CN103085393A - Thermo-sensitive type intelligent composite optical glass based on renewable resources - Google Patents

Thermo-sensitive type intelligent composite optical glass based on renewable resources Download PDF

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CN103085393A
CN103085393A CN2013100075234A CN201310007523A CN103085393A CN 103085393 A CN103085393 A CN 103085393A CN 2013100075234 A CN2013100075234 A CN 2013100075234A CN 201310007523 A CN201310007523 A CN 201310007523A CN 103085393 A CN103085393 A CN 103085393A
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temperature
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light permeable
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CN103085393B (en
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付国东
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Qingdao Huixin Mstar Technology Ltd
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付国东
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Abstract

The invention discloses thermo-sensitive type intelligent composite optical glass, which is formed by arranging active components of reversible nanometer-phase separation and temperature response type biological base material polymer gel, which is generated at a critical temperature, between optical glass materials. A bio-based polymer gel material mainly is a reproducible high molecular material modified for biological extraction. The thermo-sensitive type intelligent composite optical glass has good light transmission (the light transmission rate of a wavelength in a range of 380-2500 nanometers is more than 60%) when a temperature is lower than the critical temperature, and shows that a non-transparent state (the light transmission rate of the wavelength in the range of 380-2500 nanometers is less than 10%) when the temperature is higher than the critical temperature. The intelligent composite optical material provided by the invention can be continuously and normally used for 10-20 years in an outdoor environment at a temperature of -20 to 80 DEG C on the technical basis of a nanometer-phase separation technology, can be used for reducing energy consumption and reducing carbon emission by intelligently using solar energy, and has a very wide market prospect.

Description

A kind of temperature sensitive type Intelligent Composite optical glass based on renewable resource
Technical field
The present invention relates to a kind of intelligent optical composite material, particularly relate to a kind of temperature sensitive type Intelligent Composite optical glass by the composite preparation of reproducible bio-based functional polymer.
Background technology
Intellectual material refers to imitate life system, energy perception environmental change, and can in time adjust or change the performance parameter of material self according to the ambient parameter of institute's perception, make desired and can with change after the composite of the variation that adapts to of environment facies or material compound.Bionical life sensation and self-control are the key characters of intellectual material.
Along with the development in epoch, the intelligent construction of building can go deep into further, and the content of intelligent building and connotation are along with the development of science and technology is constantly extended, and its function is also in continuous expansion, to satisfy the growing various needs of people.Relevant prediction shows, in the middle of this century, building industry will be stepped into high-tech building materials periods, and the building material take the intelligent building material as representative will become main flow.
In numerous construction materials, glass plays an increasingly important role.Glass has irreplaceability as the architectural lighting material, glass and finely processed product thereof enlarge year by year as the application of decorating and renovating material, utilize the multifunctional material of the unique optical characteristics manufacturing of glass material to play an important role in Energy Conservation Green Construction.Except traditional energy-saving glass manufacture craft, beyond double glazing, antisolar glass and heat-reflecting glass, a lot of new technologies, new product have appearred in recent years, as photochromic glass, thermo-color glass, liquid-crystalline glasses, electrochomeric glass and electrophoresis glass etc.
The responsive to temperature type intelligent glass can present by transparent to opaque phase co-conversion with environment temperature.During lower than the temperature set, the responsive to temperature type intelligent glass has good translucidus when temperature, and during higher than the temperature set, this material will decline to a great extent to visible light or sightless transmitance when temperature, and it is opaque that intelligent glass will become.The responsive to temperature type intelligent glass can be used as the Intelligent temp controlled energy-saving material and is widely used in intelligent building.In temperature low season, the responsive to temperature type intelligent glass can allow to greatest extent sunshine see through intelligent glass and enter interior of building.When the temperature that indoor temperature feels comfortably cool higher than people, during as 24-25 ℃, intelligent glass will be changed into low transmission or opaque by the pellucidity of high permeability, and at this moment sunshine will farthest be reflected.So just can realize the Based Intelligent Control to the interior of building temperature, reduce the use of air-conditioning.Can also be artificially to the intelligent glass heating, facilitate intelligent glass by transparent to opaque transformation, thereby interior of building light is regulated.
The responsive to temperature type intelligent glass has boundless market prospects, except as the intelligent building material, outside the window and glass curtain wall that are used for mansion, senior house, machine poplar and harbour etc. in building industry, the little sunglasses of wearing to people, large porthole and protecting film to vehicles such as automobile, train, steamer and aircrafts, the field all is widely used.The conceptual product of existing intelligent glass occurs both at home and abroad at present.External representational is the Pro-display company of Britain, and the product of the said firm is called reversible intelligent glass (switchable intelligent glass), is applied in the new World Trade Organization mansion of USA New York.The representative firm of China's intelligent glass is the Nanjing Zhixian Science and Technology Co., Ltd. in Nanjing and Beijing big bold and unconstrained intelligent glass Co., Ltd.At present, the said goods all preparations take liquid crystal as sensitive material technically.As everyone knows, liquid crystal is the material of the dull and stereotyped LCD TV of preparation.And existing intelligent glass has been owing to having adopted the technology for preparing dull and stereotyped LCD TV display material, so price is very expensive.It is reported, the external product price be roughly equal to 15000 RMB/square metre, the price of home products is minimum at 4000 yuan-6000 yuan/square metre.
The responsive to temperature intelligent glass of relevant employing Temperature Responsive Polymer As material has been reported.A kind of method is the poly-N-isopropylacrylamide aqueous solution of Temperature Responsive Polymer As to be poured into glass sandwich make temperature sensitive glass.During higher than critical value, thermosensitive polymer will be separated out in temperature, makes Polymer Solution become muddy, thus reach glass by printing opacity to lighttight transformation.If but this glass is under condition higher than critical point temperature for a long time, Temperature Responsive Polymer As can precipitate, and is difficult to restore to the original state, and makes intelligent glass not have the function of reusing.Another kind of temperature sensitive intelligent glass is the network structure macromolecule that PNIPAM prepares to be placed between glass consist of, yet the PNIPAM colloid can produce contraction under for a long time higher than the critical-temperature condition, and the moisture that absorbs is squeezed out, make the environmental stability of this glass very poor, be difficult to reuse.
In patent 201110101849.4,201110311787.x, 2011397060.8, disclosed bionic intelligence optics composite glass property is excellent, and working range has the outdoor application time limit of 10～20 years at-20～80 ℃.Yet foregoing invention all is based on the bionic intelligence optics compound glass of synthetic high polymer preparation.And synthetic high polymer comes from oil, has non-renewablely, and this family macromolecule of what is more important needs with an organic solvent in building-up process again, so price is high, and environment structure is polluted.
Summary of the invention
the purpose of this invention is to provide a kind of can be in-20～80 ℃ of scopes, the temperature sensitive type Intelligent Composite optical glass in outdoor environment service life more than 5～10 years, this temperature sensitive type Intelligent Composite optical glass is based on renewable resource, be specially bio-based functional polymer compound system, homogeneous system generation nanoscale by the composite colloid material is separated or its reversible variation, have optically transparent and opaque between mutually the conversion, the transmitance of its light in 380 nanometers～2500 nanometer wavelength range obviously changes this special character, and make a kind of temperature control response type intelligent optics composite material.Intelligent glass of the present invention has better environmental stability and service life, fast responding ability and reversible round serviceability.
The present invention adopts following technical scheme:
A kind of temperature sensitive type Intelligent Composite optical glass based on renewable resource, can be according to temperature change, produce the mutual conversion between transparent and opaque under critical-temperature, it is characterized in that described temperature sensitive type Intelligent Composite optical glass is placed between two or multi-disc glass by the biological base material polymeric colloid active material of temperature-responsive consists of, and the biological base material polymeric colloid active material of described temperature-responsive produces reversible nanoscale in critical-temperature and is separated.
Described temperature sensitive type Intelligent Composite optical glass is when pellucidity, at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 60%, when the temperature sensitive type intelligent glass changes opaque state into, at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, less than 10%, most light are reflected and diffusion wavelength at the light permeable rate of 380～2500 nanometers.
Temperature sensitive type Intelligent Composite optical glass of the present invention, the biological base material polymeric colloid active material of described temperature-responsive reaches (F) anticorrisive agent formation soluble in water by (A) resin additive, (B) temperature response type bio-based macromolecule, (C) water-soluble biological extraction macromolecule, (D) inorganic salts, (E) organic micromolecule compound.During lower than critical-temperature, component A, B, C, D, E, F are dissolved in and consist of the homogeneous system in the aqueous solution, present the good transparency, are pellucidity in temperature; When temperature during higher than critical-temperature, the temperature response type macromolecule of nano-scale by in the homogeneous system free out, nanoscale occurs and be separated, thereby present opaque state.
Described critical-temperature is that the generation of temperature sensitive type Intelligent Composite optical glass is transparent in opaque transformation, or opaque specified temp to transparent transition, is also that the response temperature of transformation mutually occurs the polymeric colloid active material of temperature-responsive.Described critical-temperature is between 0-60 ℃.
The temperature response type bio-based macromolecule (B) of nano-scale of the present invention is methylcellulose, hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethylhydroxyethylcellulose, the mixture of one or more in hydroxy butyl methyl cellulose.Described temperature response type bio-based macromolecule (B) molecular weight is at 1000-50,000,000 g/mol, and substitution value DS is between 0-3.Be preferably methylcellulose, hydroxypropyl cellulose, preferred molecular weight is 10000-5,000,000 g/mol, substitution value is between 0.3-2.5.
Water-soluble biological of the present invention extracts one or more the mixture that macromolecule (C) can be selected common CMS, acetic starch, CMC, carboxymethyl cellulose, hydroxyethyl ether cellulose, sodium carboxymethylcellulose, semi-annular jade pendant acid ethyl cellulose, chitin, poly-aspartate, poly-epoxy succinic acid, Carboxymethylinulin, xanthans, melon glue, locust bean gum, flax gum pectin, Arabic gum, algin or carragheen.
In the biological base material polymeric colloid active material of temperature-responsive of the present invention, (A) resin additive refers to common light stabilizer or antioxidant etc.Light stabilizer comprises ultraviolet absorber, quencher or free radical catcher.Choose in the various resin additives that light stabilizer or antioxidant can be commonly used in the prior art.for example, ultraviolet absorber comprises benzophenone, benzotriazole, phenol benzoate class, salicylate class or triazines ultraviolet absorber, as 2,4-DihydroxyBenzophenone, 2,2 '-dihydroxy-4,4 '-dimethoxy-benzophenone, ESCALOL 567, 2,2 '-dihydroxy-4-methoxy benzophenone, 2-hydroxyl-4-oxygen base in positive heptan benzophenone, 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone, 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketone, 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) BTA, 2-(the 2'-hydroxyl-3'-tert-butyl group-5'-aminomethyl phenyl)-5-chlorinated benzotriazole, 2-(2'-hydroxyl-3', 5'-two tertiary amyl phenyl) BTA, 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, the special octyl phenyl of 2-(2'-hydroxyl-5'-) BTA, 2-(2'-hydroxyl-3', two (a, the a-dimethyl benzyl) phenyl of 5') BTA, 2-(2H-BTA-2-yl)-6-dodecyl-4-methylphenol, the septichen phenyl ester, single benzoic acid resorcinol, phenyl salicytate, the bisphenol-A sasapyrin, p-octylphenyl salicylate, p-t-butylphenyl salicylate, single benzoic acid resorcinol, 3,5-di-tert-butyl-4-hydroxybenzoic acid 2,4 ,-di-t-butyl phenyl ester, the positive hexadecyl ester of 3,5-di-tert-butyl-4-hydroxybenzoic acid or 2,4,6-three (2 '-hydroxyl-4 '-n-butoxy phenyl) 1,3,5-triazines.Quencher is optional from organic nickel complex class, as two (3,5-di-tert-butyl-4-hydroxyl benzyl monoethyl phosphate) nickel, 2,2 '-thiobis (uncle's 4-octyl phenol oxygen base) nickel-n-butylamine complex compound, 2,2-sulfo-(uncle's 4-octyl phenol oxygen base) nickel-2 ethyl hexylamine complex compound, 2,2 '-thiobis (uncle's 4-octyl phenol oxygen base) nickel, N, N-second, n-butyl dithiocarbamate nickel, nickel dimethyldithiocarbamate or dioctyl aminodithioformic acid nickel.The free radical catcher is selected from piperidines, phosphorous acid esters material, as two (2,2,6,6-tetramethyl-piperidyl) sebacate, 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, decanedioic acid two (2,2,6,6-tetramethyl-4-piperidine ester), (1,2,2,6,6-pentamethyl piperidyl) phosphite ester or 4-benzoyloxy-2,2,6,6-tetramethyl piperidine.Antioxidant comprises diphenylamines, p-phenylenediamine (PPD), EEDQ or derivatives thereof, or 2, three grades of butyl of 6--4-methylphenol, two (3, three grades of butyl of 5--4-hydroxy phenyl) thioether, four (β-(three grades of butyl of 3,5--4-hydroxy phenyl) propionic acid) pentaerythritol ester, thio-2 acid dibasic acid esters, two Lauryl Alcohol ester, two ten four carbon alcohols esters and two octadecanol ester, three monooctyl esters, three the last of the ten Heavenly stems ester, three (Lauryl Alcohol) esters and three (16 carbon alcohol) etc.described resin additive (A) is selected from following material in specific embodiment, comprise 2, 2 '-dihydroxy-4, 4 '-dimethoxy-benzophenone, 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone, 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketone, 2, 2 '-dihydroxy-4, 4 '-dimethoxy-5-diphenylsulfone ketone, 2, 2 '-dihydroxy-4, 4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 2-(2'-hydroxyl-3', the 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 1-(2' ethoxy)-2, 2, 6, 6-tetramethyl-4-piperidine alcohols, decanedioic acid two (2, 2, 6, 6-tetramethyl-4-piperidine ester), (1, 2, 2, 6, 6-pentamethyl piperidyl) phosphite ester, 2, three grades of butyl of 6--4-methylphenol, two (3, three grades of butyl of 5--4-hydroxy phenyl) thioether, four (β-(3, three grades of butyl of 5--4-hydroxy phenyl) propionic acid) one or more in pentaerythritol ester.
Inorganic salts of the present invention (D) are potassium, sodium, calcium, magnesium, zinc, iron, copper, nickel, the sulfate of the metal ions such as chromium, hydrochloride, sulphite, nitrate, carbonate, phosphate and acetate.Be preferably one or more in sodium chloride, potash, sodium nitrate, sodium sulfite or calcium chloride.
Organic micromolecule compound of the present invention (E) is one or more of ethylene glycol, ethanol, methyl alcohol, acetone, propane diols, glycerine, butanols, triethylamine, isopropyl alcohol.Be preferably ethanol, ethylene glycol or glycerine, or their mixture.
Anticorrisive agent F of the present invention is benzoic acids, sorb acids, nisin, natamycin, ε one polylysine, one or more in calcium propionate.
In biological base material polymeric colloid active material, in mass fraction, its composition comprises:
(A) resin additive is 0.01～10 part
(B) temperature response type bio-based macromolecule is 1～30 part
(C) water-soluble biological extracts 1～60 part of macromolecule
(D) inorganic salts are 1～20 part
(E) organic micromolecule compound is 2～50 parts
(F) anticorrisive agent is 0.01-2 part
Said components is soluble in water, and the formation total mass concentration is 3%～60% solution.
Above-mentioned (A) resin additive, (B) temperature response type bio-based macromolecule, (C) water-soluble biological extract macromolecule, (D) inorganic salts and (E) composition of the composite formation of organic micromolecule compound is soluble in water, the biological base material polymeric colloid active material of formation temperature response.This system is lower than the gluey solution that consists of transparent and homogeneous under critical-temperature, in this case, temperature sensitive type Intelligent Composite optical glass at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 60%.When temperature during higher than critical-temperature, the temperature response type bio-based macromolecule (B) of nano-scale produces reunion in sol system, produce the microballoon of 10～1000 nanometers, do not hold mutually with system, be separated with opaque particulate form and the generation of whole system of 10～1000 nanometers.Microballoon this in the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, at the light permeable rate of wavelength 380～2500 nanometers less than 10%.When temperature sensitive type Intelligent Composite optical glass became opaque state, less than 1%, less than 10%, most light were reflected and diffusion wavelength at the light permeable rate of 380～2500 nanometers at the light permeable rate of ultraviolet 200～380 nano wave lengths.
Described glass is existing goods unorganic glass or lucite etc.
Be placed in the thickness of the polymeric colloid active material between glass between 0.1 millimeter-100 millimeters.
Described temperature sensitive type Intelligent Composite optical glass, lower than zero point the time, the biological base material polymeric colloid active material of temperature-responsive is the good homogeneous system of mutual capacitive, whole intelligent glass presents the highly transparent state.During higher than critical value, the temperature response type bio-based macromolecule of nano-scale produces being separated of nano-scale when temperature, and the biological base material polymeric colloid active material of temperature-responsive presents opaque state.Temperature sensitive type Intelligent Composite optical glass of the present invention makes the temperature response type bio-based macromolecule of nano-scale evenly distribute, both can prevent that temperature response type bio-based macromolecule from settling in generation changes mutually, can prevent the contraction of sol system again, be conducive to keep the dimensional stability of whole sol system, thereby stable phase-separated system is provided.Simultaneously, whole system has very high environmental work scope, and its effective operating temperature is at-20～80 ℃.Described temperature sensitive type Intelligent Composite optical glass under service condition, underwent no deterioration out of doors in 10～20 years.
Beneficial effect: temperature sensitive type Intelligent Composite optical glass of the present invention, be placed between glass sandwich by the biological base material polymeric colloid active material of temperature-responsive and consist of, utilize temperature response type bio-based macromolecule and water-soluble biological to extract macromolecule molten formation colloidal sol altogether, realize other even distribution of molecular level, when variations in temperature, temperature response type bio-based macromolecule generation dissolubility changes, and produces nanoscale and be separated in sol system, presents in appearance transparent in opaque phase co-conversion.The special nature that temperature sensitive type Intelligent Composite optical glass has can be according to the environmental change in the external world, and autonomous generation stress behavior, occur in the temperature range of setting transparent in opaque transformation, thereby keep the stable of environment temperature, reach energy-conservation purpose.
In a word, responsive to temperature type intelligent glass of the present invention has advantages of the following aspects:
(1) realization of the present invention is based upon on the nanophase isolation technics basis of bioactive molecule.
(2) realization of the present invention is based upon on molecule rank nanophase isolation technics, so the environmental stability of system is high, and reaction rate is fast.
(3) temperature sensitive type Intelligent Composite optical glass of the present invention for ambient temperature conditions change autonomous produce stress behavior, do not need the people to give the purpose that signal (as energising) reaches response, be therefore a kind of intelligent power saving product truly.
(4) technology that adopts environmental protection more.The macromolecular material of the bio-based modification that intelligent glass of the present invention adopts is a kind of nontoxic, stable, eco-friendly renewable polymeric materials.If damaging or abandoning appears in intelligent glass, can not bring any environmental pollution, the production process of this macromolecular material can not brought environmental pollution yet simultaneously.
(5) intelligent glass cost of material of the present invention is low, and preparation for processing is simple.
(6) intelligent glass product of the present invention has better environmental stability and service life.This product can use continuously under-20～80 ℃ of outdoor homes and undergo no deterioration in 10～20 years, can satisfy the application under various environment.
(7) temperature sensitive Intelligent Composite optical glass of the present invention can be widely used in glass curtain wall, the vehicles.
The specific embodiment
Describe the present invention below in conjunction with the specific embodiment, described embodiment helps the understanding of the present invention and enforcement, is not to be construed as limiting the invention.Implement the present invention, polymeric colloid active material except temperature-responsive related in specific embodiment, those skilled in the art can also carry out same or analogous replacement on function to polymeric colloid active material and its preparation method of temperature-responsive wherein used, or change proportionate relationship between polymer molecular weight, component and component etc. according to different purpose.Protection scope of the present invention is not limited with the specific embodiment, but is limited by claim.
in cited embodiment, the polymeric colloid active material is by (A) resin additive, comprise light stabilizer or antioxidant, as 2, 2 '-dihydroxy-4, 4 '-dimethoxy-benzophenone, 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone, 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketone, 2, 2 '-dihydroxy-4, 4 '-dimethoxy-5-diphenylsulfone ketone, 2, 2 '-dihydroxy-4, 4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 2-(2'-hydroxyl-3', the 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 1-(2' ethoxy)-2, 2, 6, 6-tetramethyl-4-piperidine alcohols, decanedioic acid two (2, 2, 6, 6-tetramethyl-4-piperidine ester), (1, 2, 2, 6, 6-pentamethyl piperidyl) phosphite ester, 2, three grades of butyl of 6--4-methylphenol, two (3, three grades of butyl of 5--4-hydroxy phenyl) thioether, four (β-(3, three grades of butyl of 5--4-hydroxy phenyl) propionic acid) one or more in pentaerythritol ester, (B) temperature response type bio-based macromolecule is one or more mixture of methylcellulose, hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethylhydroxyethylcellulose, hydroxy butyl methyl cellulose, (C) water-soluble biological extracts one or more the mixture that macromolecule (C) can be selected common CMS, acetic starch, CMC, carboxymethyl cellulose, hydroxyethyl ether cellulose, sodium carboxymethylcellulose, semi-annular jade pendant acid ethyl cellulose, chitin, poly-aspartate, poly-epoxy succinic acid, Carboxymethylinulin, xanthans, melon glue, locust bean gum, flax gum pectin, Arabic gum, algin or carragheen, (D) inorganic salts comprise sodium chloride, calcium chloride, sodium sulfite and sodium nitrate, (E) organic micromolecule compound comprises ethanol, ethylene glycol, glycerine or their mixture, (F) anticorrisive agent, F are benzoic acids, sorb acids, nisin, natamycin, ε one polylysine, one or more mixtures such as calcium propionate, said components formation soluble in water.Then component A, B, C, D, E, F mixture is soluble in water, be prepared into concentration and be 3%～60% solution.
Example 1
5 parts of 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenones, 25 parts of hydroxypropyl celluloses (molecular weight=100,000 g/mol), 40 parts of xanthans, 5 parts of magnesium carbonate, the compound of 25 parts of propane diols, the Sodium Benzoate of 0.01 part, 28% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 2mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 21 ℃.Lower than 21 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 85%; When temperature during higher than 21 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 2
28 parts of ethylhydroxyethylcelluloses, 40 parts of poly-epoxy succinic acids, the mixture of 27 parts of ethylene glycol and ethanol (ethylene glycol: ethanol=1:1), with 2 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 3 parts of sodium chloride compounds, 0.01 the Sodium Benzoate of part, 43% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 8mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 35 ℃.Lower than 35 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 72%; When temperature during higher than 35 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 3
3 parts of 2-(2'-hydroxyl-3', the 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 17 parts of hydroxy butyl methyl celluloses, 50 parts of semi-annular jade pendant acid ethyl celluloses, 4 parts of zinc nitrates, the mixture of 26 parts of glycerine and butanols (glycerine: the compound of butanols=1:2), the Sodium Benzoate of 0.01 part, 36% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 36 ℃.Lower than 36 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 36 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1.5%.
Example 4
1 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, the mixture of 26 parts of hydroxy butyl methyl celluloses and hydroxypropyl methylcellulose (hydroxy butyl methyl cellulose: hydroxypropyl methylcellulose=1:3), 33 parts of flax gum pectin, 17 parts of calcium chloride, the compound of 23 parts of methyl alcohol, 0.01 the sorbic acid of part, 37% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 7mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 37 ℃.Lower than 37 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%; When temperature during higher than 37 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 5
3 parts of 2,4-DihydroxyBenzophenones, 28 parts of hydroxypropyl cellulose (molecular weight=50,000 g/mol, substitution value is DS=2.2), 49 parts of Arabic gums, 1 part of calcium chloride, the compound of 19 parts of butanols, the polylysine of 0.02 part, 46% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 28 ℃.Lower than 28 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%; When temperature during higher than 28 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 6
2 parts two (3, three grades of butyl of 5--4-hydroxy phenyl) thioether, 30 parts of hydroxy butyl methyl celluloses, 46 parts of locust bean gums and flax gum pectin (locust bean gum: flax gum pectin=1:1), 1 part of potash, the mixture of 21 parts of glycerine and triethylamine (glycerine: the compound of triethylamine=1:2), the Sodium Benzoate of 0.01 part, 36% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 7 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 26 ℃.Lower than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 65%, higher than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 7
4 part 2, three grades of butyl of 6--4-methylphenol, 25 parts of ethylhydroxyethylcelluloses, 30 parts of algins, 5 parts of sodium nitrate, the compound of 36 parts of ethanol, the Sodium Benzoate of 0.01 part, 40% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 12 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 38 ℃.Lower than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%, higher than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 8
1 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 20 parts of hydroxypropyl methylcelluloses, 35 parts of Carboxymethylinulins, 1 part of calcium chloride, the compound of 43 parts of ethylene glycol, the lysozyme of 0.01 part, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 42 ℃.Lower than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 9
5 part 2,2 '-dihydroxy-4,4 '-dimethoxy-benzophenone, the mixture of 18 parts of hydroxy butyl methyl celluloses and methylcellulose (hydroxy butyl methyl cellulose: methylcellulose=1:2), 40 parts of hydroxyethyl ether celluloses, 1 part of sodium sulfite, the compound of 36 parts of ethanol, 0.01 the Sodium Benzoate of part, 20% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 30 ℃.Lower than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 60%; When temperature during higher than 30 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 10
3 part (1,2,2,6,6-pentamethyl piperidyl) phosphite ester, 20 parts of hydroxypropyl celluloses (molecular weight=200,000 g/mol, DS=2.0), 38 parts of poly-aspartates, 2 parts of sodium chloride, the compound of 37 parts of ethylene glycol, the Sodium Benzoate of 0.01 part, 20% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 6mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 28 ℃.Lower than 28 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 65%; When temperature during higher than 28 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 11
2 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 18 parts of hydroxypropyl cellulose (molecular weight=300,000 g/mol, DS=1.8), 0.01 the Sodium Benzoate of part, 42 parts of chitins, 3 parts of calcium chloride, the compound of 35 parts of glycerine, 25% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 8mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 30 ℃.Lower than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 78%; When temperature during higher than 30 ℃, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 12
4 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 25 parts of hydroxy butyl methyl celluloses, 35 portions of acetic starches, 2 parts of sodium sulphate, 34 parts of glycerine and ethylene glycol (glycerine: the compound breast of ethylene glycol=1:1), 0.2% acid streptococci element, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 42 ℃.Lower than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 80%, higher than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 13
6 parts of 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 20 parts of methylcellulose (DS=1.8), 35 parts of CMSs, 4 parts of potash, the compound of 35 parts of ethylene glycol, 0.2% acid streptococci element, 35% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 48 ℃.Lower than 48 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 82%, higher than 48 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 14
2 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 18 parts of hydroxy butyl methyl celluloses, 40 parts of sodium carboxymethylcelluloses, 2 parts of potassium sulfates, the compound of 38 parts of butanols, 0.1% acid streptococci element 35% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 20 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 38 ℃.Lower than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 15
4 parts of 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenones, 21 parts of ethylhydroxyethylcelluloses, 45 parts of hydroxyethyl ether celluloses, 3 parts of sodium chloride, the compound of 27 parts of methyl alcohol, 0.2% acid streptococci element, 45% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15 mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 40 ℃.Lower than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 80%, higher than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 16
3 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 22 parts of ethylhydroxyethylcelluloses, 40 parts of semi-annular jade pendant acid ethyl celluloses, 3 parts of calcium chloride, the compound of 32 parts of ethanol, 0.2% Sodium Benzoate, 50% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10 mm.The response temperature of the temperature sensitive type type Intelligent Composite optical glass of preparation is 25 ℃.Lower than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 17
1 part 2, three grades of butyl of 6--4-methylphenol, 24 parts of methylcellulose and hydroxypropyl methylcellulose (methylcellulose: hydroxypropyl methylcellulose=1:2), 40 parts of melon glue, 5 parts of magnesium chlorides, the compound of 30 parts of ethylene glycol, 0.2% acid streptococci element, 48% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 26 ℃.Lower than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 18
3 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 26 parts of hydroxypropyl celluloses (molecular weight=100,000 g/mol, DS=1.5), 30 parts of locust bean gums, 4 parts of calcium chloride, the compound of 37 parts of ethylene glycol, 0.2% acid streptococci element, 45% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 8mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 30 ℃.Lower than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 19
1 part 2,2 '-dihydroxy-4,4 '-dimethoxy-benzophenone, 28 parts of hydroxypropyl celluloses (molecular weight=300,000 g/mol, DS=2), 35 parts of sodium carboxymethylcelluloses, 3 parts of calcium chloride, the compound of 33 parts of methyl alcohol, 0.2% acid streptococci element, 50% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 40 ℃.Lower than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 20
5 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, 16 parts of hydroxypropyl methylcelluloses, 40 parts of hydroxyethyl ether celluloses, 3 parts of potassium phosphates, the compound of 36 parts of propane diols, 0.2% acid streptococci element, 55% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 32 ℃.Lower than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 65%, higher than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 21
2 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 22 parts of hydroxypropyl methylcelluloses, 36 parts of Carboxymethylinulins, 2 parts of sodium phosphates, the compound of 38 parts of acetone, 0.2% acid streptococci element, 50% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 28 ℃.Lower than 28 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 28 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 22
6 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 25 parts of hydroxypropyl methylcelluloses, 48 parts of poly-epoxy succinic acids, 3 parts of sodium carbonate, the compound of 18 parts of triethylamines, 0.2% acid streptococci element, 40% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 8mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 35 ℃.Lower than 35 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 35 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 23
7 parts of decanedioic acid two (2,2,6,6-tetramethyl-4-piperidine ester), 23 parts of hydroxy butyl methyl celluloses, 40 parts of flax gum pectin, 2 parts of potash, the compound of 28 parts of isopropyl alcohols, 0.2% acid streptococci element, 45% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 20mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 38 ℃.Lower than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 80%, higher than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.1%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 24
4 part (1,2,2,6,6-pentamethyl piperidyl) phosphite ester, 26 parts of hydroxy butyl methyl celluloses, 38 parts of Arabic gums and algin (Arabic gum: algin=1:1), 2 parts of sodium nitrate, the compound of 30 parts of isopropyl alcohols, 1% Sodium Benzoate, 35% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 10mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 40 ℃.Lower than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 85%, higher than 40 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 25
3 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 25 parts of hydroxypropyl methylcelluloses, 40 parts of carboxymethyl celluloses, 2 parts of natrium nitrosums, the compound of 30 parts of glycerine, 2% Sodium Benzoate, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 30 ℃.Lower than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 30 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 26
2 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 24 parts of methylcellulose (molecular weight=250,000 g/mol, DS=1.2), 35 parts of sodium carboxymethylcelluloses, 7 parts of magnesium chlorides, the compound of 32 parts of ethylene glycol, 0.01% Sodium Benzoate, 20% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 25 ℃.Lower than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 27
8 part of four (β-(3, three grades of butyl of 5--4-hydroxy phenyl) propionic acid) pentaerythritol ester, 15 parts of hydroxy butyl methyl celluloses, 47 parts of hydroxyethyl ether celluloses, 2 parts of potassium chloride, 28 parts of glycerine and acetone (glycerine: the compound of acetone=1:1), 1% Sodium Benzoate, 47% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 39 ℃.Lower than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%, higher than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 28
2 parts of 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 20 parts of hydroxypropyl methylcelluloses, 38 parts of chitins, 10 parts of sodium nitrate, the compound of 30 parts of acetone, 0.3% Sodium Benzoate, 53% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 6mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 37 ℃.Lower than 37 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers greater than 73%, higher than 37 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 29
2 parts of decanedioic acid two (2,2,6,6-tetramethyl-4-piperidine ester), 25 parts of hydroxy butyl methyl celluloses, 33 parts of algins, 5 parts of natrium nitrosums, the compound of 35 parts of propane diols, 1% Sodium Benzoate, 34% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 4mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 42 ℃.Lower than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers greater than 76%, higher than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 30
2 parts of two (three grades of butyl of 3,5--4-hydroxy phenyl) thioethers, 23 parts of hydroxypropyl methylcelluloses, 40 parts of Carboxymethylinulins, 3 parts of sodium carbonate, the compound of 32 parts of methyl alcohol, 1% Sodium Benzoate, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 32 ℃.Lower than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.6%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers less than 5%.
Example 31
4 parts of 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenones, 16 parts of hydroxypropyl cellulose (molecular weight=350,000 g/mol, DS=2.2), 45 parts of hydroxyethyl ether celluloses, 5 parts of calcium chloride, the compound of 30 parts of propane diols, 2% lysozyme, 47% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 7mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 44 ℃.Lower than 44 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers greater than 78%, higher than 44 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 32
7 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 13 parts of hydroxypropyl methylcelluloses, 42 parts of xanthans, 7 parts of sodium nitrate, the compound of 51 parts of acetone, 2% lysozyme, 38% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 32 ℃.Lower than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.6%, wavelength at the light permeable rate of 380～2500 nanometers greater than 67%, higher than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 33
2 parts of 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 16 parts of hydroxypropyl methylcelluloses, 50 parts of algins, 2 parts of sodium carbonate, the compound of 30 parts of butanols, 2% lysozyme, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 13mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 23 ℃.Lower than 23 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.7%, wavelength at the light permeable rate of 380～2500 nanometers greater than 69%, higher than 23 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 34
3 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, 17 parts of ethylhydroxyethylcelluloses, 40 parts of poly-aspartates and chitin (poly-aspartate: chitin=1:1), 2 parts of sodium nitrate, the compound of 38 parts of propane diols, 2% lysozyme, 46% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 9mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 33 ℃.Lower than 33 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers greater than 63%, higher than 33 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 35
6 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 23 parts of hydroxypropyl methylcelluloses, 37 parts of semi-annular jade pendant acid ethyl celluloses, 2 parts of sodium phosphates, the compound of 32 parts of acetone, 2% lysozyme, 37% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 31 ℃.Lower than 31 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.7%, wavelength at the light permeable rate of 380～2500 nanometers greater than 72%, higher than 31 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 36
1 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 20 parts of ethylhydroxyethylcelluloses, 40 parts of hydroxyethyl ether celluloses, 4 parts of zinc sulfate, the compound of 35 parts of methyl alcohol, 2% lysozyme, 36% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 4mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 39 ℃.Lower than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.6%, wavelength at the light permeable rate of 380～2500 nanometers greater than 72%, higher than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 37
2 parts of (1,2,2,6,6-pentamethyl piperidyl) phosphite esters, 24 parts of hydroxypropyl methylcelluloses, 36 parts of CMSs, 7 parts of zinc nitrates, the compound of 31 parts of isopropyl alcohols, 2% lysozyme, 28% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 2mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 34 ℃.Lower than 34 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers greater than 73%, higher than 34 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 38
4 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 22 parts of hydroxy butyl methyl celluloses, 43 parts of xanthans, 2 parts of potassium sulfates, the compound of 29 parts of ethylene glycol, 2% lysozyme, 54% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 26 ℃.Lower than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.2%, wavelength at the light permeable rate of 380～2500 nanometers greater than 71%, higher than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 39
8 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 15 parts of hydroxypropyl methylcelluloses, 37 parts of locust bean gums, 6 parts of potassium nitrate, the compound of 34 parts of triethylamines, 2% sodium sorbate, 55% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 14mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 38 ℃.Lower than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers greater than 77%, higher than 38 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 40
5 parts of decanedioic acid two (2,2,6,6-tetramethyl-4-piperidine ester), 15 parts of ethylhydroxyethylcelluloses, 48 parts of sodium carboxymethylcelluloses and Carboxymethylinulin (sodium carboxymethylcellulose: Carboxymethylinulin=1:2), 2 parts of potassium chloride, the compound of 30 parts of butanols, 2% sodium sorbate, 32% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 6mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 43 ℃.Lower than 43 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 73%, higher than 43 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 41
3 part of four (β-(three grades of butyl of 3,5--4-hydroxy phenyl) propionic acid) pentaerythritol ester, 15 parts of hydroxypropyl methylcelluloses, 50 parts of semi-annular jade pendant acid ethyl celluloses, 1 part of calcium chloride, the compound of 31 parts of ethanol, 1% sodium sorbate, 44% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 25mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 31 ℃.Lower than 31 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.8%, wavelength at the light permeable rate of 380～2500 nanometers greater than 66%, higher than 31 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 5%.
Example 42
8 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 12 parts of ethylhydroxyethylcelluloses, 45 parts of melon glue, 5 parts of nickel chlorides, the compound of 30 parts of glycerine, 0.1% sodium sorbate, 46% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 22mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 36 ℃.Lower than 36 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.4%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 36 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 43
9 part 2, three grades of butyl of 6--4-methylphenol, 20 parts of hydroxypropyl methylcelluloses, 40 parts of poly-epoxy succinic acids, 11 parts of chromium chlorides, the compound of 20 parts of methyl alcohol, 2% sodium sorbate, 33% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 43 ℃.Lower than 43 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 83%, higher than 43 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 44
1 part of four (β-(three grades of butyl of 3,5--4-hydroxy phenyl) propionic acid) pentaerythritol ester, 15 parts of hydroxy butyl methyl celluloses, 45 parts of poly-aspartates, 6 parts of magnesium chlorides, the compound of 33 parts of acetone, 1% sodium sorbate, 52% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 14mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 39 ℃.Lower than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.6%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%, higher than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 45
4 parts (1,2,2,6,6-pentamethyl piperidyl) phosphite ester, 16 parts of ethylhydroxyethylcelluloses, 50 parts of hydroxyethyl ether celluloses, 2 parts of sodium sulphate, the compound of 28 parts of glycerine, 2% sodium sorbate, 55% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature control response type temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 25mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 42 ℃.Lower than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 85%, higher than 42 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 46
5 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, 15 parts of hydroxypropyl methylcelluloses, 45 parts of algins, 5 parts of natrium nitrosums, the compound of 30 parts of propane diols, 2% sodium sorbate, 5% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 35mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 45 ℃.Lower than 45 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 82%, higher than 45 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 5%.
Example 47
2 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 15 parts of hydroxy butyl methyl celluloses, 35 parts of Arabic gums, 8 parts of potash, the compound of 40 parts of glycerine, 2% sodium sorbate, 8% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 26mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 34 ℃.Lower than 34 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.7%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%, higher than 34 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 5%.
Example 48
3 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone, 15 parts of hydroxypropyl celluloses (molecular weight=300,000 g/mol, DS=2.2), 50 parts of carboxymethyl celluloses, 2 parts of sodium nitrate, the compound of 30 parts of isopropyl alcohols, 2% sodium sorbate, 30% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 6mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 32 ℃.Lower than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 73%, higher than 32 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 49
1 part of 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone, 20 parts of hydroxypropyl methylcelluloses, 40 parts of semi-annular jade pendant acid ethyl celluloses, 1 part of sodium chloride, the compound of 38 parts of glycerine, 2% sodium sorbate, 40% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 4mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 44 ℃.Lower than 44 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 44 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 50
2 parts (1,2,2,6,6-pentamethyl piperidyl) phosphite ester, 10 parts of ethylhydroxyethylcelluloses, 40 parts of ethylhydroxyethylcelluloses, 15 parts of sodium nitrate, the compound of 33 parts of methyl alcohol, 2% sodium sorbate, 5% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 8mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 46 ℃.Lower than 46 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 78%, higher than 46 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 51
6 parts of two (three grades of butyl of 3,5--4-hydroxy phenyl) thioethers, 15 parts of hydroxypropyl methylcelluloses, 40 parts of algins, 4 parts of sodium sulphate, the compound of 35 parts of glycerine, 0.1% sodium sorbate, 6% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 17mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 33 ℃.Lower than 33 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers greater than 77%, higher than 33 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 52
3 part 2,2 '-dihydroxy-4,4 '-dimethoxy-benzophenone, 22 parts of ethylhydroxyethylcelluloses, 40 parts of hydroxyethyl ether celluloses, 5 parts of potash, 2% sodium sorbate, the compound of 30 parts of methyl alcohol, 20% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 26 ℃.Lower than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 53
10 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 15 parts of hydroxypropyl methylcelluloses, 40 parts of poly-epoxy succinic acids, 5 parts of sodium chloride, 2% sodium sorbate, the compound of 30 parts of ethylene glycol, 23% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 24mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 27 ℃.Lower than 27 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 68%, higher than 27 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 5%.
Example 54
3 part of four (β-(3, three grades of butyl of 5--4-hydroxy phenyl) propionic acid) pentaerythritol ester, 18 parts of methylcellulose (molecular weight=350,000 g/mol, DS=1.5), 52 parts of hydroxyethyl ether celluloses, 2 parts of potash, the compound of 25 parts of triethylamines, 2% sodium sorbate, 18% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 35mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 25 ℃.Lower than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 25 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 3%.
Example 55
3 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 15 parts of hydroxypropyl methylcelluloses, 40 parts of hydroxyethyl ether celluloses, 12 parts of chromium chlorides, the compound of 30 parts of glycerine, 1% Sodium Benzoate, 15% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 25mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 24 ℃.Lower than 24 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.5%, wavelength at the light permeable rate of 380～2500 nanometers greater than 86%, higher than 24 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.
Example 56
6 parts of 2-hydroxyl-4-methoxyl group-5-diphenylsulfone ketones, 20 parts of hydroxypropyl celluloses (molecular weight=500,000 g/mol, DS=1.0), 40 parts of algins, 4 parts of calcium chloride, the compound of 30 parts of glycerine, 2% sodium sorbate, 20% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 15mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 27 ℃.Lower than 27 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.6%, wavelength at the light permeable rate of 380～2500 nanometers greater than 70%, higher than 27 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 57
5 part 2,2 '-dihydroxy-4,4 '-dimethoxy-5-diphenylsulfone ketone sodium salt, 10 parts of hydroxypropyl methylcelluloses, 40 parts of flax gum pectin, 10 parts of sodium nitrate, the compound of 35 parts of ethylene glycol, 2% sodium sorbate, 26% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 16mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 26 ℃.Lower than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 74%, higher than 26 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 2%.
Example 58
3 parts of 1-(2' ethoxy)-2,2,6,6-tetramethyl-4-piperidine alcohols, 22 parts of methylcellulose (DS=2.0), 35 parts of carboxymethyl celluloses, 10 parts of potassium sulfates, the compound of 30 parts of glycerine, 2% sodium sorbate, 15% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 5mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 20 ℃.Lower than 20 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 71%, higher than 20 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 1%.
Example 59
3 parts of 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 25 parts of hydroxypropyl methylcelluloses, 40 parts of carragheens, 2 parts of sodium acetates, the compound of 30 parts of methyl alcohol, 2% sodium sorbate, 47% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 3mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 39 ℃.Lower than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 75%, higher than 39 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 6%.
Example 60
6 parts (1,2,2,6,6-pentamethyl piperidyl) phosphite ester, 30 parts of hydroxypropyl methylcelluloses, 40 parts of semi-annular jade pendant acid ethyl celluloses, 4 parts of sodium nitrate, the compound of 20 parts of triethylamines, 2% sodium sorbate and 1 Sodium Benzoate, 27% the gum polymers colloidal activity material that is made into soluble in water.The polymeric colloid active material for preparing is placed in is prepared into temperature sensitive type Intelligent Composite glass between simple glass, polymeric colloid active material thickness is 7mm.The response temperature of the temperature sensitive type Intelligent Composite optical glass of preparation is 24 ℃.Lower than 24 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers greater than 74%, higher than 24 ℃ the time, its at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 0.3%, wavelength at the light permeable rate of 380～2500 nanometers less than 4%.

Claims (10)

1. temperature sensitive type Intelligent Composite optical glass based on renewable resource, can be according to temperature change, produce the mutual conversion between transparent and opaque under critical-temperature, it is characterized in that, described temperature sensitive type Intelligent Composite optical glass is placed between two or multi-disc glass by the biological base material polymeric colloid active material of temperature-responsive and consists of, and the biological base material polymeric colloid active material of described temperature-responsive produces reversible nanoscale in critical-temperature and is separated;
Described biological base material polymeric colloid active material extracts macromolecule C, inorganic salts D, organic micromolecule compound E by resin additive A, temperature response type bio-based macromolecule B, water-soluble biological and anticorrisive agent F is soluble in water consists of; During lower than critical-temperature, component A, B, C, D, E, F are dissolved in and consist of the homogeneous system in the aqueous solution, present pellucidity in temperature, when temperature during higher than critical-temperature, temperature response type macromolecule B out nanoscale occurred and is separated by free in the homogeneous system, presents opaque state.
2. temperature sensitive type Intelligent Composite optical glass according to claim 1, it is characterized in that, in described biological base material polymeric colloid active material, described temperature response type bio-based macromolecule B is one or more of methylcellulose, hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethylhydroxyethylcellulose or hydroxy butyl methyl cellulose.
3. temperature sensitive type Intelligent Composite optical glass according to claim 2, is characterized in that, in described biological base material polymeric colloid active material, described temperature response type bio-based macromolecule B molecular weight is at 1000-50,000,000 g/mol, substitution value DS is between 0-3.
4. temperature sensitive type Intelligent Composite optical glass according to claim 1, it is characterized in that, in described biological base material polymeric colloid active material, described water-soluble biological extraction macromolecule C is one or more in CMS, acetic starch, CMC, carboxymethyl cellulose, hydroxyethyl ether cellulose, sodium carboxymethylcellulose, semi-annular jade pendant acid ethyl cellulose, chitin, poly-aspartate, poly-epoxy succinic acid, Carboxymethylinulin, xanthans, melon glue, locust bean gum, flax gum pectin, Arabic gum, algin or carragheen.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, described temperature sensitive type Intelligent Composite optical glass is when pellucidity, at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, wavelength at the light permeable rate of 380～2500 nanometers greater than 60%, when temperature sensitive Intelligent Composite optical glass changes opaque state into, at the light permeable rate of ultraviolet 200～380 nano wave lengths less than 1%, wavelength at the light permeable rate of 380～2500 nanometers less than 10%.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, described critical-temperature is between 0～60 ℃.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, in described biological base material polymeric colloid active material, in mass fraction, its composition comprises:
(A) resin additive is 0.01～10 part
(B) temperature response type bio-based macromolecule is 1～30 part
(C) water-soluble biological extracts 1～60 part of macromolecule
(D) inorganic salts are 1～20 part
(E) organic micromolecule compound is 2～50 parts
(F) anticorrisive agent 0.01-2 part
Said components is soluble in water, and the formation total mass concentration is 3%～60% solution.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, in biological base material polymeric colloid active material, described resin additive A comprises light stabilizer or antioxidant, sulfate, hydrochloride, nitrate, carbonate, phosphate or acetate that described inorganic salts D is potassium, sodium, calcium, magnesium, zinc, iron, copper, nickel, chromium.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, in biological base material polymeric colloid active material, described organic micromolecule compound E is one or more of ethylene glycol, ethanol, methyl alcohol, acetone, propane diols, glycerine, butanols, triethylamine, isopropyl alcohol.
According to claim 1 to 4 described arbitrary temperature sensitive type Intelligent Composite optical glass, it is characterized in that, in biological base material polymeric colloid active material, described anticorrisive agent F is benzoic acid or derivatives thereof, sorbic acid or derivatives thereof, nisin, natamycin, epsilon-polylysine or calcium propionate.
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