CN103112309A - Multifunctional composite material and application thereof - Google Patents
Multifunctional composite material and application thereof Download PDFInfo
- Publication number
- CN103112309A CN103112309A CN2013100474944A CN201310047494A CN103112309A CN 103112309 A CN103112309 A CN 103112309A CN 2013100474944 A CN2013100474944 A CN 2013100474944A CN 201310047494 A CN201310047494 A CN 201310047494A CN 103112309 A CN103112309 A CN 103112309A
- Authority
- CN
- China
- Prior art keywords
- multifunctional composite
- composite according
- layer
- wire
- surface layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The invention discloses a multifunctional composite material and an application thereof. The multifunctional composite material is in a layer-like structure formed by using a binding agent to carry out hot-press compositing, and comprises an upper outer surface layer, a lower outer surface layer and a middle layer. The multifunctional composite material is characterized in that the upper outer surface layer and the lower outer surface layer are formed by transparent polymers; the middle layer contains at least one layer of textile fabric; art patterns are arranged on at least one surface of the textile fabric; and the binding agent for hot pressing is a non-light-tight polymer. The composite material disclosed by the invention has various functions of high light transmission, art decoration, light weight and convenience, high strength, strong anti-impact capability, screening of electromagnetic radiation, high toughness, isolation of ultraviolet rays and infrared rays and the like, and can be applied to various industries, such as industries of manufacturing a sun-shading and lighting product, a panel for a household appliance, an indoor decorative material, a sports protection product, a safe protection product, a partition wall, abruption, a luggage and the like. The multifunctional composite material is widely applied, can meet various functional requirements on the material in the current society, and has the advantages of practical values, energy conversation and environmental friendliness.
Description
Technical field
The present invention relates to a kind of multifunctional composite and application thereof, specifically, relate to a kind of isolated ultraviolet light and infrared light realized, high light transmittance, art pattern is ornamental, high-tensile and shock resistance, composite and the application thereof of the several functions such as shielding electromagenetic wave radiation belong to technical field of function materials.
Background technology
Along with the development of science and technology and improving constantly of human living standard, the requirement of various materials such as ornament materials is also tended to the future development of environmental protection, multifunction, high-strength light, finished products, installation code, intelligent control.Ornament materials will be paid attention to the protection to ecological environment more in the process of producing and using, to the future development of building safer, more healthy living environment; Simultaneously, the function of ornament materials also by single to development in pluralism; Building is also day by day to the development of the high level of frame-type, and skyscraper has Secretary to aspects such as the weight of material, intensity, and for ease of construction and safety, the specification of ornament materials is increasing, quality is more and more lighter, intensity is more and more higher.In the existing market, many modified ornament materials for simple function are arranged, composite board as high in visible light transmittance rate, anti-ultraviolet or infrared film-coated plate, the ornament materials of special artistic effect etc., comprehensive function, product strength are good, stability is high and simple installation need not the environment protection type multifunctional composite products such as subsequent treatment but have, and especially the environment protection type multifunctional decorative composite material still belongs to the market vacancy.
Summary of the invention
For the problems referred to above and the market demand that prior art exists, the purpose of this invention is to provide a kind of composite and application thereof that realizes isolated ultraviolet light and the several functions such as infrared light, high light transmittance, artistic decoration, high-tensile and shock resistance, shielding electromagenetic wave radiation.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of multifunctional composite, be the layer structure that adopts adhesive hot pressing to be composited, comprise upper and lower outer surface layer and intermediate layer, it is characterized in that: described upper and lower outer surface layer forms by transparent polymer, one deck weaving face fabric is at least contained in described intermediate layer, at least one surface of described weaving face fabric has art pattern, and the adhesive that carries out hot pressing is light penetrating copolymer.
As a kind of preferred version, one deck weaving face fabric is at least contained in described intermediate layer, and a surface of described weaving face fabric has art pattern, and another surface is through the vacuum coating functionalization; Described vacuum coating functionalization refers to make the surface of weaving face fabric obtain the functional film layer such as metallic luster, ceramic texture by the vacuum coating surface treatment technology.
As further preferred version, above-mentioned intermediate layer also comprises one deck optical thin film at least.
As further preferred version, the material that described vacuum coating functionalization adopts is TiO
2, TiC, TiCN, TiN, TiAlN, ZrN, AlN, CrN, CrC, TiCxNy, TiOxNy, Ag, Cu, Al
2O
3, DLC, VO
2, Ta
2O
5, SiO
2, in ZrO, ZnS any one or multiple.
As further preferred version, described vacuum coating functionalization adopts vacuum magnetron sputtering coating film technique.
As preferred version further, the parameter of described vacuum magnetron sputtering coating film technique is as follows: vacuum chamber is 1～12, and the magnetic controlled sputtering target in each vacuum chamber is 1～3, and auxiliary to strengthen ion gun be 1～2; Described auxiliary enhancing ion gun is pure N
2Or O
2, take Ar as sputter gas, described sputter gas is 1:3 with the auxiliary flow-rate ratio that strengthens ionized gas; In reative cell, vacuum is 2 * 10
-3Pa, sputtering power are 1800～2600W, and gas pressure intensity is 1.0～2.0Pa, and underlayer temperature is 80～120 ℃.
As further preferred version, described weaving face fabric is to be processed through woven, knitting or nonwovens process by non-metallic fibers.
As preferred version further, described non-metallic fibers is glass fibre, basalt fibre, carbon fiber or chemical synthetic fiber.
As further preferred version, the weight of described weaving face fabric is 5g/m
2～800g/m
2
As further preferred version, the Uneven Width width of described weaving face fabric is 300mm～2400mm.
As further preferred version, described art pattern passes through braiding or/and dyeing and printing process forms.
As further preferred version, the reflecting rate of described optical thin film is 10%～60%, light transmittance is 5%～45%, solar energy always the partition rate be 55%～78%, every ultraviolet light rate 〉=99%.
As further preferred version, above-mentioned intermediate layer also comprises one deck filament layer at least, and the diameter of described filament is 2 μ m～200 μ m.
As preferred version further, described filament is that wire is or/and nonmetal wire.
As preferred version further, described wire is selected from the metal or metal alloy silks such as copper coated iron wire, copper wire, stainless steel wire; Described nonmetal wire is selected from glass fiber, basalt fibre silk, carbon fiber wire, chemical fiber wire, conducting fiber etc.; Described chemical fiber wire is selected from dacron thread, nylon yarn, viscose, polypropylene fiber silk etc.; Described conducting fiber is chemical fiber wire to be carried out conductive modified form.
As preferred version further, uniformly-spaced cross arrangement forms described filament layer or/and unequal interval is parallel by filament.
As a kind of preferred version, the transparent polymer that forms upper and lower outer surface layer is Merlon (PC) or polyvinyl chloride (PVC).
As further preferred version, the thickness of described upper and lower outer surface layer is 25 μ m～12mm.
As a kind of preferred version, the adhesive that carries out hot pressing is EVA PUR, polyurethane binding or acrylate adhesive.
As further preferred version, the thickness of heat pressure adhesive layer is 1 μ m～50 μ m.
Above-mentioned multifunctional composite can be applicable to make sunshade lighting product, home electronic panel, house decorative material, motion Protection Product, security protection product, partition wall, partition, case and bag etc.
Compared with prior art, the present invention has following good effect:
1) composite provided by the invention has the several functions such as high light transmittance, artistic decoration, light, high strength, strong impact resistance, shielding electromagenetic wave radiation, high tenacity, isolated ultraviolet light and infrared light, can be applicable in various industries, as: make sunshade lighting product, home electronic panel, house decorative material, motion Protection Product, security protection product, partition wall, partition, case and bag etc., purposes is very extensive, can satisfy the several functions demand of society to material instantly, have practical value.
2) multifunctional composite provided by the invention need not application again and just can realize artistic decorative effect in subsequent applications, has the energy-conserving and environment-protective advantage.
Description of drawings
Fig. 1 is the structural representation of a kind of multifunctional composite provided by the invention;
Fig. 2 is the structural representation of another kind of multifunctional composite provided by the invention;
Fig. 3 is the structural representation of another multifunctional composite provided by the invention.
In figure: 1, upper outer surface layer; 2, intermediate layer; 21, weaving face fabric; 22, optical thin film; 23, filament layer; 3, lower outer surface layer; 4, adhesive layer.
The specific embodiment
Below in conjunction with embodiment and accompanying drawing to the present invention do further in detail, intactly explanation.
As shown in Figure 1: a kind of multifunctional composite provided by the invention is layer structure, comprise outer surface layer 1, intermediate layer 2 and lower outer surface layer 3, adopt between layers adhesive hot pressing to be composited, described upper outer surface layer 1 and lower outer surface layer 3 form by transparent polymer, for example: clear polycarbonate (PC) or transparent polyvinyl chloride (PVC), upper outer surface layer 1 can be the same or different with the polymer that lower outer surface layer 3 adopts; The thickness of described upper outer surface layer 1 and lower outer surface layer 3 is all at 25 μ m～12mm, and upper outer surface layer 1 can be the same or different with the thickness of lower outer surface layer 3; One deck weaving face fabric 21 is at least contained in described intermediate layer 2, and at least one surface of described weaving face fabric 21 has art pattern; The adhesive that carries out hot pressing is light penetrating copolymer, and for example: EVA PUR, polyurethane binding or acrylate adhesive, the thickness of adhesive layer 4 are 1 μ m～50 μ m.
It is stacked good successively that above-mentioned composite manufacture is that the lower outer surface layer 3, intermediate layer 2 and the lower surface that first upper surface are coated with adhesive coating or film is coated with the upper outer surface layer 1 of adhesive coating or film, then adopt the Vacuum Heat laminating machine to carry out hot pressing, cooling and get.
Because upper outer surface layer 1 and lower outer surface layer 3 form by transparent polymer, at least one surface of the weaving face fabric 21 that intermediate layer 2 is contained has art pattern, and the adhesive that carries out hot pressing is light penetrating copolymer, therefore, the composite that obtains has high light transmittance, artistic decoration and light, the several functions such as intensity is high, and processing is simple, convenient, need not to carry out the art pattern that complicated coating process can be realized various complexity, not only decorative effect is obvious, and energy-conserving and environment-protective.
As a kind of preferred version, a surface of the weaving face fabric 21 that described intermediate layer 2 is contained has art pattern, and another surface is through the vacuum coating functionalization; Described vacuum coating functionalization refers to make the surface of weaving face fabric obtain the functional film layer such as metallic luster, ceramic texture by the vacuum coating surface treatment technology.Process by the surface of weaving face fabric being carried out vacuum coating surface, can make the composite of acquisition not only have the ornamental of art pattern, can also have simultaneously metallic luster, ceramic texture and further improve intensity, making to be more suitable in making the decorative products such as large household appliance panel, furred ceiling, wardrobe, kitchen-cupboard doors, artistic lamp cover.
Described film material can be TiO
2, TiC, TiCN, TiN, TiAlN, ZrN, AlN, CrN, CrC, TiCxNy, TiOxNy, Ag, Cu, Al
2O
3, aluminum titanium alloy, VO
2, Ta
2O
5, SiO
2, in ZrO, ZnS any one or multiple.Can realize the adjusting of rete color and reflecting rate by the composition of selective membrane layer material.Described vacuum coating functionalization adopts vacuum magnetron sputtering coating film technique, and the parameter of carrying out vacuum magnetron sputtering coating film technique is as follows: vacuum chamber is 1～12, and the magnetic controlled sputtering target in each vacuum chamber is 1～3, and auxiliary enhancing ion gun is 1～2; Described auxiliary enhancing ion gun is pure N
2Or O
2, take Ar as sputter gas, described sputter gas is 1:3 with the auxiliary flow-rate ratio that strengthens ionized gas; In reative cell, vacuum is 2 * 10
-3Pa, sputtering power are 1800～2600W, and gas pressure intensity is 1.0～2.0Pa, and underlayer temperature is 80～120 ℃.
Described art pattern passes through braiding or/and dyeing and printing process forms.Described weaving face fabric 21 is to be processed through woven, knitting or nonwovens process by non-metallic fibers, and described non-metallic fibers is glass fibre, basalt fibre, carbon fiber or chemical synthetic fiber.The weight of described weaving face fabric 21 is 5g/m
2～800g/m
2, Uneven Width width is 300mm～2400mm.
As a kind of preferred version, described intermediate layer 2 comprises that also one deck optical thin film 22(is as shown in Figure 2 at least), the reflecting rate of described optical thin film is 10%～60%, light transmittance is 5%～45%, solar energy always the partition rate be 55%～78%, every ultraviolet light rate 〉=99%.By 2 establishing at least one deck optical thin film 22 in the intermediate layer, can make the composite of acquisition have simultaneously optical property, play isolated ultraviolet light and infrared light effect, be suitable for making the products such as the light-duty shading product of the high printing opacity of outdoor, glass sunlight house, external wall.
As a kind of preferred version, described intermediate layer 2 comprises that also one deck filament layer 23(as shown in Figure 3 at least), tensile strength and realization shielding electromagenetic wave radiation function to improve composite make to be more suitable in making the heavy construction sunshade lighting product of large span without guide rail.
The diameter of described filament is 2 μ m～200 μ m; Described filament is that wire is or/and nonmetal wire; Described wire is selected from the metal or metal alloy silks such as copper coated iron wire, copper wire, stainless steel wire; Described nonmetal wire is selected from glass fiber, basalt fibre silk, carbon fiber wire, chemical fiber wire, conducting fiber etc.; Described chemical fiber wire is selected from dacron thread, nylon yarn, viscose, polypropylene fiber silk etc.; Described conducting fiber is chemical fiber wire to be carried out conductive modified form; Uniformly-spaced cross arrangement forms described filament layer or/and unequal interval is parallel by filament.
The composite that the present embodiment is prepared composed as follows:
1. upper and lower outer surface layer all adopts clear polycarbonate (PC) plate that is of a size of 2000mm * 2200mm * 3.0mm;
2. the intermediate layer is the density three-dimensional carbon cloth, and surface thereof has little twill grid, and another surface is through vacuum magnetron sputtering coating film, and film material consists of titanium nitride+argent+aluminum titanium alloy, and thicknesses of layers is 100 μ m, and reflecting rate reaches 80%;
3. the THICKNESS CONTROL of EVA hot melt adhesive film is at 25 μ m.
Described composite manufacture comprises the steps:
One, vacuum magnetron sputtering coating film being carried out on the weaving face fabric surface processes
Make substrate with the density three-dimensional carbon cloth, in one group of tension force is controlled No. 1 reative cell of the smooth magnetron sputtering coater that enters continuously single chamber three plated film districts of guide roller, make the deposition table placed face down, to prevent granular impurity staining substrate surface; Reative cell is evacuated to 2 * 10
-3Pa strengthens gas input reative cell, the flow-rate ratio Ar:N of sputter/increased response gas as sputter gas and pure N2 as assisting ion with Ar
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2000W, and underlayer temperature is 120 ℃, carries out deposition growing TiN/Ag.
Enter the second vacuum coating district after the vacuum coating district completes until first group of TiN/Ag film, then with Ar as sputter gas and pure O
2Make assisting ion and strengthen gas input reative cell, the flow-rate ratio Ar:O of sputter/increased response gas
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2600W, and underlayer temperature is 80 ℃, carries out the deposition growing aluminum titanium alloy.
Thickness is determined by growth time, adopts succusion Real Time Monitoring thickness, and accurately measures with ellipsometer test.
Two, carry out heat lamination
Placing successively the thick polycarbonate plate of 3.0mm, EVA hot melt adhesive film, the density three-dimensional carbon cloth, EVA hot melt adhesive film after vacuum magnetron sputtering coating film is processed, the polycarbonate plate that 3.0mm is thick on Vacuum Heat laminating machine auxiliary working platform by laminar structure, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get after cooling and have high reflective, high strength, anticollision, ornamental multifunctional composite, can be used for making handheld anti-explosion shield, public safety with partition plate, motion Protection Product etc.
The composite that the present embodiment is prepared composed as follows:
1. go up outer surface layer adopt be of a size of clear polycarbonate (PC) plate of 2000mm * 2200mm * 3.0mm, lower outer surface layer adopts clear polycarbonate (PC) plate that is of a size of 2000mm * 2200mm * 1.5mm;
2. the intermediate layer is the high-density glass fiber cloth, and surface thereof has little twill grid, and another surface is through vacuum magnetron sputtering coating film, and film material consists of titanium nitride+argent+TiCN.
3. the THICKNESS CONTROL of EVA hot melt adhesive film is at 5 μ m.
Described composite manufacture comprises the steps:
One, vacuum magnetron sputtering coating film being carried out on the weaving face fabric surface processes
Make substrate with the high-density glass fiber cloth, in one group of tension force is controlled No. 1 reative cell of the smooth magnetron sputtering coater that enters continuously single chamber three plated film districts of guide roller, make the deposition table placed face down, to prevent granular impurity staining substrate surface; Reative cell is evacuated to 2 * 10
-3Pa, with Ar as sputter gas and pure N
2Strengthen gas input reative cell, the flow-rate ratio Ar:N of sputter/increased response gas as assisting ion
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2000W, and underlayer temperature is 120 ℃, carries out deposition growing TiN/Ag.
Enter the second vacuum coating district after the vacuum coating district completes until first group of TiN/Ag film, then with Ar as sputter gas and pure O
2Make assisting ion and strengthen gas input reative cell, the flow-rate ratio Ar:O of sputter/increased response gas
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2600W, and underlayer temperature is 80 ℃, carries out the deposition growing TiCN.
Thickness is determined by growth time, adopts succusion Real Time Monitoring thickness, and accurately measures with ellipsometer test.
Two, carry out heat lamination
Placing successively the thick polycarbonate plate of 1.5mm, EVA hot melt adhesive film, the high-density glass fiber cloth, EVA hot melt adhesive film after vacuum magnetron sputtering coating film is processed, the polycarbonate plate that 3.0mm is thick on Vacuum Heat laminating machine auxiliary working platform by laminar structure, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get after cooling have high strength, light, ornamental multifunctional composite, can be used for making light-duty draw-bar box with tank material and motion Protection Product.
The composite that the present embodiment is prepared composed as follows:
1. go up outer surface layer and lower outer surface layer and all adopt clear polycarbonate (PC) plate that is of a size of 1200mm * 2000mm * 1.0mm;
2. the intermediate layer is 20 grams/every square metre of meltblown filament embossing non-weaving cloth, and another surface is through vacuum magnetron sputtering coating film, and film material consists of titanium nitride+copper+aluminium oxide.
3. the THICKNESS CONTROL of EVA hot melt adhesive film is at 12 μ m.
Described composite manufacture comprises the steps:
One, vacuum magnetron sputtering coating film being carried out on the weaving face fabric surface processes
Make substrate with 20 grams/every square metre of meltblown filament embossing non-weaving cloth, in one group of tension force is controlled No. 1 reative cell of the smooth magnetron sputtering coater that enters continuously single chamber three plated film districts of guide roller, make the deposition table placed face down, to prevent granular impurity staining substrate surface; Reative cell is evacuated to 2 * 10
-3Pa, with Ar as sputter gas and pure N
2Strengthen gas input reative cell, the flow-rate ratio Ar:N of sputter/increased response gas as assisting ion
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 1800W, and underlayer temperature is 120 ℃, carries out deposition growing TiN/Cu.
Enter the second vacuum coating district after the vacuum coating district completes until first group of TiN/Cu film, then with Ar as sputter gas and pure O
2Make assisting ion and strengthen gas input reative cell, the flow-rate ratio Ar:O of sputter/increased response gas
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2600W, and underlayer temperature is 80 ℃, carries out deposition growing Al
2O
3
Thickness is determined by growth time, adopts succusion Real Time Monitoring thickness, and accurately measures with ellipsometer test.
Two, carry out heat lamination
Placing successively the thick polycarbonate sheet of 1.0mm, EVA hot melt adhesive film, the non-weaving cloth, EVA hot melt adhesive film after vacuum magnetron sputtering coating film is processed, the polycarbonate sheet that 1.0mm is thick on Vacuum Heat laminating machine auxiliary working platform by laminar structure, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get after cooling have high strength, light, ornamental strong multifunctional composite, can be used for making the products such as wardrobe door, kitchen-cupboard doors, art lampshade.
The composite that the present embodiment is prepared composed as follows:
1. go up outer surface layer and lower outer surface layer and all adopt clear polycarbonate (PC) plate that is of a size of 1200mm * 2000mm * 1.0mm;
2. the intermediate layer is high density chemical fibre jacquard yarn dyed fabric, and another surface is through vacuum magnetron sputtering coating film, and film material consists of titanium nitride+copper+aluminium oxide.
3. the THICKNESS CONTROL of EVA hot melt adhesive film is at 10 μ m.
Described composite manufacture comprises the steps:
One, vacuum magnetron sputtering coating film being carried out on the weaving face fabric surface processes
Make substrate with high density chemical fibre jacquard yarn dyed fabric, in one group of tension force is controlled No. 1 reative cell of the smooth magnetron sputtering coater that enters continuously single chamber three plated film districts of guide roller, make the deposition table placed face down, to prevent granular impurity staining substrate surface; Reative cell is evacuated to 2 * 10
-3Pa, with Ar as sputter gas and pure N
2Strengthen gas input reative cell, the flow-rate ratio Ar:N of sputter/increased response gas as assisting ion
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 1800W, and underlayer temperature is 120 ℃, carries out deposition growing TiN/Cu.
Enter the second vacuum coating district after the vacuum coating district completes until first group of TiN/Cu film, then with Ar as sputter gas and pure O
2Make assisting ion and strengthen gas input reative cell, the flow-rate ratio Ar:O of sputter/increased response gas
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2600W, and underlayer temperature is 80 ℃, carries out deposition growing Al
2O
3
Thickness is determined by growth time, adopts succusion Real Time Monitoring thickness, and accurately measures with ellipsometer test.
Two, carry out heat lamination
Placing successively the thick polycarbonate sheet of 1.0mm, EVA hot melt adhesive film, the high density chemical fibre jacquard yarn dyed fabric, EVA hot melt adhesive film after vacuum magnetron sputtering coating film is processed, the polycarbonate sheet that 1.0mm is thick on Vacuum Heat laminating machine auxiliary working platform by laminar structure, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get after cooling have high strength, light, ornamental strong multifunctional composite, can be used for making the products such as wardrobe door, kitchen-cupboard doors, art lampshade.
Embodiment 5
The composite that the present embodiment is prepared composed as follows:
1. go up outer surface layer and lower outer surface layer and all adopt clear polycarbonate (PC) plate that is of a size of 1200mm * 2000mm * 1.0mm;
2. the intermediate layer is the optical thin film of high density chemical fibre jacquard yarn dyed fabric and one-sided plating anti-reflection film, and another surface of described high density chemical fibre jacquard yarn dyed fabric is through vacuum magnetron sputtering coating film, and film material consists of titanium nitride+copper+aluminium oxide; The thickness of described optical thin film is 12 μ m;
3. the THICKNESS CONTROL of EVA hot melt adhesive film is at 10 μ m.
Described composite manufacture comprises the steps:
One, vacuum magnetron sputtering coating film being carried out on the weaving face fabric surface processes
Make substrate with high density chemical fibre jacquard yarn dyed fabric, in one group of tension force is controlled No. 1 reative cell of the smooth magnetron sputtering coater that enters continuously single chamber three plated film districts of guide roller, make the deposition table placed face down, to prevent granular impurity staining substrate surface; Reative cell is evacuated to 2 * 10
-3Pa, with Ar as sputter gas and pure N
2Strengthen gas input reative cell, the flow-rate ratio Ar:N of sputter/increased response gas as assisting ion
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 1800W, and underlayer temperature is 120 ℃, carries out deposition growing TiN/Cu.
Enter the second vacuum coating district after the vacuum coating district completes until first group of TiN/Cu film, then with Ar as sputter gas and pure O
2Make assisting ion and strengthen gas input reative cell, the flow-rate ratio Ar:O of sputter/increased response gas
2=1:3, gas pressure intensity are 1.0Pa, and sputtering power is 2600W, and underlayer temperature is 80 ℃, carries out deposition growing Al
2O
3
Thickness is determined by growth time, adopts succusion Real Time Monitoring thickness, and accurately measures with ellipsometer test.
Two, carry out heat lamination
Placing successively the thick polycarbonate sheet of 1.0mm, EVA hot melt adhesive film, the high density chemical fibre jacquard yarn dyed fabric, EVA hot melt adhesive film, optical thin film, EVA hot melt adhesive film after vacuum magnetron sputtering coating film is processed, the polycarbonate sheet that 1.0mm is thick on Vacuum Heat laminating machine auxiliary working platform by laminar structure, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get after cooling have high strength, the multifunctional composite of light, ornamental strong, high printing opacity, can be used for making the products such as wardrobe door, kitchen-cupboard doors, art lampshade.
Embodiment 6
The composite that the present embodiment is prepared composed as follows:
1. go up outer surface layer adopt be of a size of transparent polyvinyl chloride (PVC) plate of 2000mm * 2200mm * 1.5mm, lower outer surface layer adopts transparent polyvinyl chloride (PVC) plate that is of a size of 2000mm * 2200mm * 2.5mm;
2. the intermediate layer is terylene woven fabric and optical thin film, two surfaces of described terylene woven fabric all have plain weave, and described optical thin film is that reflecting rate reaches 50%, the infrared light light transmittance is reached 38%, and visible light transmission is reached 80%, reach 99% PET optical thin film every ultraviolet rate, thickness is 25 μ m.
Place successively the thick polyvinyl chloride of 2.5mm (PVC) plate, EVA hot melt adhesive film, optical thin film, EVA hot melt adhesive film, terylene woven fabric, EVA hot melt adhesive film, polyvinyl chloride (PVC) plate that 1.5mm is thick by laminar structure on Vacuum Heat laminating machine auxiliary working platform, above-mentioned stacked good sheet material is moved on on Vacuum Heat laminating machine platform carry out heat lamination, namely get multifunctional composite after cooling.
Detect through LS102 light transmittance measuring instrument and learn: the reflecting rate of the composite that obtains is 45%, is 35% to the infrared light light transmittance, be 75% to visible light transmission, be 99% every ultraviolet rate, illustrate that this material can effectively completely cut off ultraviolet light and infrared light, and visible light transmittance rate is high, can be used for making the substitution material of the light-duty shading product of the high printing opacity of outdoor, glass sunlight house, external wall glass.
Be necessary at last in this explanation to be: above embodiment only is used for technical scheme of the present invention is described in more detail; can not be interpreted as limiting the scope of the invention, some nonessential improvement that those skilled in the art's foregoing according to the present invention is made and adjustment all belong to protection scope of the present invention.
Claims (18)
1. multifunctional composite, be the layer structure that adopts adhesive hot pressing to be composited, comprise upper and lower outer surface layer and intermediate layer, it is characterized in that: described upper and lower outer surface layer forms by transparent polymer, one deck weaving face fabric is at least contained in described intermediate layer, at least one surface of described weaving face fabric has art pattern, and the adhesive that carries out hot pressing is light penetrating copolymer.
2. multifunctional composite according to claim 1, it is characterized in that: a surface of described weaving face fabric has art pattern, and another surface is through the vacuum coating functionalization.
3. multifunctional composite according to claim 2 is characterized in that: the material that described vacuum coating functionalization adopts is TiO
2, TiC, TiCN, TiN, TiAlN, ZrN, AlN, CrN, CrC, TiCxNy, TiOxNy, Ag, Cu, Al
2O
3, aluminum titanium alloy, VO
2, Ta
2O
5, SiO
2, in ZrO, ZnS any one or multiple.
4. multifunctional composite according to claim 3, is characterized in that: described vacuum coating functionalization employing vacuum magnetron sputtering coating film technique.
5. multifunctional composite according to claim 4, is characterized in that, the parameter of described vacuum magnetron sputtering coating film technique is as follows: vacuum chamber is 1～12, and the magnetic controlled sputtering target in each vacuum chamber is 1～3, and auxiliary enhancing ion gun is 1～2; Described auxiliary enhancing ion gun is pure N
2Or O
2, take Ar as sputter gas, described sputter gas is 1:3 with the auxiliary flow-rate ratio that strengthens ionized gas; In reative cell, vacuum is 2 * 10
-3Pa, sputtering power are 1800～2600W, and gas pressure intensity is 1.0～2.0Pa, and underlayer temperature is 80～120 ℃.
6. multifunctional composite according to claim 1 and 2, it is characterized in that: described weaving face fabric is to be processed through woven, knitting or nonwovens process by non-metallic fibers.
7. multifunctional composite according to claim 6, it is characterized in that: described non-metallic fibers is glass fibre, basalt fibre, carbon fiber or chemical synthetic fiber.
8. multifunctional composite according to claim 6, it is characterized in that: the weight of described weaving face fabric is 5g/m
2～800g/m
2The Uneven Width width of described weaving face fabric is 300mm～2400mm.
9. multifunctional composite according to claim 1 and 2 is characterized in that: described art pattern by braiding or/and dyeing and printing process form.
10. multifunctional composite according to claim 1 and 2, it is characterized in that: described intermediate layer also comprises one deck optical thin film at least.
11. multifunctional composite according to claim 10 is characterized in that: the reflecting rate of described optical thin film is 10%～60%, light transmittance is 5%～45%, solar energy always the partition rate be 55%～78%, every ultraviolet light rate 〉=99%.
12. multifunctional composite according to claim 1 and 2 is characterized in that: described intermediate layer also comprises one deck filament layer at least, and the diameter of described filament is 2 μ m～200 μ m.
13. multifunctional composite according to claim 12 is characterized in that: described filament is that wire is or/and nonmetal wire.
14. multifunctional composite according to claim 13 is characterized in that: described wire is selected from copper coated iron wire, copper wire or stainless steel wire; Described nonmetal wire is selected from glass fiber, basalt fibre silk, carbon fiber wire, chemical fiber wire or conducting fiber.
15. multifunctional composite according to claim 12 is characterized in that: uniformly-spaced cross arrangement forms described filament layer or/and unequal interval is parallel by filament.
16. multifunctional composite according to claim 1 is characterized in that: the transparent polymer that forms upper and lower outer surface layer is Merlon (PC) or polyvinyl chloride (PVC); The adhesive that carries out hot pressing is EVA PUR, polyurethane binding or acrylate adhesive.
17. multifunctional composite according to claim 16 is characterized in that: the thickness of upper and lower outer surface layer is 25 μ m～12mm; The thickness of heat pressure adhesive layer is 1 μ m～50 μ m.
18. the application of the described multifunctional composite of any one in claim 1 to 17 is for making sunshade lighting product, home electronic panel, house decorative material, motion Protection Product, security protection product, partition wall, partition or case and bag.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310047494.4A CN103112309B (en) | 2013-02-06 | 2013-02-06 | A kind of multifunctional composite and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310047494.4A CN103112309B (en) | 2013-02-06 | 2013-02-06 | A kind of multifunctional composite and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103112309A true CN103112309A (en) | 2013-05-22 |
| CN103112309B CN103112309B (en) | 2016-01-20 |
Family
ID=48410729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310047494.4A Expired - Fee Related CN103112309B (en) | 2013-02-06 | 2013-02-06 | A kind of multifunctional composite and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103112309B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103327801A (en) * | 2013-05-31 | 2013-09-25 | 中国舰船研究设计中心 | Control method of cabin electromagnetic environment |
| CN103945669A (en) * | 2014-04-14 | 2014-07-23 | 联想(北京)有限公司 | Electronic device |
| CN104085136A (en) * | 2014-06-12 | 2014-10-08 | 东莞市正升手袋辅料有限公司 | Environment-friendly composite plate and manufacturing process thereof |
| CN104339787A (en) * | 2014-10-22 | 2015-02-11 | 安徽梦谷纤维材料科技有限公司 | Fabric for luggage and preparation method of fabric |
| CN104999763A (en) * | 2015-06-19 | 2015-10-28 | 安徽工程大学 | Preparation method of flexible nanometer interface composite textile material |
| WO2017004530A1 (en) * | 2015-07-01 | 2017-01-05 | Tumi, Inc | Suitcase molding process with overlay |
| CN106758163A (en) * | 2016-11-09 | 2017-05-31 | 江南大学 | The infrared stealth fabric and preparation method of a kind of multi-layer compound structure |
| CN107077834A (en) * | 2014-06-30 | 2017-08-18 | 赫斯特伍德农场钢琴演奏室有限公司 | Soundboard device and forming method |
| CN107680698A (en) * | 2016-08-02 | 2018-02-09 | 波音公司 | Multi-functional composite construction for extreme environment |
| WO2019032056A1 (en) * | 2017-08-10 | 2019-02-14 | Leowkijsiri Phalatt | Multi-material foldable product |
| CN110230184A (en) * | 2019-06-24 | 2019-09-13 | 张锦潇 | A kind of polyester fabric preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3335669A1 (en) * | 1983-09-30 | 1985-05-02 | Konrad Hornschuch Ag, 7119 Weissbach | Injection-laminateable web-shaped plastics composite material, process for the production thereof and use thereof |
| CN1687507A (en) * | 2005-04-12 | 2005-10-26 | 夏芝林 | Method for preparing silver metallized organic fiber and textile |
| CN102152510A (en) * | 2010-11-30 | 2011-08-17 | 吴江市圆明印花厂 | Nanometer composite elastic knitted fabric |
| CN102452194A (en) * | 2010-11-01 | 2012-05-16 | 常熟市鑫特都制衣有限公司 | Multifunctional composite fabric |
| CN102632646A (en) * | 2012-03-30 | 2012-08-15 | 蒙特集团（香港）有限公司 | Shutter material for transmitting curtain with flexible composite structure and method for manufacturing shutter material |
-
2013
- 2013-02-06 CN CN201310047494.4A patent/CN103112309B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3335669A1 (en) * | 1983-09-30 | 1985-05-02 | Konrad Hornschuch Ag, 7119 Weissbach | Injection-laminateable web-shaped plastics composite material, process for the production thereof and use thereof |
| CN1687507A (en) * | 2005-04-12 | 2005-10-26 | 夏芝林 | Method for preparing silver metallized organic fiber and textile |
| CN102452194A (en) * | 2010-11-01 | 2012-05-16 | 常熟市鑫特都制衣有限公司 | Multifunctional composite fabric |
| CN102152510A (en) * | 2010-11-30 | 2011-08-17 | 吴江市圆明印花厂 | Nanometer composite elastic knitted fabric |
| CN102632646A (en) * | 2012-03-30 | 2012-08-15 | 蒙特集团（香港）有限公司 | Shutter material for transmitting curtain with flexible composite structure and method for manufacturing shutter material |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103327801B (en) * | 2013-05-31 | 2016-02-24 | 中国舰船研究设计中心 | Control method of cabin electromagnetic environment |
| CN103327801A (en) * | 2013-05-31 | 2013-09-25 | 中国舰船研究设计中心 | Control method of cabin electromagnetic environment |
| CN103945669A (en) * | 2014-04-14 | 2014-07-23 | 联想(北京)有限公司 | Electronic device |
| CN104085136A (en) * | 2014-06-12 | 2014-10-08 | 东莞市正升手袋辅料有限公司 | Environment-friendly composite plate and manufacturing process thereof |
| CN107077834A (en) * | 2014-06-30 | 2017-08-18 | 赫斯特伍德农场钢琴演奏室有限公司 | Soundboard device and forming method |
| CN104339787A (en) * | 2014-10-22 | 2015-02-11 | 安徽梦谷纤维材料科技有限公司 | Fabric for luggage and preparation method of fabric |
| CN104999763A (en) * | 2015-06-19 | 2015-10-28 | 安徽工程大学 | Preparation method of flexible nanometer interface composite textile material |
| CN104999763B (en) * | 2015-06-19 | 2019-02-12 | 安徽工程大学 | A kind of preparation method of flexible nano interface composite material for weaving |
| WO2017004530A1 (en) * | 2015-07-01 | 2017-01-05 | Tumi, Inc | Suitcase molding process with overlay |
| US10143278B2 (en) | 2015-07-01 | 2018-12-04 | Tumi, Inc. | Suitcase molding process with overlay |
| CN107680698A (en) * | 2016-08-02 | 2018-02-09 | 波音公司 | Multi-functional composite construction for extreme environment |
| CN107680698B (en) * | 2016-08-02 | 2023-06-06 | 波音公司 | Multifunctional composite structure for extreme environments |
| CN106758163A (en) * | 2016-11-09 | 2017-05-31 | 江南大学 | The infrared stealth fabric and preparation method of a kind of multi-layer compound structure |
| WO2019032056A1 (en) * | 2017-08-10 | 2019-02-14 | Leowkijsiri Phalatt | Multi-material foldable product |
| CN110230184A (en) * | 2019-06-24 | 2019-09-13 | 张锦潇 | A kind of polyester fabric preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103112309B (en) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103112309B (en) | A kind of multifunctional composite and application thereof | |
| Shahidi et al. | A review-application of physical vapor deposition (PVD) and related methods in the textile industry | |
| AU2011336403B2 (en) | Near infrared reflecting composition and coverings for architectural openings incorporating same | |
| US4645704A (en) | Reflecting textile web and method for the production thereof | |
| US20220055359A1 (en) | Room Darkening Material And Architectural Covering Made From Same | |
| CN105084781B (en) | A kind of golden low radiation film coating glass and preparation method thereof | |
| CN203110782U (en) | Multifunctional decorative board | |
| CN203110460U (en) | Multifunctional composite board | |
| CN102584023A (en) | Solar control coated glass preparation method and glass thereof | |
| CN105084780B (en) | A kind of sunshade type double-silver low-emissivity coated glass and preparation method thereof | |
| CN102673042A (en) | Novel broad-breadth sun-shading material and preparation method thereof | |
| CN105084779A (en) | Highly-transparent type double-silver low-e reflective glass and preparation method thereof | |
| CN1693249A (en) | Process for preparing seven-colour discoloration glass | |
| CN102632646A (en) | Shutter material for transmitting curtain with flexible composite structure and method for manufacturing shutter material | |
| CN201519033U (en) | No-wash antiflaming reflection energy-saving curtain | |
| CN105084776B (en) | A kind of gold solar-control glazing and preparation method thereof | |
| CN109665723A (en) | A kind of special muted color double-silver low-emissivity coated glass and preparation method clearly | |
| CN202556836U (en) | Roller shutter material for transparent curtain of flexible composite structure | |
| CN203399947U (en) | Heat insulation curtain cloth | |
| CN105082670B (en) | A kind of green sunshade type coated glass and preparation method thereof | |
| CN202986217U (en) | Flexible high-definition intelligent curtain | |
| CN102886927A (en) | Flexible high definition intelligent curtain | |
| CN203284562U (en) | Full-shading coating decoration cloth | |
| CN106435475B (en) | A kind of energy saving fenestrated membrane of blue-green three-silver low radiation and preparation method thereof | |
| CN202934858U (en) | Novel broad-breadth sun-shading material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180227 Address after: 201616 101 rooms, No. 199, Guanghua Road, Kunshan Town, Songjiang District, Shanghai Patentee after: Shanghai Yi Yan Industrial Co., Ltd. Address before: 201600 Kungang highway 888, Kunshan Town, Songjiang District, Shanghai, 4 Patentee before: Shanghai Vakia Coating Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160120 Termination date: 20210206 |