CN103113604B - The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves - Google Patents
The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves Download PDFInfo
- Publication number
- CN103113604B CN103113604B CN201310031083.6A CN201310031083A CN103113604B CN 103113604 B CN103113604 B CN 103113604B CN 201310031083 A CN201310031083 A CN 201310031083A CN 103113604 B CN103113604 B CN 103113604B
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- prepreg
- preparation
- polyurethane prepolymer
- base polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001730 Moisture cure polyurethane Polymers 0.000 title claims abstract description 22
- 238000013035 low temperature curing Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000003822 epoxy resin Substances 0.000 claims abstract description 50
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 50
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000012948 isocyanate Substances 0.000 claims abstract description 16
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- DGUJJOYLOCXENZ-UHFFFAOYSA-N 4-[2-[4-(oxiran-2-ylmethoxy)phenyl]propan-2-yl]phenol Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 DGUJJOYLOCXENZ-UHFFFAOYSA-N 0.000 claims description 10
- -1 polyoxyethylene Polymers 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000002313 adhesive film Substances 0.000 claims description 8
- 238000013329 compounding Methods 0.000 claims description 8
- 150000003672 ureas Chemical class 0.000 claims description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 6
- 229920003986 novolac Polymers 0.000 claims description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 4
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 claims description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 3
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 229940106691 bisphenol a Drugs 0.000 claims description 2
- VOOLKNUJNPZAHE-UHFFFAOYSA-N formaldehyde;2-methylphenol Chemical compound O=C.CC1=CC=CC=C1O VOOLKNUJNPZAHE-UHFFFAOYSA-N 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 2
- 239000012528 membrane Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 9
- 238000001723 curing Methods 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention provides the preparation method of low temperature curing prepreg interlaminar shear strength in the improvement of a kind of base polyurethane prepolymer for use as.First isocyanic ester and polyether glycol are obtained by reacting isocyanate terminated base polyurethane prepolymer for use as by proportion-controllable by the method, again by isocyanate terminated base polyurethane prepolymer for use as reactive grafting to bisphenol-type epoxy resin, and add composition epoxy resin and obtain toughening-modifiedepoxy resin matrix, then mix with solidifying agent and promoter component and obtain prepreg resin system, finally resin system is prepared into glued membrane, with fortifying fibre or fabric compound, the middle low temperature curing prepreg that preparation cohesiveness is excellent.Prepreg preparation technology of the present invention is reasonable, and the cohesive strength of resin system and fiber is high, and the interlaminar shear strength of matrix material obtains and obviously improves, and is particularly useful for the prepreg of low-temperature curing.
Description
Technical field
The present invention relates to field of compound material, relate in particular to the preparation method of low temperature curing prepreg interlaminar shear strength in the improvement of a kind of base polyurethane prepolymer for use as.
Background technology
Along with the maturation day by day of prepreg technology, prepreg is applied to the manufacture of large-scale composite material component more and more widely, as wind power generation blade, automotive composite material component etc.Because middle low temperature curing prepreg has unique advantage in starting material, technique, production technology, suitability etc., especially the die cost of large-scale component can be saved, extend the mold use life-span, therefore, low temperature curing prepreg is more and more favored.
Because fiber, resin are different from the thermal expansivity of mold material, matrix material shrinks seriously on curing at elevated temperature, inevitablely produces internal stress at material internal, easily cause the warpage of large-scale component.Reduce solidification value, can reduce the internal stress of matrix material, but to compare hot setting matrix material lower due to cross-linked network density, middle low-temperature curing composite property is on the low side, and especially the interlaminar shear strength of matrix material is on the low side.Therefore while low-temperature curing, need the Interlaminar shear strengths improving matrix material further, improve the weather resistance of matrix material in guarantee prepreg.
Summary of the invention
The object of the invention is for the problem on the low side of low temperature curing prepreg interfacial bond property in solution, the preparation method of low temperature curing prepreg interlaminar shear strength in being improved by a kind of base polyurethane prepolymer for use as, utilize high bond strength and the shock-resistance of polyurethane modified epoxy resin, obtain the prepreg that a kind of resin and fiber have high-peeling strength and high interlaminar shear strength.
Main technical schemes of the present invention: isocyanic ester and polyether glycol add in reactor according to the molar ratio of 2:1 ~ 4:3 by (1), in 70 DEG C of reaction 4 ~ 6h, obtains isocyanate terminated base polyurethane prepolymer for use as; (2) isocyanate terminated base polyurethane prepolymer for use as and bisphenol-type epoxy resin are reacted 5 ~ 8h in the stirring tank of 60 ~ 100 DEG C, obtain the epoxy resin of polyurethane grafted modification, then add composition epoxy resin to stir, obtain toughening-modifiedepoxy resin matrix; (3) in above-mentioned toughening-modifiedepoxy resin matrix, add solidifying agent and promoter component, mix final vacuum deaeration, prepare epoxy resin for prepreg system; (4) above-mentioned epoxy-resin systems is adopted adhesive film machine film, then via compounding machine and fortifying fibre or fabric compound, prepare the middle low temperature curing prepreg that cohesiveness is excellent.
Described isocyanic ester is one or more in diphenylmethanediisocyanate (MDI), tolylene diisocyanate (TDI), hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI); Described polyether glycol is one or more in polyoxyethylene glycol or poly(propylene oxide).
The molecular weight of described isocyanate terminated base polyurethane prepolymer for use as is 1000 ~ 2500.
Described bisphenol-type epoxy resin matrix can be one or more in bis-phenol A glycidyl ether, Bisphenol F glycidyl ether, dihydroxyphenyl propane D glycidyl ether; Described composition epoxy resin can be the mixed assemblage of bisphenol-type epoxy resin and novolac epoxy, o-cresol formaldehyde epoxy resin, bisphenol-A phenolic epoxy resin, glycidyl amine type epoxy resin.
Described isocyanate terminated base polyurethane prepolymer for use as is 5:100 ~ 15:100 with the massfraction ratio of all epoxy resin.
Described solidifying agent can be Dyhard RU 100, the one of modified dicyandiamine or its combination, and described promotor can be one or more in carbamide derivative, imdazole derivatives.
Relative to 100 parts of epoxy resin, the mass fraction of described solidifying agent is 5 ~ 10 parts, and the mass fraction of described promotor is 1 ~ 5 part.
The middle low temperature curing prepreg that described cohesiveness is excellent, its solidification value is 80 ~ 120 DEG C.
Effect of the present invention is, utilize urethane and epoxy resin compound, unique interpenetrating polymer networks (IPN) system can be formed, IPN structure force mutual tolerance and synergistic effect, the snappiness of urethane and the good heat resistance of epoxy resin and cementability are organically combined, polyurethane-modified epoxy-resin systems is made to have high-adhesive-strength, good shock-resistance and excellent lap shear strength, especially can be used for the adhesive property improving fibre reinforced prepreg, thus give the high stripping strength of prepreg and good interlaminar shear strength.The interlaminar shear strength of the prepreg that effect of the present invention is solidified for lesser temps is more obvious, specifically sees Fig. 1.
Accompanying drawing explanation
Fig. 1 is the interlaminar shear strength schematic diagram of different prepreg system.
Embodiment
Below by way of specific embodiment, more detailed description is done to the present invention:
Embodiment 1:
Isophorone diisocyanate (IPDI) and poly(propylene oxide) are added in reactor according to the molar ratio of 4:3, in 70 DEG C of reaction 6h, obtain the isocyanate terminated base polyurethane prepolymer for use as that molecular weight is 2500, by 15 parts of (mass fractions, be 100 parts with the final consumption of epoxy resin to calculate, down together) isocyanate terminated base polyurethane prepolymer for use as and bis-phenol A glycidyl ether epoxy resin react 8h in the stirring tank of 60 DEG C, then bis-phenol A glycidyl ether epoxy resin is added and glycidyl amine type epoxy resin stirs, obtain toughening-modifiedepoxy resin matrix, add 10 parts of dicy-curing agents and 5 parts of carbamide derivative promotor again, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and fortifying fibre compound, prepares Unidirectional fiber prepreg, the prepreg cut is placed in mould, in 80 DEG C of cure under pressures 8 hours, obtain composite board, test interlaminar shear strength was 81MPa.
Embodiment 2:
Diphenylmethanediisocyanate (MDI) and polyoxyethylene glycol are added in reactor according to the molar ratio of 5:3, in 70 DEG C of reaction 5h, obtain the isocyanate terminated base polyurethane prepolymer for use as that molecular weight is 1800, 10 parts of isocyanate terminated base polyurethane prepolymer for use as and Bisphenol F tetraglycidel ether epoxy resin are reacted 7h in the stirring tank of 80 DEG C, then bis-phenol A glycidyl ether epoxy resin is added and novolac epoxy stirs, obtain toughening-modifiedepoxy resin matrix, add 6 parts of modified dicyandiamine solidifying agent and 3 parts of carbamide derivative promotor again, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and enhanced fabrics compound, prepares carbon fibre fabric prepreg, the prepreg of cutting is placed in mould, in 100 DEG C of cure under pressures 3 hours, obtain composite board, test interlaminar shear strength was 85MPa.
Embodiment 3:
Toluene di-iso-cyanide ester (TDI) and polyoxyethylene glycol are added in reactor according to the molar ratio of 2:1, in 70 DEG C of reaction 4h, obtain the isocyanate terminated base polyurethane prepolymer for use as that molecular weight is 1000, 5 parts of isocyanate terminated base polyurethane prepolymer for use as and bis-phenol A glycidyl ether epoxy resin are reacted 5h in the stirring tank of 100 DEG C, then bis-phenol A glycidyl ether epoxy resin is added and novolac epoxy stirs, obtain toughening-modifiedepoxy resin matrix, add 5 parts of dicy-curing agents and 1 part of carbamide derivative promotor again, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and fortifying fibre compound, prepares Unidirectional fiber prepreg, the prepreg of cutting is placed in mould, in 120 DEG C of cure under pressures 1.5 hours, obtain composite board, test interlaminar shear strength was 87MPa.
Comparative example 1:
Bis-phenol A glycidyl ether epoxy resin and glycidyl amine type epoxy resin are stirred in the reactor of 60 DEG C, add 10 parts of modified dicyandiamine solidifying agent and 5 parts of carbamide derivative promotor again, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and fortifying fibre compound, prepares Unidirectional fiber prepreg, the prepreg of cutting is placed in mould, in 80 DEG C of cure under pressures 8 hours, obtain composite board, test interlaminar shear strength was 65MPa.
Comparative example 2:
Bis-phenol A glycidyl ether epoxy resin and novolac epoxy are stirred in the reactor of 80 DEG C, then adds 6 parts of dicy-curing agents and 3 parts of carbamide derivative promotor, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and fortifying fibre compound, prepares carbon fibre fabric prepreg, the prepreg of cutting is placed in mould, in 100 DEG C of cure under pressures 3 hours, obtain composite board, test interlaminar shear strength was 73MPa.
Comparative example 3:
Bis-phenol A glycidyl ether epoxy resin and novolac epoxy are stirred in the reactor of 100 DEG C, then adds 5 parts of dicy-curing agents and 1 part of carbamide derivative promotor, mix final vacuum deaeration, prepare epoxy resin for prepreg system.Above-mentioned resin system is adopted adhesive film machine film, then via compounding machine and fortifying fibre compound, prepares Unidirectional fiber prepreg, the prepreg of cutting is placed in mould, in 120 DEG C of cure under pressures 1.5 hours, obtain composite board, test interlaminar shear strength was 79MPa.
Claims (8)
1. a base polyurethane prepolymer for use as improve in the preparation method of low temperature curing prepreg interlaminar shear strength, it is characterized by, comprise the following steps: isocyanic ester and polyether glycol add in reactor according to the molar ratio of 2:1 ~ 4:3 by (1), in 70 DEG C of reaction 4 ~ 6h, obtain isocyanate terminated base polyurethane prepolymer for use as; (2) above-mentioned isocyanate terminated base polyurethane prepolymer for use as and bisphenol-type epoxy resin are reacted 5 ~ 8h in the stirring tank of 60 ~ 100 DEG C, obtain the epoxy resin of polyurethane grafted modification, then add composition epoxy resin to stir, obtain toughening-modifiedepoxy resin matrix; (3) in above-mentioned toughening-modifiedepoxy resin matrix, add solidifying agent and promoter component, mix final vacuum deaeration, prepare epoxy resin for prepreg system; (4) above-mentioned epoxy-resin systems is adopted adhesive film machine film, then via compounding machine and fortifying fibre or fabric compound, prepare the middle low temperature curing prepreg that cohesiveness is excellent.
2. preparation method according to claim 1, is characterized in that: described isocyanic ester is one or more in diphenylmethanediisocyanate (MDI), tolylene diisocyanate (TDI), hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI); Described polyether glycol is one or more in polyoxyethylene glycol or poly(propylene oxide).
3. preparation method according to claim 1, is characterized in that: the molecular weight of described isocyanate terminated base polyurethane prepolymer for use as is 1000 ~ 2500.
4. preparation method according to claim 1, is characterized in that: described bisphenol-type epoxy resin is one or more in bis-phenol A glycidyl ether, Bisphenol F glycidyl ether, dihydroxyphenyl propane D glycidyl ether; Described composition epoxy resin is the mixed assemblage of bisphenol-type epoxy resin and novolac epoxy, o-cresol formaldehyde epoxy resin, bisphenol-A phenolic epoxy resin, glycidyl amine type epoxy resin.
5. preparation method according to claim 1, is characterized in that: described isocyanate terminated base polyurethane prepolymer for use as is 5:100 ~ 15:100 with the massfraction ratio of all epoxy resin.
6. preparation method according to claim 1, is characterized in that: described solidifying agent can be one or more in Dyhard RU 100, modified dicyandiamine, and described promotor can be one or more in carbamide derivative, imdazole derivatives.
7. preparation method according to claim 1, is characterized in that: relative to 100 parts of epoxy resin, and the mass fraction of described solidifying agent is 5 ~ 10 parts, and the mass fraction of described promotor is 1 ~ 5 part.
8. preparation method according to claim 1, is characterized in that: the middle low temperature curing prepreg that described cohesiveness is excellent, and its solidification value is 80 ~ 120 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310031083.6A CN103113604B (en) | 2013-01-28 | 2013-01-28 | The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310031083.6A CN103113604B (en) | 2013-01-28 | 2013-01-28 | The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103113604A CN103113604A (en) | 2013-05-22 |
| CN103113604B true CN103113604B (en) | 2015-08-12 |
Family
ID=48412028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310031083.6A Active CN103113604B (en) | 2013-01-28 | 2013-01-28 | The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103113604B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928809A (en) * | 2017-03-21 | 2017-07-07 | 新疆科能防水防护技术股份有限公司 | A kind of epoxy coating and preparation method thereof |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104369516B (en) * | 2013-08-12 | 2017-01-25 | 佛山市高明区业晟聚氨酯有限公司 | Preparation method of composite polyurethane film |
| CN104629342A (en) * | 2014-12-10 | 2015-05-20 | 广东生益科技股份有限公司 | Resin composition and covering film prepared from resin composition |
| CN105001824B (en) * | 2015-08-03 | 2017-08-29 | 中国工程物理研究院化工材料研究所 | A kind of cold curing ultralow temperature epoxy sealing glue and preparation method thereof |
| CN105252947B (en) * | 2015-10-28 | 2018-03-27 | 绍兴县寿春针纺织有限公司 | A kind of Fabric transfer technique |
| CN105238249B (en) * | 2015-10-28 | 2017-12-15 | 绍兴县寿春针纺织有限公司 | A kind of Fabric transfer coating and preparation method thereof |
| ES2736530T3 (en) * | 2015-10-30 | 2020-01-02 | Evonik Operations Gmbh | Prepreg products with controllable adhesion |
| CN106543648B (en) * | 2016-12-07 | 2019-06-18 | 江苏科技大学 | Modified epoxy resin-based super-weather-resistant composite material for bus duct |
| CN108530874A (en) * | 2017-03-02 | 2018-09-14 | 北京化工大学 | A kind of preparation method of high temperature tough epoxy resin and its rapid shaping carbon fiber prepreg |
| CN106867008A (en) * | 2017-03-24 | 2017-06-20 | 北京化工大学 | A kind of preparation method of toughness reinforcing intermediate temperature setting prepreg |
| EP3663338A4 (en) * | 2017-07-31 | 2021-07-07 | Toray Industries, Inc. | Sheet molding compound, prepreg, and fiber-reinforced composite material |
| CN108410130A (en) * | 2018-02-08 | 2018-08-17 | 芜湖天道绿色新材料有限公司 | A kind of sheet molding compound cured epoxy composition and preparation method thereof |
| CN108589301B (en) * | 2018-05-17 | 2019-10-25 | 北京化工大学 | Application, aramid fiber-resin composite materials and preparation method of the sizing agent as aramid fiber surface modification inorganic agent |
| WO2020073156A1 (en) * | 2018-10-08 | 2020-04-16 | Dow Global Technologies Llc | Polyurethane prepolymer and adhesive compositions containing same |
| CN110240794A (en) * | 2019-05-06 | 2019-09-17 | 阜阳大可新材料股份有限公司 | A kind of mould proof fiber board adhesive |
| CN110144035A (en) * | 2019-05-24 | 2019-08-20 | 桂林电子科技大学 | A kind of polyethylene glycol Graft Epoxy Resin composite material and preparation method |
| JP6958751B2 (en) * | 2019-08-06 | 2021-11-02 | Dic株式会社 | Curable composition, cured product, fiber reinforced composite material and molded product |
| CN111004408A (en) * | 2019-12-23 | 2020-04-14 | 江苏恒神股份有限公司 | Preparation method of white-point-free fast-curing epoxy prepreg |
| CN112062924B (en) * | 2020-08-21 | 2022-04-01 | 南京聚发新材料有限公司 | Polyurethane resin for winding process, resin/fiber composite material, and preparation method and application thereof |
| CN111909620B (en) * | 2020-08-21 | 2022-05-27 | 湖南创瑾科技有限公司 | Adhesive with anti-corrosion function |
| CN112442273A (en) * | 2020-11-25 | 2021-03-05 | 界首市兴隆渔具有限公司 | Composite material for preparing carbon fiber fishing rod and preparation method thereof |
| CN112300539A (en) * | 2020-11-30 | 2021-02-02 | 常州市宏发纵横新材料科技股份有限公司 | Preparation method of epoxy resin material for improving wettability of carbon fiber |
| CN113896861A (en) * | 2021-11-26 | 2022-01-07 | 中航复合材料有限责任公司 | Dicyandiamide cured epoxy resin suitable for out-of-tank molding and preparation method thereof |
| CN114181372A (en) * | 2021-12-14 | 2022-03-15 | 中威北化科技有限公司 | High-toughness epoxy resin suitable for RTM (resin transfer molding) rapid curing requirement and synthesis method thereof |
| CN115182548B (en) * | 2022-08-11 | 2024-04-26 | 山东扬名新材料技术有限公司 | Organic-inorganic combined composite industrial grinding stone and preparation method thereof |
| CN116141703A (en) * | 2023-04-18 | 2023-05-23 | 天津爱思达航天科技股份有限公司 | Polyurethane toughened epoxy damping composite material and preparation method thereof |
| CN116535822B (en) * | 2023-06-29 | 2023-10-17 | 泰和新材集团股份有限公司 | Resin glue solution for aramid composite material IV type bottle and preparation method |
-
2013
- 2013-01-28 CN CN201310031083.6A patent/CN103113604B/en active Active
Non-Patent Citations (1)
| Title |
|---|
| 环氧改性水性聚氨酯的合成及其在碳纤维上胶剂中的应用;刘占清;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20121215(第12期);B016-62 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928809A (en) * | 2017-03-21 | 2017-07-07 | 新疆科能防水防护技术股份有限公司 | A kind of epoxy coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103113604A (en) | 2013-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103113604B (en) | The preparation method of low temperature curing prepreg interlaminar shear strength during a kind of base polyurethane prepolymer for use as improves | |
| CN101818037B (en) | Room-temperature curing epoxy structural adhesive composition and preparation method thereof | |
| CN103975002B (en) | Prepreg, fiber reinforced composite material and manufacture method, composition epoxy resin | |
| CA2650559C (en) | Epoxy resin composition for fiber-reinforced composite material | |
| CN104603173B (en) | Fibre-reinforced composite material assembly and its preparation | |
| CN101698787A (en) | Epoxy resin binder used for repairing blade and preparation method thereof | |
| CN104781303B (en) | Epoxy-resin systems for the tetramine containing polyethylene of resin transfer moulding method | |
| CN102746622A (en) | Prepreg with moderate-temperature cured epoxy resin as substrate material and preparation method thereof | |
| EP2480587A1 (en) | Curable epoxy resin compositions and composites made therefrom | |
| CN104119827A (en) | Room-temperature-curing epoxy-acid anhydride adhesive and preparation method thereof | |
| CN113811574B (en) | Polyisocyanurate based polymer and fiber reinforced composite | |
| CN106867008A (en) | A kind of preparation method of toughness reinforcing intermediate temperature setting prepreg | |
| CN103923557A (en) | Special prime coat for spraying polyurea elastomer and preparation method of special prime coat | |
| CN104449508A (en) | Flexible epoxy structural adhesive and preparation method thereof | |
| CN107868401A (en) | Rapid shaping intermediate temperature setting prepreg resin matrix and preparation method thereof | |
| KR20190082313A (en) | Curable Epoxy / Polyurethane Hybrid Resin System for SMC | |
| KR102361346B1 (en) | Epoxy resin composition for fiber-reinforced composite material, and fiber-reinforced composite material | |
| WO2019026724A1 (en) | Sheet molding compound, prepreg, and fiber-reinforced composite material | |
| CN116694030A (en) | Ultra-light high-strength composite material and preparation method and application thereof | |
| CN105566858A (en) | Preparation method of moderate-temperature-curing high-temperature-resistant prepreg by chemorheological regulation | |
| EP3705508A1 (en) | Epoxy resin composition and cured object obtained therefrom | |
| JP6639387B2 (en) | Isocyanate epoxy foam type | |
| CN108929520A (en) | A kind of rapid curing tack prepreg and preparation method thereof | |
| CN101851395A (en) | Epoxy resin and production method thereof | |
| CN112313261A (en) | Toughened epoxy compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161221 Address after: 264200 Weihai Province torch high tech Industrial Development Zone, the town of the early Qing Shan Street, No. 2 Patentee after: Weihai North Europe carbon fiber composite material Co., Ltd. Address before: 213164 Changzhou Institute of Advanced Materials Research Institute, Beijing University of Chemical Technology, Changzhou, Jiangsu, China, No. 520, science and Technology City, No. 801 Chang Wu Road, A Patentee before: Changzhou Advanced Materials Institute, Beijing University of Chemical Industry |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: 264210 No. 2, Chui Shan Street, early Village Town, torch hi tech Industrial Development Zone, Shandong, Weihai Patentee after: Zhongwei North Technology Co. Ltd. Address before: 264200 Weihai Province torch high tech Industrial Development Zone, the town of the early Qing Shan Street, No. 2 Patentee before: Weihai North Europe carbon fiber composite material Co., Ltd. |
|
| CP03 | Change of name, title or address | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for improving interlaminar shear strength of medium/low-temperature cured prepreg by using polyurethane prepolymer Effective date of registration: 20190122 Granted publication date: 20150812 Pledgee: Weihai City Commercial Bank Limited by Share Ltd high tech branch Pledgor: Zhongwei North Technology Co. Ltd. Registration number: 2019990000070 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220407 Granted publication date: 20150812 Pledgee: Weihai City Commercial Bank Limited by Share Ltd. high tech branch Pledgor: SINO-CF COMPOSITE SCI. & TECH. (WEIHAI) CO.,LTD. Registration number: 2019990000070 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of polyurethane prepolymer for improving interlayer shear strength of medium and low temperature curing prepreg Effective date of registration: 20220418 Granted publication date: 20150812 Pledgee: Weihai City Commercial Bank Limited by Share Ltd. high tech branch Pledgor: SINO-CF COMPOSITE SCI. & TECH. (WEIHAI) CO.,LTD. Registration number: Y2022980004141 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |