CN103046070A - Ion membrane electrolytic tank - Google Patents

Ion membrane electrolytic tank Download PDF

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Publication number
CN103046070A
CN103046070A CN2012105384668A CN201210538466A CN103046070A CN 103046070 A CN103046070 A CN 103046070A CN 2012105384668 A CN2012105384668 A CN 2012105384668A CN 201210538466 A CN201210538466 A CN 201210538466A CN 103046070 A CN103046070 A CN 103046070A
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China
Prior art keywords
water
steam
section
temperature evaporation
output tube
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Pending
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CN2012105384668A
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Chinese (zh)
Inventor
黄东
包金祥
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Suzhou New District Chemical Equipment Plant
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Suzhou New District Chemical Equipment Plant
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Priority to CN2012105384668A priority Critical patent/CN103046070A/en
Publication of CN103046070A publication Critical patent/CN103046070A/en
Pending legal-status Critical Current

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Abstract

The invention relates to an ion membrane electrolytic tank with a purification device, comprising a electrolytic tank, a steam boiler and a pressure steam purification chamber, wherein the electrolytic tank is connected to an alkaline liquor output tube, a hydrogen output tube and a chlorine output tube, the alkaline liquor is connected to the liquid inlet of the pressure steam purification chamber, and the steam outlet of the steam boiler is connected to the steam inlet of the pressure steam purification chamber. The electrolytic tank of the invention is arranged with the steam purification device on an alkaline liquor outlet of the similar electrolytic tank, which fully reduces the heat loss of the alkaline liquor in the transport process, reduces the energy consumption, and makes a contribution to low carbon production.

Description

A kind of ion-exchange membrane electrolyzer that is provided with purifying plant
Technical field
The present invention relates to a kind of preparation of sodium hydroxide equipment, be specifically related to a kind of ion-exchange membrane electrolyzer that is provided with the evaporation purifying plant.
Background technology
The ion-exchange membrane electrolysis alkaline is state-of-the-art processing method in the middle of the suitability for industrialized production caustic soda in the world, has that energy consumption is low, three-waste pollution is few, cost low and the advantage such as convenient operation and management.The chlorine of by-product and hydrogen can synthetic hydrochloric acids, or deep processing chlorine derived product such as PVC, organosilicon and methane chloride etc.Caustic soda is widely used in the industrial sectors such as papermaking, weaving, printing and dyeing, enamel, medicine, dyestuff, agricultural chemicals, process hides, petroleum refining, animal-plant oil processing, rubber, light industry, also is used for the extraction of aluminum oxide and the processing of metal products.Ion film caustic soda adopts exactly the ion exchange membrane electrolytic saltwater and makes caustic soda (being sodium hydroxide), its cardinal principle is because the cationic exchange membrane that uses, this film has special selection perviousness, only allow positively charged ion to pass through to stop negatively charged ion and gas to pass through, namely only allow H+, Na+ passes through, and Cl-, OH-and the two poles of the earth product H2 and Cl2 can't pass through, thereby played and prevent that anodic product Cl2 from mixing mutually with cathode product H2 and the danger that may cause exploding, also played and avoided Cl2 and another product of negative electrode NaOH reaction and generate the effect that NaClO affects caustic soda purity.
In daily production, generally need further the alkali lye of direct extraction to be purified.Usually the method that adopts is to produce steam by boiler alkali lye is heated, and makes water molecules evaporation wherein, therefore need to consume a large amount of energy when alkali lye is purified.At present, common way is that the intermediate receptacle of packing into without the alkali lye of purifying is transported to the purification workshop, with certain remaining temperature, and through aforesaid pilot process this alkali lye with temperature is cooled off gradually when alkali lye has just extracted in the electrolyzer, caused the waste of heat energy.And the employed energy is the non-clean energies such as coal when generally producing steam, has more increased the weight of environmental pollution.
Summary of the invention
The technical problem to be solved in the present invention is: the ion-exchange membrane electrolyzer that proposes a kind of alkali lye purifying plant with taking full advantage of temperature more than the alkali lye and reducing polluted emission.
The present invention is that the technical scheme that solves the problems of the technologies described above proposition is: a kind of ion-exchange membrane electrolyzer that is provided with purifying plant, comprise electrolyzer, described electrolyzer is connected with alkali lye output tube, hydrogen output tube and chlorine output tube, comprise steam boiler and pressure steam purification chamber, described alkali lye output tube is connected to the fluid inlet of described pressure steam purification chamber, and the steam outlet of described steam boiler is connected to the steam inlet of described pressure steam purification chamber.
The invention has the beneficial effects as follows:
The present invention arranges the steam purifying plant by the alkali lye equipped at outlet port at close electrolyzer, fully reduces the calorific loss that alkali lye causes in transportation.Obtained to reduce the effect of energy consumption, for contribution has been made in low-carbon (LC) production.
Having improved of technique scheme:
In order to use the extra energy, the hydrogen that goes out by electrolysis production is fully used, described steam boiler is hydrogen gas boiler, described hydrogen output tube is connected to the hydrogen input aperture of described hydrogen gas boiler.
Further improving of hydrogen gas boiler in the technique scheme had: described hydrogen gas boiler comprises drum, economize the coal section, superheat section, the low-temperature evaporation section, the high temperature evaporation section, burner hearth, boiler integral body is a cube formula shaft structure, the top of described burner hearth is furnished with superheat section successively, the low-temperature evaporation section, the high temperature evaporation section, economize the coal section, and it all is positioned at the formed cavity of boiler jacket body, described burner hearth is specially water-evaporating furnace, the below of described water-evaporating furnace is provided with combustion engine, the outside top of described cavity is provided with described drum, the external feedwater of the water-in of described economizer, the water outlet of described economizer connects the top of described drum by water inlet pipe, the top of described drum connects the import of described superheat section by the steam fairlead, the external superheated vapour outlet of the outlet of described superheat section, the bottom of described drum connects respectively the water wall entrance of described water-evaporating furnace by downtake, the water inlet of low-temperature evaporation section, the water outlet of described low-temperature evaporation section connects the water inlet of described high temperature evaporation section, the water outlet of described high temperature evaporation section, the water wall outlet of water-evaporating furnace connects described drum by upcast respectively.
In order further to reduce heat-energy losses, be coated with thermal insulation layer on the described alkali lye output tube.
Description of drawings
Below in conjunction with accompanying drawing a kind of ion-exchange membrane electrolyzer that is provided with purifying plant of the present invention is described further.
Fig. 1 is the structural representation that is provided with the ion-exchange membrane electrolyzer of purifying plant.
Embodiment
Embodiment
According to shown in Figure 1, the ion-exchange membrane electrolyzer that is provided with purifying plant among the present invention comprises electrolyzer 1, comprises hydrogen gas boiler 2 and pressure steam purification chamber 3.
Wherein, electrolyzer is connected with alkali lye output tube 5, hydrogen output tube 6 and chlorine output tube 4.
Wherein, the fluid inlet of pressure steam purification chamber 3 is comparable to electrolyzer 1, and is connected to alkali lye output tube 5, and the steam outlet of hydrogen gas boiler 2 is connected to the steam inlet of pressure steam purification chamber 3, and hydrogen output tube 6 is connected to the hydrogen input aperture of hydrogen gas boiler 2.
Be coated with thermal insulation layer on the alkali lye output tube.
Hydrogen gas boiler comprises drum, economize the coal section, superheat section, the low-temperature evaporation section, the high temperature evaporation section, burner hearth, boiler integral body is a cube formula shaft structure, the top of burner hearth is furnished with superheat section successively, the low-temperature evaporation section, the high temperature evaporation section, economize the coal section, and it all is positioned at the formed cavity of boiler jacket body, burner hearth is specially water-evaporating furnace, the below of water-evaporating furnace is provided with combustion engine, the outside top of cavity is provided with drum, the external feedwater of the water-in of economizer, the water outlet of economizer connects the top of drum by water inlet pipe, the top of drum connects the import of superheat section by the steam fairlead, the external superheated vapour outlet of the outlet of superheat section, the bottom of drum connects respectively the water wall entrance of water-evaporating furnace by downtake, the water inlet of low-temperature evaporation section, the water outlet of low-temperature evaporation section connects the water inlet of high temperature evaporation section, the water outlet of high temperature evaporation section, the water wall outlet of water-evaporating furnace connects drum by upcast respectively.
The above-described embodiment that is not limited to of the present invention, all employings are equal to replaces the technical scheme that forms, and all drops in the protection domain of requirement of the present invention.

Claims (4)

1. ion-exchange membrane electrolyzer that is provided with purifying plant, comprise electrolyzer, described electrolyzer is connected with alkali lye output tube, hydrogen output tube and chlorine output tube, it is characterized in that: comprise steam boiler and pressure steam purification chamber, the fluid inlet of described pressure steam purification chamber is comparable to described electrolyzer and is connected to the alkali lye output tube, and the steam outlet of described steam boiler is connected to the steam inlet of described pressure steam purification chamber.
2. the described ion-exchange membrane electrolyzer that is provided with purifying plant according to claim 1, it is characterized in that: described steam boiler is hydrogen gas boiler, described hydrogen output tube is connected to the hydrogen input aperture of described hydrogen gas boiler.
3. the described ion-exchange membrane electrolyzer that is provided with purifying plant according to claim 2, it is characterized in that: described hydrogen gas boiler comprises drum, economize the coal section, superheat section, the low-temperature evaporation section, the high temperature evaporation section, burner hearth, boiler integral body is a cube formula shaft structure, the top of described burner hearth is furnished with superheat section successively, the low-temperature evaporation section, the high temperature evaporation section, economize the coal section, and it all is positioned at the formed cavity of boiler jacket body, described burner hearth is specially water-evaporating furnace, the below of described water-evaporating furnace is provided with combustion engine, the outside top of described cavity is provided with described drum, the external feedwater of the water-in of described economizer, the water outlet of described economizer connects the top of described drum by water inlet pipe, the top of described drum connects the import of described superheat section by the steam fairlead, the external superheated vapour outlet of the outlet of described superheat section, the bottom of described drum connects respectively the water wall entrance of described water-evaporating furnace by downtake, the water inlet of low-temperature evaporation section, the water outlet of described low-temperature evaporation section connects the water inlet of described high temperature evaporation section, the water outlet of described high temperature evaporation section, the water wall outlet of water-evaporating furnace connects described drum by upcast respectively.
4. the described ion-exchange membrane electrolyzer that is provided with purifying plant according to claim 1 is characterized in that: be coated with thermal insulation layer on the described alkali lye output tube.
CN2012105384668A 2012-12-13 2012-12-13 Ion membrane electrolytic tank Pending CN103046070A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012105384668A CN103046070A (en) 2012-12-13 2012-12-13 Ion membrane electrolytic tank

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Application Number Priority Date Filing Date Title
CN2012105384668A CN103046070A (en) 2012-12-13 2012-12-13 Ion membrane electrolytic tank

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CN103046070A true CN103046070A (en) 2013-04-17

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54110981A (en) * 1978-02-20 1979-08-30 Tokuyama Soda Co Ltd Electrolysis
CN201852078U (en) * 2010-11-18 2011-06-01 浙江特富锅炉有限公司 Membrane wall structured hydrogen gas boiler
CN102607004A (en) * 2012-03-21 2012-07-25 江苏太湖锅炉股份有限公司 Hydrogen boiler structure
CN203007428U (en) * 2012-12-13 2013-06-19 苏州新区化工节能设备厂 Ion-exchange membrane electrolyzer provided with purification device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54110981A (en) * 1978-02-20 1979-08-30 Tokuyama Soda Co Ltd Electrolysis
CN201852078U (en) * 2010-11-18 2011-06-01 浙江特富锅炉有限公司 Membrane wall structured hydrogen gas boiler
CN102607004A (en) * 2012-03-21 2012-07-25 江苏太湖锅炉股份有限公司 Hydrogen boiler structure
CN203007428U (en) * 2012-12-13 2013-06-19 苏州新区化工节能设备厂 Ion-exchange membrane electrolyzer provided with purification device

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Application publication date: 20130417