CN103058758A - Slow release compound fertilizer applicable to plantation of vegetable - Google Patents

Slow release compound fertilizer applicable to plantation of vegetable Download PDF

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Publication number
CN103058758A
CN103058758A CN2012105750486A CN201210575048A CN103058758A CN 103058758 A CN103058758 A CN 103058758A CN 2012105750486 A CN2012105750486 A CN 2012105750486A CN 201210575048 A CN201210575048 A CN 201210575048A CN 103058758 A CN103058758 A CN 103058758A
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preparation
powder
fertilizer
vegetable
compound manure
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Inventor
解永军
吕庆淮
邵明升
吕瑞新
卢晓东
孙召梅
庄慧荣
刘继敏
张建民
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Shikefeng Chemical Industry Co Ltd
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Shikefeng Chemical Industry Co Ltd
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Abstract

The invention provides a slow release compound fertilizer applicable to plantation of vegetable. The slow release compound fertilizer is a mixture of a plurality of fertilizers containing substances which exert influence on nitrification of urea in soil and components with no special fertilizer efficiency and is prepared from the following raw materials by mass: 30 to 50 parts of urea, 8 to 22 parts of ammonium sulfate, 22 to 45 parts of potassium sulfate, 7 to 12 parts of a granulating agent and a proper amount of water. A preparation method for the slow release compound fertilizer comprises the following steps: (1) preparation of a compound of a potash fertilizer and a nitrogen fertilizer; (2) preparation of mixed particles of the components of the compound fertilizer; (3) coating with stearic acid; (4) powder spreading of a modified zeolite powder material; and (5) screening, metering and quality inspection. The slow release compound fertilizer applicable to plantation of vegetable provided by the invention can improve both output and quality of vegetable, increase raphaninin in vegetable and reduce enrichment of heavy metals in vegetable and the content of nitrate in vegetable.

Description

Be suitable for the slow-release compound fertilizer that growing vegetables is used
Technical field
The present invention is a kind of slow-release compound fertilizer that growing vegetables is used that is suitable for.The multiple fertilizer that belongs to the material that contains influential urea nitrification in soil and mixture without special fertilizer efficiency component.
Background technology
Vegetables contain abundant VITAMIN, and food ingestion is large in daily life, lay equal stress on grain in the human diet structure, and its output and cultivated area have obvious ascendant trend.In the people's livelihood and national economy, occupy critical role.The vegetables economic benefit depends on output and the production cost of vegetables.The target of the high-quality especially people unremitting pursue of vegetables.Effectively utilize the Limited Land resource, the yield and quality that improves vegetable crop is the direction that people make great efforts.
Vegetables are to need the more crop of nitrogenous fertilizer, and the nitrogen element that its necessary for growth absorbs is in the majority, and nitrogenous fertilizer is to improving the vegetable crop successful.This is that still, the enrichment of the nitrate in the vegetables constitutes a threat to HUMAN HEALTH because vegetables are happiness nitre crop simultaneously.Studies show that, excess ingestion nitrate, nitrite are one of inducible factors of the diseases such as human cancer.Nitrate in the vegetables is the important sources of human picked-up nitrate.So, can satisfy vegetables to the demand of nitrogen element, can reduce again nitrate in the vegetables and the content of nitrite, also be the target that fertilizer industry is pursued.
In addition, research finds that sulforaphen has extremely strong promotion carcinogens degraded, the effect that anticancer generates.And find that sulforaphen is one of active skull cap components that antitumour activity is the strongest in vegetables.At present, utilize chemical synthesis process to prepare sulforaphen and realize that industrialization generates, also be difficult to realize.Therefore, the method for the sulforaphen in the raising vegetables is that people expect.
The high-quality nitrogenous fertilizer that urea is nitrogenous height, fertilizer efficiency is fast, consumption is large.But urea in use easily runs off by approach such as volatilization, leaching, decomposition and runoffs, causes the fertilizer efficiency utilization ratio not high, and this has not only caused the waste of chemical fertilizer, and the environment of depending on for existence for mankind such as atmosphere, water body soil.
In order to solve the problems of the technologies described above, at present, sulphur and the various macromolecule resins of adopting carry out the coating processing to urea more both at home and abroad.Perhaps add uric acid inhibitor and nitrification inhibitor; Utilize the material coated even multilayer coating of the high molecular polymers such as cyclochloride resin, acrylic resin or severally comprise that fertiliser granulates mixing etc. forms sustained-release and controlled release fertilizer; Coated fertilizer is difficult in degraded in soil edatope be worked the mischief.And complex process, manufacturing cost is high, contaminate environment.
Chinese patent application number 201110021688.8 " biodegradable coated ureas " of Shikefeng Chemical Industry Co., Ltd.'s application have successfully solved the above problem that urea nitrogenous fertilizer exists, the stearic acid that utilization can be degraded under the soil microorganisms effect is as the coated fertilizer of nitrogenous fertilizer urea, provide a kind of coated fertilizer biodegradable, pollution-free, can improve again the biodegradable coated urea product of the utilization ratio of fertilizer.But it is a kind of high-quality nitrogenous fertilizer, and nutritive ingredient is single, can not be as the slow release fertilizer that is suitable for growing vegetables and uses.
In sum, there is following deficiency in vegetable fertilizer of the prior art:
1.. the multilayer coating, complex manufacturing, investment is large, production cost is high.
2. coated fertilizer hard degradation, life-time service can bring negative impact to soil; Even soil polluted, affect the quality of agricultural-food.
3. improve sulforaphen, the enrichment of reduction heavy metal in vegetables, the fertilizer of the nitrate content in the reduction vegetables in the vegetables, there is not yet report.
5. can improve the slow-release compound fertilizer that growing vegetables is used that is suitable for that vegetable crop can improve again quality of vegetable, also rare.
Summary of the invention
The object of the invention is to avoid above-mentioned weak point of the prior art, can improve the slow-release compound fertilizer that growing vegetables is used that is suitable for that vegetable crop can improve quality of vegetable and provide a kind of.Have the sulforaphen, the enrichment of reduction heavy metal in vegetables, the effect of the nitrate content in the reduction vegetables that improve in the vegetables concurrently,
Purpose of the present invention can reach by following measure:
Of the present inventionly be suitable for the compound manure that growing vegetables is used, it is characterized in that being made by following raw material according to the mass fraction meter:
Figure BDA00002658350200021
Described granulation aid is mixed by the bauxitic clay powder of 60%~80% wilkinite and 40%~20% and is formed;
Its preparation method comprises the steps:
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first behind urea 30~50 weight part heating and meltings, add ammonium sulfate 8~22 weight parts and vitriolate of tartar 22~45 weight parts and mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, for subsequent use;
2.. the preparation of each component composite grain of compound manure
Potash fertilizer, nitrogenous fertilizer mixture and granulation aid 7~12 weight parts that 1. step prepares are evenly mixed, add suitable quantity of water, utilize traditional tablets press with each component mixing granulation of described compound manure, for subsequent use;
3.. stearic acid is filmed
Stearic consumption is 0.5%~3.0% of each component composite grain quality of compound manure of 2. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the prescription accurate-metering, in the input stearic acid fusion tank, is heated to molten state with stearic acid, and is for subsequent use;
B.. coating
2. each the component composite grain of compound manure for preparing according to prescription accurate-metering step, melting stearic acid with step a preparation carries out spraying outside the particle in drum-type mixing granulation machine, makes the composite grain outside surface form as far as possible uniformly coating, warm air drying, the cooling of room temperature wind, for subsequent use; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
4.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 0.5%~1.5%, the proportioning raw materials of zeolite powder 99.5%~98.5% accurately takes by weighing respectively each component of raw material, mix, and grinding flour, the control powder fineness is crossed 120 mesh sieves, and is for subsequent use;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at each component composite grain face powder 10~15kg of compound manure that 3. every 1000kg step prepares;
5.. screening, metering, quality test, qualified rear packing makes and is suitable for the compound manure that growing vegetables is used; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour;
Quality product reaches following technical indicator:
N constituent content % 〉=16
K 2O content % 〉=10
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
Prescription of the present invention be according to vegetables to the Demand Design of nutrient, high nitrogen high-sulfur is the characteristics of prescription of the present invention, the nitrogen element content height has satisfied the demand of vegetables high yield to nitrogen; Made contribution for improving vegetable crop.
Element sulphur in the composition of raw materials of the present invention adds with the form of soluble sulphate, and large percentage, and the fourth-largest nutritive element that plant growth is necessary directly provides the sulphur nutrient for vegetables grow up.Sulphur is the important composition that consists of protein, and S can produce positively effect at plant growth, prevention and elimination of disease and pests and improvement soil aspect many.The more important thing is that element sulphur in the fertilizer component has the content of the nitrate that reduces in the vegetables and nitrite, improves the sulforaphen in the vegetables and reduce vegetables to the effect of the enriching quantity of heavy metal.
The individual layer coating, generating process is simple, low equipment investment, production cost is low.Coated fertilizer can be degraded under the soil microorganisms effect, has avoided the pollution of coated fertilizer to edatope.
Purpose of the present invention can also reach by following measure:
Of the present inventionly be suitable for the compound manure that growing vegetables is used, it is characterized in that being made by following raw material according to the mass fraction meter:
Figure BDA00002658350200041
It is preferred technical scheme.
Of the present inventionly be suitable for the compound manure that growing vegetables is used, it is characterized in that being made by following raw material according to the mass fraction meter:
Figure BDA00002658350200042
It is a preferred technical scheme.
The application process that is suitable for the compound manure that growing vegetables uses of the present invention, it is characterized in that disposable employed, 40-50Kg/ mu.
Of the present inventionly be suitable for the slow-release compound fertilizer that the cigarette growing vegetables is used, compared to existing technology by following positively effect:
1. provide a kind of and can improve the slow-release compound fertilizer that growing vegetables is used that is suitable for that vegetable crop can improve again quality of vegetable.Have the sulforaphen, the enrichment of reduction heavy metal in vegetables, the effect of the nitrate content in the reduction vegetables that improve in the vegetables concurrently,
2. individual layer coating, generating process is simple, low equipment investment, production cost is low, had good sustained release effect.
3. coated fertilizer can be degraded under the soil microorganisms effect, has avoided the pollution of coated fertilizer to edatope.
4. the main nutrient elements N in the fertilizer, S reasonable ratio, the element sulphur in the prescription adds with the form of soluble sulphate, and large percentage, for vegetables directly provide the sulphur nutrient.Improve output and the quality of vegetables.
5.. because of chloride ion-containing not, be used for the fertilizer special for vegetable material, have the effect of increasing production and improying productivity.
6. use evidence through the land for growing field crops, on average improve vegetable crop 7.3%~21.4%.The per kilogram Nitrate Content in Lettuce is dropped to after using≤1650mg by the front 5600mg~8000mg of test.
Embodiment
The present invention will now be further detailed embodiment:
Embodiment 1
Prepare the compound manure that growing vegetables is used that is suitable for of the present invention according to the following step
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first behind the urea 35 weight part heating and meltings, add ammonium sulfate 15 weight parts and vitriolate of tartar 40 weight parts and mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, for subsequent use;
2.. the preparation of each component composite grain of compound manure
Potash fertilizer, nitrogenous fertilizer mixture and granulation aid 10 weight parts that 1. step prepares are evenly mixed, add suitable quantity of water, utilize traditional tablets press with each component mixing granulation of described compound manure, for subsequent use;
3.. stearic acid is filmed
Stearic consumption is 0.5%~3.0% of each component composite grain quality of compound manure of 2. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the prescription accurate-metering, in the input stearic acid fusion tank, is heated to molten state with stearic acid, and is for subsequent use;
B.. coating
2. each the component composite grain of compound manure for preparing according to prescription accurate-metering step, melting stearic acid with step a preparation carries out spraying outside the particle in drum-type mixing granulation machine, makes the composite grain outside surface form as far as possible uniformly coating, warm air drying, the cooling of room temperature wind, for subsequent use; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
4.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 0.5%~1.5%, the proportioning raw materials of zeolite powder 99.5%~98.5% accurately takes by weighing respectively each component of raw material, mix, and grinding flour, the control powder fineness is crossed 120 mesh sieves, and is for subsequent use;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at each component composite grain face powder 10~15kg of compound manure that 3. every 1000kg step prepares;
5.. screening, metering, quality test, qualified rear packing makes and is suitable for the compound manure that growing vegetables is used; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour;
Quality product reaches following technical indicator:
N constituent content % 〉=16
K 2O content % 〉=10
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
Use evidence through the land for growing field crops, on average improve vegetable crop 7.3%~21.4%.The per kilogram Nitrate Content in Lettuce is dropped to after using≤1650mg by the front 5800mg of test.
Embodiment 2~embodiment 7
According to method and the step of embodiment 1, according to the prescription of table 1, prepare the compound manure that growing vegetables is used that is suitable for of the present invention
Table 1
Raw material Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Urea ?30 ?42 ?36 ?50 ?46 ?50
Ammonium sulfate ?16 ?22 ?15 ?12 ?20 ?8
Vitriolate of tartar ?45 ?28 ?42 ?30 ?22 ?32
Granulation aid ?9 ?8 ?7 ?8 ?12 ?10
Water In right amount In right amount In right amount In right amount In right amount In right amount
Make and be suitable for the slow-release compound fertilizer that growing vegetables is used; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour;
Quality product reaches following technical indicator:
N constituent content % 〉=16
K 2O content % 〉=10
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
Use evidence through the land for growing field crops, on average improve vegetable crop 7.3%~21.4%.The per kilogram Nitrate Content in Lettuce is dropped to after using≤1650mg by the front 5600mg~8000mg of test.

Claims (4)

1. one kind is suitable for the compound manure that growing vegetables is used, and it is characterized in that being made by following raw material according to the mass fraction meter:
Figure FDA00002658350100011
Described granulation aid is mixed by the bauxitic clay powder of 60%~80% wilkinite and 40%~20% and is formed;
Its preparation method comprises the steps:
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first behind urea 30~50 weight part heating and meltings, add ammonium sulfate 8~22 weight parts and vitriolate of tartar 22~45 weight parts and mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, for subsequent use;
2.. the preparation of each component composite grain of compound manure
Potash fertilizer, nitrogenous fertilizer mixture and granulation aid 7~12 weight parts that 1. step prepares are evenly mixed, add suitable quantity of water, utilize traditional tablets press with each component mixing granulation of described compound manure, for subsequent use;
3.. stearic acid is filmed
Stearic consumption is 0.5%~3.0% of each component composite grain quality of compound manure of 2. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the prescription accurate-metering, in the input stearic acid fusion tank, is heated to molten state with stearic acid, and is for subsequent use;
B.. coating
2. each the component composite grain of compound manure for preparing according to prescription accurate-metering step, melting stearic acid with step a preparation carries out spraying outside the particle in drum-type mixing granulation machine, makes the composite grain outside surface form as far as possible uniformly coating, warm air drying, the cooling of room temperature wind, for subsequent use; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
4.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 0.5%~1.5%, the proportioning raw materials of zeolite powder 99.5%~98.5% accurately takes by weighing respectively each component of raw material, mix, and grinding flour, the control powder fineness is crossed 120 mesh sieves, and is for subsequent use;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at each component composite grain face powder 10~15kg of compound manure that 3. every 1000kg step prepares;
5.. screening, metering, quality test, qualified rear packing makes and is suitable for the compound manure that growing vegetables is used; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour;
Quality product reaches following technical indicator:
N constituent content % 〉=16
K 2O content % 〉=10
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
According to claim 1 be suitable for the compound manure that growing vegetables is used, it is characterized in that being made by following raw material according to the mass fraction meter:
Figure FDA00002658350100021
According to claim 1 be suitable for the compound manure that growing vegetables is used, it is characterized in that being made by following raw material according to the mass fraction meter:
Figure FDA00002658350100022
4. the application process that is suitable for the compound manure that growing vegetables uses of a claim 1, it is characterized in that disposable employed, 40~50Kg/ mu.
CN2012105750486A 2012-12-26 2012-12-26 Slow release compound fertilizer applicable to plantation of vegetable Pending CN103058758A (en)

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1612200A2 (en) * 2004-06-28 2006-01-04 Inabonos, S.A. Fertilising composition and process for the obtainment thereof
CN101657395A (en) * 2007-01-08 2010-02-24 迪帕克·普兰吉万达斯·沙阿 Novel agricultural composition
CN102093144A (en) * 2011-01-19 2011-06-15 施可丰化工股份有限公司 Biodegradable coated urea
CN102432374A (en) * 2011-09-02 2012-05-02 史丹利化肥股份有限公司 Melt biomass composite potassium sulfate type slow-release fertilizer and preparation method thereof
CN102826890A (en) * 2012-09-21 2012-12-19 史丹利化肥股份有限公司 Efficient polymorphous fertilizer special for vegetables and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1612200A2 (en) * 2004-06-28 2006-01-04 Inabonos, S.A. Fertilising composition and process for the obtainment thereof
CN101657395A (en) * 2007-01-08 2010-02-24 迪帕克·普兰吉万达斯·沙阿 Novel agricultural composition
CN102093144A (en) * 2011-01-19 2011-06-15 施可丰化工股份有限公司 Biodegradable coated urea
CN102432374A (en) * 2011-09-02 2012-05-02 史丹利化肥股份有限公司 Melt biomass composite potassium sulfate type slow-release fertilizer and preparation method thereof
CN102826890A (en) * 2012-09-21 2012-12-19 史丹利化肥股份有限公司 Efficient polymorphous fertilizer special for vegetables and preparation method thereof

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Application publication date: 20130424