CN103058579B - High-adhesive-force composite material and preparation method thereof - Google Patents
High-adhesive-force composite material and preparation method thereof Download PDFInfo
- Publication number
- CN103058579B CN103058579B CN201310029810.5A CN201310029810A CN103058579B CN 103058579 B CN103058579 B CN 103058579B CN 201310029810 A CN201310029810 A CN 201310029810A CN 103058579 B CN103058579 B CN 103058579B
- Authority
- CN
- China
- Prior art keywords
- solution
- preparation
- adhesive force
- high adhesive
- titanium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention provides a high-adhesive-force composite material and a preparation method thereof. The high-adhesive-force composite material comprises the following components in percentage by weight: 22-26% of nano zirconium oxide-titanium oxide composite powder, 10-12% of furnace slag powder, 0.10-0.2% of polyethyleneglycol, 2-5% of sodium carboxymethyl cellulose, 0.1-0.5% of polyacrylate emulsion, 4-6% of mullite powder and the balance of 3-methyl-2-butenyl-1-ol acetate composite solution. The furnace slag comprises the following components in percentage by weight: 36-40% of CaO, 13-15% of Al2O3, 6-9% of MgO, 0.3-0.5% of FeO and the balance of SiO2; and the particle size of the furnace slag powder is 80-100 mu m. The particle size of the nano zirconium oxide-titanium oxide composite powder is 80-100 nm, and the particle size of the mullite powder is 0.5-0.8 mm.
Description
Technical field
The invention belongs to field of compound material, relate to a kind of high adhesive force matrix material and preparation method thereof.
Background technology
No. 201210197038.3 applications provide a kind of high adhesive force interior wall material composition, and described in it, composition is mainly made up of following components by weight percent: filmogen 35.0～40.0 weight parts; Wherein said filmogen is the water-based mixed emulsion of high molecular and low-molecular-weight epoxy resin, and described high molecular and/or low-molecular-weight epoxy resin contain can stable complexation silver ions functional group; Solidifying agent 0～5.0 weight part; Freeze-thaw stabiliser 0.4～0.6 weight part, described freeze-thaw stabiliser is oblong link oxidative ethane (EO) block fatty alcohol-polyoxyethylene ether; Color stuffing 35.0～40.0 weight parts; Material auxiliary agent 5～7 weight parts; Adhesion promoter 0～0.2 weight part; And water that can receiving amount; In described composition, the total content of volatile chemical (VOC) is not higher than 0.01 % by weight, in composition total weight.The emulsion particle diameter of filmogen is distributed as 100～120nm, solid constituent between 47～53%, silver ion complexation degree >=5%, second-order transition temperature Tg is between 5～7 DEG C, minimum film-forming temperature MFFT is between 2～0 DEG C; Solidifying agent is cashew nut phenols curing agent.The molecular weight of high molecular expoxy resin is in 900～7000 scope, being preferably 900,1000,1200,1500,1800,2000,2200,2500,2800,3000,3200,3500,3800,4000,4200,4500,4800,5000,5200,5500,5800,6000,6200,6500,6800,7000, is more preferably 1000,1500,2000,2500.The molecular weight of low-molecular-weight epoxy resin, in 400～600 scope, is preferably 400,450,480,520,550,580,600, is more preferably 420.The mass ratio of high molecular expoxy resin and described low-molecular-weight epoxy resin is 8: 1～3: 1, preferably 6: 1～4: 1, and more preferably 5: 1.Described freeze-thaw stabiliser is oxyethane (EO) the block fatty alcohol-polyoxyethylene ether of long-chain.Normal temperature abrasion resistance is greater than 12000 times.Low temperature abrasion resistance is greater than 6000 times.Water tolerance is greater than 96 hours.Alkali resistance is greater than 48 hours.Sticking power is greater than 15MPa.The subject matter that above-mentioned materials exists is that sticking power is strong not.
Summary of the invention
Object of the present invention is exactly for above-mentioned technological deficiency, and a kind of high adhesive force matrix material is provided, and this material has good water tolerance, and high adhesive force.
Another object of the present invention is to provide above-mentioned high adhesive force composite material and preparation method thereof, and this preparation method's technique is simple, and production cost is low, is suitable for suitability for industrialized production.
Matrix material of the present invention is not only for building, and can be used for outdoor goods, clothes, military affairs etc. in needs insulations, the extensive application of heat insulation occasion.
the object of the invention is to be achieved through the following technical solutions:
A kind of high adhesive force matrix material, it is characterized in that, in this material, the weight percent of each composition is: nano level zirconium white titanium oxide composite granule 22-26%, slag powder 10-12%, polyoxyethylene glycol 0.10-0.2%, Xylo-Mucine 2-5%, polyacrylate dispersion 0.1-0.5%, mullite powder 4-6%, all the other are 3-M2BOL acetic ester composite solution;
Wherein, the weight percent of slag composition is CaO 36-40%, Al2O3 13-15%, and MgO 6-9%, FeO 0.3-0.5%, all the other SiO2, the particle diameter of slag powder is 80-100 μ m; The particle diameter of nano level zirconium white titanium oxide composite granule is 80-100nm, and the particle diameter of mullite powder is 0.5-0.8mm.
The preparation method of above-mentioned high adhesive force matrix material, the method comprises the following steps:
1) preparation of nano level zirconium white titanium oxide composite granule:
Get the ZrOCl2 aqueous solution, using ammoniacal liquor as precipitation agent, be that 50kHz, power are under the condition of 400W continuously stirring in ultrasonic frequency, the ZrOCl2 aqueous solution is added drop-wise in precipitation agent with the speed of 2mL/min, the pH value of controlling solution is 9, after dropwising, continues to stir 3h, then leave standstill aging 6h, obtain Zr (OH)
4water-sol A stand-by;
Under ice-water bath, 90mL titanium tetrachloride is slowly added dropwise in 420mL Virahol, in solution, adds 4.8mL concentrated hydrochloric acid, stir, then drip 135mL ammoniacal liquor, form solution B, stand-by; Wherein, the volume ratio of titanium tetrachloride, Virahol, concentrated hydrochloric acid, ammoniacal liquor is: 90:420:4.8:135;
By above-mentioned water-sol A with solution B in mass ratio for 1:1.1-1.3 mixes, after mixing, at ultrasonic frequency 50kHz, power is in 50-55 DEG C of ultrasonic agitation 1.5h under 400W; Then by gained mixed solution at 95 DEG C of rotary evaporation in vacuo, obtain solid gel, then 120 DEG C dry, be milled into 80-100nm powder, obtain nano level zirconium white titanium oxide composite granule; Then put into 550 DEG C of muffle furnaces, be incubated after 40 minutes, take out and be nano level zirconium white titanium oxide composite granule, for subsequent use;
2) preparation of 3-M2BOL acetic ester composite solution:
The weight percent of each raw material is: DOP dioctyl phthalate 5%, propyl carbinol 1%, polyvinyl alcohol 6%, Potassium Persulphate 0.15-0.19%, 3-M2BOL acetic ester 45-50%, water surplus;
DOP dioctyl phthalate is mixed with propyl carbinol, stir it is dissolved, form solution first stand-by; In container, add water, be heated to 80 DEG C, under agitation add polyvinyl alcohol, be warming up to 95 DEG C, insulation is to all dissolving.After to be dissolved, stop heating and make temperature be down to 68～70 DEG C, under agitation add 3-M2BOL acetic ester, form solution second stand-by.Solution first and solution second are mixed, add Potassium Persulphate, be uniformly mixed, be warmed up between 65～70 DEG C, stop 1 hour, obtain 3-M2BOL acetic ester composite solution, stand-by;
3) preparation of high adhesive force matrix material:
Each composition is prepared burden as following weight percent: above-mentioned nano level zirconium white titanium oxide composite granule 22-26%, slag powder 10-12%, polyoxyethylene glycol 0.10-0.2%, Xylo-Mucine 2-5%, polyacrylate dispersion 0.1-0.5%, mullite powder 4-6%, all the other are 3-M2BOL acetic ester composite solution, each composition is put into container and stir, obtain high adhesive force material.
The concentration of preparing the aqueous solution of ZrOCl2 used in water-sol A in step 1) is 0.2mol/L; The mass percent concentration 2.5% of ammoniacal liquor used.
The mass percentage concentration of preparing concentrated hydrochloric acid used in solution B in step 1) is 37%; Ammoniacal liquor mass percentage concentration used is 28%.
the present invention has following beneficial effect compared to existing technology:
In high adhesive force matrix material of the present invention, nano level zirconium white titanium oxide composite granule, has a large amount of micro interfaces, has good thermal insulation; And there is higher body cohesive strength, thereby contribute to sticking power to improve.
Polyoxyethylene glycol, Xylo-Mucine, polyacrylate dispersion and the combination of 3-M2BOL acetic ester composite solution in material, lead to and excessively strengthen the cross-link intensity of adhesive material in nano coating, greatly improve the cohesive strength of coated substrate, improved the sticking power of material.In addition, Xylo-Mucine, polyacrylate dispersion and 3-M2BOL acetic ester composite solution and nanometer grade composit powder body have good avidity, also can significantly improve the intensity of coating.
In material, slag powder has microcosmic porous, both can improve the heat-insulating capability of material, and reduce costs.
It has higher sticking power matrix material of the present invention, and has satisfactory stability and practicality, can be widely used in the field such as outdoor building, fabric.
brief description of the drawings:
Fig. 1 is the tissue of the material that obtains of the embodiment of the present invention 1.
As seen from Figure 1, coated material is uniformly distributed.
embodiment:
in following embodiment, raw materials used model is: polyoxyethylene glycol is cetomacrogol 1000; Polyacrylate dispersion (model DC-W10); Mullite powder is commercial, and its composition is AL 2 o 3 69-73%, Fe 2 o 3 1.0%, K 2 o+Na 2 o≤0.35%, all the other SiO 2 ,the particle diameter of mullite powder is 0.5-0.8mm.
embodiment mono-:
The preparation process of high adhesive force matrix material of the present invention is as follows:
1) preparation of zirconium white titanium oxide composite granule:
By ZrOCl
2.8H
2o and water are made the aqueous solution that concentration is 0.2mol/LZrOCl2; Mass percent concentration 25% ammoniacal liquor is diluted to 10 times as precipitation agent; Be that 50kHz, power are under the condition of 400W continuously stirring in ultrasonic frequency, the ZrOCl2 aqueous solution is added drop-wise in precipitation agent with the speed of 2mL/min, the pH value of controlling solution is 9, after dropwising, continue to stir 3h, then leave standstill aging 6h, obtain Zr (OH)
4water-sol A is stand-by;
Under ice-water bath (0 DEG C), 90mL titanium tetrachloride is slowly added dropwise in 420mL Virahol, in solution, adds 4.8mL concentrated hydrochloric acid (mass percentage concentration of concentrated hydrochloric acid is 37%), stir, drip again 135mL ammoniacal liquor (ammoniacal liquor mass percentage concentration is 28%), form solution B, stand-by;
By above-mentioned water-sol A with solution B in mass ratio for 1:1.1 mixes, after mixing, at ultrasonic frequency 50kHz, power is in 50-55 DEG C of ultrasonic agitation 1.5h under 400W; Then gained mixed solution is evaporated at 95 DEG C of vacuum rotatings (960 revs/min of rotating speeds), obtain solid gel, then 120 DEG C are dried, and are milled into 80-100nm powder, obtain nano level zirconium white titanium oxide composite granule; Then put into 550 DEG C of muffle furnaces, be incubated after 40 minutes, take out and be zirconium white titanium oxide composite granule, for subsequent use;
2) preparation of 3-M2BOL acetic ester composite solution:
The weight percent of each raw material is: DOP dioctyl phthalate 5%, propyl carbinol 1%, polyvinyl alcohol 6%, Potassium Persulphate 0.15-0.19%, 3-M2BOL acetic ester 45-50%, water surplus;
DOP dioctyl phthalate is mixed with propyl carbinol, stir it is dissolved, form solution first stand-by; In container, add water, be heated to 80 DEG C, under agitation add polyvinyl alcohol, be warming up to 95 DEG C, insulation is to all dissolving.After to be dissolved, stop heating and make temperature be down to 68～70 DEG C, under agitation add 3-M2BOL acetic ester, form solution second stand-by.Solution first and solution second are mixed, add Potassium Persulphate, be uniformly mixed, be warmed up between 65～70 DEG C, stop 1 hour, obtain 3-M2BOL acetic ester composite solution, stand-by;
3) preparation of high adhesive force matrix material:
Each composition is prepared burden as following weight percent: above-mentioned nano level zirconium white titanium oxide composite granule 22%, slag powder 10%, polyoxyethylene glycol 0.10%, Xylo-Mucine 2%, polyacrylate dispersion 0.1%, mullite powder 4%, all the other are 3-M2BOL acetic ester composite solution.Each composition is put into container and stir, obtain high adhesive force material.
embodiment bis-:
In step 1) in the preparation of nano level zirconium white titanium oxide composite granule, water-sol A with solution B in mass ratio for 1:1.2 mixes.
In step 3) high adhesive force matrix material, the weight percent of each composition is: nano level zirconium white titanium oxide composite granule 26%, slag powder 12%, polyoxyethylene glycol 0.2%, Xylo-Mucine 5%, polyacrylate dispersion 0.5%, mullite powder 6%, all the other are 3-M2BOL acetic ester composite solution.
Other preparation process is with embodiment mono-.
embodiment tri-:
In step 1) in the preparation of nano level zirconium white titanium oxide composite granule, water-sol A with solution B in mass ratio for 1:1.3 mixes.
In step 3) high adhesive force matrix material, the weight percent of each composition is: in material, weight percent weighs: nano level zirconium white titanium oxide composite granule 24%, slag powder 11%, polyoxyethylene glycol 0.15%, Xylo-Mucine 4%, polyacrylate dispersion 0.3%, mullite powder 5%, all the other are 3-M2BOL acetic ester composite solution.
Other preparation process is with embodiment mono-.
embodiment tetra-: proportioning components is not within the scope of design proportion of the present invention.
In step 1) in the preparation of nano level zirconium white titanium oxide composite granule, water-sol A with solution B in mass ratio for 1:0.8 mixes.
In step 3) high adhesive force matrix material, the weight percent of each composition is: in material, weight percent weighs: nano level zirconium white titanium oxide composite granule 20%, slag powder 9%, polyoxyethylene glycol 0.05%, Xylo-Mucine 1%, polyacrylate dispersion 0.05%, mullite powder 3%, all the other are 3-M2BOL acetic ester composite solution.
Other preparation process is with embodiment mono-.
embodiment five: proportioning components is not within the scope of design proportion of the present invention.
In step 1) in the preparation of nano level zirconium white titanium oxide composite granule, water-sol A with solution B in mass ratio for 1:1.5 mixes.
In step 3) high adhesive force matrix material, the weight percent of each composition is: in material, weight percent weighs: nano level zirconium white titanium oxide composite granule 28%, slag powder 14%, polyoxyethylene glycol 0.3%, Xylo-Mucine 6%, polyacrylate dispersion 0.6%, mullite powder 7%, all the other are 3-M2BOL acetic ester composite solution.
Other preparation process is with embodiment mono-.
test:
| material number | material composition | be greater than/MPa of sticking power. | normal temperature abrasion resistance is greater than/time. | water tolerance is greater than/hour |
| contrast material | 201210197038.3 number material that obtains of application | 15 | 12000 | 96 |
| material 1 | adopt the high adhesive force matrix material of embodiment mono- | 16 | 12800 | 165 |
| material 2 | adopt the high adhesive force matrix material of embodiment bis- | 18 | 13000 | 170 |
| material 3 | adopt the high adhesive force matrix material of embodiment tri- | 19 | 13100 | 175 |
| material 4 | adopt the high adhesive force matrix material of embodiment tetra- | 15 | 12200 | 150 |
| material 5 | the microstructure of composite that adopts the material of embodiment five to make | 14 | 12300 | 155 |
In matrix material of the present invention, 3-M2BOL acetic ester composite solution is caking agent, and the very few solvent action that do not have, too much understands diluted material; Polyoxyethylene glycol, Xylo-Mucine, polyacrylate dispersion are the caking agent enhancement component in material, very fewly do not have a bonding effect, too much can dilute insulation particle and solvent; Zirconium white titanium oxide composite granule, mullite powder and slag powder are aggregate, very fewly do not have a heat insulation and enhancement, too much can reduce the bonding effect of caking agent.
Claims (4)
1. a preparation method for high adhesive force matrix material, is characterized in that, the method comprises the following steps:
1) preparation of nano level zirconium white titanium oxide composite granule:
Get ZrOCl
2the aqueous solution, using ammoniacal liquor as precipitation agent, is that 50kHz, power are under the condition of 400W continuously stirring, by ZrOCl in ultrasonic frequency
2the aqueous solution is added drop-wise in precipitation agent with the speed of 2mL/min, and the pH value of controlling solution is 9, after dropwising, continues to stir 3h, then leaves standstill aging 6h, obtains Zr (OH)
4water-sol A stand-by;
Under ice-water bath, titanium tetrachloride is slowly added dropwise in Virahol, in solution, adds concentrated hydrochloric acid, stir, then drip ammoniacal liquor, form solution B, stand-by; Wherein, the volume ratio of titanium tetrachloride, Virahol, concentrated hydrochloric acid, ammoniacal liquor is: 90:420:4.8:135;
By above-mentioned water-sol A with solution B in mass ratio for 1:1.1-1.3 mixes, after mixing, at ultrasonic frequency 50kHz, power is in 50-55 DEG C of ultrasonic agitation 1.5h under 400W; Then by gained mixed solution at 95 DEG C of rotary evaporation in vacuo, obtain solid gel, then 120 DEG C dry, be milled into 80-100nm powder, obtain zirconium white titanium oxide composite granule; Then put into 550 DEG C of muffle furnaces, be incubated after 40 minutes, take out and be nano level zirconium white titanium oxide composite granule, for subsequent use;
2) preparation of 3-M2BOL acetic ester composite solution:
The weight percent of each raw material is: DOP dioctyl phthalate 5%, propyl carbinol 1%, polyvinyl alcohol 6%, Potassium Persulphate 0.15-0.19%, 3-M2BOL acetic ester 45-50%, water surplus;
DOP dioctyl phthalate is mixed with propyl carbinol, stir it is dissolved, form solution first stand-by; In container, add water, be heated to 80 DEG C, under agitation add polyvinyl alcohol, be warming up to 95 DEG C, insulation is to all dissolving; After to be dissolved, stop heating and make temperature be down to 68～70 DEG C, under agitation add 3-M2BOL acetic ester, form solution second stand-by; Solution first and solution second are mixed, add Potassium Persulphate, be uniformly mixed, be warmed up between 65～70 DEG C, stop 1 hour, obtain 3-M2BOL acetic ester composite solution, stand-by;
3) preparation of high adhesive force matrix material:
Each composition is prepared burden as following weight percent: above-mentioned nano level zirconium white titanium oxide composite granule 22-26%, slag powder 10-12%, polyoxyethylene glycol 0.10-0.2%, Xylo-Mucine 2-5%, polyacrylate dispersion 0.1-0.5%, mullite powder 4-6%, all the other are 3-M2BOL acetic ester composite solution, each composition is put into container and stir, obtain high adhesive force material.
2. the preparation method of high adhesive force matrix material according to claim 1, is characterized in that: step 1) in prepare ZrOCl used in water-sol A
2the concentration of the aqueous solution be 0.2mol/L; The mass percent concentration 2.5% of ammoniacal liquor used.
3. the preparation method of high adhesive force matrix material according to claim 1, is characterized in that: step 1) in preparation solution B the mass percentage concentration of concentrated hydrochloric acid used be 37%; Ammoniacal liquor mass percentage concentration used is 28%.
4. the high adhesive force matrix material that described in claim 1 prepared by method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310029810.5A CN103058579B (en) | 2013-01-25 | 2013-01-25 | High-adhesive-force composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310029810.5A CN103058579B (en) | 2013-01-25 | 2013-01-25 | High-adhesive-force composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103058579A CN103058579A (en) | 2013-04-24 |
| CN103058579B true CN103058579B (en) | 2014-10-22 |
Family
ID=48101515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310029810.5A Expired - Fee Related CN103058579B (en) | 2013-01-25 | 2013-01-25 | High-adhesive-force composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103058579B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473698A (en) * | 2017-08-07 | 2017-12-15 | 安徽凤凰松包装有限公司 | A kind of anti-oxidant synthetic plastic |
| CN109053037B (en) * | 2018-10-24 | 2021-02-23 | 山西新华防化装备研究院有限公司 | Preparation method of millimeter-sized zirconium oxide particles applied to chemical protection field |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1417282A (en) * | 2002-12-13 | 2003-05-14 | 湖南省第六工程公司 | Structural glue containing nano material |
| CN101255299A (en) * | 2007-12-28 | 2008-09-03 | 马鞍山钢铁股份有限公司 | Environment protection heat-proof acrylic resin insulation paint |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4758872B2 (en) * | 2006-11-22 | 2011-08-31 | 独立行政法人産業技術総合研究所 | Method for producing barium titanate powder |
-
2013
- 2013-01-25 CN CN201310029810.5A patent/CN103058579B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1417282A (en) * | 2002-12-13 | 2003-05-14 | 湖南省第六工程公司 | Structural glue containing nano material |
| CN101255299A (en) * | 2007-12-28 | 2008-09-03 | 马鞍山钢铁股份有限公司 | Environment protection heat-proof acrylic resin insulation paint |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2008-127258A 2008.06.05 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103058579A (en) | 2013-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101649147B (en) | Water transparent heat insulation paint and preparation method thereof | |
| CN107163855B (en) | A kind of silica aerogel reflective insulation exterior wall paint and preparation method thereof | |
| CN102557051B (en) | Method for preparing hollow mesocellular silica nanometer particles based on polymer formwork | |
| CN103056289B (en) | Casting paint for high-chromium cast iron and preparation method thereof | |
| CN104725990B (en) | A kind of preparation method of the self-cleaning coating based on modified nano-titanium dioxide | |
| CN107089666B (en) | A kind of preparation process of rare earth toughening silica aerogel presoma and solid-state silica aerogel | |
| CN103058579B (en) | High-adhesive-force composite material and preparation method thereof | |
| CN106085303A (en) | A kind of aqueous acrylic emulsion adhesive capable of releasing negative ion and preparation method | |
| CN108623822A (en) | A kind of SiO2The preparation method of/cellulose hybrid aerogel | |
| CN113953441B (en) | Starch modified silica sol and preparation method thereof | |
| CN103056288B (en) | Lost foam casting paint for chromium-containing cast iron and preparation method thereof | |
| CN110627402B (en) | Cement-based composite phase-change heat-storage temperature-regulating material based on mixed ester phase-change microcapsules | |
| CN101962521A (en) | Opening time adjustable wallpaper adhesive and preparation method thereof | |
| CN103073959B (en) | Washable coating material and preparation method thereof | |
| CN111646743A (en) | Bonding mortar for bonding smooth interface and preparation method thereof | |
| CN208711725U (en) | Reaction kettle is used in a kind of production of parental type silicon dioxide composite aerogel | |
| CN103340754B (en) | Preparation method of zirconia nanotube reinforced denture powder | |
| CN103056290A (en) | Heat-resisting cast iron casting coating and preparation method thereof | |
| CN107163823B (en) | A kind of preparation method of the ball-type nano ATO insulating moulding coating with high IR absorptivity | |
| CN110105833A (en) | The preparation method and product of the water-borne heat-insulating slurry of modified dispersion and application | |
| CN105969000A (en) | Matte woodenware coating and manufacturing method thereof | |
| CN105665965A (en) | Waterproof and dampproof welding rod coating and preparation method thereof | |
| CN105831154B (en) | A kind of titanium dioxide antibiotic colloidal sol and preparation method thereof | |
| CN109401377A (en) | The environment-friendly type coating of tunnel fireproof mould-proof | |
| CN107892880A (en) | A kind of phosphate high temperature resistant binder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141022 Termination date: 20180125 |