CN103044979B - Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide - Google Patents
Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide Download PDFInfo
- Publication number
- CN103044979B CN103044979B CN201210559544.2A CN201210559544A CN103044979B CN 103044979 B CN103044979 B CN 103044979B CN 201210559544 A CN201210559544 A CN 201210559544A CN 103044979 B CN103044979 B CN 103044979B
- Authority
- CN
- China
- Prior art keywords
- coating
- spraying
- chromium
- raw material
- function powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011247 coating layer Substances 0.000 title abstract 4
- HYQNWBVCWZFDEY-UHFFFAOYSA-N aluminum chromium(3+) manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Al+3].[Cr+3].[O-2].[O-2].[O-2] HYQNWBVCWZFDEY-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 claims abstract description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001694 spray drying Methods 0.000 claims abstract description 20
- 238000010521 absorption reaction Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 11
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229920002050 silicone resin Polymers 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 41
- 239000000843 powder Substances 0.000 claims description 40
- 238000005507 spraying Methods 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 27
- 239000010408 film Substances 0.000 claims description 24
- QQHSIRTYSFLSRM-UHFFFAOYSA-N alumanylidynechromium Chemical compound [Al].[Cr] QQHSIRTYSFLSRM-UHFFFAOYSA-N 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000011572 manganese Substances 0.000 claims description 15
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910003310 Ni-Al Inorganic materials 0.000 claims description 6
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- 238000003980 solgel method Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000001238 wet grinding Methods 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 238000007750 plasma spraying Methods 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
Landscapes
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of solar energy photo-thermal utilization, in particular to a preparation method for functional power of a solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide. The composite coating layer comprises the following raw materials of a mixed raw material, a bonder and a dispersing agent, which are mixed at the ratio of 500:10:2, wherein the mixed raw material comprises the following components in percentage by mass: 55 percent of chromium oxide, 35 percent of aluminum oxide and 10 percent of manganese chloride tetrahydrate; and the bonder is 1053 silicone resin; and the dispersing agent is glycerine. According to the invention, the functional power prepared by using a spray drying method has excellent flowability and can meet the requirements of plasma spraying on material delivery. A phase structure of the coating layer is stable in selective absorption, can be fixedly combined with a matrix, and has excellent thermal shock resistance both in property and structure.
Description
Technical field
The present invention relates to solar energy thermal utilization technical field, particularly relate to a kind of based on high temperature solar absorber coatings preparation method in chromium aluminium Mn oxide function powder.
Background technology
Current, under the background that the Nonrenewable energy resources such as fossil are increasingly rare, will there is significant change in world energy sources structure, and sun power will replace conventional energy resources gradually, become indispensable important energy source, and the solar thermal utilization research of sun power has been current focus.Among the generating of Salar light-gathering heat, the solar thermal utilization of high temperature is the development trend of Solar use from now on, wherein the solar energy absorbing coating of coating type is both economical, and the main technical schemes of dealing with problems to develop high performance middle high temperature solar energy selective absorption coating material, its key point to improve the assimilated efficiency of coating to sun power, it also to be made to have lower coatings emissivity, also will solve the high thermal resistance of coating and good cost performance in addition.But present coating type coating all can not solve temperature resistance problem well and take into account good assimilated efficiency and lower emittance problem.
Summary of the invention
The technical problem to be solved in the present invention is the deficiency existed for prior art, provides system a kind of preparation method based on high temperature solar composite coating for absorbing in chromium aluminium Mn oxide function powder.
The present invention's one is achieved by following technical proposals based on chromium aluminium Mn oxide function powder solar absorption preparation method of composite coating: a kind of preparation method based on high temperature solar composite coating for absorbing in chromium aluminium Mn oxide function powder, it is characterized in that coating comprises following mixing raw material: chromium sesquioxide mass ratio 55%, the aluminium sesquioxide 35% of interpolation, tetrahydrate manganese chloride 10%; Binding agent is 1053 silicone resins, and dispersion agent is glycerol, and ratio is mixing raw material: binding agent: dispersion agent=500:10:2;
Described method comprises the steps:
Raw material mixing step by mixing raw material, binding agent, dispersion agent, deionized water with the ratio of 500:10:2:1000 mixing Keep agitation 40-60 minute uniformly slip;
Break-in whipping step slip is put into colloidal mill and carries out wet-milling mixing, each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 160-170 DEG C, and air outlet temperature is set to 40-60 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 17000--20000r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, and adjustment pH value is 4-5;
After substrate is preheated to 90-120 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 90-120 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 25-30 micron; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 100 DEG C of-120 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2h-2.5h, prepares solar absorption compound coating.
The present invention's one has following beneficial effect compared with prior art based on chromium aluminium Mn oxide function powder solar absorption preparation method of composite coating: the function powder that the present invention adopts spray-drying process to prepare, possess good mobility, meet plasma spraying feeding requirement.
Coating specific absorption is greater than 0.89, and emittance is less than 0.06, and take out after 10 minutes with 600 DEG C of insulations in retort furnace, within 5 minutes, air cooling is to room temperature.After 100 thermal shocks, coating structure is complete, and do not come off variable color.High-temperature stability is good, and coating can be used on the solar energy collector under middle hot environment.
The present invention, relative to single (chromium sesquioxide) black chrome coating, possesses better solar selectively absorptive character.
The phase structure of coating, selective absorbing stable performance, be combined with matrix firmly, on performance and structure, all possesses good thermal shock resistance.
Embodiment
Below in conjunction with embodiment, the present invention's one is further described based on chromium aluminium Mn oxide function powder solar absorption preparation method of composite coating technical scheme.
The present invention is a kind of, and based on high temperature solar composite coating for absorbing preparation method in chromium aluminium Mn oxide function powder, described coating comprises following mixing raw material: chromium sesquioxide mass ratio 55%, the aluminium sesquioxide 35% of interpolation, tetrahydrate manganese chloride 10%; Binding agent is 1053 silicone resins, and dispersion agent is glycerol, and ratio is mixing raw material: binding agent: dispersion agent=500:10:2;
Described method comprises the steps:
Raw material mixing step by mixing raw material, binding agent, dispersion agent, deionized water with the ratio of 500:10:2:1000 mixing Keep agitation 40-60 minute uniformly slip;
Break-in whipping step slip is put into colloidal mill and carries out wet-milling mixing, each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 160-170 DEG C, and air outlet temperature is set to 40-60 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 17000--20000r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, and adjustment pH value is 4-5;
After substrate is preheated to 90-120 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 90-120 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 25-30 micron; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 100 DEG C of-120 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2h-2.5h, prepares solar absorption compound coating.
Embodiment 1.
Get 500g mixing raw material, mass ratio is chromium sesquioxide 55%, the aluminium sesquioxide of 35%, the tetrahydrate manganese chloride of 10%.
Get 10g1053 silicone resin, 2-3ml glycerol, 1000ml deionized water and the abundant mix and blend of mixing raw material 40 minutes.
Break-in whipping step slip is put into colloidal mill and carries out wet-milling mixing, each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 160 DEG C, and air outlet temperature is set to 40 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 17000r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, regulates pH value to be 4;
After substrate is preheated to 90 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 90 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 25 microns; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 100 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2h, prepares solar absorption compound coating.
Embodiment 2.
Get 500g mixing raw material, mass ratio is chromium sesquioxide 55%, the aluminium sesquioxide of 35%, the tetrahydrate manganese chloride of 10%.
Get 10g1053 silicone resin, 2-3ml glycerol, 1000ml deionized water and the abundant mix and blend .50 minute of mixing raw material.
Break-in whipping step slip is put into colloidal mill and carries out wet-milling mixing, each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 165 DEG C, and air outlet temperature is set to 50 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 18500r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, regulates pH value to be 4.5;
After substrate is preheated to 105 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 90-120 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 28 microns; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 110 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2.3h, prepares solar absorption compound coating.
Embodiment 3.
Get 500g mixing raw material, mass ratio is chromium sesquioxide 55%, the aluminium sesquioxide of 35%, the tetrahydrate manganese chloride of 10%.
Get 10g1053 silicone resin, 2-3ml glycerol, 1000ml deionized water and the abundant mix and blend of mixing raw material 60 minutes.
Break-in whipping step slip is put into colloidal mill and carries out wet-milling mixing, each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 170 DEG C, and air outlet temperature is set to 60 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 20000r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, regulates pH value to be 5;
After substrate is preheated to 120 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 120 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 30 microns; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 120 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2.5h, prepares solar absorption compound coating.
Claims (1)
1., based on a high temperature solar composite coating for absorbing preparation method in chromium aluminium Mn oxide function powder, it is characterized in that coating comprises following mixing raw material: chromium sesquioxide mass ratio 55%, the aluminium sesquioxide 35% of interpolation, tetrahydrate manganese chloride 10%; Binding agent is 1053 silicone resins, and dispersion agent is glycerol, and ratio is mixing raw material: binding agent: dispersion agent=500:10:2;
Described method comprises the steps:
Raw material mixing step by mixing raw material, binding agent, dispersion agent, deionized water with the ratio of 500:10:2:1000 mixing Keep agitation 40-60 minute uniformly slip;
Break-in whipping step slip is put into colloidal mill and is carried out wet-milling mixing, and each component fully in dispersion slip, stirs 1 hour;
Drying step adopts spray-drying process to prepare function powder, and the intake air temperature of spray-drying tower is set to 160-170 DEG C, and air outlet temperature is set to 40-60 DEG C, and take away pump rotating speed is set to 800r/min, and spraying gun rotating speed is 17000-20000r/min; Slip is sent into spray-drying tower, can function powder be prepared; Its granularity of powder is no more than 50 μm;
Prepare and adopt sol-gel method outside coating, to prepare stannic oxide selectivity through film through film acid adjustment step, using anhydrous stannic chloride as Xi Yuan, dehydrated alcohol is as solvent, and initial soln concentration is 0.5mol/L, and adds appropriate Glacial acetic acid, and adjust ph is 4-5;
After substrate is preheated to 90-120 DEG C by spraying function powder step, spraying Ni-Al adhesive linkage; After being again cooled to 90-120 DEG C, spraying chromium aluminium Mn oxide function powder, thickness is 25-30 micron; Coating after clean spraying, prepares SnO 2 thin film in its surface; With 20mm/min speed lift film, dry 20min in 100 DEG C of-120 DEG C of baking ovens, then anneal film sample at 550 DEG C in retort furnace 2h-2.5h, prepares solar absorption compound coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210559544.2A CN103044979B (en) | 2012-12-21 | 2012-12-21 | Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210559544.2A CN103044979B (en) | 2012-12-21 | 2012-12-21 | Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103044979A CN103044979A (en) | 2013-04-17 |
| CN103044979B true CN103044979B (en) | 2015-05-20 |
Family
ID=48057848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210559544.2A Expired - Fee Related CN103044979B (en) | 2012-12-21 | 2012-12-21 | Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103044979B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104294270B (en) * | 2014-10-16 | 2016-08-31 | 太原理工大学 | Prepare the new technology of solar selectively absorbing coating |
| CN109354929A (en) * | 2018-08-30 | 2019-02-19 | 江苏京展能源科技有限公司 | A kind of preparation method of selective solar spectrum composite coating for absorbing |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101273238A (en) * | 2005-08-02 | 2008-09-24 | 桑斯翠普有限公司 | Nickel-alumina coated solar absorbers |
| CN102093767A (en) * | 2010-12-02 | 2011-06-15 | 无锡中阳新能源科技有限公司 | Medium and high temperature solar selective absorption coating and coating layer and preparation method thereof |
-
2012
- 2012-12-21 CN CN201210559544.2A patent/CN103044979B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101273238A (en) * | 2005-08-02 | 2008-09-24 | 桑斯翠普有限公司 | Nickel-alumina coated solar absorbers |
| CN102093767A (en) * | 2010-12-02 | 2011-06-15 | 无锡中阳新能源科技有限公司 | Medium and high temperature solar selective absorption coating and coating layer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103044979A (en) | 2013-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105131741B (en) | A kind of body absorption-type solar selective heat-absorbing paint and preparation method and application | |
| CN101314523B (en) | Titanium dioxide thin film and preparation thereof | |
| CN108410283A (en) | A kind of aqueous reflective heat-insulation paint and preparation method thereof | |
| CN103762249A (en) | Back-field passivated-aluminum conductive slurry for crystalline-silicon solar cell and preparation method | |
| CN105482603A (en) | Flat plate solar energy heat absorption coating | |
| CN103555019A (en) | Anti-aging heat radiation paint for LED lamp and preparation method thereof | |
| CN103044979B (en) | Preparation method for functional power of solar energy absorbed composite coating layer based on chromium-aluminum-manganese oxide | |
| CN105713502A (en) | High-light-absorptivity solar heat-absorbing paint | |
| CN104724757A (en) | Method for directly synthesizing rutile phase vanadium dioxide nano powder based on solvothermal reaction at low temperature | |
| CN107046740B (en) | Preparation method of electrothermal film | |
| CN105860611B (en) | A kind of infrared radiation coating and preparation method thereof | |
| CN104403558A (en) | Preparation method for solar-energy selectively-adsorbing paint with self cleaning function | |
| CN106433457A (en) | Modified casein-gelatin-containing solar energy heat absorbing coating material | |
| CN109111808A (en) | A kind of solar energy heat absorbing coating and preparation method thereof | |
| CN101767081A (en) | Preparation method of metal-dielectric solar spectrum selective absorption coating | |
| CN109651853B (en) | MoSi stable in high-temperature air2-SiO2Composite photo-thermal coating and preparation method thereof | |
| CN105482607A (en) | Solar heat absorption coating | |
| CN107090220A (en) | A kind of solar energy heat absorbing coating and preparation method thereof | |
| CN105694647A (en) | Heat-absorbing paint | |
| CN105482608A (en) | Solar heat absorption material containing modified silkworm protein-gelatin | |
| CN103044980B (en) | Method for preparing copper aluminum manganese oxide functional powder solar absorbing coating | |
| CN104356849A (en) | Solar cell backboard coating and preparation method thereof | |
| CN103740202A (en) | Preparation method of solar heat absorption coating | |
| CN109373618A (en) | A kind of preparation method of selective solar composite coating for absorbing | |
| CN109988506B (en) | Solar heat-absorbing material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20151030 Address after: 810007 No. 33 Minhe Road, Xining Economic Development Zone, Qinghai, Xining Patentee after: Hao Yong Patentee after: Electric Power Research Institute of State Grid Qinghai Electric Power Company Patentee after: Qinghai Heng Ming Photoelectric Technology Co., Ltd. Address before: 810007 No. 33 Minhe Road, Xining Economic Development Zone, Qinghai, Xining Patentee before: Hao Yong |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150520 Termination date: 20171221 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |