CN103044015A - Active energy porcelain, preparation method and second-boiling type slightly alkaline fresh boiled water electric heater - Google Patents
Active energy porcelain, preparation method and second-boiling type slightly alkaline fresh boiled water electric heater Download PDFInfo
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- CN103044015A CN103044015A CN2012105325072A CN201210532507A CN103044015A CN 103044015 A CN103044015 A CN 103044015A CN 2012105325072 A CN2012105325072 A CN 2012105325072A CN 201210532507 A CN201210532507 A CN 201210532507A CN 103044015 A CN103044015 A CN 103044015A
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Abstract
The invention discloses active energy porcelain, a preparation method and a second-boiling type slightly alkaline fresh boiled water electric heater. The active energy porcelain consists of the following materials in percentage by weight: 10-50% of tourmaline powder, 10-30% of medical stone powder, 1-10% of intermetallic compound powder, 1-15% of calcium sulfite powder and 20-40% of boron-silicon glass powder. Through adopting the invention, the treated water has the advantages that the water does not contain any substance toxic or harmful to human body and with peculiar smell and is rich in mineral substrates necessary to human body, the content of mineral substances is moderate, the pH value shows slight alkalinity, and the water is energetic micro-cluster water and has the media nutrition physiological function of water, namely the dissolving capacity, seepage force, diffusion force, metabolism force, emulsifying force and the like are superior to those of various types of drinking water on the market. The second-boiling type slightly alkaline fresh boiled water electric heater disclosed by the invention also has the advantages of simple structure, strong practicability and operability and great market prospect.
Description
Technical field
The present invention relates to the fresh and alive boiling water electric heater of formula weakly alkaline that boils a kind of active-energy porcelain, making method and second.
Background technology
Water is Source of life, the earliest life is born in the water exactly in the world, the proportion of moisture content accounts for 70% in adult's tissue, the proportion of moisture content accounts for 60% in middle-aged people's the tissue, and the proportion of moisture content accounts for 50% in the old tissue, and wherein the moisture content in the blood accounts for 90%, moisture content accounts for 85% in the cerebral tissue, moisture content accounts for 75% in the muscle, and moisture content accounts for 50% in the bone, and the moisture content in newborn infant's body can be up to 80%-90%.If the proportion of moisture content is lower than 50% in the human body, people's life will be subject to danger.As seen, important to people's life of water.
If the people thinks healthy existence, just need drinking healthy water, the detailed standard of the healthy water that World Health Organization works out, summary is summed up and is following several: the one, healthy water must be clean, sanitary, safe and not contain any objectionable impurities; The 2nd, be weakly alkaline, body endotoxin removing is tieed up weakly alkaline in the special human body; The 3rd, activity is arranged, be small molecules bunch state, can be absorbed by the human body natural and do not cause load to internal organ, solve the human body water shortage status.
At present, the tap water kind is a lot of on the market, but all has multiple deficiency: Shuifu County contains various trace elements, and is useful to HUMAN HEALTH, and still, it is not weakly alkaline, also do not possess activity; Distilled water is clean hygiene, and same, it is not weakly alkaline, does not possess activity yet; It also is clean also having pure water, also is not to be weakly alkaline, does not also possess activity.Brine electrolysis is weakly alkaline, possesses activity, and still, its trace element is few, also do not meet the standard of healthy water, and the weakly alkaline of brine electrolysis is extremely unstable, after brine electrolysis is heated, will lose weakly alkaline; In addition, electrolyzed water machine also can produce acid waste water and cause waste when producing alkalescent water, and the electrolyzed water machine power consumption causes operation and maintenance cost high, is unfavorable for promoting.
Summary of the invention
In order to overcome above-mentioned problems of the prior art, the purpose of this invention is to provide and a kind ofly make Natural Water be weakly alkaline, water molecule cluster is diminished and improve the activity of water, and the active-energy porcelain of clean hygiene, making method and the fresh and alive boiling water electric heater of formula weakly alkaline that boils second, this electric heater can be market and common large from the inexpensive fresh and alive boiling water of weakly alkaline is provided.
Technical scheme of the present invention is: a kind of active-energy porcelain is provided, and described active-energy porcelain is comprised of the material of following weight (WT) per-cent:
Tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%;
Sulfurous acid calcium powder 1-15%; Borosilicate glass powder 20-40%;
Wherein, the components in weight percent of described borosilicate glass powder is: silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; Calcium oxide 0.3-2%.
Among the present invention, described intermetallic compound powder is boron series intermetallic compound powder.
Described boron series intermetallic compound powder is the intermetallic compound powders such as lanthanum boride, aluminum boride, FeB, chromium boride, nickel borides or boron copper.
The present invention also provides a kind of manufacture method of active-energy porcelain, comprise as follows,
One, the preparation of borosilicate glass powder
(11), the borosilicate glass preparation of raw material, press silicon-dioxide 70-95%; Boron trioxide 1-25%; The ratio weighing each component of potassium oxide 0.5-3% calcium oxide 0.3-2%;
(12), ball mill mixing, with ball mill various components are mixed;
(13), high temperature melting, in 1500-1700 degree centigrade situation, with the fusing of mixed raw material;
(14), water granulation, will melt after borosilicate glass become wire to insert in the water, make borosilicate glass liquid in water, be cooled to the glass grain;
(15), pull the glass grain out, under 100-120 degree centigrade temperature, with the moisture content oven dry of glass grain surface;
(16), the ball grinds, the glass grain after the oven dry is added in the ball mill, ball milling is for subsequent use to the 300-1000 order.
Two, the active-energy porcelain is made
(21) batch mixing is pressed tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%; Sulfurous acid calcium powder 1-15%; After the described ratio weighing of borosilicate glass powder 20-40%, put into container and fully mix;
(22) granulation with the well-mixed mixture of the first step, is inserted in the tablets press, adds by weight the water-soluble binder of 10-20%, makes mobile spheroidal particle powder, and described water-soluble binder is the aqueous solution that contains the 2-3% polyvinyl alcohol;
(23) dry-pressing formed, mobile spheroidal particle powder is inserted in the mould, strike out predetermined shape;
(24) low temperature binder removal under 300-400 degree centigrade temperature, carries out the low temperature binder removal;
(25) oxidizing atmosphere sintering, under aerobic environment, 600-800 degree centigrade temperature is incubated 1-2 hour;
(26); After the cooling, be the active-energy porcelain.
In the manufacture method of this active-energy porcelain, described predetermined shape is sheet, spherical or Else Rule geometrical shape.
In the manufacture method of this active-energy porcelain; the making method that also comprises intermetallic compound powder under the protection of nitrogen, is heated to intermetallic compound intermetallic compound and is fused into liquid; compound is sprayed into powder between the liquid metal that will dissolve with high pressure nitrogen again, cools off for subsequent use.
The present invention also provides the fresh and alive boiling water electric heater of formula weakly alkaline that boils a kind of second, comprises heater body, is provided with the active-energy ceramic products in the hot water flux of described heater body, and described active-energy ceramic products is comprised of the material of following weight (WT) per-cent:
Tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%;
Sulfurous acid calcium powder 1-15%; Borosilicate glass powder 20-40%;
Wherein, the components in weight percent of described borosilicate glass powder is: silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; Calcium oxide 0.3-2%.
As the improvement to the fresh and alive boiling water electric heater of formula weakly alkaline that boils second, described heater body comprises that the outside is with the electricradiator base plate of electric heating film, water flow passage device and electricradiator cover plate, described water flow passage device is positioned at the accommodation space that forms after the inboard and described electricradiator cover plate of described electricradiator base plate fastens, and is provided with in the water flow passage of described water flow passage device be used to the active-energy ceramic products that purifies water.
As the further improvement to the fresh and alive boiling water electric heater of formula weakly alkaline that boils second, described intermetallic compound powder is boron series intermetallic compound powder.
Described boron series intermetallic compound powder is the intermetallic compound powders such as lanthanum boride, aluminum boride, FeB, chromium boride, nickel borides, boron copper or titanium boride.
As the further improvement to the fresh and alive boiling water electric heater of formula weakly alkaline that boils second, the shape of described active-energy ceramic products is sheet, spherical or Else Rule geometrical shape.
As improvement of the present invention, in the hot water flux of described heater body, also be provided with the Kai Defei filtrate, in the container that the packaged water of described Kai Defei filtrate can pass through.
Described container can be with being permitted lacunary can, such as stainless steel box or aluminium alloy box etc.
Described container also can two ends with pipeline of filter plate etc.
Among the present invention, tourmalinite is that a kind of boracic is the cyclosilicate crystal mineral of aluminium, sodium, iron, calcium and the magnesium of feature, and its chemical structure of general formula can be expressed as XY
3Z
6Si
6O
18(BO3)
3W
4, wherein, X=Na, Ca, K or room; Y=Mg, Fe, Mn, Al or Li; Z=Al, Fe, Cr or Mg; W=OH, F or O.Tourmalinite is a kind of permanent electric polarity that both had, has again emitting far-infrared mineral material, the permanent electric polarity of tourmalinite makes the tourmalinite surface have electromagnetic field up to 107V/M in thickness is tens microns scope, can be the water molecules electrolysis, make water be weakly alkaline, thereby improve the interfacial activity of water, strengthen seepage force and the solvency power of water.Tourmalinite at normal temperatures emission wavelength is 4-14um, and transmitting frequency is at the far infrared rays more than 0.9, can the activated water molecular cluster, reduce the degree of association of water molecules, and can make the macromole cluster become water molecule cluster water, make human body cell be easy to absorb; Tourmalinite has thermoelectric effect, and under the heated condition, its above-mentioned feature is more obvious; Tourmalinite is reusable, without any pollution.
Medical stone is a kind of natural medicine ore, contains 18 kinds of trace elements such as the necessary potassium of human body, sodium, calcium, magnesium, phosphorus major element and zinc, iron, selenium, copper, strontium, iodine, fluorine, metasilicic acid.With medical stone process water can make water become band+,-electric atomic group many water.Medical stone energy planar water middle reaches ion, medical stone is behind water, leachable to trace elements such as human body and organism useful major element K, Ca, Mg and Si, Fe, Zn, Cu, Mo, Se, Mn, Sr, Ni, V, Li, Co, Cr, I, Ge, Ti, enrich the trace element in the water.
Intermetallic compound Main Function among the present invention has 2 points, and the one, it is oxidized to prevent that the active-energy porcelain is present in the metal of active-energy porcelain inside when high temperature sintering, thereby its conducting function was not lost efficacy, and keeps the various features of active-energy porcelain constant; The 2nd, intermetallic compound also can cause electrolytic surface from polarity charge with what the tourmalinite deep layer produced, strengthens electrolytic effect and the activating effect of water molecules.
Calcium sulfite among the present invention is mainly used in removing the chlorine residue in the water, comprises combined residual chlorine NH
2Cl, NHCl
2And NCl
3Three kinds and free residual chlorine ClO-(hypochlorite ion), HClO(hypochlorous acid), Cl
2(chlorine) etc.; Borosilicate glass among the present invention can play the carrier as other composition on the one hand, on the other hand it can also slowly-releasing the similar compound of part borosilicate acids and tourmalinite, the compound of this class boracic plays a very important role to the normal physiological function tool of keeping human body.It is to keep one of the health of bone and calcium, phosphorus, the needed trace element of magnesium eubolism.Boron also is improved brain function, improves the effect of response capacity.Therefore, the boiling water with the fresh and alive boiling water electric heater of formula weakly alkaline that boils the second of containing the active-energy porcelain is made has following features:
1. the fresh and alive boiling water of weakly alkaline with the interior acid poison of human body, promotes the acid base equilibrium of human body in the energy.
2. small water molecule cluster water, seepage force is strong, is easy to the permeation cell membranous wall, and the washing metabolic waste improves microcirculation in human body.
3. association force is little between water molecule cluster, keeps the water molecules high efficiency energy, active cells, and activating enzyme is active.
4. solvency power strengthens, and can effectively moltenly release three high materials in the blood, and namely hyperlipidemia, hyperglycemia and hypercholesterolemia have the benefit that purifies the blood.
5. have negative potential, can remove superfluous free radical in the human body.
6. near the fresh and alive water of human body cell, active cells can strengthen body immunity.
7. the mineral substance and the trace element that contain a large amount of needed by human body, delicate mouthfeel, sweetness.
8. residual chlorine in the removal water is removed peculiar smell.
9. removal heavy metal suppresses microorganism.
The fresh and alive boiling water electric heater of formula weakly alkaline that boils the second of making of active-energy porcelain of the present invention has simple for structurely, becomes the fresh and alive boiling water of weakly alkaline small molecules cluster after tap water can being boiled second, and it is good and cheap, has good cost performance, has market popularization value.
Description of drawings
Fig. 1 is the making schematic flow sheet of borosilicate glass powder among the present invention.
Fig. 2 is the making schematic flow sheet of active-energy porcelain of the present invention.
Fig. 3 be among the present invention second the boil decomposition texture synoptic diagram of the fresh and alive boiling water electric heater of formula weakly alkaline.
Embodiment
Be listed as to illustrate advantage and disadvantage of the present invention below in conjunction with implementation.
At first determine function and the effectiveness of the each component among the present invention.
Among the present invention, tourmalinite, medical stone and intermetallic compound are main ingredients of the present invention, wherein:
Tourmalinite is that a kind of boracic is the cyclosilicate crystal mineral of aluminium, sodium, iron, calcium and the magnesium of feature, and its chemical structure of general formula can be expressed as XY
3Z
6Si
6O
18(BO3)
3W
4, wherein, X=Na, Ca, K or room; Y=Mg, Fe, Mn, Al or Li; Z=Al, Fe, Cr or Mg; W=OH, F or O.Tourmalinite is a kind of permanent electric polarity that both had, and has again emitting far-infrared mineral material, and there is up to 10 the tourmalinite surface in the permanent electric polarity of tourmalinite in thickness is tens microns scope
7The strength of electric field of V/M can make the water molecules electrolysis water be weakly alkaline, thereby improves the interfacial activity of water, strengthens seepage force and the solvency power of water.Tourmalinite at normal temperatures emission wavelength is 4-14um, transmitting frequency is at the far infrared rays more than 0.9, tourmalinite has higher infrared emissing ability in the infrared signature absorption region of water, satisfy the radiation peak band principle consistent with the absorption peak band of infrared absorption material of ir radiation material, the bond energy of hydrogen bond is 29-42KJ/mol between the water molecules, is equivalent to the photon energy that the infrared region wavelength is 2.7-4.1um.Therefore, the far infrared rays of tourmalinite radiation has enough energy and interrupts hydrogen bond in the water.When the infrared ray action of tourmalinite radiation during in water, the absorbing wavelength of ultrared wavelength and water is corresponding, produces resonance absorption, thereby the severed segment hydrogen bond so the surface tension of water reduces, diminishes water molecule cluster and obtains activation.
Medical stone is a kind of natural medicine ore, contains 18 kinds of trace elements such as the necessary potassium of human body, sodium, calcium, magnesium, phosphorus major element and zinc, iron, selenium, copper, strontium, iodine, fluorine, metasilicic acid.With medical stone process water can make water become band+,-electric atomic group many water.Medical stone energy planar water middle reaches ion, medical stone is behind water, leachable to trace elements such as human body and organism useful major element K, Ca, Mg and Si, Fe, Zn, Cu, Mo, Se, Mn, Sr, Ni, V, Li, Co, Cr, I, Ge, Ti, enrich the trace element in the water.
Intermetallic compound Main Function among the present invention has 2 points, and the one, it is oxidized to prevent that the active-energy porcelain is present in the metal of active-energy porcelain inside when high temperature sintering, thereby its conducting function was not lost efficacy, and keeps the various features of active-energy porcelain constant; The 2nd, intermetallic compound also can cause electrolytic surface from polarity charge with what the tourmalinite deep layer produced, strengthens electrolytic effect and the activating effect of water molecules.
The molecular formula of calcium sulfite is CaSO
31/2H
2O is colourless six reef knot crystalline substance or white powders.Density is 1.595g/cm
3, formula weight was 120 (not containing crystal water), lost crystal water at 360 ~ 390 ℃.Calcium sulfite is mainly used in removing the chlorine residue in the water body, comprises combined residual chlorine NH
2Cl, NHCl
2And NCl
3Three kinds and free residual chlorine ClO-(hypochlorite ion), HClO(hypochlorous acid), Cl
2(chlorine) etc.Compare, the not advantage such as breed bacteria efficient, safe, high temperature resistant except chlorine residue has with calcium sulfite except chlorine residue with traditional gac.
Borosilicate glass can play on the one hand the carrier as other composition, and it can also slowly-releasing part borosilicate acids and the similar compound of tourmalinite on the other hand, and the compound of this class boracic plays a very important role to the normal physiological function tool of keeping human body.It is to keep one of the health of bone and calcium, phosphorus, the needed trace element of magnesium eubolism.Boron also is improved brain function, improves the effect of response capacity.
Various component of the present invention is except borosilicate glass, and other component all can buied on the market.Among following each embodiment, the granularity of described raw material all between the 300-1000 order, is the powder shape.
Embodiment one (borosilicate glass, weight percent, lower same)
Silicon-dioxide 70%; Boron trioxide 1%;
Potassium oxide 0.5%; Calcium oxide 0.3%.
Embodiment two (borosilicate glass)
Silicon-dioxide 85%; Boron trioxide 15%;
Potassium oxide 2%; Calcium oxide 1%.
Embodiment three (borosilicate glass)
Silicon-dioxide 95%; Boron trioxide 25%;
Potassium oxide 3%; Calcium oxide 2%.
Above-described embodiment one to embodiment three behind the prescription, is processed by the making of borosilicate glass powder shown in Figure 1 in proportion, can obtain borosilicate glass.Specifically, the preparation of borosilicate glass powder comprises the steps:
(11), the borosilicate glass preparation of raw material, in the ratio weighing each component of any one prescription among the embodiment one to embodiment three;
(12), ball mill mixing, with ball mill various components are mixed;
(13), high temperature melting, in 1500-1700 degree centigrade situation, with the fusing of mixed raw material;
(14), water granulation, will melt after borosilicate glass become wire to insert in the water, make borosilicate glass liquid in water, be cooled to the glass grain;
(15), pull the glass grain out, under 100-120 degree centigrade temperature, with the moisture content oven dry of glass grain surface;
(16), the ball grinds, the glass grain after the oven dry is added in the ball mill, ball milling is for subsequent use to the 300-1000 order.
Embodiment four (the active-energy porcelain, weight percent, lower same)
Tourmaline powder 10%; Medical stone powder 10%; Intermetallic compound powder 1%;
Sulfurous acid calcium powder 1%; Borosilicate glass powder 20%.
Embodiment five (active-energy porcelain, weight percent)
Sulfurous acid calcium powder 10%; Borosilicate glass powder 30%.
Embodiment six (active-energy porcelain, weight percent)
Tourmaline powder 50%; Medical stone powder 30%; Intermetallic compound powder 10%;
Sulfurous acid calcium powder 15%; Borosilicate glass powder 40%.
Above-described embodiment four to embodiment six behind the prescription, is processed by the making of borosilicate glass powder shown in Figure 2 in proportion, can obtain borosilicate glass.Specifically, active-energy porcelain making method is as follows:
(21) batch mixing is pressed tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%; Sulfurous acid calcium powder 1-15%; After the described ratio weighing of borosilicate glass powder 20-40%, put into container and fully mix;
(22) granulation with the well-mixed mixture of the first step, is inserted in the tablets press, adds by weight the water-soluble binder of 10-20%, makes mobile spheroidal particle powder, and described water-soluble binder is the aqueous solution that contains the 2-3% polyvinyl alcohol;
(23) dry-pressing formed, mobile spheroidal particle powder is inserted in the mould, strike out predetermined shape;
(24) low temperature binder removal under 300-400 degree centigrade temperature, carries out the low temperature binder removal;
(25) low-temperature sintering, under aerobic environment, 600-800 degree centigrade temperature is incubated 1-2 hour;
(26); After the cooling, be the active-energy porcelain.
Intermetallic compound powder is boron series intermetallic compound powder described in above-described embodiment four to embodiment six.
Described boron series intermetallic compound powder is the intermetallic compound powders such as lanthanum boride, aluminum boride, FeB, chromium boride, nickel borides, boron copper or titanium boride.
Among the present invention, the making method of described intermetallic compound powder is: with intermetallic compound under nitrogen or oxygen-free atmosphere, be heated to intermetallic compound and be fused into liquid, will be fused into liquid intermetallic compound with high pressure nitrogen again and spray into powder, cool off for subsequent use.
See also Fig. 3, shown in Figure 3 is the fresh and alive boiling water electric heater of formula weakly alkaline that boils a kind of second, comprise heater body 100, described heater body 100 comprises that interior tail band has the electricradiator base plate 110 of electric heating film, water flow passage device 120 and electricradiator cover plate 130, described electricradiator base plate 110 is to be stamped to form with 430 stainless steel plates, outer side at described electricradiator base plate 110 is provided with electric heating film, after the energising, the water heating of described electric heating film heating in can the runner of feedwater flow road device 120, inboard and described electricradiator cover plate 130 that described water flow passage device 120 is positioned at described electricradiator base plate 110 fasten the rear accommodation space that forms, in the water flow passage of described water flow passage device 120, be provided with for the active-energy ceramic products 140(present embodiment that purifies water, the active-energy ceramic products that described active-energy ceramic products 140 is sheets, certainly, also can do as required spherical, or the active-energy ceramic products of Else Rule geometrical shape), be provided with projection 141 on the surface of active-energy ceramic products 140, with the contact area of increase with water, reach the purpose of processing better water.Described active-energy ceramic products 140 is comprised of the material of following weight (WT) per-cent:
Tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%;
Sulfurous acid calcium powder 1-15%; Borosilicate glass powder 20-40%;
Wherein, the components in weight percent of described borosilicate glass powder is: silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; Calcium oxide 0.3-2%.
Specifically, active-energy ceramic products 140 can be by the made sheet active-energy ceramic products 140 in the assembly side among the embodiment four to embodiment six, through test, employing active-energy ceramic products 140 cooperates with hot water, it processes the better effects if of water, especially greatly refinement water molecule cluster, mouthfeel is better.
Among the present invention, described active-energy ceramic products 140 can Kai Defei filtrate in the container that water can pass through replaces with being arranged on, perhaps part active-energy ceramic products 140 replaced by the Kai Defei filtrate as, one or more pieces active-energy ceramic products 140 are wherein replaced by the Kai Defei filtrate.Described Kai Defei filtrate can be packaged in being permitted in lacunary can, such as stainless steel box; Also may be packaged in two ends with in the pipeline of filter plate etc., the processed water of wish is through can or pipeline the time, and water is then processed by the Kai Defei filtrate.
(english abbreviation is KDF owing to the Kai Defei filtrate, together lower) be a kind of novel, multi-functional, reproducible copper zinc alloy material for water treatment, it is by DonHeskett professor (U.S.) invention in 1984, and has passed through the water conditioning material of the authentication of the mechanisms such as national sanitary foundation international (NSF), water quality association (WQA).The Kai Defei filtrate is compared with traditional filtrate, and it has long service life, can 100% recovers filtration capacity, can effectively reduce or remove chlorine in the water and heavy metal, control microorganism;
Specifically, the Kai Defei filtrate has following function, and (1) removes strong oxidizer (chlorine residue), and the Kai Defei filtrate has powerful reducing power, can remove the various strong oxidizers in the water, and is effective especially to chlorine residue.The Kai Defei filtrate is comprised of copper, two kinds of different metals of zinc, and when contacting with water, the positive copper of current potential becomes negative electrode in the alloy, and the negative zinc of current potential is anode, consists of galvanic cell.Zinc anode has lost electronics in reaction, generate zine ion and enter solution, the reduction reaction of free chlorine occurs on the cathode, and the dissolving of metallic copper can not occur, water and chlorine residue become last electronics recipient, it is as follows to generate simultaneously hydrogen ion, hydroxide ion and chlorion net reaction: Zn+HOCl+H2O+2e-Zn2++Cl-+H++2OH-, other oxygenant in the water, as ozone, bromine, iodine etc. with also similar redox reaction can occur after the Kai Defei filtrate contacts.(2) removal heavy metal, the Kai Defei filtrate can be removed the contents of many kinds of heavy metal ion in the water, such as lead, mercury, copper, nickel, cadmium, arsenic, antimony, aluminium and other many soluble heavy metal ions, their removal is finished by replacement(metathesis)reaction and physics and chemistry absorption reaction.The mechanism of Kai Defei filtrate heavy-metal ion removal is as follows: adsorption of metal ions is in the surface of Kai Defei filtrate, and with the Kai Defei filtrate in zinc generation replacement(metathesis)reaction, the metal that generates or be adsorbed on the Kai Defei filter material surface, or enter in the Kai Defei filtrate lattice, thereby the toxic heavy metal pollutent is combined on the Kai Defei filtrate.For example, the lead ion that dissolves in the water is reduced into insoluble lead atom, and is adsorbed in the surface of Kai Defei filtrate, and similar reaction also occurs for mercury ion and Kai Defei filtrate, and X-ray diffraction studies finds that the removal of mercury is to have formed copper-mercury alloys.The chemical equation of Kai Defei filtrate processing heavy metal ion is as follows: Zn/Cu/Zn+Pb2+ → Zn/Cu/Pb+Zn2+ Zn/Cu/Zn+Hg2+ → Zn/Cu/Hg+Zn2+, hydrolysis formed precipitate metal hydroxides when metal ion raise at the PH of water, also can remove metal ion.(3) remove hydrogen sulfide, when applying membrane carries out water treatment, make the water source if select underground water, may have hydrogen sulfide in the water, hydrogen sulfide will pollute the filter membrane surface as being oxidized to sulphur, and the Kai Defei filtrate has the function of removing hydrogen sulfide, the cupric sulfide that generates is water insoluble, can remove when the back flushing of Kai Defei filtrate, chemical equation is as follows: Cu/Zn+H2S → Cu/Zn+CuS+H2,2H2+02 → 2H20; (4) reduce suspended solids, the particle mean size of Kai Defei filtrate is approximately 60 orders, and minimum about 110 orders of particle also can play the effect that physical filtering is removed suspended matter, and the Kai Defei filtrate can be removed diameter effectively less than the particle to 50 μ m usually.During the water delivery pipe fitting corrosion of being made by ferrous materials, the iron oxidation forms the FeO colloid, FeO contacts with the Kai Defei filtrate, also redox reaction can occur, FeO finally forms the Fe2O3 solid precipitation at the Kai Defei filter material surface, available back-flushing method is removed them, and chemical equation is as follows: Zn+FeO=ZnO+Fe, 2Fe+3O2=2Fe2O3; (5) reduce the mineral substance fouling, the Kai Defei filtrate has aspect on two to the effect of calcium carbonate scale.On the one hand, according to the relation between PH, gas concentration lwevel and the dissolution of calcium carbonate degree, when carbonic acid gas was removed from solution, pH value raise, thereby the solubleness of calcium carbonate is reduced.The Kai Defei filtrate also makes the pH value of water raise by electrochemical reaction, reduces the solubleness of calcium carbonate, and the result separates out calcium carbonate scale easily.On the other hand, because the stripping of zine ion in the Kai Defei filtrate, zinc ion content in the water increases to some extent, the existence of zine ion can change the mechanism of crystal growth of dirt in the water, make the calcium carbonate scale in the water produce precipitation with the crystal habit of aragonite, wall at container forms soft dirt, rather than crystallization is the hard scale of calcite type.Once the someone studied impurity in the water and had impact on the calcite crystalline growth, and research is found, even when the concentration of zine ion is very low, also can be stoped the formation of calcite crystallization.Can prove further that by test the Kai Defei filtrate prevents formation and the accumulation of mineral hard scale, mainly be the crystallization that stops calcite form calcium carbonate.Adopting scanning electronic microscope and X-ray diffraction to carry out crystallography studies have shown that, the hard scale that produces in the water without the processing of Kai Defei filtrate is that some are relatively large, have the needle-like calcium salt of conformation of rules and the crystallization of magnesium salts, these salt quality are hard, solubleness is low, has reticulated structure, it is glass Wingdale dirt, through the dirt of forming in the Kai Defei filtrate treated water, fundamentally changed the form of calcium carbonate (magnesium) crystallization, dirt shape diminishes relatively, outward appearance is smooth rounded, granulated and clavate, all be to be become to be grouped into by not hard powdery, these compositions can not adhere to metal, the surface of plastics or pottery is easy to the physical filtering method they be removed.(6) suppress microbial reproduction, the Kai Defei filtrate is not by a kind of mechanism but the breeding of several mechanism microbial growth, reaches the effect that suppresses microorganism by each independent role or synergy.Dominant mechanism comprises: the variation of redox potential, the formation of hydroxide ion and hydrogen peroxide, stripping of zinc etc. in the medium.In the ordinary course of things, the Kai Defei filtrate is during as the preprocessing means of reverse osmosis membrane, can anti-bacteria, the breeding of the microorganism such as algae, thus prevented the destruction of microorganism to film.The variation of redox potential, when water passes through the Kai Defei filtrate, its redox potential changes to-500mV from+200mV, in the ordinary course of things, various types of microorganisms can only grow under specific redox potential, the significant variation of current potential can destroy the cell of bacterium, thereby has controlled microbial growth.But, the redox potential of water changes very little, with Kai Defei filtrate control bacterium, bacterium is directly contacted with the Kai Defei filtrate, the Kai Defei filtrate mainly betides on Kai Defei filtrate and the water engaging surface the restraining effect of bacterium, so only depend on the variation of redox potential can not control microorganism fully.Hydroxide ion and hydrogen peroxide, at the Kai Defei filtrate oxidation of divalent can be produced hydroxide ion and hydrogen peroxide in ferric process, this just can suppress those and can survive in suboxide current potential fashion, but the microorganism to hydrogen ion and hydrogen peroxide sensitivity, but the life-span of hydroxide ion and hydrogen peroxide is short, just have high reactive behavior in filtration procedure, apparent in view to the inhibition of microorganism, the residual effect in flowing out water is smaller.Zine ion is to the control of microorganism, and the zinc that discharges in the Kai Defei filtrate has obvious control action kou to microorganism, and zinc can stop Enzyme Production, thereby affects organic normal growth, reaches the purpose that suppresses microbial reproduction.In addition, the Kai Defei filtrate is by stoping the synthetic algal grown of controlling of chlorophyll, and the existence of zine ion is from having reduced in essence the ability that organism is produced food from photosynthesis, and this is with the growth of remarkably influenced bacterium.
Claims (10)
1. an active-energy porcelain is characterized in that, described active-energy porcelain is comprised of the material of following weight (WT) per-cent:
Tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%;
Sulfurous acid calcium powder 1-15%; Borosilicate glass powder 20-40%;
Wherein, the components in weight percent of described borosilicate glass powder is: silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; Calcium oxide 0.3-2%.
2. active-energy porcelain according to claim 1 is characterized in that:
Described intermetallic compound powder is boron series intermetallic compound powder.
3. the manufacture method of an active-energy porcelain is characterized in that: comprise as follows,
One, the preparation of borosilicate glass powder
(11), the borosilicate glass preparation of raw material, press silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; The part by weight weighing each component of calcium oxide 0.3-2%;
(12), ball mill mixing, with ball mill various components are mixed;
(13), high temperature melting, in 1500-1700 degree centigrade temperature range, with the fusing of mixed raw material;
(14), water granulation, will melt after borosilicate glass become wire to insert in the water, make borosilicate glass liquid in water, be cooled to the glass grain;
(15), pull the glass grain out, under 100-120 degree centigrade temperature, with the moisture content oven dry of glass grain surface;
(16), the ball grinds, the glass grain after the oven dry is added in the ball mill, ball milling is for subsequent use to the 300-1000 order;
Two, the active-energy porcelain is made
(21) batch mixing is pressed tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%; Sulfurous acid calcium powder 1-15%; After the described part by weight weighing of borosilicate glass powder 20-40%, put into container and fully mix;
(22) granulation with the well-mixed mixture of the first step, is inserted in the tablets press, adds by weight the water-soluble binder of 10-20%, makes mobile spheroidal particle powder, and described water-soluble binder is the aqueous solution that contains the 2-3% polyvinyl alcohol;
(23) dry-pressing formed, mobile spheroidal particle powder is inserted in the mould, strike out predetermined shape;
(24) low temperature binder removal under 300-400 degree centigrade temperature, carries out the low temperature binder removal;
(25) oxidizing atmosphere sintering, under aerobic environment, 600-800 degree centigrade temperature is incubated 1-2 hour;
(26); After the cooling, be the active-energy porcelain.
4. the manufacture method of active-energy porcelain according to claim 3, it is characterized in that: described predetermined shape is sheet, spherical or Else Rule geometrical shape.
5. the manufacture method of active-energy porcelain according to claim 3; it is characterized in that: the making method that also comprises intermetallic compound powder; with intermetallic compound under the protection of nitrogen; be heated to intermetallic compound and be fused into liquid; with high pressure nitrogen compound between the liquid metal of fusing is sprayed into powder again, cool off for subsequent use.
6. the fresh and alive boiling water electric heater of formula weakly alkaline boils a second, comprise heater body, it is characterized in that: be provided with the active-energy ceramic products in the hot water flux of described heater body, described active-energy ceramic products is comprised of the material of following weight (WT) per-cent:
Tourmaline powder 10-50%; Medical stone powder 10-30%; Intermetallic compound powder 1-10%;
Sulfurous acid calcium powder 1-15%; Borosilicate glass powder 20-40%;
Wherein, the components in weight percent of described borosilicate glass powder is: silicon-dioxide 70-95%; Boron trioxide 1-25%; Potassium oxide 0.5-3%; Calcium oxide 0.3-2%.
7. the fresh and alive boiling water electric heater of formula weakly alkaline boils second according to claim 6, it is characterized in that: described heater body comprises that the outside is with the electricradiator base plate of electric heating film, water flow passage device and electricradiator cover plate, described water flow passage device is positioned at described electricradiator base plate and described electricradiator cover plate fastens the rear accommodation space that forms, and is provided with in the water flow passage of described water flow passage device be used to the active-energy ceramic products that purifies water.
8. according to claim 6 or the fresh and alive boiling water electric heater of formula weakly alkaline that boils for 7 described seconds, it is characterized in that: described intermetallic compound powder is boron series intermetallic compound powder.
9. according to claim 6 or the fresh and alive boiling water electric heater of formula weakly alkaline that boils for 7 described seconds, it is characterized in that: the shape of described active-energy ceramic products is sheet, spherical or Else Rule geometrical shape.
10. according to claim 6 or the fresh and alive boiling water electric heater of formula weakly alkaline that boils for 7 described seconds, it is characterized in that: also be provided with the Kai Defei filtrate in the hot water flux of described heater body, described Kai Defei filtrate is established and is contained in the container that water can pass through.
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| CN201210532507.2A CN103044015B (en) | 2012-09-25 | 2012-12-12 | Active energy porcelain, preparation method and second-boiling type slightly alkaline fresh boiled water electric heater |
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| CN 201210360235 CN102863206A (en) | 2012-09-25 | 2012-09-25 | Active energy ceramic and manufacturing method thereof and second boiling type electric alkalescent fresh water heater |
| CN201210360235.2 | 2012-09-25 | ||
| CN201210532507.2A CN103044015B (en) | 2012-09-25 | 2012-12-12 | Active energy porcelain, preparation method and second-boiling type slightly alkaline fresh boiled water electric heater |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1600740A (en) * | 2004-09-18 | 2005-03-30 | 孙吉春 | Artware of basalt and preparation method |
| CN101088921A (en) * | 2007-06-30 | 2007-12-19 | 周衍贵 | Water purifier |
| CN102503363A (en) * | 2011-10-27 | 2012-06-20 | 温州磊石康保健用品有限公司 | Health-care medical stone ceramic material and application thereof |
-
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- 2012-09-25 CN CN 201210360235 patent/CN102863206A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1600740A (en) * | 2004-09-18 | 2005-03-30 | 孙吉春 | Artware of basalt and preparation method |
| CN101088921A (en) * | 2007-06-30 | 2007-12-19 | 周衍贵 | Water purifier |
| CN102503363A (en) * | 2011-10-27 | 2012-06-20 | 温州磊石康保健用品有限公司 | Health-care medical stone ceramic material and application thereof |
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| CN102863206A (en) | 2013-01-09 |
| CN103044015B (en) | 2014-04-16 |
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