CN103058626A - Ecological healthy functional work of art and production method of same - Google Patents
Ecological healthy functional work of art and production method of same Download PDFInfo
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- CN103058626A CN103058626A CN201310014510XA CN201310014510A CN103058626A CN 103058626 A CN103058626 A CN 103058626A CN 201310014510X A CN201310014510X A CN 201310014510XA CN 201310014510 A CN201310014510 A CN 201310014510A CN 103058626 A CN103058626 A CN 103058626A
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- 239000000843 powder Substances 0.000 claims abstract description 52
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- -1 oxygen ions Chemical class 0.000 claims abstract description 21
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 10
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- 238000004381 surface treatment Methods 0.000 claims abstract description 6
- 238000000748 compression moulding Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 27
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 9
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- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 6
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- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
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Images
Abstract
The invention provides a powder with continuous air optimization function, wherein the powder is prepared by mixing and stirring inorganic matrix, alga and mineral modifying agent according to the weight ratio of 72.5-90:5-20:5-8.5. The invention further provides a work of art with continuous air optimization function, according to part by weight, the work of art is prepared with the powder with continuous air optimization function by the steps of mixing and stirring in a compounded solution, pouring, vacuumizing or compression molding, maintaining and drying, and surface treatment. In comparison with the traditional technology, the work of art provided by the invention has the characteristics of decorative artistry and accumulation property of the traditional work of art, by special crystal and function, the synthesis and culture of the crystal are promoted, the product further has the ecological healthy functions of continuously purifying formaldehyde, generating negative oxygen ions, dispelling odor, being antibacterial and preserving moisture.
Description
Technical field
The invention belongs to artistic craft product manufacturing technology field, particularly a kind of artwork with lasting air optimizational function.
Background technology
The modern science and technology fast development, urbanization process is constantly accelerated, on the one hand, people are with growth in the living standard, more and more pay attention to the raising of quality of the life, by arranging some artwork, with the artistic decoration of room for promotion environment and express to life, to the succession residence analogy property of culture; And on the other hand, the kind nuisance that air environmental pollution day by day exists in the serious and modern architecture material in various degree discharges, severe contamination the indoor environment of our live and work every day, the pollutions such as formaldehyde (toluene) obnoxious flavour, metal particle, harmful floating dust, germ are on the rise, and exponential sum negative oxygen ion index with fresh air is more and more lower, leukemia, respiratory disease, subhealth state, the diseases such as immunity degradation are endangering our healthy constantly, and air quality problems needs to be resolved hurrily.
And current, at numerous resin bone carvings, acryl, glass, pottery, metal, rise in volume, cloth art, woodcarving, stone carving, bamboo carving, crystal, the charcoal carving, a feast for the eyes in the various artwork.Wherein, resin bone carving, acrylic class artwork are organic polymer in material, not environmental protection, without avidity, artistry limitation; Glass, ceramic-like artwork material are non-metal kind, but the high temperature sintering moulding process is harsh, do not have a feature of environmental protection; The metal matrix artwork is mainly take reserve value as main, the samely do not have artistry and a feature of environmental protection; And rattan plaited, cloth art, woodcarving, stone carving, bamboo carving are chiseled and carved with the manual Seiko of natural resource uniqueness, that have artistry or are worked out, and take artistic decoration and collection as main, do not have environment-protection functional; Wherein, only have crystal, charcoal to carve the existing decorative art of two class artwork, again human body is had to a certain degree healthy functions, crystal is based on far infrared rays and electric field or magnetic field effect to the impact of HUMAN HEALTH, but scarcity of resources and complete processing are complicated.And in CN102555643 disclosed " a kind of activated carbon process preparation method for environmental protection charcoal carver skill ", CN102756606A disclosed " a kind of can anion releasing and the charcoal carving of far infrared rays ", CN201586465U disclosed " a kind of activated carbon carving that can purify air ", CN101734080A disclosed " a kind of active carbon artware and production method thereof " is based on the physisorption of gac or its and inlays or gluing negative ion powder agglomates has adsorption function and anion releasing and far infrared rays to obnoxious flavour at the charcoal piece, play to a certain extent and purify air, the health-care effect that promotes health, but ornamental at artwork, all await on the environment-protection functional further solving improving.In the ornamental angle of artwork, mix the afterwards industrial analysis of compression moulding with the organic polymer latax based on gac and activity charcoal powder, product can't show exquisite fine and smooth artistic texture because plasticity is limited; On environment-protection functional, the purification environmental-protection of obnoxious flavour is functional, and adsorption cycle is long, adsorption rate is limited upward by single physisorption, and simultaneously, obnoxious flavour is saturated, easy desorption easily.
Summary of the invention
The objective of the invention is to solve existing artistic product environmental protection affinity, production technique mildness, plastic exquisiteness, environmental health on material, the calcareous crystal of tool human body avidity and the algae crystal of 5000～6000 times of environment-protection functionals of superior gac are compounded to form algae calcium crystal in the cast of normal temperature liquid phase medium or are pressed into various artistic designs, because it has plasticity-and the unrivaled environmental health of algae of calcareous crystal excellence concurrently, thereby provide a kind of artwork with lasting air optimizational function.
The invention provides a kind of artwork and production method with lasting air optimizational function, by calcium-contg. inorganic material, algae, modification agent, through raw materials pretreatment, the algae crystal and the active degree of depth of rigidity short cylinder calcium sulphate crystal that are flexible disk sieve shape are excited, again with fortifying fibre and combination solution mix and blend, make its hydration and hardening under liquid phase medium, and once again polymerization is the inorganic network structure material that integral body bonds continuous " diatom--calcareous microcrystal unit " and local " diatom--calcareous micropore " that disperses.
By giving fine and smooth surperficial texture by inorganic " diatom--calcareous " distinctive plasticity-of crystalloid, can guarantee the high fidelity (Hi-Fi) expressive force of various surface reliefs, plastic relief, hollow out carve, skin texture decorative pattern etc.; The principle of its air optimization is the synergy of physical adsorption and chemical degradation, passes through diatom--after calcareous micropore adsorbs all kinds of obnoxious flavoures such as formaldehyde, toluene etc., relend by the function promotion crystal redox reaction that forms and form the OH(hydroxyl free radical), O
2 -(peroxy radical) and have very strong oxidative decomposition capacity and destroy C in the organism-C key, C-H key, C-N key, C-O key, O-H key, N-H key through forming intermediate product formic acid HCOOH, and finally is oxidized to CO
2And H
2O, thus reach the effect of last decomposition environment purification, 95% purification rate index is had no place to hide obnoxious flavour, 90.1% water holdup index, form do not retain, unique quality unsaturated, that again do not discharge.Its negative ion genesis mechanism is for producing electric microfield by the atom generation redox reaction of appraising at the current rate in algae, the environmental mineral class component, and under the katalysis of internal composition, carry out continually and steadily, when airborne water molecules enters material internal structure micropore, water molecules is ionized to hydrogen ion and the electronegative hydroxide ion of positively charged, the hydrogen ion of positively charged is incorporated into hydrogen, be discharged in the air, constantly discharge a large amount of negative oxygen ions, reach 840/cm
3Burst size, greatly improved negative oxygen ion content in the space, the phenomenon of releasing negative oxygen ion in this similar forest, has natural Ecology characteristic, grow the negative oxygen ion of the title that air keeps being arranged can be constantly for your environment manufacturing, the pure and fresh cleaning of guarantee environment without any negative product, better people's living environment, improve body constitution.
One of technical solution of the present invention provides a kind of powder with lasting air optimizational function, by calcic mineral-type matrix, algae, modification agent, makes by the weight ratio mix and blend of 72.5 ~ 90:5 ~ 20:5 ~ 8.5.
Described calcic mineral-type matrix is: one or more in calcium sulphate hemihydrate, calcium phosphate or the calcium aluminate; Preferred calcium sulphate hemihydrate; One or more of the powder of powder after high-temperature calcination that the powder that preferred form is natural formation or the powder of chemosynthesis or industrial by-product desulfurization form.
Described algae is: one or both in diatomite or the marine alga soil; The preferred commercially available diatomite of powdery, its granularity reaches 300 ~ 800 orders.
Described modification agent is that Calucium Silicate powder, tourmalinite, sepiolite are by the epipastic mineral properties-correcting agent of the composite formation of weight ratio of 5.0 ~ 8.5:0 ~ 2.0:0 ~ 1.5.
Preparation method with powder of lasting air optimizational function of the present invention be with calcic mineral-type matrix, algae properties-correcting agent in described ratio pre-mixing after ageing 3 ~ 15 days and get final product in aging bunker.
Two of technical solution of the present invention provides a kind of artwork with lasting air optimizational function, and by weight, it is to be vacuumized or compression moulding, maintenance are dry, surface treatment is made through mix and blend, perfusion in combination solution by powder raw material; Described powder raw material is comprised of the described powder of one of 58 ~ 76 parts of technical solution of the present invention and auxiliary material; Described auxiliary material is the mixture of a kind of in 0.08 ~ 0.12 part of fortifying fibre or 15 ~ 20 parts of stopping composition or two kinds; Described combination solution consumption is 24 ~ 40 parts; Described combination solution is mixed by clear water, polyvinyl alcohol, crystal modifier, water-resisting agent, defoamer and the plant flowers extraction liquid weight ratio with 100:8 ~ 24:0.15 ~ 0.2:0.4 ~ 0.5:0.4 ~ 0.5:0.008 ~ 0.012.
Described fortifying fibre is one or more in vegetable fibre, glass fibre or the mineral fibre; Described stopping composition is the inorganic particle of various lightweights, porous; Described crystal modifier is one or more in Trisodium Citrate, Tai-Ace S 150 or the potassium aluminium sulfate; Described water-resisting agent is one or both in methyl silicon sodium alcoholate or the siloxanes; Described defoamer is one or more in tributyl phosphate, propyl carbinol or the primary isoamyl alcohol.Described plant flowers extraction liquid is the liquid that aromatising flavour is arranged that is obtained by microwave extracting by the flower with aromatising flavour.
The present invention preferably has the artwork of lasting air optimizational function, is prepared from by following several groups of raw materials:
The weight ratio of calcic mineral-type matrix, algae, modification agent, fortifying fibre and combination solution is: 52 ~ 54:3.6 ~ 12:3.6 ~ 5:0.08 ~ 0.12:24 ~ 40;
The weight ratio of calcic mineral-type matrix, algae, modification agent, stopping composition, combination solution is: 52 ~ 54:3.6 ~ 12:3.6 ~ 5:15 ~ 20:24 ~ 40;
Perhaps
The weight ratio of calcic mineral-type matrix, algae, modification agent, fortifying fibre, stopping composition, combination solution is: 52 ~ 54:3.6～12:3.6 ~ 5:0.08 ~ 0.12:15 ~ 20:24 ~ 40.
Three of technical solution of the present invention provides described production method with artwork of lasting air optimizational function, and production method is finished as follows:
(1) pre-treatment of raw material: calcic mineral-type matrix, algae, properties-correcting agent by ageing 3 ~ 15 days in aging bunker after the weight ratio pre-mixing of 72.5 ~ 90:5 ~ 20:5 ~ 8.5, are prepared into the described powder of one of technical solution of the present invention;
(2) compound stirs: in described ratio, with the described combination solution of the slow adding of the powder of auxiliary material and step (1), action of forced stirring after its liquid phase medium fully infiltrates powder, mixing speed are 280 ~ 400 rev/mins, and churning time is 15 ~ 32 seconds; Make mixed slurry form half wet paste or pasty material;
(3) the repressed moulding of material that step (2) is obtained or vibrating casting are in each artistic forming mould;
(4) treat that its curing and demolding, maintenance are dry, surface finish and colouring process.
The described moulding of step (3), any one in preferred following four kinds of modes:
The first is: the half wet paste compound that will stir is by the compression moulding mode, and the upper and lower mould demoulding forms different entity work in-process after slip final set;
The second is: by extruding pouring type injection moulding mould, the demoulding can form the work in-process of arbitrary plane and solid, hollow out, overwrought moulding after slip final set with the mixed slurry that stirs;
The described drying of step (4) can adopt seasoning 3 ~ 5 days, perhaps one or both in 10 ~ 12 hours the drying mode of 50 ~ 65 ℃ of dryings of dry kiln; Until material moisture is less than 3.5%.
The described post processing mode of step (4) is for after adopting 300～1000 order sand paper that its surface finish is smooth, adopt one or more surface treatment modes in coating, baking vanish, UV plated film, silk-screen, gold stamping or other material veneers, behind its surface cure, form described series product with artwork of lasting air optimizational function.
Artwork with lasting air optimizational function of the present invention is compared with artwork of the prior art, has following advantage:
First, main raw material(s) of the present invention is the calcareous crystal and the algae crystal that is better than 5000～6000 times of environment-protection functionals of gac of tool human body avidity, the main material of its product is inorganic algae calcium crystal, by by inorganic " diatom--calcareous " the distinctive plasticity-of crystalloid, give the surperficial texture of product exquisiteness, can guarantee the high fidelity (Hi-Fi) expressive force of various surface reliefs, plastic relief, hollow out carve, skin texture decorative pattern etc., simultaneously its " diatom--calcareous " micropore and function promote crystal to give the environmental health function of material uniqueness.
Second; the present invention is normal temperature compacting and casting, lower dry at nature and low temperature (50 ~ 65 ℃) in Technology; without high temperature, high energy consumption severe condition; its stirring, vibrating casting, vacuumize, the operation such as compacting is all the operation of device fabrication line; without a large amount of manual operation task difficulties; can realize in batches mass-producing, repeat the equalization form, not be subjected to the restrictions such as resource, task difficulty.
The 3rd, the air optimizational function that product of the present invention continues is to promote the physical adsorption of crystal and chemical reaction from-inner-to-outer to show by " diatom--calcareous " micropore and function to comprise that obnoxious flavour continues the environmental health function of the various features such as purification property, negative oxygen ion generation, dispelling abnormal flavor anti-bacteria wet keeping.
Wherein, the cleaning principle of obnoxious flavour is the synergy of physical adsorption and chemical degradation, by " diatom--calcareous " micropore with absorption such as all kinds of obnoxious flavoures such as formaldehyde, toluene after, relend by the function promotion crystal redox reaction that forms and form the OH(hydroxyl free radical), O
2 -(peroxy radical) and have very strong oxidative decomposition capacity and destroy C-C key, c h bond, C-N key, C-O key, O-H key, N-H key in the organism through forming intermediate product formic acid HCOOH, and finally is oxidized to CO
2And H
2O, thus reach the effect of last decomposition environment purification, the purification rate index of 95% formaldehyde is had no place to hide obnoxious flavour, 90.1% formaldehyde water holdup index, form do not retain, unique quality unsaturated, that again do not discharge.
Its negative ion genesis mechanism is that the atom generation redox reaction of appraising at the current rate in algae calcium crystal composition and the environmental mineral class component produces electric microfield, and under the katalysis of internal composition, carry out continually and steadily, when airborne water molecules enters material internal structure micropore, water molecules is ionized to hydrogen ion and the electronegative hydroxide ion of positively charged, the hydrogen ion of positively charged is incorporated into hydrogen, be discharged in the air, constantly discharge a large amount of negative oxygen ions, reach 840/cm
3Burst size, greatly improved negative oxygen ion content in the space, the phenomenon of releasing negative oxygen ion in this similar forest, has natural Ecology characteristic, grow the negative oxygen ion of the title that air keeps being arranged can be constantly for your environment manufacturing, the pure and fresh cleaning of guarantee environment without any negative product, better people's living environment, improve body constitution.
Its dispelling abnormal flavor anti-bacteria wet keeping is based on the powerful respiratory function of " diatom--calcareous " micropore and capture function with the peculiar smell capture filter, staphylococcus antibacterium rate is 97.97%, the intestinal bacteria antibiotic rate is 99.99%, rate of moisture absorption is 12%, separates wet rate is 8%, has excellent damping moisture retention, in addition, the plant extraction liquid that has fragrance is followed repeatedly moisture absorption and desorption also can put speed according to suction and is discharged various pure fragrance.
In a word, artwork of the present invention has multiple air optimizational function, and production technique is simple, aboundresources, with short production cycle, stably manufactured in batches, can be widely used in office, household, hotel in one's power in the car, artwork decorative article and the suspension member in the little spaces such as wardrobe, freezer, refrigerator.
Description of drawings
Fig. 1 is the process flow sheet of the production method of the artwork with lasting air optimizational function of the present invention.
Fig. 2 is the microtexture material figure of the artwork of the embodiment of the invention 1, and wherein, 2A is diatom--the bonding interface of calcareous microcrystal unit; 2B is diatom--the interspersed synoptic diagram of the intersection of rigidity crystal in the calcareous microcrystal unit; 2C is diatom--calcareous micropore unit.
Embodiment
The present invention can conduct further description the present invention by the following examples by the technical scheme implementation that illustrates in the summary of the invention, yet scope of the present invention is not limited to following embodiment.
Embodiment 1
A kind of powder with lasting air optimizational function, it is comprised of the component of following weight part:
80 parts of the natural powders of calcium sulphate hemihydrate
15 parts in the commercially available diatomite of 300-500 purpose
Calucium Silicate powder, tourmalinite, sepiolite are pressed 5 parts of the epipastic mineral properties-correcting agent of the composite formation of weight ratio of 7:1:1
With above-mentioned raw materials in described ratio pre-mixing after ageing 15 days and get final product in aging bunker.
Embodiment 2
A kind of powder with lasting air optimizational function, it is comprised of the component of following weight part:
75 parts of the natural powders of calcium phosphate
20 parts in 500-800 purpose marine alga soil
5 parts of powdered silicate calcium
With above-mentioned raw materials in described ratio pre-mixing after ageing 15 days and get final product in aging bunker.
Embodiment 3
A kind of powder with lasting air optimizational function, it is comprised of the component of following weight part:
90 parts of the natural powders of calcium aluminate
5 parts in 500-800 purpose marine alga soil
Calucium Silicate powder and tourmalinite are pressed 8 parts of the epipastic mineral properties-correcting agent of the composite formation of weight ratio of 5:2
With above-mentioned raw materials in described ratio pre-mixing after ageing 15 days and get final product in aging bunker.
Embodiment 4
A kind of powder with lasting air optimizational function, it is comprised of the component of following weight part:
73 parts of the powders that calcium sulphate hemihydrate mixes with calcium aluminate
20 parts in 500-800 purpose diatomite
Calucium Silicate powder and sepiolite are pressed 7 parts of the epipastic mineral properties-correcting agent of the composite formation of weight ratio of 8.5:1.5
With above-mentioned raw materials in described ratio pre-mixing after ageing 15 days and get final product in aging bunker.
Embodiment 5
A kind of environmental health function artwork, it is prepared from by following raw material:
1, prescription forms (physical measurement unit is weight part):
(1) natural calcium aluminate is 52 parts;
(2) marine alga soil: granularity 400 ~ 800 orders are through 10 parts of the native powders of the marine alga of grinding;
(3) modification agent: 4.8 parts of Calucium Silicate powder, 0.2 part of tourmaline powder;
(4) the chopped silk of fortifying fibre: length is on 0.1 part on 15 ~ 18mm vegetable fibre.
(5) combination solution: clear water, polyvinyl alcohol, Trisodium Citrate, methyl silicon sodium alcoholate, tributyl phosphate and Flos Caryophylli extraction liquid mix with the weight ratio of 100:15:0.1:0.4:0.5:0.01;
2, process for producing as shown in Figure 1, may further comprise the steps:
(1) pre-treatment of raw material: calcium aluminate, marine alga soil, Calucium Silicate powder, tourmaline powder by the respectively accurate measurement of weight part of upper 52:10:4.8:0.2, pre-mixing after in aging bunker ageing preparation in 3 ~ 15 days mixed powder;
(2) compound stirs: behind 32.9 parts of independent accurate-meterings of combination solution, mixed powder and 0.1 part of vegetable fibre of step (1) being made slowly add again, action of forced stirring after its liquid phase medium fully infiltrates powder, mixing speed are 280 ~ 400 rev/mins, and churning time is 15 ~ 32 seconds;
(3) vibrating casting moulding: under vibrational state, with in the slip injection moulding mould that stirs, after slip is filled with the slip casting mould is moved into vacuum lumen and vacuumize;
(4) maintenance is dry: naturally place in employing seasoning after the typing maintenance in 2 hours or the dry kiln drying mode one or both after the demoulding, seasoning 3 ~ 5 days, the dry kiln drying temperature is 50 ~ 65 ℃, dry 10 ~ 12 hours, when weight in wet base becomes work in-process less than 3.5% the time;
(5) aftertreatment: dried work in-process are smooth with 300 ~ 1000 order sand paperings, adopt one or more surface treatment modes in coating, baking vanish, UV plated film, silk-screen, gold stamping or other material veneers, behind its surface cure, form a kind of artwork with environmental health function.
Embodiment 6. 1 kinds of environmental health functions artwork and production method
1, prescription forms (physical measurement unit is weight part):
(1) natural calcium phosphocaseinate is 54 parts;
(2) diatomite: granularity 400 ~ 800 orders are through 3.6 parts of the diatomite powders of grinding;
(3) modification agent: 5 parts of calcium silicate powders;
(4) inorganic particle filled material is 15 parts.
(5) combination solution: 25 parts of the combination solutions that clear water, polyvinyl alcohol, Tai-Ace S 150, siloxanes, propyl carbinol and Flower of Arabian Jasmine extraction liquid get with the weight ratio mixing and stirring of 100:15:0.1:0.4:0.5:0.01.
2, process for producing as shown in Figure 1, may further comprise the steps:
(1) pre-treatment of raw material: calcium phosphate, diatomite, Calucium Silicate powder by the respectively accurate measurement of above-mentioned weight part, pre-mixing after in aging bunker ageing preparation in 3 ~ 15 days mixed powder;
(2) compound stirs: behind 25 parts of independent accurate-meterings of combination solution, mixed powder and 5 parts of inorganic particle filled material of step (1) being made slowly add again, action of forced stirring after its liquid phase medium fully infiltrates powder, mixing speed are 280 ~ 400 rev/mins, and churning time is 15 ~ 32 seconds;
(3) vibrating casting moulding: under vibrational state, with in the slip injection moulding mould that stirs, after slip is filled with the slip casting mould is moved into vacuum lumen and vacuumize;
(4) maintenance is dry: naturally place in employing seasoning after the typing maintenance in 2 hours or the dry kiln drying mode one or both after the demoulding, seasoning 3 ~ 5 days, the dry kiln drying temperature is 50 ~ 65 ℃, dry 10 ~ 12 hours, when weight in wet base becomes work in-process less than 3.5% the time;
(5) aftertreatment: dried work in-process are smooth with 300 ~ 1000 order sand paperings, adopt one or more surface treatment modes in coating, baking vanish, UV plated film, silk-screen, gold stamping or other material veneers, behind its surface cure, form a kind of artwork with environmental health function.
The effect example
1. the artwork with embodiment 5 preparation carries out electron-microscope scanning, and the result shows its structure as shown in Figure 2, forms to be the inorganic network structure material that integral body bonds continuous " diatom--calcareous microcrystal unit " and local " diatom--calcareous micropore " that disperses.
2. purifying formaldehyde functional test results:
Test result sees Table 1.
The environmental health of the artwork of table 1 embodiment 5 preparations
Claims (9)
1. powder with lasting air optimizational function, it is characterized in that: it is made by the weight ratio mix and blend of 72.5 ~ 90:5 ~ 20:5 ~ 8.5 by calcic mineral-type matrix, algae, modification agent.
2. powder claimed in claim 1 is characterized in that: described calcic mineral-type matrix is one or more the mixture in calcium sulphate hemihydrate, calcium phosphate or the calcium aluminate.
3. claim 1 or 2 described any one powders, it is characterized in that: described calcic mineral-type matrix granularity reaches 120 ~ 300 orders.
4. powder claimed in claim 1 is characterized in that: described algae is one or both the mixture in diatomite or the marine alga soil.
5. claim 1 or 4 described any one powders, it is characterized in that: described algae granularity reaches 300 ~ 800 orders.
6. powder claimed in claim 1, it is characterized in that: described modification agent is by the composite epipastic mineral properties-correcting agent that forms of the weight ratio of 5.0 ~ 8.5:0 ~ 2.0:0 ~ 1.5 by Calucium Silicate powder, tourmalinite, sepiolite.
7. artwork with lasting air optimizational function is characterized in that: by weight, it be by powder raw material in combination solution through mix and blend, perfusion vacuumizes or compression moulding, maintenance are dry, surface treatment is made; Described powder raw material is comprised of 58 ~ 76 parts of powders claimed in claim 1 and auxiliary material; Described auxiliary material is the mixture of a kind of in 0.08 ~ 0.12 part of fortifying fibre or 15 ~ 20 parts of stopping composition or two kinds; Described combination solution consumption is 24 ~ 40 parts; Described combination solution is mixed by clear water, polyvinyl alcohol, crystal modifier, water-resisting agent, defoamer and the plant flowers extraction liquid weight ratio with 100:8 ~ 24:0.15 ~ 0.2:0.4 ~ 0.5:0.4 ~ 0.5:0.008 ~ 0.012.
8. artwork claimed in claim 7, it is characterized in that: described fortifying fibre is one or more in vegetable fibre, glass fibre or the mineral fibre; Described crystal modifier is one or more in Trisodium Citrate, Tai-Ace S 150 or the potassium aluminium sulfate; Described water-resisting agent is one or both in methyl silicon sodium alcoholate or the siloxanes; Described defoamer is one or more in tributyl phosphate, propyl carbinol or the primary isoamyl alcohol.
9. the preparation method of artwork claimed in claim 7 may further comprise the steps:
(1) pre-treatment of raw material: calcic mineral-type matrix, algae, properties-correcting agent by ageing 3 ~ 15 days in aging bunker after the weight ratio pre-mixing of 72.5 ~ 90:5 ~ 20:5 ~ 8.5, are prepared into powder;
(2) compound stirs: in described ratio, with the described combination solution of the slow adding of the powder of auxiliary material and step (1), action of forced stirring after its liquid phase medium fully infiltrates powder, mixing speed are 280 ~ 400 rev/mins, and churning time is 15 ~ 32 seconds; Make mixed slurry form half wet paste or pasty material;
(3) the repressed moulding of material that step (2) is obtained or vibrating casting are in each artistic forming mould;
(4) treat that its curing and demolding, maintenance are dry, surface finish and colouring process.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104386982A (en) * | 2014-10-28 | 2015-03-04 | 成都尚科厨房设备有限公司 | Environmental-friendly tourmaline composite home decoration material and preparation method thereof |
| CN105148832A (en) * | 2015-08-18 | 2015-12-16 | 王秀宝 | Material based on ultrafine diatomaceous earth powder and used for removing formaldehyde and odor in air in cabinet and preparation method of material |
| CN105413629A (en) * | 2015-12-31 | 2016-03-23 | 湖北格林森新型建材科技有限公司 | Alga-calcium-mineral air purification medium and preparation method and application thereof |
| CN105731969A (en) * | 2016-03-02 | 2016-07-06 | 湖北格林森新型建材科技有限公司 | Photocatalytic inorganic ecological decoration board and production method thereof |
| CN105884317A (en) * | 2016-04-19 | 2016-08-24 | 沈阳化工大学 | Interior trimming part having air self-purification function and preparation method of interior trimming part |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102633450A (en) * | 2012-05-17 | 2012-08-15 | 湖北格林森新型建材科技有限公司 | Composite material with anion biomimetic function and production method thereof |
-
2013
- 2013-01-16 CN CN201310014510.XA patent/CN103058626B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102633450A (en) * | 2012-05-17 | 2012-08-15 | 湖北格林森新型建材科技有限公司 | Composite material with anion biomimetic function and production method thereof |
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| CN104386982A (en) * | 2014-10-28 | 2015-03-04 | 成都尚科厨房设备有限公司 | Environmental-friendly tourmaline composite home decoration material and preparation method thereof |
| CN105148832A (en) * | 2015-08-18 | 2015-12-16 | 王秀宝 | Material based on ultrafine diatomaceous earth powder and used for removing formaldehyde and odor in air in cabinet and preparation method of material |
| CN105148832B (en) * | 2015-08-18 | 2016-10-12 | 王秀宝 | Based on kieselguhr micropowder except formaldehyde in air, abnormal flavour material and preparation method thereof in wardrobe |
| CN105413629A (en) * | 2015-12-31 | 2016-03-23 | 湖北格林森新型建材科技有限公司 | Alga-calcium-mineral air purification medium and preparation method and application thereof |
| CN105413629B (en) * | 2015-12-31 | 2018-03-16 | 湖北格林森绿色环保材料股份有限公司 | Algae calcium mineral air purifying medium and preparation method and application |
| CN105731969A (en) * | 2016-03-02 | 2016-07-06 | 湖北格林森新型建材科技有限公司 | Photocatalytic inorganic ecological decoration board and production method thereof |
| CN105731969B (en) * | 2016-03-02 | 2018-03-16 | 湖北格林森绿色环保材料股份有限公司 | A kind of inorganic ecological decoration sheet material of photocatalysis and its production method |
| CN105906293A (en) * | 2016-04-15 | 2016-08-31 | 湖北森绿环保材料有限公司 | Flue gas desulfurization gypsum high-strength crystal decorative sheet and manufacturing method thereof |
| CN105906293B (en) * | 2016-04-15 | 2017-11-03 | 湖北森绿环保材料有限公司 | A kind of desulfurated plaster high-strength crystal decorative panel and preparation method thereof |
| CN105884317A (en) * | 2016-04-19 | 2016-08-24 | 沈阳化工大学 | Interior trimming part having air self-purification function and preparation method of interior trimming part |
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Address after: 430223 Hubei City, East Lake Province, New Technology Development Zone, Optics Valley Road, No. 78, international garden, building 3, floor 8, layer Patentee after: HUBEI GREENS ENVIRONMENTAL MATERIALS CO.,LTD. Address before: 430200 East Lake international high tech Zone, Wuhan, Hubei Road, No. 38 Optics Valley international headquarters space 3-404 Patentee before: Hubei Greens New Building Materials Science and Technology Co.,Ltd. |
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Denomination of invention: An ecological health functional art and its production method Effective date of registration: 20220525 Granted publication date: 20140618 Pledgee: Ye Wei|Wen Yu|Hubei Ping An Intelligent Fire Engineering Co.,Ltd. Pledgor: HUBEI GREENS ENVIRONMENTAL MATERIALS CO.,LTD. Registration number: Y2022420000134 |
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