CN103039496A - Pesticide composition, pesticide and application thereof - Google Patents

Pesticide composition, pesticide and application thereof Download PDF

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Publication number
CN103039496A
CN103039496A CN201210585590XA CN201210585590A CN103039496A CN 103039496 A CN103039496 A CN 103039496A CN 201210585590X A CN201210585590X A CN 201210585590XA CN 201210585590 A CN201210585590 A CN 201210585590A CN 103039496 A CN103039496 A CN 103039496A
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Prior art keywords
carboxin
agent
diacloden
tmtd
pesticide
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CN103039496B (en
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刘世禄
徐妍
潘静
罗湘仁
陶婧
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Jiangsu Mingde Rieter crop Technology Co. Ltd.
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BEIJING MINDLEADER AGROSCIENCE Co Ltd
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Abstract

The invention relates to a pesticide composition, which contains active ingredients and is characterized in that the active ingredients comprise thiamethoxam, carboxin and thiram in weight ratio of 1 to (0.01-90) to (0.01-90). The invention further relates to pesticide prepared from the pesticide composition and application of the pesticide in prevention and treatment of plant disease and insect pests. The pesticide composition has effect enhancing function and can improve the prevention and treatment effect as compared with the thiamethoxam, the carboxin and the thiram in single ingredient; and moreover, the pesticide composition can prevent and treat various plant diseases and insect pests occurring synchronously, thereby lowering the pesticide dosage, saving the cost and reducing pollution of the environment.

Description

A kind of composition pesticide and agricultural chemicals and application thereof
Technical field
The present invention relates to a kind of composition pesticide and agricultural chemicals and application thereof, particularly, relate to a kind of composition pesticide that contains Diacloden, carboxin and tmtd, and prepared agricultural chemicals and the application of this agricultural chemicals in the control plant pest of this composition pesticide.
Background technology
The problem that in agricultural production practice, usually has dissimilar disease and insect mixed occurrence, leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, damping off, bakanae disease, the mashed kind are the damage by disease and insect that often exists or in succession exist simultaneously, such as on the crops such as corn, peanut, cotton, wheat and paddy rice.
Often need to adopt respectively different agricultural chemicals to prevent and treat for above-mentioned common disease and pest, for example, leafhopper generally adopts Rogor to prevent and treat, aphid generally adopts decis or carbosulfan to prevent and treat, plant hopper generally adopts Diacloden to prevent and treat, wireworm generally adopts phoxim or carbofuran to prevent and treat, cutworm generally adopts chlopyrifos or phoxim to prevent and treat, grub generally adopts chlopyrifos to prevent and treat, root rot generally adopts carbendazim or tpn to prevent and treat, stem rot generally adopts tmtd to prevent and treat, smut generally adopts Tebuconazole to prevent and treat, damping off generally adopts carboxin to prevent and treat, and bakanae disease generally adopts the mould spirit of evil to prevent and treat, and the mashed kind of general Prochloraz that adopts prevented and treated.
The present extermination of disease and insect pest not only control efficiency is poor, and for various disease, insect, also will use different agricultural chemicals, expends a large amount of human and material resources and financial resources cost, also can cause the pollution of environment.
Summary of the invention
The objective of the invention is to overcome the defects of prior art, provide a kind of control efficiency good, can prevent and treat composition pesticide and agricultural chemicals and the application thereof of the multiple variety classes damage by disease and insect of mixed occurrence.
The present inventor is unexpected the discovery under study for action, when the active component of composition pesticide contains Diacloden, carboxin and tmtd, and Diacloden, when the weight ratio of carboxin and tmtd is 1:0.01-90:0.01-90, particularly work as Diacloden, the weight ratio of carboxin and tmtd is 1:0.1-10:0.1-10, more preferably, Diacloden, when the weight ratio of carboxin and tmtd is 1:0.3-1.5:0.3-1.5, composition pesticide is with respect to oligomict Diacloden, carboxin or tmtd, has synergistic effect, control efficiency is good, and can prevent and treat multiple different types of damage by disease and insect of mixed occurrence.
Therefore, to achieve these goals, on the one hand, the invention provides a kind of composition pesticide, described composition contains active component, it is characterized in that, described active component contains Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90.
Preferably, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10, and more preferably, the weight ratio of Diacloden, carboxin and tmtd is 1:0.3-1.5:0.3-1.5.
On the other hand, the invention provides the prepared agricultural chemicals of aforesaid composition pesticide, wherein, the formulation of described agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
The third aspect the invention provides the application in aforesaid agricultural chemicals one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and mashed the kind.
Composition pesticide of the present invention has synergistic effect with respect to oligomict Diacloden, carboxin or tmtd, can improve control efficiency; Can prevent and treat multiple different types of plant pest of mixed occurrence, thereby can reduce dosage, save cost, alleviate the pollution to environment.
Other features and advantages of the present invention will partly be described in detail in embodiment subsequently.
Embodiment
Below the specific embodiment of the present invention is elaborated.Should be understood that, embodiment described herein only is used for description and interpretation the present invention, is not limited to the present invention.
The invention provides a kind of composition pesticide, said composition contains active component, and active component contains Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90.
Among the present invention, the chemical name of Diacloden is 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine.
Among the present invention, the chemical name of carboxin is 5,6-dihydro-2-methyl-N-phenyl-Isosorbide-5-Nitrae-oxathiene-3-formamide.
Among the present invention, the chemical name of tmtd is two (dimethyl thiocarbamoyl) two sulphur things.
According to the present invention, although the active component of composition pesticide contains Diacloden, carboxin and tmtd, the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90, can realize purpose of the present invention, be that composition pesticide has synergistic effect, control efficiency is good; Can prevent and treat multiple different types of plant pest of mixed occurrence.But under the preferable case, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10,1:0.3-1.5:0.3-1.5 more preferably, and the synergistic effect of composition pesticide is more remarkable, can further improve control efficiency.
Among the present invention, for the total content of active component in composition pesticide without specific (special) requirements, can select conventional consumption according to the different dosage form of composition pesticide preparation, this is conventionally known to one of skill in the art, for example, based on the gross weight of composition pesticide, the content of active component is the 1-95 % by weight.
Among the present invention, for the composition of other except active component in the composition pesticide without specific (special) requirements, can match as required this area composition commonly used, for example, dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and solid inert carrier.Therefore, composition pesticide of the present invention also contains one or more in dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and the solid inert carrier.These compositions can be according to the consumption of the dosage form selection routine of composition pesticide preparation, and this is conventionally known to one of skill in the art, does not repeat them here.
Among the present invention, all without specific (special) requirements, can adopt this area material commonly used for mentioned component, for example:
Dispersant and wetting agent can be for polyvinylpyrrolidone, maleic acid-acrylic acid copolymer sodium salt, sodium methylene bis-naphthalene sulfonate, sodium lignin sulfonate, calcium lignosulfonate, calcium dodecyl benzene sulfonate, succinate sodium sulfonates, pull open in powder, sldium lauryl sulfate, sodium alkyl sulfonate, lauryl sodium sulfate, polyoxyethylene nonylphenol ether and the fatty alcohol-polyoxyethylene ether one or more.
Antifreezing agent can be in ethylene glycol, 1,2-PD, glycerine and the urea one or more.
Film forming agent can be gum Arabic, animal glue, methylcellulose, ethyl cellulose, sodium cellulose glycolate, polyvinyl alcohol, polyethylene glycol, polyacrylamide, Sodium Polyacrylate and equal one or more in the polyvinyl acetate, is preferably polyvinyl alcohol and equal mixtures of polyvinyl acetate.
Binding agent can be in starch, gypsum, glucose, polyvinyl alcohol, gum Arabic and the dextrin one or more.
Thickener can be in Magnesiumaluminumsilicate, xanthans, polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose and the phenolic resins one or more.
Solid inert carrier can be in clay, silica, diatomite, kaolin, attapulgite, imvite, bentonite, talcum powder and the precipitated calcium carbonate one or more.
Stabilizing agent, preservative and colouring agent also adopt this area material commonly used, and this is conventionally known to one of skill in the art, does not repeat them here.
Composition pesticide of the present invention can provide with the finished product form, and namely each composition mixes in the composition; Also can every kind composition provide with the form of independent preparation, directly carry out bucket during use mixed.
On the other hand, the present invention also provides aforesaid composition pesticide prepared agricultural chemicals, and wherein, the formulation of agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
Among the present invention, consider from the angle of agricultural chemicals using method, the formulation of agricultural chemicals is preferably suspension seed-coating agent.
Other composition in above-mentioned each formulation except active component and the content of content and active component thereof can adopt the proportioning of this area routine without specific (special) requirements, for example:
Aqueous suspension agent contains 5-70 % by weight active component, 0.5-12 % by weight dispersant, 0.5-5 % by weight wetting agent, 0.1-10 % by weight antifreezing agent, other additive of 0-10 % by weight such as stabilizing agent, preservative, thickener usually, and surplus is water.Suspending agent usually need wet pulverizing stable to obtain, can flow, the easy suspension liquid of measurement volumes.
Suspension seed-coating agent contains 5-70 % by weight active component, 0.5-12 % by weight dispersant, 0.5-5 % by weight wetting agent, 0.1-10 % by weight antifreezing agent, 0.5-10 % by weight film forming agent usually, the 0.5-5% warning colouration, other additive of 0-10 % by weight such as stabilizing agent, preservative, thickener, surplus are water.
Wetting powder contains 3-95 % by weight active component, 0.5-10 % by weight dispersant, 0.5-5 % by weight wetting agent, other additive of 0-10 % by weight such as stabilizing agent etc. usually, and surplus is solid inert carrier, such as kaolin etc.
Water dispersible granules contains 3-95 % by weight active component, 0.5-10 % by weight dispersant, 0.5-5 % by weight wetting agent, other additive of 0-10 % by weight such as stabilizing agent, adhesive usually, and surplus is solid inert carrier, such as kaolin etc.Water dispersible granules is made 10-100 order international standard sieve mesh (1676-152 μ m) particle usually, can pass through the method preparations such as mist projection granulating, extruder grain, High Rotation Speed granulation, fluidized bed prilling.
Among the present invention, without specific (special) requirements, can adopt the whole bag of tricks well known in the art for the preparation method of various formulations, not repeat them here.
It will be understood by those skilled in the art that the various formulations among the present invention can dilute use according to actual needs when reality is used.
The third aspect the invention provides the application in aforesaid agricultural chemicals one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and mashed the kind.
Among the present invention, above-mentioned damage by disease and insect all has generation on various crop.For example, on the crops such as corn, peanut, cotton, wheat and paddy rice.
Among the present invention, agricultural chemicals can adopt this area method commonly used to use, and for example, directly spreads fertilizer over the fields in the field and uses, or carry out field spray after the dilution and use, or carry out seed treatment.Consider from the angle that the agricultural chemicals availability is high, the method for use agricultural chemicals is preferably with agricultural chemicals carries out seed treatment.Seed treatment comprises dressing or seed dressing.
Embodiment
The present invention is further illustrated for following embodiment, but therefore do not limit the present invention.
Embodiment 135% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that 3:2:2(namely is about 1:0.67:0.67))
Diacloden 15 % by weight, carboxin 10 % by weight, tmtd 10 % by weight, maleic acid-acrylic acid copolymer sodium salt 3 % by weight, pull open powder 2 % by weight, xanthans 0.3 % by weight, aluminium-magnesium silicate 0.5 % by weight, silicone defoaming agent 0.2 % by weight, polyvinyl alcohol 0.5%, equal polyvinyl acetate 0.5%, acid scarlet 1.0%, water are added into 100 % by weight.
Embodiment 235% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is 1:0.375:0.375)
Diacloden 20 % by weight, carboxin 7.5 % by weight, tmtd 7.5 % by weight, all the other components and content are with embodiment 1.
Embodiment 335% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that 9:13:13(namely is about 1:1.44:1.44))
Diacloden 9 % by weight, carboxin 13 % by weight, tmtd 13 % by weight, all the other components and content are with embodiment 1.
Embodiment 435% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that 29:3:3(namely is about 1:0.103:0.103))
Diacloden 29 % by weight, carboxin 3 % by weight, tmtd 3 % by weight, all the other components and content are with embodiment 1.
Embodiment 535% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is 1:8.25:8.25)
Diacloden 2 % by weight, carboxin 16.5 % by weight, tmtd 16.5 % by weight, all the other components and content are with embodiment 1.
Embodiment 635% Diacloden carboxin tmtd suspension seed-coating agent (weight ratio of Diacloden, carboxin and tmtd is that 68:1:1(namely is about 1:0.015:0.015))
Diacloden 34 % by weight, carboxin 0.5 % by weight, tmtd 0.5 % by weight, all the other components and content are with embodiment 1.
(weight ratio of Diacloden, carboxin and tmtd is 1:87:87 to embodiment 735% Diacloden carboxin tmtd suspension seed-coating agent
Diacloden 0.2 % by weight, carboxin 17.4 % by weight, tmtd 17.4 % by weight, all the other components and content are with embodiment 1.
Comparative Examples 135% Diacloden suspension seed-coating agent
According to the prescription of embodiment 7, different is that Diacloden, carboxin, tmtd are all substituted with Diacloden.
Comparative Examples 235% carboxin suspension seed-coating agent
According to the prescription of embodiment 7, different is that Diacloden, carboxin, tmtd are all substituted with carboxin.
Comparative Examples 335% tmtd suspension seed-coating agent
According to the prescription of embodiment 7, different is that Diacloden, carboxin, tmtd are all substituted with tmtd.
Test case 1
Test site: big dragon village, Hepu County four crossway township, soil belongs to pool tide sandy soil, in the fertility on, each the routinely production management for the treatment of region peanut after the plantation.Peanut varieties is sweet osmanthus No. 21.
Adopt respectively the kind clothing agent of embodiment 1-7 and Comparative Examples 1-3 that peanut is carried out Cotton seeds, and establish one group of blank (namely peanut not being carried out Cotton seeds), the consumption of every all clothing agent is the 150g/100kg seed.Respectively above-mentioned kind of clothing agent being watered dilution 50% fully shakes up afterwards.Contained seed after selected with plastic sack, dilute liquid medicine has been poured on the seed rocks fast, (judged according to color) until liquid is evenly distributed on the seed, then cold is opened for subsequent use.On May 1st, 2012 sowing, flat kind, line-spacing 33cm, pier be apart from 20cm, every mu of 10,000 piers, the two grain sowings of every pier.The investigation statistics method of peanut damage by disease and insect is as follows:
In the control efficiency of investigation on June 30 peanut cutworm, wireworm, grub, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, and every 4 caves amount to 20 caves.Shoveling sampling survey borer population alive during investigation, digging depth calculates vermins-proof effect (control efficiency) to 30cm according to formula (I).
Figure BDA00002679796700081
In the control efficiency of investigation on June 1 peanut aphid, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, every 4 strains, and the aphid number on the investigation peanut leaf calculates vermins-proof effect according to above-mentioned formula.
In investigation on June 30 Roots of Peanut maize ear rot, stem rot, rust, leaf blight control efficiency, concrete grammar is as follows:
Each treatment region adopts random 5 samplings, and each is processed the residential quarter and investigates 30 strains, investigates diseased plant rate and the disease index of each treatment region root rot in seedling stage, calculates control efficiency according to formula (II) and formula (III).
Root rot severity Scaling index: 0 grade: on stem foot and the main fibrous root all without scab; 1 grade: a small amount of scab is arranged on stem foot and the main root; 3 grades: scab is more on stem foot and the main root, and lesion area accounts for the 1/4-1/2 of stem foot and the root gross area; 5 grades: scab is many and large on stem foot and the main root, and lesion area accounts for the 1/2-3/4 of stem foot and the root gross area; 7 grades: scab forms in flakes around neck phenomenon on stem foot and the main root, but root system is not dead; 9 grades: root system is downright bad, and the plant overground part is wilted or be dead.
Stem rot, rust, leaf blight state of an illness statistics are with reference to " pesticide field efficacy medicine test criterion ".
Figure BDA00002679796700091
Peanut extermination of disease and insect pest effect is as shown in table 1.
Table 1
Figure BDA00002679796700092
Test case 2
Test site: Bai Miao village, Ge Bukou township, Yuanyang County, Henan Province.This plot physical features is smooth, and two close soil, the fertility uniformity, and water retention property is good, and irrigation and drainage are convenient.Each routinely production management for the treatment of region wheat after the plantation.Wheat breed is new wheat 18.
Adopt respectively the kind clothing agent of embodiment 1-7 and Comparative Examples 1-3 that wheat is carried out Cotton seeds, and establish one group of blank (namely wheat not being carried out Cotton seeds), the consumption of every all clothing agent is the 200g/100kg seed.Respectively above-mentioned kind of clothing agent being watered dilution 50% fully shakes up afterwards.Contained seed after selected with plastic sack, dilute liquid medicine has been poured on the seed rocks fast, (judged according to color) until liquid is evenly distributed on the seed, then cold is opened for subsequent use.The line-spacing sowings such as artificial sowing machine are adopted in sowing on October 20th, 2011, and line-spacing is 20cm, the amount of broadcasting 15kg/ mu.The investigation statistics method of Wheat Diseases And Insect Pests is as follows:
In the control efficiency of investigation on March 20th, 2012 wheat wireworm, cutworm, grub, concrete grammar is with test case 1.
In the control efficiency of investigation on March 20th, 2012 wheat aphid, concrete grammar is with test case 1.
Prevent and treat situation on April 20th, 2012 investigation wheat smut and root rot, each treatment region adopts random 5 samplings, each is processed the residential quarter and investigates 30 strains, investigate diseased plant rate and the disease index of each treatment region root rotof flax, calculate control efficiency according to formula (II) and formula (III), root rotof flax severity Scaling index is seen test case 1.And the diseased plant number of investigation smut, the control efficiency of smut is calculated according to formula (IV).The state of an illness statistics of wheat smut is with reference to " pesticide field efficacy medicine test criterion ".
Figure BDA00002679796700101
Table 2
Test case 3
Test site: the Wujiang, Jiangsu, in the fertility on, each the routinely production management for the treatment of region paddy rice after the plantation.Rice varieties is elegant water-04.
Adopt respectively the kind clothing agent of embodiment 1-7 and Comparative Examples 1-3 that paddy rice is carried out Cotton seeds, and establish one group of blank (namely paddy rice not being carried out Cotton seeds), the consumption of every all clothing agent is the 200g/100kg seed.Respectively above-mentioned kind of clothing agent being watered dilution 50% fully shakes up afterwards.Contained seed after selected with plastic sack, dilute liquid medicine has been poured on the seed rocks fast, (judged according to color) until liquid is evenly distributed on the seed, then cold is opened for subsequent use.Sowing on March 20th, 2012, seeding row spacing 16.7cm * 20.0cm.The investigation statistics method of rice pest is as follows:
In the control efficiency of investigation on May 30 water rice hopper, aphid, leafhopper, investigation method is calculated preventive effect (control efficiency) with reference to " pesticide field efficacy medicine test criterion " according to the formula (I) of test case 1.
In the control efficiency of the mashed kind of investigation on April 20, bakanae disease, damping off, investigation method is calculated preventive effect with reference to " pesticide field efficacy medicine test criterion " according to formula (II) and the formula (III) of test case 1.
Table 3
Figure BDA00002679796700111
1-3 can find out from table, and composition pesticide of the present invention is with respect to oligomict Diacloden, carboxin or tmtd, and control efficiency is good, has synergistic effect; Composition pesticide of the present invention can be prevented and treated multiple different types of disease and insect of mixed occurrence.
Embodiment 1-3 is compared and can find out with embodiment 4-7 respectively, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10, can further improve control efficiency; When the weight ratio of Diacloden, carboxin and tmtd is 1:0.3-1.5:0.3-1.5, can further improve control efficiency.
Composition pesticide of the present invention has synergistic effect with respect to oligomict Diacloden, carboxin or tmtd, can improve control efficiency; Can prevent and treat multiple different types of disease and insect of mixed occurrence, thereby can reduce dosage, save cost, alleviate the pollution to environment.
More than describe preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in the above-mentioned embodiment, in technical conceive scope of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
Need to prove in addition, each concrete technical characterictic described in above-mentioned embodiment in reconcilable situation, can make up by any suitable mode, for fear of unnecessary repetition, the present invention is to the no longer separately explanation of various possible combinations.
In addition, also can carry out any combination between the various embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.

Claims (7)

1. composition pesticide, described composition contains active component, it is characterized in that, and described active component contains Diacloden, carboxin and tmtd, and the weight ratio of Diacloden, carboxin and tmtd is 1:0.01-90:0.01-90.
2. composition pesticide according to claim 1, wherein, the weight ratio of Diacloden, carboxin and tmtd is 1:0.1-10:0.1-10.
3. composition pesticide according to claim 2, wherein, the weight ratio of Diacloden, carboxin and tmtd is 1:0.3-1.5:0.3-1.5.
4. the described composition pesticide of any one according to claim 1-3, wherein, based on the gross weight of described composition pesticide, the content of described active component is the 1-95 % by weight.
5. the described composition pesticide of any one according to claim 1-3, wherein, described composition also contains one or more in dispersant, wetting agent, antifreezing agent, stabilizing agent, preservative, thickener, film forming agent, binding agent, colouring agent and the solid inert carrier.
6. the prepared agricultural chemicals of the described composition pesticide of any one among the claim 1-5, wherein, the formulation of described agricultural chemicals is suspending agent, suspension seed-coating agent, wetting powder or water dispersible granules.
7. the application in agricultural chemicals claimed in claim 6 one or more plant pests in control leafhopper, aphid, plant hopper, wireworm, cutworm, grub, root rot, stem rot, smut, rust, leaf blight, damping off, bakanae disease and mashed the kind.
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CN101227820A (en) * 2004-08-17 2008-07-23 先正达参股股份有限公司 Anabasine composition containing water for seed processing
EP1925204A1 (en) * 2006-11-23 2008-05-28 Syngeta Participations AG Plant propagation material treatment nematicides
CN101647337A (en) * 2008-08-15 2010-02-17 上海农业科技种子有限公司 Novel anti-pest seed coating agent for waxy corn

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