CN103113024B - Preparation method of glass lining coating - Google Patents
Preparation method of glass lining coating Download PDFInfo
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- CN103113024B CN103113024B CN201310048703.7A CN201310048703A CN103113024B CN 103113024 B CN103113024 B CN 103113024B CN 201310048703 A CN201310048703 A CN 201310048703A CN 103113024 B CN103113024 B CN 103113024B
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Abstract
The invention relates to a preparation method of a glass lining coating. The preparation method comprises the following steps: according to the percentage by weight, mixing 50%-60% of glass lining powder, 5%-16% of amorphous silicon dioxide, 1%-4% of aluminum oxide, 2%-4% of clay deflocculant and 30%-40% of water to get coating; and performing deoiling and annealing treatment on the surface of an industrial steel plate, then coating the coating on the surface of the steel plate, drying, and sintering under the condition of 860-900 DEG C for 6-10min to get the glass lining coating. The coating prepared by the preparation method disclosed by the invention has the advantages of excellent acid resistance and resistance to sharp temperature variation, and long service life; and the preparation process has the advantages of simple requirements and simplicity and convenience in operation, and is suitable for industrial production.
Description
Technical field
The invention belongs to the preparation field of lass lining material, particularly a kind of preparation method of lass lining coating.
Background technology
Be that the lass lining material of matrix has the advantages such as physical strength is high, acid-resistant chemical stability is excellent with steel plate, be widely used in the industries such as chemical industry, pharmacy, food.But common lass lining material main component is silicate glass body, although acid-resistant chemical stability is excellent, but fragility is larger, heatproof shock property is poor, the heatproof shock property of general lass lining product is no more than 200 DEG C, which also limits further broadened application (Lu Jieping, the application of enamel for glassed steel characteristic parameter and the mensuration in enamel firing technique of lass lining material, " glass and enamel " 04 phase in 1992, P.5-10.).
For improving the heatproof shock property of lass lining material, the method generally adopted at present is the chemical constitution of adjustment lass lining material, and to its heat-treat make lass lining material produce micritization, but the method complex process, technology controlling and process difficulty, the micritization treatment time is long, production efficiency is low, and require very high to the temperature homogeneity of firing furnace, also production (the Shen Dingcheng of jumbo lass lining reaction vessel is not suitable with, Chen Baihua, Li Yunpeng, Wang Yunfu, Lu Jiajun, the research of acidproof nucerite, " material protection " the 06th phase in 1979, P.15-20., Li Chunbin, the sour test of nucerite, " glass and enamel " the 04th phase in 1973, P.12-16.).In view of the foregoing, be necessary that a kind of acute degeneration of resistance to temperature difference of invention is excellent, and preparation technology requires simply, easy and simple to handle, be suitable for the lass lining material of suitability for industrialized production.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of preparation method of lass lining coating, lass lining coating prepared by the method have acidproof, the acute degeneration of resistance to the temperature difference is excellent, long service life; The method preparation technology requires simply, easy and simple to handle, is suitable for suitability for industrialized production.
The preparation method of a kind of lass lining coating of the present invention, comprising:
(1) by mass percent, by quartzy 55-60%, borax 12-18%, SODIUMNITRATE 1-5%, soda ash 6-10%, Quilonum Retard 1-5%, aluminium sesquioxide 1-3%, calcium carbonate 3-5%, Strontium carbonate powder 2-5%, ice crystal 3-5%, nickel oxide 1-2.5%, cobalt oxide 1-1.5%, ferric oxide 2-3%, mixing, obtain admixtion, then by batch melting, make frit through shrend, oven dry, dry ball milling, sieve, obtain lass lining powder;
(2) by mass percent, lass lining powder 50%-60%, amorphous silicon di-oxide 5%-16%, aluminum oxide 1%-4%, deflocculating agent 2%-4% and water 30% ~ 40% are mixed, obtains coating;
(3) process surface of steel plate, then above-mentioned coating is coated in surface of steel plate, dry, under 860-900 DEG C of condition, sintering 6-10min, obtains lass lining coating.
In described step (1) under 1350 DEG C of conditions, fusing 1-3h.
In described step (1), sieve is 160 orders.
Described step presses mass percent in (2), lass lining powder 60%, amorphous silicon di-oxide powder 7%, aluminum oxide powder 1%, deflocculating agent 2% and water mixing 30%.
Described step presses mass percent in (2), lass lining powder 50%, amorphous silicon di-oxide 12.5%, aluminum oxide 2%, deflocculating agent 2.5% and water mixing 33%.
Described step presses mass percent in (2), lass lining powder 53%, amorphous silicon di-oxide 5%, aluminum oxide 3%, deflocculating agent 4% and water mixing 35%.
Steel plate in described step (3) is mild steel plate, does not need through special processing, and the size of steel plate can be arbitrary.
In described step (3), processing mode is the process of oil removing annealing borax.
In described step (3), drying temperature is 85-120 DEG C, and time of drying is 10-30min.
beneficial effect
(1) preparation method of the lass lining coating that prepared by the present invention is a kind of acidproof, the acute degeneration of resistance to the temperature difference is excellent, its coating prepared have acidproof, the acute degeneration of resistance to the temperature difference is excellent, long service life;
(2) preparation technology of the present invention requires simply, easy and simple to handle, is suitable for suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, set forth the present invention further.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
Embodiment 1
(1) by mass percent, by quartz 57, borax 12, SODIUMNITRATE 5, soda ash 6, Quilonum Retard 5, aluminium sesquioxide 1, calcium carbonate 3, Strontium carbonate powder 2, ice crystal 3, nickel oxide 2.5, cobalt oxide 1.5, ferric oxide 2(lass lining powder formula material massfraction ratio) be mixed to get admixtion;
(2) melted 2 hours in 1350 DEG C, the electric furnace of Si-Mo rod by admixtion, the compound after fusing makes frit through shrend, after being dried by frit, also crosses 160 object sieves obtain lass lining powder through dry ball milling;
(3) lass lining powder 60% by mass percentage, amorphous silicon di-oxide powder 7%, aluminum oxide powder 1%, deflocculating agent 2% and water mixing 30%;
(4) oil removing anneal is carried out to the surface of industrial steel plate sample, then according to the paint steel plate sample surface after the pre-treatment that (3) prepare, then the sample of coating will be coated with in drying at 85 DEG C of temperature 20 minutes, after drying is complete, sample is placed in the High Temperature Furnaces Heating Apparatus of 860 DEG C, carry out burning till for 8 minutes, namely obtain the lass lining coating acidproof, the acute degeneration of resistance to the temperature difference is excellent on steel plate sample surface.
According to (measuring method of the standard GB/T/T7989-2003 enamel for glassed steel hydrochloric acid of resistance to boiling steam corrosion performance), the acid resistance of lass lining sample is measured, measure the acute degeneration of resistance to temperature difference of lass lining sample according to (national standard: the GB/T7987-2003 glass-lined coating acute degeneration of resistance to temperature difference test method), test result is in table 1
Table 11 lass lining sample is acidproof, the acute degeneration of resistance to temperature difference test result
| Test performance | Acid resistance | The acute degeneration of resistance to the temperature difference |
| Test result | 1.0 grams/m of skies | 300℃ |
Embodiment 2
(1) by mass percent, by quartz 56, borax 12, SODIUMNITRATE 5, soda ash 6, Quilonum Retard 5, aluminium sesquioxide 2, calcium carbonate 3, Strontium carbonate powder 2, ice crystal 3, nickel oxide 2.5, cobalt oxide 1.5, ferric oxide 2(lass lining powder formula material massfraction ratio) be mixed to get admixtion;
(2) melted 2 hours in 1350 DEG C, the electric furnace of Si-Mo rod by admixtion, the compound after fusing makes frit through shrend, after being dried by frit, also crosses 160 object sieves obtain lass lining powder through dry ball milling;
(3) lass lining powder 50% by mass percentage, amorphous silicon di-oxide 12.5%, aluminum oxide 2%, deflocculating agent 2.5% and water mixing 33% is mixed to get compound;
(4) oil removing anneal is carried out to the surface of industrial steel plate sample, then according to the paint steel plate sample surface after the pre-treatment that (3) prepare, then the sample of coating will be coated with in drying at 100 DEG C of temperature 10 minutes, after drying is complete, sample is placed in the High Temperature Furnaces Heating Apparatus of 900 DEG C, carry out burning till for 10 minutes, namely obtain the lass lining coating acidproof, the acute degeneration of resistance to the temperature difference is excellent on steel plate sample surface.
According to (measuring method of the standard GB/T/T7989-2003 enamel for glassed steel hydrochloric acid of resistance to boiling steam corrosion performance), the acid resistance of lass lining sample is measured, measure the acute degeneration of resistance to temperature difference of lass lining sample according to (national standard: the GB/T7987-2003 glass-lined coating acute degeneration of resistance to temperature difference test method), test result is in table 2
Table 12 lass lining sample is acidproof, the acute degeneration of resistance to temperature difference test result
| Test performance | Acid resistance | The acute degeneration of resistance to the temperature difference |
| Test result | 1.3 grams/m of skies | 330℃ |
Embodiment 3
(1) by mass percent, by quartz 55, borax 12, SODIUMNITRATE 5, soda ash 6, Quilonum Retard 5, aluminium sesquioxide 3, calcium carbonate 3, Strontium carbonate powder 2, ice crystal 3, nickel oxide 2.5, cobalt oxide 1.5, ferric oxide 2(lass lining powder formula material massfraction ratio) be mixed to get admixtion;
(2) melted 2 hours in 1350 DEG C, the electric furnace of Si-Mo rod by admixtion, the compound after fusing makes frit through shrend, after being dried by frit, also crosses 160 object sieves obtain lass lining powder through dry ball milling;
(3) lass lining powder 53% by mass percentage, amorphous silicon di-oxide 5%, aluminum oxide 3%, deflocculating agent 4% and water mixing 35% is mixed to get compound;
(4) oil removing anneal is carried out to the surface of industrial steel plate sample, then according to the paint steel plate sample surface after the pre-treatment that (3) prepare, then the sample of coating will be coated with in drying at 90 DEG C of temperature 15 minutes, after drying is complete, sample is placed in the High Temperature Furnaces Heating Apparatus of 880 DEG C, carry out burning till for 10 minutes, namely obtain the lass lining coating acidproof, the acute degeneration of resistance to the temperature difference is excellent on steel plate sample surface.
According to (measuring method of the standard GB/T/T7989-2003 enamel for glassed steel hydrochloric acid of resistance to boiling steam corrosion performance), the acid resistance of lass lining sample is measured, measure the acute degeneration of resistance to temperature difference of lass lining sample according to (national standard: the GB/T7987-2003 glass-lined coating acute degeneration of resistance to temperature difference test method), test result is in table 3
Table 13 lass lining sample is acidproof, the acute degeneration of resistance to temperature difference test result
| Test performance | Acid resistance | The acute degeneration of resistance to the temperature difference |
| Test result | 1.1 grams/m of skies | 310℃ |
Claims (9)
1. a preparation method for lass lining coating, comprising:
(1) by mass percent, by quartzy 55-60%, borax 12-18%, SODIUMNITRATE 1-5%, soda ash 6-10%, Quilonum Retard 1-5%, aluminium sesquioxide 1-3%, calcium carbonate 3-5%, Strontium carbonate powder 2-5%, ice crystal 3-5%, nickel oxide 1-2.5%, cobalt oxide 1-1.5%, ferric oxide 2-3%, mixing, obtain admixtion, then by batch melting, make frit through shrend, oven dry, dry ball milling, sieve, obtain lass lining powder;
(2) by mass percent, lass lining powder 50%-60%, amorphous silicon di-oxide 5%-16%, aluminum oxide 1%-4%, deflocculating agent 2%-4% and water 30% ~ 40% are mixed to get coating;
(3) process industrial surface of steel plate, then above-mentioned coating is coated in surface of steel plate, dry, under 860-900 DEG C of condition, sintering 6-10min, obtains lass lining coating.
2. the preparation method of a kind of lass lining coating according to claim 1, is characterized in that: in described step (1) under 1350 DEG C of conditions, fusing 1-3h.
3. the preparation method of a kind of lass lining coating according to claim 1, is characterized in that: in described step (1), sieve is 160 orders.
4. the preparation method of a kind of lass lining coating according to claim 1, it is characterized in that: by mass percent in described step (2), lass lining powder 60%, amorphous silicon di-oxide 7%, aluminum oxide 1%, deflocculating agent 2% and water 30% mixes.
5. the preparation method of a kind of lass lining coating according to claim 1, it is characterized in that: by mass percent in described step (2), lass lining powder 50%, amorphous silicon di-oxide 12.5%, aluminum oxide 2%, deflocculating agent 2.5% and water 33% mixes.
6. the preparation method of a kind of lass lining coating according to claim 1, it is characterized in that: by mass percent in described step (2), lass lining powder 53%, amorphous silicon di-oxide 5%, aluminum oxide 3%, deflocculating agent 4% and water 35% mixes.
7. the preparation method of a kind of lass lining coating according to claim 1, is characterized in that: the steel plate in described step (3) is mild steel plate.
8. the preparation method of a kind of lass lining coating according to claim 1, is characterized in that: in described step (3), processing mode is the process of oil removing annealing borax.
9. the preparation method of a kind of lass lining coating according to claim 1, is characterized in that: in described step (3), drying temperature is 85-120 DEG C, and time of drying is 10-30min.
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| CN103693849B (en) * | 2013-12-09 | 2015-11-18 | 常熟市永达化工设备厂 | The preparation method of lass lining coating |
| CN103803800B (en) * | 2013-12-28 | 2016-06-01 | 华中科技大学 | A kind of titanium alloy protective coating and its preparation method |
| CN106442281A (en) * | 2016-08-30 | 2017-02-22 | 无锡上工搪化工设备有限公司 | Pendant for testing performance of glass lining porcelain glaze |
| CN106477890B (en) * | 2016-09-30 | 2019-06-04 | 东华大学 | A kind of wear-resisting enamel and preparation method thereof |
| CN107640897A (en) * | 2017-11-08 | 2018-01-30 | 常熟市永达化工设备厂 | refractory metal enamel glaze |
| CN107814490A (en) * | 2017-11-08 | 2018-03-20 | 常熟市永达化工设备厂 | The preparation technology of enamel coating |
| CN114835398A (en) * | 2022-05-13 | 2022-08-02 | 石家庄正中科技有限公司 | Method for preparing pinhole defect resistant enamel for assembled tank |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519276A (en) * | 2009-03-27 | 2009-09-02 | 上海应用技术学院 | Photocatalytic self-cleaning nano-titania porcelain enamel substrate and method for preparing same |
| CN101921063A (en) * | 2010-08-05 | 2010-12-22 | 奇瑞汽车股份有限公司 | Enamel and preparation method thereof |
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| JPH0794163B2 (en) * | 1988-11-04 | 1995-10-11 | 神鋼パンテツク株式会社 | Glass-lining equipment using stainless steel and manufacturing method thereof |
| JP5587538B2 (en) * | 2005-09-30 | 2014-09-10 | 株式会社カネカ | Method for producing organic polymer having terminal end of trimethoxysilyl group |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101519276A (en) * | 2009-03-27 | 2009-09-02 | 上海应用技术学院 | Photocatalytic self-cleaning nano-titania porcelain enamel substrate and method for preparing same |
| CN101921063A (en) * | 2010-08-05 | 2010-12-22 | 奇瑞汽车股份有限公司 | Enamel and preparation method thereof |
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|---|
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