CN103039496B - Pesticide composition, pesticide and application thereof - Google Patents

Pesticide composition, pesticide and application thereof Download PDF

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Publication number
CN103039496B
CN103039496B CN201210585590.XA CN201210585590A CN103039496B CN 103039496 B CN103039496 B CN 103039496B CN 201210585590 A CN201210585590 A CN 201210585590A CN 103039496 B CN103039496 B CN 103039496B
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agent
carboxin
diacloden
tmtd
weight
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CN103039496A (en
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刘世禄
徐妍
潘静
罗湘仁
陶婧
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Jiangsu Mingde Rieter crop Technology Co. Ltd.
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BEIJING MINDLEADER AGROSCIENCE Co Ltd
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Abstract

The invention relates to a pesticide composition, which contains active ingredients and is characterized in that the active ingredients comprise thiamethoxam, carboxin and thiram in weight ratio of 1 to (0.01-90) to (0.01-90). The invention further relates to pesticide prepared from the pesticide composition and application of the pesticide in prevention and treatment of plant disease and insect pests. The pesticide composition has effect enhancing function and can improve the prevention and treatment effect as compared with the thiamethoxam, the carboxin and the thiram in single ingredient; and moreover, the pesticide composition can prevent and treat various plant diseases and insect pests occurring synchronously, thereby lowering the pesticide dosage, saving the cost and reducing pollution of the environment.

Description

A kind of composition pesticide and agricultural chemicals and application thereof
Technical field
The present invention relates to a kind of composition pesticide and agricultural chemicals and application thereof, particularly, relate to a kind of composition pesticide containing Diacloden, carboxin and tmtd, and agricultural chemicals prepared by this composition pesticide and the application of this agricultural chemicals in control plant pest.
Background technology
The problem that the mixing of dissimilar disease and insect occurs usually is there is in agricultural production practice, leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, damping off, bakanae disease, rotten kind are the damage by disease and insect often existing simultaneously or in succession exist, such as, on the crops such as corn, peanut, cotton, wheat and paddy rice.
Above-mentioned common disease and pest is often needed to adopt different agricultural chemicals to prevent and treat respectively, such as, leafhopper generally adopts Rogor to prevent and treat, aphid generally adopts decis or carbosulfan to prevent and treat, plant hopper generally adopts Diacloden to prevent and treat, wireworm generally adopts phoxim or carbofuran to prevent and treat, cutworm generally adopts chlopyrifos or phoxim to prevent and treat, grub generally adopts chlopyrifos to prevent and treat, root rot generally adopts carbendazim or tpn to prevent and treat, stem rot generally adopts tmtd to prevent and treat, smut generally adopts Tebuconazole to prevent and treat, damping off generally adopts carboxin to prevent and treat, bakanae disease generally adopts the mould spirit of evil to prevent and treat, rotten kind generally adopts Prochloraz to prevent and treat.
The current extermination of disease and insect pest not only control efficiency is poor, and for various disease, insect, also will use different agricultural chemicals, and the human and material resources of at substantial and financial resources cost, also can cause the pollution of environment.
Summary of the invention
The object of the invention is the above-mentioned defect overcoming prior art, provide a kind of control efficiency good, the composition pesticide and agricultural chemicals and application thereof that mix the multiple variety classes damage by disease and insect occurred can be prevented and treated.
The present inventor surprisingly finds under study for action, when the active component of composition pesticide contains Diacloden, carboxin and tmtd, and Diacloden, when the weight ratio of carboxin and tmtd is 1:0.01-90:0.01-90, particularly work as Diacloden, the weight ratio of carboxin and tmtd is 1:0.1-10:0.1-10, more preferably, Diacloden, when the weight ratio of carboxin and tmtd is 1:0.3-1.5:0.3-1.5, composition pesticide is relative to oligomict Diacloden, carboxin or tmtd, there is synergistic effect, control efficiency is good, and multiple different types of damage by disease and insect of mixing generation can be prevented and treated.
Therefore, to achieve these goals, on the one hand, the invention provides a kind of composition pesticide, described composition contains active component, it is characterized in that, described active component contains Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90.
Preferably, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10, and more preferably, the weight ratio of Diacloden, carboxin and tmtd is 1:0.3-1.5:0.3-1.5.
On the other hand, the invention provides the agricultural chemicals prepared by composition pesticide as above, wherein, the formulation of described agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
The third aspect, the invention provides the application in agricultural chemicals as above one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and rotten kind.
Composition pesticide of the present invention, relative to oligomict Diacloden, carboxin or tmtd, has synergistic effect, can improve control efficiency; Multiple different types of plant pest that mixing occurs can be prevented and treated, thus can dosage be reduced, cost-saving, alleviate the pollution to environment.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of composition pesticide, said composition contains active component, and active component contains Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90.
In the present invention, the chemical name of Diacloden is 3-(the chloro-1,3-thiazoles of 2--5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine.
In the present invention, the chemical name of carboxin is 5,6-dihydro-2-Methyl-N-phenyl-Isosorbide-5-Nitrae-oxathiene-3-formamide.
In the present invention, the chemical name of tmtd is two (dimethylthiocarbamoyl) two sulphur thing.
According to the present invention, although the active component of composition pesticide contains Diacloden, carboxin and tmtd, the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90, can realize object of the present invention, namely composition pesticide has synergistic effect, and control efficiency is good; Multiple different types of plant pest that mixing occurs can be prevented and treated.But under preferable case, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10, more preferably 1:0.3-1.5:0.3-1.5, the synergistic effect of composition pesticide is more remarkable, can further improve control efficiency.
In the present invention, for the total content of active component in composition pesticide without particular/special requirement, conventional consumption can be selected according to the different dosage form of composition pesticide preparation, this is conventionally known to one of skill in the art, such as, based on the gross weight of composition pesticide, the content of active component is 1-95 % by weight.
In the present invention, for other composition in addition to the active ingredient (s in composition pesticide without particular/special requirement, the composition that this area is conventional can be matched as required, such as, dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and solid inert carrier.Therefore, composition pesticide of the present invention is also containing one or more in dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and solid inert carrier.These compositions can according to the consumption of the dosage form selection routine of composition pesticide preparation, and this is conventionally known to one of skill in the art, does not repeat them here.
In the present invention, for mentioned component all without particular/special requirement, the material that this area is conventional can be adopted, such as:
Dispersant and wetting agent can for polyvinylpyrrolidone, maleic acid-acrylic acid copolymer sodium salt, sodium methylene bis-naphthalene sulfonate, sodium lignin sulfonate, calcium lignosulfonate, calcium dodecyl benzene sulfonate, succinate sodium sulfonate, pull open in powder, sldium lauryl sulfate, sodium alkyl sulfonate, lauryl sodium sulfate, polyoxyethylene nonylphenol ether and fatty alcohol-polyoxyethylene ether one or more.
Antifreezing agent can be one or more in ethylene glycol, 1,2-PD, glycerine and urea.
Film forming agent can be gum Arabic, animal glue, methylcellulose, ethyl cellulose, sodium cellulose glycolate, polyvinyl alcohol, polyethylene glycol, polyacrylamide, Sodium Polyacrylate and one or more all in polyvinyl acetate, is preferably the mixture of polyvinyl alcohol and equal polyvinyl acetate.
Binding agent can be one or more in starch, gypsum, glucose, polyvinyl alcohol, gum Arabic and dextrin.
Thickener can be one or more in Magnesiumaluminumsilicate, xanthans, polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose and phenolic resins.
Solid inert carrier can be one or more in clay, silica, diatomite, kaolin, attapulgite, imvite, bentonite, talcum powder and precipitated calcium carbonate.
The material that stabilizing agent, preservative and colouring agent also adopt this area conventional, this is conventionally known to one of skill in the art, does not repeat them here.
Composition pesticide of the present invention can provide with final product form, and namely in composition, each composition mixes; Also can provide with the form of independent preparation by often kind of composition, directly carry out bucket during use and mix.
On the other hand, present invention also offers the agricultural chemicals prepared by composition pesticide as above, wherein, the formulation of agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
In the present invention, consider from the angle of Pesticide use method, the formulation of agricultural chemicals is preferably suspension seed-coating agent.
In above-mentioned each formulation, the content of other composition in addition to the active ingredient (s and content and active component is without particular/special requirement, can adopt the proportioning of this area routine, such as:
Aqueous suspension agent contains 5-70 % by weight active component, 0.5-12 % by weight dispersant, 0.5-5 % by weight wetting agent, 0.1-10 % by weight antifreezing agent, other additive of 0-10 % by weight usually as stabilizing agent, preservative, thickener, and surplus is water.Suspending agent usually need wet pulverizing with obtain stable, can flow, the suspension liquid of easy measurement volumes.
Suspension seed-coating agent is usually containing 5-70 % by weight active component, 0.5-12 % by weight dispersant, 0.5-5 % by weight wetting agent, 0.1-10 % by weight antifreezing agent, 0.5-10 % by weight film forming agent, 0.5-5% warning colouration, other additive of 0-10 % by weight is as stabilizing agent, preservative, thickener, and surplus is water.
Wetting powder contains 3-95 % by weight active component, 0.5-10 % by weight dispersant, 0.5-5 % by weight wetting agent, other additive of 0-10 % by weight usually as stabilizing agent etc., and surplus is solid inert carrier, as kaolin etc.
Water dispersible granules contains 3-95 % by weight active component, 0.5-10 % by weight dispersant, 0.5-5 % by weight wetting agent, other additive of 0-10 % by weight usually as stabilizing agent, adhesive, and surplus is solid inert carrier, as kaolin etc.Water dispersible granules makes 10-100 order international standard sieve mesh (1676-152 μm) particle usually, by method preparations such as mist projection granulating, extruder grain, High Rotation Speed granulation, fluidized bed prillings.
In the present invention, for the preparation method of various formulation without particular/special requirement, various method well known in the art can be adopted, do not repeat them here.
It will be understood by those skilled in the art that the various formulations in the present invention can dilute use according to actual needs when reality uses.
The third aspect, the invention provides the application in agricultural chemicals as above one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and rotten kind.
In the present invention, above-mentioned damage by disease and insect all has generation in various crop.Such as, on the crops such as corn, peanut, cotton, wheat and paddy rice.
In the present invention, the method that agricultural chemicals can adopt this area conventional uses, and such as, directly spreads fertilizer over the fields and uses in field, or carry out field spray use after dilution, or carry out seed treatment.The angle high from agricultural chemicals availability is considered, uses the method for agricultural chemicals preferably to carry out seed treatment with agricultural chemicals.Seed treatment comprises dressing or seed dressing.
Embodiment
The present invention is further illustrated for following embodiment, but therefore do not limit the present invention.
Embodiment 135% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that namely 3:2:2(is about 1:0.67:0.67))
Diacloden 15 % by weight, carboxin 10 % by weight, tmtd 10 % by weight, maleic acid-acrylic acid copolymer sodium salt 3 % by weight, pull open powder 2 % by weight, xanthans 0.3 % by weight, aluminium-magnesium silicate 0.5 % by weight, silicone defoaming agent 0.2 % by weight, polyvinyl alcohol 0.5%, equal polyvinyl acetate 0.5%, acid scarlet 1.0%, water is added into 100 % by weight.
Embodiment 235% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is 1:0.375:0.375)
Diacloden 20 % by weight, carboxin 7.5 % by weight, tmtd 7.5 % by weight, all the other components and content are with embodiment 1.
Embodiment 335% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that namely 9:13:13(is about 1:1.44:1.44))
Diacloden 9 % by weight, carboxin 13 % by weight, tmtd 13 % by weight, all the other components and content are with embodiment 1.
Embodiment 435% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that namely 29:3:3(is about 1:0.103:0.103))
Diacloden 29 % by weight, carboxin 3 % by weight, tmtd 3 % by weight, all the other components and content are with embodiment 1.
Embodiment 535% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is 1:8.25:8.25)
Diacloden 2 % by weight, carboxin 16.5 % by weight, tmtd 16.5 % by weight, all the other components and content are with embodiment 1.
Embodiment 635% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that namely 68:1:1(is about 1:0.015:0.015))
Diacloden 34 % by weight, carboxin 0.5 % by weight, tmtd 0.5 % by weight, all the other components and content are with embodiment 1.
(weight ratio of Diacloden, carboxin and tmtd is 1:87:87 to embodiment 735% Diacloden carboxin tmtd suspension seed-coating agent
Diacloden 0.2 % by weight, carboxin 17.4 % by weight, tmtd 17.4 % by weight, all the other components and content are with embodiment 1.
Comparative example 135% Diacloden suspension seed-coating agent
According to the formula of embodiment 7, unlike, Diacloden, carboxin, tmtd are all substituted with Diacloden.
Comparative example 235% carboxin suspension seed-coating agent
According to the formula of embodiment 7, unlike, Diacloden, carboxin, tmtd are all substituted with carboxin.
Comparative example 335% tmtd suspension seed-coating agent
According to the formula of embodiment 7, unlike, Diacloden, carboxin, tmtd are all substituted with tmtd.
Test case 1
Test site: big dragon village of Hepu County four crossway township, soil belongs to pool tide sandy soil, in fertility, each treatment region peanut production management routinely after plantation.Peanut varieties is sweet osmanthus No. 21.
Adopt the seed coat agent of embodiment 1-7 and comparative example 1-3 to carry out Cotton seeds to peanut respectively, and establish one group of blank (namely not carrying out Cotton seeds to peanut), the consumption of often kind of seed coat agent is 150g/100kg seed.Fully shake up after respectively above-mentioned seed coat agent being watered dilution 50%.With plastic sack contained selected after seed, dilute liquid medicine is poured on seed and rocks fast, until liquid to be evenly distributed on seed (judging according to color), then cool open for subsequent use.On May 1st, 2012 is sowed, flat kind, line-spacing 33cm, pier distance 20cm, every mu of 10,000 piers, the two grain sowing of every pier.The investigation statistics method of peanut damage by disease and insect is as follows:
In the control efficiency of investigation on June 30 peanut cutworm, wireworm, grub, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, often 4 caves, amounts to 20 caves.Shoveling sampling survey borer population alive during investigation, digging depth, to 30cm, calculates vermins-proof effect (control efficiency) according to formula (I).
In the control efficiency of investigation on June 1 peanut aphid, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, often 4 strains, and the aphid head number on investigation peanut leaf, according to above-mentioned formulae discovery vermins-proof effect.
In investigation on June 30 Roots of Peanut maize ear rot, stem rot, rust, leaf blight control efficiency, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, and 30 strains are investigated in each process community, investigate diseased plant rate and the disease index of each treatment region root rot in seedling stage, calculate control efficiency according to formula (II) and formula (III).
Root rot severity Scaling index: 0 grade: all without scab on stem foot and main fibrous root; 1 grade: stem foot and main root have a small amount of scab; 3 grades: on stem foot and main root, scab is more, and lesion area accounts for the 1/4-1/2 of stem foot and the root gross area; 5 grades: on stem foot and main root, scab is many and large, and lesion area accounts for the 1/2-3/4 of stem foot and the root gross area; 7 grades: on stem foot and main root, scab in flakes, formed around neck phenomenon, but root system is not dead; 9 grades: root system is downright bad, plant above ground portion wilts or death.
Stem rot, rust, leaf blight state of an illness statistics is with reference to " pesticide field efficacy medicine test criterion ".
Peanut extermination of disease and insect pest effect is as shown in table 1.
Table 1
Test case 2
Test site: Bai Miao village of Ge Bukou township, Yuanyang County, Henan Province.This plot physical features is smooth, and two close soil, fertility uniformity, and water retention property is good, and irrigation and drainage are convenient.Each treatment region wheat production management routinely after plantation.Wheat breed is new wheat 18.
Adopt the seed coat agent of embodiment 1-7 and comparative example 1-3 to carry out Cotton seeds to wheat respectively, and establish one group of blank (namely not carrying out Cotton seeds to wheat), the consumption of often kind of seed coat agent is 200g/100kg seed.Fully shake up after respectively above-mentioned seed coat agent being watered dilution 50%.With plastic sack contained selected after seed, dilute liquid medicine is poured on seed and rocks fast, until liquid to be evenly distributed on seed (judging according to color), then cool open for subsequent use.On October 20th, 2011 is sowed, and adopt the line-spacing sowings such as artificial sowing machine, line-spacing is 20cm, the amount of broadcasting 15kg/ mu.The investigation statistics method of Wheat Diseases And Insect Pests is as follows:
In the control efficiency of investigation on March 20th, 2012 wheat wireworm, cutworm, grub, concrete grammar is with test case 1.
In the control efficiency of investigation on March 20th, 2012 wheat aphid, concrete grammar is with test case 1.
In on April 20th, 2012 investigation wheat smut and root rot prevent and treat situation, each treatment region adopts random 5 samplings, 30 strains are investigated in each process community, investigate diseased plant rate and the disease index of each treatment region root rotof flax, calculate control efficiency according to formula (II) and formula (III), root rotof flax severity Scaling index is shown in test case 1.And investigate the diseased plant number of smut, the control efficiency of smut calculates according to formula (IV).The state of an illness statistics of wheat smut is with reference to " pesticide field efficacy medicine test criterion ".
Table 2
Test case 3
Test site: Wujiang, Jiangsu, in fertility, each treatment region paddy rice production management routinely after plantation.Rice varieties is elegant water-04.
Adopt the seed coat agent of embodiment 1-7 and comparative example 1-3 to carry out Cotton seeds to paddy rice respectively, and establish one group of blank (namely not carrying out Cotton seeds to paddy rice), the consumption of often kind of seed coat agent is 200g/100kg seed.Fully shake up after respectively above-mentioned seed coat agent being watered dilution 50%.With plastic sack contained selected after seed, dilute liquid medicine is poured on seed and rocks fast, until liquid to be evenly distributed on seed (judging according to color), then cool open for subsequent use.On March 20th, 2012 is sowed, seeding row spacing 16.7cm × 20.0cm.The investigation statistics method of rice pest is as follows:
In the control efficiency of investigation on May 30 water rice hopper, aphid, leafhopper, investigation method is with reference to " pesticide field efficacy medicine test criterion ", and the formula (I) according to test case 1 calculates preventive effect (control efficiency).
Investigated the control efficiency of rotten kind, bakanae disease, damping off April 20, investigation method with reference to " pesticide field efficacy medicine test criterion ", calculates preventive effect according to the formula (II) of test case 1 and formula (III).
Table 3
As can be seen from table 1-3, composition pesticide of the present invention is relative to oligomict Diacloden, carboxin or tmtd, and control efficiency is good, has synergistic effect; Composition pesticide of the present invention can prevent and treat multiple different types of disease and insect that mixing occurs.
Compared with embodiment 4-7 respectively by embodiment 1-3 and can find out, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10, can further improve control efficiency; When the weight ratio of Diacloden, carboxin and tmtd is 1:0.3-1.5:0.3-1.5, further can improve control efficiency.
Composition pesticide of the present invention, relative to oligomict Diacloden, carboxin or tmtd, has synergistic effect, can improve control efficiency; Multiple different types of disease and insect that mixing occurs can be prevented and treated, thus can dosage be reduced, cost-saving, alleviate the pollution to environment.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible combination.
In addition, also can be combined between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.

Claims (4)

1. a composition pesticide, described composition contains active component, it is characterized in that, described active component is made up of Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 3:2:2;
Wherein, based on the gross weight of described composition pesticide, the content of described active component is 35 % by weight.
2. composition pesticide according to claim 1, wherein, described composition is also containing one or more in dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and solid inert carrier.
3. the agricultural chemicals prepared by the composition pesticide described in claim 1 or 2, wherein, the formulation of described agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
4. the application in agricultural chemicals according to claim 3 one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and rotten kind.
CN201210585590.XA 2012-12-28 2012-12-28 Pesticide composition, pesticide and application thereof Active CN103039496B (en)

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Address after: 223215 Jiangsu city of Huaian Province Chemical New Material Industrial Park hole Lin Road No. 9

Patentee after: Jiangsu Mingde Rieter crop Technology Co. Ltd.

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Patentee before: Beijing Mindleader Agroscience Co., Ltd.

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Denomination of invention: Pesticide composition and pesticide and application thereof

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