in the direction of energy quality decline, and all cold energy will always be spontaneously converted to the atmospheric environment. The process of improving the energy quality of cold energy cannot be carried out automatically and independently. One process of energy quality improvement must be accompanied by another process of energy quality decline. This process of energy quality decline is the process of realizing energy quality improvement The necessary compensation condition is to promote the realization of the process of energy quality improvement at the cost of energy quality decline and as compensation. In the actual process, the process of decreasing energy quality as a price must be sufficient to compensate for the process of increasing energy quality, so as to satisfy the general law that the total energy quality must decrease. Therefore, under certain compensation conditions for energy quality decline, the process of energy quality improvement must have a maximum theoretical limit. This theoretical limit can only be reached under perfectly reversible ideal conditions. At this time, the increase in energy quality is exactly equal to the compensation value for the decrease in energy quality, so that the total energy quality remains unchanged. It can be seen that the reversible process is a purely idealized energy-mass conservation process; the total energy-mass must decrease in the irreversible process; in any case, it is impossible to realize the process of increasing the total energy-mass of an isolated system. This is the physical connotation of the principle of energy-mass decay, the essence of the second law of cold dynamics, and the essence of the second law of thermodynamics. It reveals the objective laws of the direction, conditions and limits of the process that all macroscopic processes must follow.

描述冷力学第二定律的基本公式为:The basic formula describing the second law of cold dynamics is:

ηη cc == 11 -- TT cc 22 TT cc 11 -- -- -- (( 33 ))

公式(3)中,Tc2<Tc1<To,To为环境温度,均为开氏温标。In the formula (3), Tc2<Tc1<To, and To is the ambient temperature, both in Kelvin scale.

相对环境温度To而言,冷源在Tc1、Tc2下的最大冷效率为:Relative to the ambient temperature To, the maximum cooling efficiency of the cold source under Tc1 and Tc2 is:

&eta;&eta; cc == 11 -- TT cc 11 TT 00 -- -- -- (( 44 ))

&eta;&eta; cc == 11 -- TT cc 22 TT 00 -- -- -- (( 55 ))

假设为q2循环的制冷量,w0为循环所消耗的净功,则在冷源温度为Tc1时:Assuming that q 2 is the cooling capacity of the cycle, and w 0 is the net work consumed by the cycle, then when the temperature of the cold source is Tc1:

ww 00 == (( 11 -- TT cc 11 TT 00 )) qq 22 -- -- -- (( 66 ))

同样,在冷源温度为Tc2时:Similarly, when the cold source temperature is Tc2:

ww 00 == (( 11 -- TT cc 22 TT 00 )) qq 22 -- -- -- (( 77 ))

从公式(4)至(7)不难看出,冷力学的效率为0到1之间,由于实际过程中不可逆性的不可避免,制冷循环效率是小于1的;环境温度To确定时,冷源温度越低,输入同样的功,获得的制冷量越多,从而为构造新的制冷循环指明了方向。From the formulas (4) to (7), it is not difficult to see that the efficiency of cold mechanics is between 0 and 1. Due to the inevitable irreversibility in the actual process, the efficiency of the refrigeration cycle is less than 1; when the ambient temperature To is determined, the cooling source The lower the temperature, the more cooling capacity can be obtained with the same work input, which points out the direction for the construction of a new refrigeration cycle.

需要说明的是:It should be noted:

(1)冷量是自发从低温冷源向环境温度传递的;(1) The cooling capacity is spontaneously transferred from the low-temperature cold source to the ambient temperature;

(2)不可能把冷量从低温冷源传到更低的冷源而不引起其他变化;(2) It is impossible to transfer cold energy from a low-temperature cold source to a lower cold source without causing other changes;

(3)冷量从低温冷源传递向环境时,与外界交换的功量为w0,其中包含对环境所做的无用功p0(V0-Vc),p0为大气压力,Vo为环境温度下的体积,Vc为冷源温度下的体积,所能做的最大可逆有用功为:(3) When the cold energy is transferred from the low-temperature cold source to the environment, the amount of work exchanged with the outside world is w 0 , which includes the useless work done to the environment p 0 (V 0 -V c ), p 0 is the atmospheric pressure, and Vo is The volume at ambient temperature, Vc is the volume at the temperature of the cold source, and the maximum reversible useful work that can be done is:

(( WW uu )) maxmax == WW 00 -- pp 00 (( VV 00 -- VV cc )) == (( 11 -- TcTc ToTo )) QQ 00 -- pp 00 (( VV 00 -- VV cc ))

(4)冷量从低温冷源传递向环境时,向环境传递的无用能为:(4) When the cold energy is transferred from the low-temperature cold source to the environment, the useless energy transferred to the environment is:

向环境传递的无用功为:p0(V0-Vc)The useless work transferred to the environment is: p 0 (V 0 -V c )

对应于热量的有用能“”、无用能“烬”,对热量、冷量取水火会意,对于冷量的有用能,取名为“冷量涟”,冷量向环境传递的无用能称为“冷量浕”,“浕”读音为“尽”。Useful energy corresponding to heat" ", the useless energy "Jin", understands heat and cold, water and fire, and the useful energy of cold is named "cold ripple", and the useless energy transferred from cold to the environment is called "cold 浕", ""浕" is pronounced as "Jian".

(5)冷能向环境温度传递时,向外做功的最佳型式为采用塞贝克(Seebeck)效应的温差发电机,即冷力发电机;(5) When the cold energy is transferred to the ambient temperature, the best type of external work is a thermoelectric generator using the Seebeck effect, that is, a cold generator;

(6)冷力学中能量必须、也必然要符合能量转化和守恒定律;(6) Energy in cold mechanics must and must conform to the law of energy transformation and conservation;

(7)通过借鉴有限时间热力学的构思,可以发展有限时间冷力学基本理论;(7) By referring to the idea of finite-time thermodynamics, the basic theory of finite-time cold mechanics can be developed;

(8)不能脱离环境来评价冷量的品位。(8) The grade of cold capacity cannot be evaluated in isolation from the environment.

从上述理论基础可以看出,假设的冷力学具有和热力学对称的理论框架体系,符合科学美学的基本原则,即相反相成、对称原则。From the above theoretical basis, it can be seen that the hypothetical cold mechanics has a theoretical framework system that is symmetrical to thermodynamics, which is in line with the basic principles of scientific aesthetics, that is, opposites complement each other and the principle of symmetry.

基于上述基本原理,本发明提出不同于传统的冷力循环制冷方法及装置。Based on the above basic principles, the present invention proposes a refrigeration method and device different from the traditional refrigeration cycle.

本发明的目的是通过以下措施实现的:The object of the present invention is achieved by the following measures:

一种冷力循环制冷装置,其特征在于:A cold cycle refrigeration device, characterized in that:

从制冷剂贮罐1出来的液体制冷剂2,经液体循环泵3增压后,经用冷单元4出来的制冷剂5,经节流阀6节流后进入制冷剂贮罐1,从而形成制冷工质的冷力循环回路。The liquid refrigerant 2 from the refrigerant storage tank 1 is pressurized by the liquid circulation pump 3, and the refrigerant 5 from the cooling unit 4 enters the refrigerant storage tank 1 after being throttled by the throttle valve 6, thereby forming Refrigerant refrigerant circulation circuit.

所述的制冷工质即制冷剂,是指在标准状态下沸点小于-10℃的单一组分的低沸点制冷工质,或以标准状态下沸点小于-10℃的低沸点制冷工质为主的混合制冷工质。The refrigerant is the refrigerant, which refers to a single-component low-boiling refrigerant with a boiling point of less than -10°C under standard conditions, or a low-boiling refrigerant with a boiling point of less than -10°C under standard conditions. mixed refrigerant.

设有回冷器7:从制冷剂贮罐1出来的液体制冷剂2,经液体循环泵3增压后,经回冷器7、用冷单元4、回冷器7出来的制冷剂5,经节流阀6节流后进入制冷剂贮罐1,从而形成制冷工质的冷力循环回路。There is a recooler 7: the liquid refrigerant 2 from the refrigerant storage tank 1 is pressurized by the liquid circulation pump 3, and then the refrigerant 5 from the recooler 7, the cooling unit 4, and the recooler 7, After throttling by the throttle valve 6, it enters the refrigerant storage tank 1, thereby forming a cold cycle circuit of the refrigerant.

设有节流阀8、回冷器9、回冷器10、回冷器11、节流阀12:从制冷剂贮罐1出来的液体制冷剂2,经液体循环泵3、过回冷器11后进行分流,其中分流出的一路制冷剂经节流阀8、回冷器9、回冷器10、回冷器11、节流阀12返回制冷剂贮罐1,另外一路制冷剂经回冷器10、用冷单元4、回冷器9、节流阀6返回制冷剂贮罐1,从而形成制冷剂的冷力循环回路。Throttle valve 8, recooler 9, recooler 10, recooler 11, throttle valve 12: the liquid refrigerant 2 from the refrigerant storage tank 1 passes through the liquid circulation pump 3, and the recooler After 11, the flow is divided, and the refrigerant flowing out of one path returns to the refrigerant storage tank 1 through the throttle valve 8, the recooler 9, the recooler 10, the recooler 11, and the throttle valve 12, and the other refrigerant flows through the return The cooler 10, the cooling unit 4, the recooler 9, and the throttle valve 6 return to the refrigerant storage tank 1, thereby forming a refrigerant cycle loop.

设有节流阀8、回冷器9、回冷器10、回冷器11、节流阀12:从制冷剂贮罐1出来的液体制冷剂2,经液体循环泵3、过回冷器11后进行分流,其中分流出的一路制冷剂经节流阀8、回冷器9、回冷器10、回冷器11、节流阀12返回制冷剂贮罐1,另外一路制冷剂经回冷器10、回冷器7、用冷单元4、回冷器7、回冷器9、节流阀6返回制冷剂贮罐1,从而形成制冷剂的冷力循环回路。Throttle valve 8, recooler 9, recooler 10, recooler 11, throttle valve 12: the liquid refrigerant 2 from the refrigerant storage tank 1 passes through the liquid circulation pump 3, and the recooler After 11, the flow is divided, and the refrigerant flowing out of one path returns to the refrigerant storage tank 1 through the throttle valve 8, the recooler 9, the recooler 10, the recooler 11, and the throttle valve 12, and the other refrigerant flows through the return The cooler 10, the recooler 7, the cooling unit 4, the recooler 7, the recooler 9, and the throttling valve 6 return to the refrigerant storage tank 1, thereby forming a refrigerant cycle loop.

所述的用冷单元4包括但不限于空调、冷库等用冷设备。The cooling unit 4 includes but not limited to air conditioners, refrigerators and other cooling equipment.

所述的回冷器7、回冷器9、回冷器10、回冷器11即传统制冷循环中所谓的回热器、热交换器,采用管壳式换冷器、板翅式换冷器、微通道换冷器或其他型式的换冷器,其结构与传统制冷循环中的管壳式换热器、板翅式换热器、微通道换热器等的结构相同或相似。The recooler 7, recooler 9, recooler 10, and recooler 11 are the so-called regenerators and heat exchangers in the traditional refrigeration cycle. Its structure is the same or similar to that of shell-and-tube heat exchangers, plate-fin heat exchangers, and micro-channel heat exchangers in traditional refrigeration cycles.

所述的制冷剂贮罐1采用绝热保冷措施,如采用绝热真空容器、珠光砂等隔热保冷材料。The refrigerant storage tank 1 adopts heat insulation and cold insulation measures, such as heat insulation and cold insulation materials such as vacuum containers and pearl sand.

本发明中未说明的设备及其备用系统、管道、仪表、阀门、保冷、具有调节功能旁路设施等采用公知的传统制冷循环中的成熟技术进行配套。Equipment not described in the present invention and its backup system, pipelines, instruments, valves, cold insulation, bypass facilities with regulating functions, etc. are matched with well-known mature technologies in traditional refrigeration cycles.

本发明的装置同样适用于开式冷力制冷系统:即经节流阀6或节流阀12降压、降温的制冷剂外供用于其他用冷单元,向制冷剂贮罐补充相同质量、数量的制冷剂,从而形成制冷剂的能质平衡。The device of the present invention is also applicable to open-type cold refrigeration systems: that is, the refrigerant depressurized and cooled by the throttle valve 6 or the throttle valve 12 is externally supplied to other cooling units, and the same quality and quantity are added to the refrigerant storage tank. The refrigerant, thus forming the energy-mass balance of the refrigerant.

设有与本发明的制冷循环装置配套的安全、调控设施,使装置能经济、安全、高热效率运行,达到节能降耗、环保的目的。Equipped with safety and control facilities matched with the refrigeration cycle device of the present invention, the device can operate economically, safely and with high thermal efficiency, and achieve the goals of energy saving, consumption reduction and environmental protection.

本发明相比现有技术具有如下优点:Compared with the prior art, the present invention has the following advantages:

1、节能效果显著:取代传统制冷循环中的蒸汽压缩式制冷机组,利用液体的接近不可压缩流体的性质,采用低温液体循环泵进行增压替代,结合冷力学第二定律,能够有效提高制冷循环的效率,与传统制冷装置相比,相同制冷量的节能率可达30%以上。1. Significant energy-saving effect: replace the vapor compression refrigeration unit in the traditional refrigeration cycle, use the liquid’s close to incompressible fluid properties, use a low-temperature liquid circulation pump for pressurization instead, and combine the second law of cold mechanics to effectively improve the refrigeration cycle. Compared with traditional refrigeration equipment, the energy saving rate of the same cooling capacity can reach more than 30%.

2、无需传统蒸汽压缩式制冷循环中的冷凝器及其配套的冷却水系统,流程设置更加简洁,更符合节能环保原则。2. There is no need for the condenser and its supporting cooling water system in the traditional vapor compression refrigeration cycle, the process setting is more concise, and it is more in line with the principle of energy saving and environmental protection.

3、回冷器可以封存在一个装置中,跑冷损失减少。3. The recooler can be sealed in a device, reducing the cooling loss.

4、设备的维修工作量较传统的制冷循环有极大程度的降低,可以方便地采用无油润滑技术,消除传统蒸汽压缩机润滑油的变质以及对制冷循环的影响,维修及运行成本下降较多。4. The maintenance workload of the equipment is greatly reduced compared with the traditional refrigeration cycle, and the oil-free lubrication technology can be easily adopted to eliminate the deterioration of the lubricating oil of the traditional steam compressor and the impact on the refrigeration cycle, and the maintenance and operation costs are reduced. many.

5、传热强化:较传统的制冷循环技术,可以更方便地采用强化传冷元件,制冷设备及其制冷效率更加紧凑、高效。。5. Heat transfer enhancement: Compared with the traditional refrigeration cycle technology, it is more convenient to use enhanced cold transfer elements, and the refrigeration equipment and its refrigeration efficiency are more compact and efficient. .

附图说明Description of drawings

图1是本发明的一种冷力循环制冷装置流程示意图。Fig. 1 is a schematic flow diagram of a cold cycle refrigeration device of the present invention.

图1中:1-制冷剂贮罐,2-液体制冷剂,3-液体循环泵,4-用冷单元,5-制冷剂,6-节流阀,7-回冷器,8-节流阀,9-回冷器,10-回冷器,11-回冷器,12-节流阀。In Figure 1: 1-refrigerant storage tank, 2-liquid refrigerant, 3-liquid circulation pump, 4-cooling unit, 5-refrigerant, 6-throttle valve, 7-refrigerator, 8-throttling Valve, 9-regenerator, 10-regenerator, 11-regenerator, 12-throttle valve.

具体实施方式Detailed ways

以下结合附图和具体实施例对本发明作进一步详细描述。The present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

实施例1:Example 1:

如图1所示,一种冷力循环制冷装置,制冷剂采用液氮,具体实施例如下:As shown in Figure 1, a cold cycle refrigeration device, the refrigerant adopts liquid nitrogen, the specific examples are as follows:

从制冷剂贮罐1出来的液体制冷剂2,经液体循环泵3、过回冷器11后进行分流,其中分流出的一路制冷剂经节流阀8、回冷器9、回冷器10、回冷器11、节流阀12返回制冷剂贮罐1,另外一路制冷剂经回冷器10、回冷器7、用冷单元4、回冷器7、回冷器9、节流阀6返回制冷剂贮罐1,从而形成制冷剂的冷力循环回路。The liquid refrigerant 2 coming out of the refrigerant storage tank 1 is divided after passing through the liquid circulation pump 3 and the sub-refrigerator 11, and the refrigerant flowing out of it passes through the throttling valve 8, the sub-cooler 9 and the sub-refrigerator 10 , recooler 11, throttling valve 12 return to the refrigerant storage tank 1, and another way of refrigerant passes through recooler 10, recooler 7, cooling unit 4, recooler 7, recooler 9, throttle valve 6 to return to the refrigerant storage tank 1, thereby forming a refrigeration cycle of the refrigerant.

所述的回冷器7、回冷器9、回冷器10、回冷器11采用传统的板翅式换热器或微通道换热器;所述的制冷剂贮罐1采用绝热真空容器,采用珠光砂为隔热保冷材料。The recooler 7, recooler 9, recooler 10, and recooler 11 adopt traditional plate-fin heat exchangers or micro-channel heat exchangers; the refrigerant storage tank 1 adopts an insulated vacuum container , Pearlescent sand is used as heat insulation and cold insulation material.

本发明中未说明的设备及其备用系统、管道、仪表、阀门、保冷、具有调节功能旁路设施等采用公知的传统制冷循环中的成熟技术进行配套。Equipment not described in the present invention and its backup system, pipelines, instruments, valves, cold insulation, bypass facilities with regulating functions, etc. are matched with well-known mature technologies in traditional refrigeration cycles.

设有与本发明的制冷循环装置配套的安全、调控设施,使装置能经济、安全、高热效率运行,达到节能降耗、环保的目的。Equipped with safety and control facilities matched with the refrigeration cycle device of the present invention, the device can operate economically, safely and with high thermal efficiency, and achieve the goals of energy saving, consumption reduction and environmental protection.

虽然本发明已以较佳实施例公开如上,但它们并不是用来限定本发明,任何熟悉此技艺者,在不脱离本发明之精神和范围内,自当可作各种变化或润饰,同样属于本发明之保护范围。因此本发明的保护范围应当以本申请的权利要求所界定的为准。Although the present invention has been disclosed above with preferred embodiments, they are not intended to limit the present invention, and any skilled person can make various changes or modifications without departing from the spirit and scope of the present invention. Belong to the protection scope of the present invention. Therefore, the protection scope of the present invention should be defined by the claims of the present application.

Claims (6)

1.一种冷力循环制冷装置,其特征在于: 1. A cold cycle refrigeration device, characterized in that: 所述的冷力循环,是指从制冷剂贮罐(1) 出来的液体制冷剂(2),经液体循环泵(3) 增压后,经用冷单元(4)出来的制冷剂(5),经第一节流阀(6) 节流后进入制冷剂贮罐(1),从而形成制冷工质的冷力循环回路; The cold cycle refers to the liquid refrigerant (2) coming out of the refrigerant storage tank (1), after being pressurized by the liquid circulation pump (3), the refrigerant (5) coming out of the cooling unit (4) ), enters the refrigerant storage tank (1) after throttling by the first throttle valve (6), thereby forming a cold cycle circuit of the refrigerant; 所述的制冷剂(2) 即制冷工质,是指在标准状态下沸点小于-10℃的单一组分的低沸点制冷工质,或以标准状态下沸点小于-10℃的低沸点制冷工质为主的混合制冷工质。 The above-mentioned refrigerant (2) is a refrigerant, which refers to a single-component low-boiling refrigerant with a boiling point of less than -10°C under standard conditions, or a low-boiling refrigerant with a boiling point of less than -10°C under standard conditions. Quality-based mixed refrigerant. 2.根据权利要求1所述的装置,其特征在于: 2. The device according to claim 1, characterized in that: 设有第一回冷器(7):从制冷剂贮罐(1) 出来的液体制冷剂(2),经液体循环泵(3) 增压后,经第一回冷器(7)、用冷单元(4)、第一回冷器(7) 出来的制冷剂(5),经第一节流阀(6) 节流后进入制冷剂贮罐(1),从而形成制冷工质的冷力循环回路。 There is a first recooler (7): the liquid refrigerant (2) coming out of the refrigerant storage tank (1) is pressurized by the liquid circulation pump (3), then passes through the first recooler (7), The refrigerant (5) from the cold unit (4) and the first recooler (7) enters the refrigerant storage tank (1) after being throttled by the first throttle valve (6), thereby forming a cooling power cycle. 3.根据权利要求1或2所述的装置,其特征在于: 3. The device according to claim 1 or 2, characterized in that: 设有第二节流阀(8)、第二回冷器(9)、第三回冷器(10)、第四回冷器(11)、第三节流阀(12):从制冷剂贮罐(1)出来的液体制冷剂(2),经液体循环泵(3)、第四回冷器(11)后进行分流,其中一路制冷剂经第二节流阀(8)、第二回冷器(9)、第三回冷器(10)、第四回冷器(11)、第三节流阀(12)返回制冷剂贮罐(1),另外一路制冷剂经第三回冷器(10)、用冷单元(4)、第二回冷器(9)、第一节流阀(6)返回制冷剂贮罐(1),从而形成制冷剂的冷力循环回路。 There are a second throttle valve (8), a second recooler (9), a third recooler (10), a fourth recooler (11), and a third throttle valve (12): from the refrigerant The liquid refrigerant (2) from the storage tank (1) is divided after passing through the liquid circulation pump (3) and the fourth recooler (11), and one of the refrigerants passes through the second throttle valve (8), the second The recooler (9), the third recooler (10), the fourth recooler (11), and the third throttle valve (12) return to the refrigerant storage tank (1), and the other refrigerant goes through the third circuit The cooler (10), the cooling unit (4), the second recooler (9), and the first throttle valve (6) return to the refrigerant storage tank (1), thereby forming a refrigerant cycle circuit. 4.根据权利要求3所述的装置,其特征在于: 4. The device according to claim 3, characterized in that: 从制冷剂贮罐(1)出来的液体制冷剂(2),经液体循环泵(3)、第四回冷器(11)后进行分流,其中一路制冷剂经第二节流阀(8)、第二回冷器(9)、第三回冷器(10)、第四回冷器(11)、第三节流阀(12)返回制冷剂贮罐(1),另外一路制冷剂经第三回冷器(10)、第一回冷器(7)、用冷单元(4)、第一回冷器(7)、第二回冷器(9)、第一节流阀(6)返回制冷剂贮罐(1),从而形成制冷剂的冷力循环回路。 The liquid refrigerant (2) from the refrigerant storage tank (1) is divided after passing through the liquid circulation pump (3) and the fourth recooler (11), and one of the refrigerants passes through the second throttling valve (8) , the second recooler (9), the third recooler (10), the fourth recooler (11), and the third throttling valve (12) return to the refrigerant storage tank (1), and the other refrigerant passes through The third recooler (10), the first recooler (7), the cooling unit (4), the first recooler (7), the second recooler (9), the first throttle valve (6 ) to return to the refrigerant storage tank (1), thereby forming a cold cycle circuit of the refrigerant. 5.根据权利要求4所述的装置,其特征在于: 5. The device according to claim 4, characterized in that: 所述的装置同样适用于开式制冷系统:即经第一节流阀(6)或第三节流阀(12)降压、降温的制冷剂外供用于其他用冷单元,向制冷剂贮罐(1)补充相同成分、质量的制冷剂,从而形成制冷剂的能质平衡。 The device described above is also applicable to open refrigeration systems: that is, the refrigerant depressurized and cooled by the first throttle valve (6) or the third throttle valve (12) is externally used for other cooling units, and is supplied to the refrigerant storage unit. The tank (1) supplements the refrigerant with the same composition and quality, so as to form the energy-mass balance of the refrigerant. 6.根据权利要求1所述的装置,其特征在于: 6. The device according to claim 1, characterized in that: 所述的装置同样适用于开式制冷系统:即经第一节流阀(6)降压、降温的制冷剂外供用于其他用冷单元,向制冷剂贮罐(1)补充相同成分、质量的制冷剂,从而形成制冷剂的能质平衡。 The device described above is also applicable to open refrigeration systems: that is, the refrigerant depressurized and cooled by the first throttling valve (6) is externally used for other cooling units, and the refrigerant storage tank (1) is replenished with the same composition and quality The refrigerant, thus forming the energy-mass balance of the refrigerant.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5046320A (en) * 1990-02-09 1991-09-10 National Refrigeration Products Liquid refrigerant transfer method and system
CN2085936U (en) * 1990-08-30 1991-10-02 孙洪宽 Refrigerator
WO2009122455A1 (en) * 2008-04-04 2009-10-08 Giuseppe Floris Heat exchanger operating at different pressures
CN102522180A (en) * 2011-12-29 2012-06-27 中国电子科技集团公司第十六研究所 Liquid nitrogen closed cycle system for SQUID (superconducting quantum interference device) probe
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