CN105349018A - Intelligent temperature control reflective coating - Google Patents
Intelligent temperature control reflective coating Download PDFInfo
- Publication number
- CN105349018A CN105349018A CN201510939376.3A CN201510939376A CN105349018A CN 105349018 A CN105349018 A CN 105349018A CN 201510939376 A CN201510939376 A CN 201510939376A CN 105349018 A CN105349018 A CN 105349018A
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- temperature control
- reflective coating
- intelligent temperature
- control reflective
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an intelligent temperature control reflective coating prepared from the following raw materials: polyurethane resin, organic silicon resin, a melamine-formaldehyde resin prepolymer, ammonium polyphosphate, a dispersion liquid, a surfactant, inorganic natural pigment, an intelligent assistant and a discoloring assistant. By using the intelligent temperature control reflective coating, the shading performance of glass can be automatically regulated on the premise that the light transmitting requirement is met, so that the glass has the functions of releasing heat and preserving heat indoor in winter and absorbing heat and shading indoor in summer.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of intelligent temperature control reflective coating.
Background technology
Temperature control coating that is that existing market is applied and that researching and developing is that independent reflected sunlight is pigment coated to the white coating or temperature induced color changing specialty inorganic that reach cooling substantially.A solar heat reflection paint reflected sunlight makes the absorption of object minimizing to sunlight, effectively can not absorb sunlight, reach intelligent temperature control effect when outside temperature is very low in the winter time.
Summary of the invention
The object of this invention is to provide a kind of intelligent temperature control reflective coating, under the prerequisite that the present invention can require at guarantee printing opacity, automatically regulate the shading performance of glass, glass is had, and indoor heat release in winter, insulation and Summer Indoor absorb heat, the function of sunshade.
A kind of intelligent temperature control reflective coating, its starting material comprise: urethane resin, silicone resin, terpolycyantoamino-formaldehyde resin performed polymer, ammonium polyphosphate, dispersion liquid, tensio-active agent, inorganic natural pigment, intelligent auxiliary agent and variable color auxiliary agent.
The formula of described intelligent temperature control reflective coating is as follows: urethane resin 20-30 part, silicone resin 5-20 part, terpolycyantoamino-formaldehyde resin performed polymer 2-10 part, ammonium polyphosphate 7-15 part, dispersion liquid 20-30 part, tensio-active agent 2-5 part, inorganic natural pigment 1-2 part, intelligent auxiliary agent 3-8 part and variable color auxiliary agent 2-5 part.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts polyester silicone resin or epoxy silicone resin.
Further, described polyester silicone resin adopts polyester modified organic silicon resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:60-90.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.2-0.5.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 0.5-1.5.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Intelligent temperature control reflective coating also comprises solidifying agent and stiffening agent, described solidifying agent 2-4 part, stiffening agent 3-5 part.
Described solidifying agent comprises one or more in aliphatic polyamine, alicyclic polyamine, aromatic polyamine, phenolic aldehyde, acid anhydrides.
Described stiffening agent comprises the one in ammonium chloride or primary ammonium phosphate, ammonium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate acid salt.
Compared with prior art, the present invention has following beneficial effect: under the prerequisite that the present invention can require at guarantee printing opacity, automatically regulate the shading performance of glass, glass is had, and indoor heat release in winter, insulation and Summer Indoor absorb heat, the function of sunshade.。
Embodiment
Below in conjunction with embodiment, the present invention is described further:
Embodiment 1
A kind of intelligent temperature control reflective coating, fills a prescription as follows: urethane resin 20 parts, silicone resin 5 parts, terpolycyantoamino-formaldehyde resin performed polymer 2 parts, ammonium polyphosphate 7 parts, dispersion liquid 20 parts, 2 parts, tensio-active agent, inorganic natural pigment 1 part, intelligent auxiliary agent 3 parts and variable color auxiliary agent 2 parts.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts epoxy silicone resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:60.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.2.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 0.5.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Visible light transmissivity ultraviolet permeability and infrared average transmittances are as following table:
Embodiment 2
A kind of intelligent temperature control reflective coating, fills a prescription as follows: urethane resin 30 parts, silicone resin 20 parts, terpolycyantoamino-formaldehyde resin performed polymer 10 parts, ammonium polyphosphate 15 parts, dispersion liquid 30 parts, 5 parts, tensio-active agent, inorganic natural pigment 2 parts, intelligent auxiliary agent 8 parts and variable color auxiliary agent 5 parts.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts polyester modified organic silicon resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:90.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.5.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 1.5.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Visible light transmissivity ultraviolet permeability and infrared average transmittances are as following table:
Embodiment 3
A kind of intelligent temperature control reflective coating, fill a prescription as follows: urethane resin 25 parts, silicone resin 12 parts, terpolycyantoamino-formaldehyde resin performed polymer 6 parts, ammonium polyphosphate 11 parts, dispersion liquid 24 parts, 3 parts, tensio-active agent, inorganic natural pigment 2 parts, intelligent auxiliary agent 5 parts and variable color auxiliary agent 3 parts, 2 parts, solidifying agent, stiffening agent 3 parts.
Described solidifying agent comprises aliphatic polyamine.
Described stiffening agent comprises ammonium chloride.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts polyester silicone resin or epoxy silicone resin.
Further, described polyester silicone resin adopts polyester modified organic silicon resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:70.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.3.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 1.0.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Visible light transmissivity ultraviolet permeability and infrared average transmittances are as following table:
Embodiment 4
A kind of intelligent temperature control reflective coating, fill a prescription as follows: urethane resin 20 parts, silicone resin 5 parts, terpolycyantoamino-formaldehyde resin performed polymer 2 parts, ammonium polyphosphate 7 parts, dispersion liquid 20 parts, 2 parts, tensio-active agent, inorganic natural pigment 1 part, intelligent auxiliary agent 3 parts and variable color auxiliary agent 2 parts, 4 parts, solidifying agent, stiffening agent 5 parts.
Described solidifying agent comprises alicyclic polyamine.
Described stiffening agent comprises ammonium hydrogen phosphate.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts epoxy silicone resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:60.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.2.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 0.5.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Visible light transmissivity ultraviolet permeability and infrared average transmittances are as following table:
Embodiment 5
A kind of intelligent temperature control reflective coating, fill a prescription as follows: urethane resin 30 parts, silicone resin 20 parts, terpolycyantoamino-formaldehyde resin performed polymer 10 parts, ammonium polyphosphate 15 parts, dispersion liquid 30 parts, 5 parts, tensio-active agent, inorganic natural pigment 2 parts, intelligent auxiliary agent 8 parts and variable color auxiliary agent 5 parts, 3 parts, solidifying agent, stiffening agent 4 parts.
Described solidifying agent comprises phenolic aldehyde.
Described stiffening agent comprises SODIUM PHOSPHATE, MONOBASIC.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts polyester modified organic silicon resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:90.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.5.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 1.5.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Embodiment 6
A kind of intelligent temperature control reflective coating, fills a prescription as follows: urethane resin 25 parts, silicone resin 12 parts, terpolycyantoamino-formaldehyde resin performed polymer 6 parts, ammonium polyphosphate 11 parts, dispersion liquid 24 parts, 3 parts, tensio-active agent, inorganic natural pigment 2 parts, intelligent auxiliary agent 5 parts and variable color auxiliary agent 3 parts.
Described urethane resin adopts hydroxyl acrylic urethane resin.
Described silicone resin adopts polyester silicone resin or epoxy silicone resin.
Further, described polyester silicone resin adopts polyester modified organic silicon resin.
In described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:70.
Described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.3.
Described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 1.0.
Described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, and containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
Described variable color auxiliary agent adopts heat discoloration microencapsulation material.
Visible light transmissivity ultraviolet permeability and infrared average transmittances are as following table:
The Specifeca tion speeification of embodiment 1-6
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.。
Claims (12)
1. an intelligent temperature control reflective coating, it is characterized in that: its starting material comprise: urethane resin, silicone resin, terpolycyantoamino-formaldehyde resin performed polymer, ammonium polyphosphate, dispersion liquid, tensio-active agent, inorganic natural pigment, intelligent auxiliary agent and variable color auxiliary agent; Its formula is as follows: urethane resin 20-30 part, silicone resin 5-20 part, terpolycyantoamino-formaldehyde resin performed polymer 2-10 part, ammonium polyphosphate 7-15 part, dispersion liquid 20-30 part, tensio-active agent 2-5 part, inorganic natural pigment 1-2 part, intelligent auxiliary agent 3-8 part and variable color auxiliary agent 2-5 part.
2. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, described urethane resin adopts hydroxyl acrylic urethane resin.
3. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, described silicone resin adopts polyester silicone resin or epoxy silicone resin.
4. a kind of intelligent temperature control reflective coating according to claims 3, is characterized in that, described polyester silicone resin adopts polyester modified organic silicon resin.
5. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, in described terpolycyantoamino-formaldehyde resin performed polymer, the mass ratio of trimeric cyanamide and formaldehyde is 126:60-90.
6. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, described dispersion liquid adopts aqueous ethanolic solution, and the mass ratio of ethanol and water is 1:0.2-0.5.
7. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, described tensio-active agent adopts the mixture of polyvinylpyrrolidone and ether of cellulose, and the proportioning of described polyvinylpyrrolidone and ether of cellulose is 0.5-1.5.
8. a kind of intelligent temperature control reflective coating according to claims 1, it is characterized in that, described intelligent auxiliary agent adopts modified nano-silica vanadium suspension liquid, containing tungsten in described modified nano-silica vanadium, in described intelligent auxiliary agent, the content of vanadium dioxide is 5%, and the content of described tungsten is 0.1%.
9. a kind of intelligent temperature control reflective coating according to claims 1, is characterized in that, described variable color auxiliary agent adopts heat discoloration microencapsulation material.
10. a kind of intelligent temperature control reflective coating according to claims 2, is characterized in that, its formula also comprises solidifying agent and stiffening agent, described solidifying agent 2-4 part, stiffening agent 3-5 part.
11. a kind of intelligent temperature control reflective coatings according to claims 10, it is characterized in that, described solidifying agent comprises one or more in aliphatic polyamine, alicyclic polyamine, aromatic polyamine, phenolic aldehyde, acid anhydrides.
12. a kind of intelligent temperature control reflective coatings according to claims 10, is characterized in that, described stiffening agent comprises the one in ammonium chloride or primary ammonium phosphate, ammonium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate acid salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510939376.3A CN105349018B (en) | 2015-12-16 | 2015-12-16 | A kind of intelligent temperature control reflective coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510939376.3A CN105349018B (en) | 2015-12-16 | 2015-12-16 | A kind of intelligent temperature control reflective coating |
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| CN105349018A true CN105349018A (en) | 2016-02-24 |
| CN105349018B CN105349018B (en) | 2017-07-14 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105711386A (en) * | 2016-03-10 | 2016-06-29 | 安徽省地坤汽车天窗科技有限公司 | Sun shield for vehicle |
| CN105799470A (en) * | 2016-03-10 | 2016-07-27 | 安徽省地坤汽车天窗科技有限公司 | Vehicle skylight sun shield matched with guide rail |
| CN106634065A (en) * | 2016-09-28 | 2017-05-10 | 浙江大学自贡创新中心 | Intelligent inorganic thermal insulation coating containing two components |
| CN107652881A (en) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | A kind of transparent color glass coating for plated film |
| CN110511671A (en) * | 2019-08-07 | 2019-11-29 | 安徽海德化工科技有限公司 | One kind being used for petroleum-oil column cracking resistance heat-resisting paint |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102021101065A1 (en) * | 2021-01-19 | 2022-07-21 | Chemische Fabrik Budenheim Kg | Set of chemicals for the production of a polymer |
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2015
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105711386A (en) * | 2016-03-10 | 2016-06-29 | 安徽省地坤汽车天窗科技有限公司 | Sun shield for vehicle |
| CN105799470A (en) * | 2016-03-10 | 2016-07-27 | 安徽省地坤汽车天窗科技有限公司 | Vehicle skylight sun shield matched with guide rail |
| CN107652881A (en) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | A kind of transparent color glass coating for plated film |
| CN106634065A (en) * | 2016-09-28 | 2017-05-10 | 浙江大学自贡创新中心 | Intelligent inorganic thermal insulation coating containing two components |
| CN110511671A (en) * | 2019-08-07 | 2019-11-29 | 安徽海德化工科技有限公司 | One kind being used for petroleum-oil column cracking resistance heat-resisting paint |
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| Publication number | Publication date |
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| CN105349018B (en) | 2017-07-14 |
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