CN107892880A - A kind of phosphate high temperature resistant binder and preparation method thereof - Google Patents
A kind of phosphate high temperature resistant binder and preparation method thereof Download PDFInfo
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- CN107892880A CN107892880A CN201711385262.4A CN201711385262A CN107892880A CN 107892880 A CN107892880 A CN 107892880A CN 201711385262 A CN201711385262 A CN 201711385262A CN 107892880 A CN107892880 A CN 107892880A
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- high temperature
- boron carbide
- titanium dioxide
- temperature resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The invention provides a kind of phosphate high temperature resistant binder, raw material includes:Aluminium dihydrogen phosphate, magnesium dihydrogen phosphate, di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modifying titanium dioxide, modified boron carbide.Its preparation method is to mix boron carbide and diatomite, adds sodium hydroxide solution, ball milling, obtains being modified boron carbide after drying;Titanium dioxide and coupling agent are mixed again, ultrasonic disperse, modifying titanium dioxide is obtained after drying;Aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, aluminium phosphate magnesium adhesive is obtained, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modifying titanium dioxide and modified boron carbide, stir, produce.The phosphate high temperature resistant binder of the present invention has good resistance to elevated temperatures and high temperature cohesive strength.
Description
Technical field
The invention belongs to high temperature resistant binder technical field, and in particular to a kind of phosphate high temperature resistant binder and its preparation
Method.
Background technology
High-temperature resistance adhesive refers to that in high temperature environments its physicochemical properties remains to meet a kind of gluing of requirement
Agent.At present, the adhesive that can meet situations below is typically referred to as high-temperature resistance adhesive:(1)It is long-term use of at 121-175 DEG C
(Accumulative 1-5);(2)Add up to use 20000-40000h at 204-232 DEG C;(3)Add up to use 200- at 260-371 DEG C
1000h;(4)Add up to use 34-200h at 371-427 DEG C;(5)2-10min is used at 528-816 DEG C.Meanwhile high temperature resistant
Adhesive is in addition to it will meet certain temperature requirement, it is also necessary to possess good physical and chemical performance, excellent high temperature bonding is strong
Degree and durability, and good processing characteristics.
High-temperature resistance adhesive typically can be divided into organic adhesion agent and the major class of inorganic adhesive two according to the difference of base-material.It is inorganic
Adhesive can be divided into by its Main chemical component:Phosphate, silicate, borate, oxide, sulfate etc..Inorganic adhesive
Possess the outstanding advantages of inorganic material, i.e. resistance to elevated temperatures is excellent, can be used within the scope of a very wide temperature, except this it
Outside, it is also small with good endurance, cure shrinkage, and environmentally safe, production cost is low, and preparation technology is simple, user
Just the advantages that, compared to organic high temperature-resistant adhesive, inorganic high-temperature resistant adhesive is more suitable for applying in hot environment, but
It is that inorganic adhesive fragility is big, poor solvent resistance, and poor impact resistance, adhesion strength is not high enough, and resistance to ag(e)ing is poor, it is serious to restrict
Its application.
The content of the invention
The present invention asks for the universal not high technology of resistance to elevated temperatures and high temperature cohesive strength of current high-temperature resistance adhesive
A kind of topic, there is provided phosphate high temperature resistant binder and preparation method thereof.
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:Aluminium dihydrogen phosphate 40-50 parts, biphosphate
Magnesium 5-10 parts, di-iron trioxide 1-1.5 parts, zinc oxide 0.5-0.8 parts, aluminium nitride 12-15 parts, flake asbestos 4-8 parts, three oxidations two
Chromium 3-7 parts, lignin 1-3 parts, modifying titanium dioxide 5-8 parts, modified boron carbide 21-25 parts;
The modified boron carbide is doped with the diatomaceous boron carbides of 5-10wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 3-5wt.% coupling agents.
Preferably, the coupling agent is titanate coupling agent, aluminate coupling agent, silane coupler, zirconium aluminate coupling
One or more in agent.
Preferably, the di-iron trioxide is by 800 DEG C of heat treatments.
Preferably, the average grain diameter of the zinc oxide is in 500-700nm.
Preferably, the granularity of the aluminium nitride is in 200-400 mesh.
Preferably, the granularity of the flake asbestos is in 80-100 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titanium dioxide and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
The present invention, as binder substrate, adds nano zine oxide and the di-iron trioxide after heat treatment using aluminium phosphate magnesium
As curing agent, mixed resin is used as using aluminium nitride, flake asbestos, chrome green, lignin, modifying titanium dioxide and boron carbide
Binding agent is made, there is good resistance to elevated temperatures and high temperature cohesive strength.
Embodiment
Embodiment 1
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:40 parts of aluminium dihydrogen phosphate, 5 parts of magnesium dihydrogen phosphate, three
Aoxidize 1 part of two iron, 0.5 part of zinc oxide, 12 parts of aluminium nitride, 4 parts of flake asbestos, 3 parts of chrome green, 1 part of lignin, modified dioxy
Change 5 parts of titanium, modified 21 parts of boron carbide;
The modified boron carbide is doped with the diatomaceous boron carbides of 5wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 3wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 200 mesh;The granularity of the flake asbestos is in 80 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
Embodiment 2
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:43 parts of aluminium dihydrogen phosphate, 6 parts of magnesium dihydrogen phosphate, three
1.1 parts of two iron is aoxidized, 0.6 part of zinc oxide, 13 parts of aluminium nitride, 5 parts of flake asbestos, 4 parts of chrome green, 1.6 parts of lignin, is modified
7 parts of titanium dioxide, modified 23 parts of boron carbide;
The modified boron carbide is doped with the diatomaceous boron carbides of 6wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 4wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 200 mesh;The granularity of the flake asbestos is in 80 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
Embodiment 3
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:47 parts of aluminium dihydrogen phosphate, 8 parts of magnesium dihydrogen phosphate, three
1.4 parts of two iron is aoxidized, 0.7 part of zinc oxide, 14 parts of aluminium nitride, 7 parts of flake asbestos, 6 parts of chrome green, 2 parts of lignin, is modified two
7 parts of titanium oxide, modified 24 parts of boron carbide;
The modified boron carbide is doped with the diatomaceous boron carbides of 8wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 4wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 400 mesh;The granularity of the flake asbestos is in 100 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
Embodiment 4
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:50 parts of aluminium dihydrogen phosphate, 10 parts of magnesium dihydrogen phosphate,
1.5 parts of di-iron trioxide, 0.8 part of zinc oxide, 15 parts of aluminium nitride, 8 parts of flake asbestos, 7 parts of chrome green, 3 parts of lignin are modified
8 parts of titanium dioxide, modified 25 parts of boron carbide;
The modified boron carbide is doped with the diatomaceous boron carbides of 10wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 5wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 400 mesh;The granularity of the flake asbestos is in 100 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
Embodiment 5
The present embodiment and the difference of embodiment 2 are:Boron carbide is not modified.
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:43 parts of aluminium dihydrogen phosphate, magnesium dihydrogen phosphate 6
Part, 1.1 parts of di-iron trioxide, 0.6 part of zinc oxide, 13 parts of aluminium nitride, 5 parts of flake asbestos, 4 parts of chrome green, lignin 1.6
Part, 7 parts of modifying titanium dioxide, 23 parts of boron carbide;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 4wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 200 mesh;The granularity of the flake asbestos is in 80 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy
Change titanium and modified boron carbide, stir, produce.
Embodiment 6
The present embodiment and the difference of embodiment 2 are:Lignin is not added.
A kind of phosphate high temperature resistant binder, raw material include in parts by weight:43 parts of aluminium dihydrogen phosphate, magnesium dihydrogen phosphate 6
Part, 1.1 parts of di-iron trioxide, 0.6 part of zinc oxide, 13 parts of aluminium nitride, 5 parts of flake asbestos, 4 parts of chrome green, modified titanium dioxide
7 parts of titanium, modified 23 parts of boron carbide;
The modified boron carbide is doped with the diatomaceous boron carbides of 6wt.%;
The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 4wt.% titanate coupling agents.
Wherein, the di-iron trioxide is by 800 DEG C of heat treatments;The average grain diameter of the zinc oxide is in 500-
700nm;The granularity of the aluminium nitride is in 200 mesh;The granularity of the flake asbestos is in 80 mesh.
The preparation method of above-mentioned phosphate high temperature resistant binder, comprises the following steps:
Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying
After obtain being modified boron carbide;
Step 2, titania powder and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;
Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus
Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, modifying titanium dioxide and
Modified boron carbide, stirs, produces.
The gained binding agent of embodiment 1 to 6 is coated uniformly on ceramic sheet matrix or the stainless steel base surface by pretreatment, so
Afterwards two pieces of matrixes of the same race are overlapped to obtain bonding sample.Obtained binding agent bonding sample avoids water prior to air-drying 24h in air
Point volatilization is too fast, and 24h is dried in 70 DEG C of baking oven so that moisture fully volatilizees, then solidifies 2h at 140 DEG C, then distinguishes
2h is heat-treated at 200 DEG C, 400 DEG C, 600 DEG C, 800 DEG C, 1000 DEG C, 1200 DEG C, the binding agent bonding examination after being heat-treated
Sample, determine the shear strength of the gained binding agent of embodiment 1 to 6.
The present invention, as binder substrate, adds nano zine oxide and the di-iron trioxide conduct after heat treatment using aluminium phosphate magnesium
Curing agent, it is made using aluminium nitride, flake asbestos, chrome green, lignin, modifying titanium dioxide and boron carbide as mixed resin
Binding agent, there is good resistance to elevated temperatures and high temperature cohesive strength.Di-iron trioxide after heating, the reactivity with phosphoric acid
Reduce so that the phosphate high molecular polymer of formation is more complete, so as to add the cohesive force of Phosphate adhesive, bonds
The shear strength of agent sample improves.Boron carbide is due to being oxidized generation diboron trioxide so can improve binding agent at 800 DEG C
More than adhesive property, but when temperature is more than 1200 DEG C, diboron trioxide can volatilize, and cause adhesive strength to decline.The present invention
Boron carbide is modified using diatomite, the volatilization of diboron trioxide can be reduced, effectively improves binding agent more than 1200 DEG C
Adhesive property.The addition of lignin, the structure of binder system can be improved, strengthen the interaction of binder component, from
And improve the resistance to elevated temperatures and high temperature cohesive strength of binding agent.
Claims (7)
- A kind of 1. phosphate high temperature resistant binder, it is characterised in that:Raw material includes in parts by weight:Aluminium dihydrogen phosphate 40-50 parts, Magnesium dihydrogen phosphate 5-10 parts, di-iron trioxide 1-1.5 parts, zinc oxide 0.5-0.8 parts, aluminium nitride 12-15 parts, flake asbestos 4-8 parts, Chrome green 3-7 parts, lignin 1-3 parts, modifying titanium dioxide 5-8 parts, modified boron carbide 21-25 parts;The modified boron carbide is doped with the diatomaceous boron carbides of 5-10wt.%;The modifying titanium dioxide is the titanium dioxide that surface modification is carried out using 3-5wt.% coupling agents.
- 2. phosphate high temperature resistant binder according to claim 1, it is characterised in that:The coupling agent is coupled for titanate esters One or more in agent, aluminate coupling agent, silane coupler, zirconium aluminate coupling agent.
- 3. phosphate high temperature resistant binder according to claim 1, it is characterised in that:The di-iron trioxide be by 800 DEG C heat treatment.
- 4. phosphate high temperature resistant binder according to claim 1, it is characterised in that:The average grain diameter of the zinc oxide exists 500-700nm。
- 5. phosphate high temperature resistant binder according to claim 1, it is characterised in that:The granularity of the aluminium nitride is in 200- 400 mesh.
- 6. phosphate high temperature resistant binder according to claim 1, it is characterised in that:The granularity of the flake asbestos is in 80- 100 mesh.
- 7. the preparation method of the phosphate high temperature resistant binder described in claim 1, it is characterised in that:Comprise the following steps:Step 1, boron carbide and diatomite are mixed, adds the 10wt.% of 0.1 times of weight sodium hydroxide solution, ball milling, drying After obtain being modified boron carbide;Step 2, titanium dioxide and coupling agent are mixed, ultrasonic disperse, modifying titanium dioxide is obtained after drying;Step 3, aluminium hydroxide and magnesia mixed-powder are added in the concentrated sulfuric acid under agitation, heating stirring, obtains phosphorus Sour magnalium adhesive, add di-iron trioxide, zinc oxide, aluminium nitride, flake asbestos, chrome green, lignin, modified dioxy Change titanium and modified boron carbide, stir, produce.
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Cited By (2)
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CN109913135A (en) * | 2019-02-18 | 2019-06-21 | 安徽鸿智菱科技有限公司 | A kind of cable formula liquid-level floater switch high-temperature-resistant adhesive |
CN113147114A (en) * | 2021-04-26 | 2021-07-23 | 因达孚先进材料(苏州)有限公司 | High-temperature-resistant viscose-based graphite felt and preparation process thereof |
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