CN103146149B - 一种固化剂组合物及其制备方法和应用 - Google Patents
一种固化剂组合物及其制备方法和应用 Download PDFInfo
- Publication number
- CN103146149B CN103146149B CN201310074411.0A CN201310074411A CN103146149B CN 103146149 B CN103146149 B CN 103146149B CN 201310074411 A CN201310074411 A CN 201310074411A CN 103146149 B CN103146149 B CN 103146149B
- Authority
- CN
- China
- Prior art keywords
- solidifying agent
- curing agent
- acid
- polyamide
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 47
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 97
- 239000003822 epoxy resin Substances 0.000 claims abstract description 36
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 36
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 20
- 229920000768 polyamine Polymers 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 14
- 239000004698 Polyethylene Substances 0.000 claims abstract description 12
- -1 polyethylene Polymers 0.000 claims abstract description 12
- 229920000573 polyethylene Polymers 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 42
- 229920002292 Nylon 6 Polymers 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000004033 plastic Substances 0.000 claims description 17
- 229920003023 plastic Polymers 0.000 claims description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 150000002632 lipids Chemical class 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- 238000007711 solidification Methods 0.000 claims description 10
- 230000008023 solidification Effects 0.000 claims description 10
- 229910001220 stainless steel Inorganic materials 0.000 claims description 10
- 239000010935 stainless steel Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 238000007493 shaping process Methods 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- 229960004232 linoleic acid Drugs 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000011054 acetic acid Nutrition 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 235000021313 oleic acid Nutrition 0.000 claims description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 229960001124 trientine Drugs 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229940098695 palmitic acid Drugs 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 238000010189 synthetic method Methods 0.000 claims description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 abstract description 11
- 239000004593 Epoxy Substances 0.000 abstract description 6
- 239000004952 Polyamide Substances 0.000 abstract description 3
- 229920002647 polyamide Polymers 0.000 abstract description 3
- 239000011148 porous material Substances 0.000 abstract description 3
- 230000006641 stabilisation Effects 0.000 abstract description 3
- 238000011105 stabilization Methods 0.000 abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 2
- 229930195729 fatty acid Natural products 0.000 abstract description 2
- 239000000194 fatty acid Substances 0.000 abstract description 2
- 150000004665 fatty acids Chemical class 0.000 abstract description 2
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 abstract description 2
- 239000000539 dimer Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 150000008431 aliphatic amides Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310074411.0A CN103146149B (zh) | 2013-03-10 | 2013-03-10 | 一种固化剂组合物及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310074411.0A CN103146149B (zh) | 2013-03-10 | 2013-03-10 | 一种固化剂组合物及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103146149A CN103146149A (zh) | 2013-06-12 |
CN103146149B true CN103146149B (zh) | 2015-02-25 |
Family
ID=48544491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310074411.0A Expired - Fee Related CN103146149B (zh) | 2013-03-10 | 2013-03-10 | 一种固化剂组合物及其制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103146149B (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104803867B (zh) * | 2014-11-28 | 2016-12-28 | 上海美东生物材料股份有限公司 | 一种腰果酚改性环氧树脂固化剂的制备方法 |
CN106220844B (zh) * | 2016-07-26 | 2018-06-26 | 湖北绿色家园材料技术股份有限公司 | 一种低成本、环保型聚酰胺类环氧树脂固化剂 |
CN106046326A (zh) * | 2016-07-27 | 2016-10-26 | 中科院广州化学有限公司南雄材料生产基地 | 一种环氧树脂透水材料固化剂及其制备方法和应用 |
CN106589318A (zh) * | 2016-11-30 | 2017-04-26 | 江苏芯锐传感科技有限公司 | 超柔环氧固化剂组合物及其制备方法 |
CN106916321B (zh) * | 2017-01-12 | 2021-07-30 | 上海小海龟科技有限公司 | 一种油包水连续相、其制备方法及应用 |
CN106995525A (zh) * | 2017-05-19 | 2017-08-01 | 江苏三木化工股份有限公司 | 一种硫脲改性的聚酰胺环氧固化剂及制备方法 |
CN111032595A (zh) * | 2017-08-11 | 2020-04-17 | 康宁股份有限公司 | 包含反相乳液的生坯陶瓷批料混合物及形成陶瓷体的方法 |
CN110564332B (zh) * | 2019-09-24 | 2020-07-31 | 苏州世华新材料科技股份有限公司 | 一种弹性压敏胶层、压敏胶带及压敏胶带的制备方法 |
CN113462260A (zh) * | 2021-06-08 | 2021-10-01 | 成都上筑建材有限公司 | 一种空心石膏大板芯管脱模的方法 |
CN116042131B (zh) * | 2023-01-31 | 2024-07-23 | 哈尔滨工业大学 | 一种纳米导电粘接剂的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1962757A (zh) * | 2006-05-25 | 2007-05-16 | 山东轻工业学院 | 陶瓷成型用环氧树脂基模具材料及其制备方法 |
CN101602854A (zh) * | 2009-07-23 | 2009-12-16 | 福州百盛精细化学品有限公司 | 一种聚酰胺环氧固化剂及其制备方法 |
CN101613471A (zh) * | 2009-07-23 | 2009-12-30 | 福州百盛精细化学品有限公司 | 聚酰胺环氧固化剂及其制备方法 |
-
2013
- 2013-03-10 CN CN201310074411.0A patent/CN103146149B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1962757A (zh) * | 2006-05-25 | 2007-05-16 | 山东轻工业学院 | 陶瓷成型用环氧树脂基模具材料及其制备方法 |
CN101602854A (zh) * | 2009-07-23 | 2009-12-16 | 福州百盛精细化学品有限公司 | 一种聚酰胺环氧固化剂及其制备方法 |
CN101613471A (zh) * | 2009-07-23 | 2009-12-30 | 福州百盛精细化学品有限公司 | 聚酰胺环氧固化剂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
刘登良."涂料合成树脂工".《涂料合成树脂工》.2007, * |
Also Published As
Publication number | Publication date |
---|---|
CN103146149A (zh) | 2013-06-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103146149B (zh) | 一种固化剂组合物及其制备方法和应用 | |
CN109982786B (zh) | 覆膜砂和其制造方法以及使用其的铸型的制造方法 | |
CN104325065B (zh) | 一种覆膜砂及其制备方法 | |
CN106633656B (zh) | 一种较低粘度下微孔发泡环氧树脂基材料的制备方法 | |
KR20040047545A (ko) | 금속 비누를 포함하는 레이저 소결 분말, 이의 제조방법및 이러한 레이저 소결 분말로부터 제조된 성형체 | |
CN103113544B (zh) | 一种酚醛改性胺类固化剂及其制备方法 | |
CN110099761A (zh) | 覆膜砂和其制造方法以及使用其的铸型的制造方法 | |
WO2018043412A1 (ja) | 鋳型の製造方法 | |
CN102443126A (zh) | 低温发泡酚醛树脂、其制备方法及改性酚醛泡沫的制备方法 | |
CN104010518A (zh) | 充气的巧克力 | |
CN104448713B (zh) | 一种开孔型导热性环氧基复合多孔材料及其制法与应用 | |
CN105647166B (zh) | 一种相变储能型沥青聚氨酯硬质泡沫及其制备方法 | |
CN105063460A (zh) | 一种不锈钢泡沫金属的制备方法 | |
CN106046326A (zh) | 一种环氧树脂透水材料固化剂及其制备方法和应用 | |
CN102616767A (zh) | 一种泡沫炭复合材料及其制备方法 | |
CN109982785A (zh) | 覆膜砂和其制造方法以及使用其的铸型的制造方法 | |
CN104496523B (zh) | 一种陶瓷泡沫固化成型的方法 | |
CN106279674B (zh) | 聚酰胺组合物及其制备方法 | |
RU2060239C1 (ru) | Состав для изготовления теплоизоляционного материала | |
CN103194040A (zh) | 一种酚醛树脂组合物 | |
CN107216601A (zh) | 一种腐殖酸改性增强酚醛泡沫材料及其制备方法 | |
CN108453213B (zh) | 陶瓷空心微粒、制备方法以及包含其的铸造用粘合树脂 | |
CN106243716A (zh) | 纳米陶瓷粉改性双马来酰亚胺树脂制备复合材料的方法 | |
CN103113556A (zh) | 适用于环氧树脂基微孔陶瓷成型模具的固化剂制备方法 | |
CN202344747U (zh) | 热固性树脂基发泡复合板材的挤出成型设备 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent for invention or patent application | ||
CB02 | Change of applicant information |
Address after: 250353 Science Park, West University Town, University Road, Changqing District, Ji'nan, Shandong Applicant after: Qilu University of Technology Address before: 250353 Science Park, West University Town, University Road, Changqing District, Ji'nan, Shandong Applicant before: Shandong Institute of Light Industry |
|
COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SHANDONG INSTITUTE OF LIGHT INDUSTRY TO: QILU UNIVERSITY OF TECHNOLOGY |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150225 Termination date: 20160310 |
|
CF01 | Termination of patent right due to non-payment of annual fee |