Summary of the invention
Technical problem to be solved by this invention is, provide a kind of can automation control paper look, the production method of the product form and aspect are stable, cost is low colored paperboard.
The production method of colored paperboard of the present invention is: with base stock bleached sulphate softwood pulp and BRATSK successively through making beating, with slurry, starching, manufacture paper with pulp, front drying, top sizing, after dry, press polish make into paper with the rewinding operation, in process flow, add dyestuff and auxiliary material; Transfer sequence according to material, described pulping process material successively through pulper, kowtow front stock tank, fiberizer and kowtow after stock tank, described with slurry operation material passes through with slurry pond, transfer stock tank, paper machine stock tank and header box successively, and described upper slurry process material is successively through 1
#Fan pump, scummer, 2
#Fan pump and pressurized screen, the described operation material of manufacturing paper with pulp passes through flow box, wet end and press section successively; The 60-70% of the total consumption of described dyestuff adds at dosing chamber, and the 10-20% of the total consumption of dyestuff adds at the top sizing place, and is remaining in the header box interpolation, is used for accurate form and aspect control.The interpolation total amount of dyestuff is determined according to shade and kind of dyes.The method is by the datumization control to color, use toning software according to the data of three primary color theory and survey, dyestuff or the stoste good dilution are transported to continuously toning in the header box with accurate measuring pump accurate measurement, realize the automated production of colored paperboard, can adjust quickly and easily required color, simplify production operation, make things convenient for quality control, the toning precision is high, becomes the paper form and aspect stable.
Between described press polish operation and the curling operation color detection means is set, the detection signal of color detection means exports the automatic color regulating system to, and the control instruction control measuring pump of automatic color regulating system output is regulated the dyestuff that the header box place adds.
In the described with slurry operation, the mass ratio of the bleached sulphate softwood pulp in the base stock is 10%-15%, and the mass ratio of BRATSK is 85%-90%, and the pulpboard whiteness is all greater than 85%; The cationic starch that adds conventional amount used in the with slurry pond.
Add the AKD of conventional amount used in the described header box; Described 1# fan pump porch adds calcium carbonate, and consumption is the 18-22% of oven dry stock quality, because dyestuff is filled after adding dyestuff easily with the filler loss, can allow dyestuff and fiber have enough contacting to dye the time; Described 2# fan pump porch adds color-fixing agent, and color-fixing agent consumption light color is the 0.1-0.2% of oven dry stock quality, and dark color is the 0.3-0.4% of oven dry stock quality, add color-fixing agent after adding dyestuff in the slurry, can improve the reservation of dyestuff, improve the COLOR FASTNESS of paper, improve the poor problem in two sides; The preservative that before pressurized screen, adds conventional amount used.
The present invention combines batch dyeing in top sizing dyeing and the slurry, divides 3 addings with dyestuff at dosing chamber, header box and top sizing, adopts modernized automatic color regulating system successfully to produce desirable colored paperboard, and its advantage applies exists:
(1) dyestuff divides 3 addings, can significantly reduce the DYE PRODUCTION cost, satisfies the requirement to form and aspect, is beneficial to accurate control, the automated production of coloured paper.
(2) this automation tinting system toning flexibly and fast can access various required form and aspect at short notice, and production control is convenient, and paper forming rate is high; Different form and aspect can be manufactured paper with pulp continuously, and the plain boiled water utilization rate is high, and is little to the pollution of environment, and comprehensive production cost is low; Can adapt to various fluctuations, the toning precision is high, becomes the paper form and aspect stable, consistent.
The colored paperboard of (3) producing with the method is bright in luster, color and luster is even, positive and negative aberration is little, COLOR FASTNESS good.
The specific embodiment
The present invention is described further below in conjunction with specific embodiment.
Embodiment 1: paper look L*, a* and b* value are 84.01 ,-13.26 and-9.91, and quantitative 140gsm manufactures paper with pulp
The production method of colored paperboard uses common fourdrinier wire wire multi-cylinder paper machine to produce, and the technological process of production is making beating, with slurry, starching, manufacture paper with pulp, drying, top sizing, press polish are made into paper with rewinding.Colored paperboard is take bleached sulphate pin, hardwood pulp as main raw material(s), take chemical assistant dyestuff, cationic starch, AKD (alkyl ketene dimer), calcium carbonate, color-fixing agent and preservative as auxiliary raw material.Concrete technology is as follows:
(1) wet end furnish: bleached sulphate softwood pulp adapted 15%, BRATSK 85%;
(2) dyestuff uses:
Dosing chamber adds dyestuff Turquoise R-Z 1000ppm/ oven dry stock (accounting for the total consumption 62% of this dyestuff),
Top sizing is added in and keeps relatively poor Turquoise R-Z 200ppm/ oven dry stock (account for the total consumption of this dyestuff 12%) in the slurry,
Add at last the about 425ppm/ oven dry stock of Turquoise R-Z, the about 36ppm/ oven dry stock of Red 2B-Z, Yellow S-Z about the 48ppm/ oven dry stock carries out automatic color regulating at the header box place.
(3) other auxiliary materials:
Calcium carbonate consumption 20%/oven dry stock,
Color-fixing agent consumption 0.2%/oven dry stock,
Cationic starch, AKD and preservative be routinely consumption interpolation then.
When production is carried out, softwood pulp and hardwood pulp are disperseed through hydrabrusher successively, through kowtowing front stock tank, making beating is stored in kowtows rear stock tank, according to proportioning softwood pulp and hardwood pulp being put into dosing chamber mixes, add successively cationic starch and dyestuff, the mixed slurry that configures is sent into the transfer stock tank successively, paper machine stock tank, header box, in header box, add successively AKD and dyestuff, slurry arrives the 1# fan pump through header box, add calcium carbonate at 1# fan pump entrance, through arriving the 2# fan pump behind the scummer, add color-fixing agent at 2# fan pump entrance, slurry enters pressurized screen, add preservative before pressurized screen, slurry enters press section through flow box and wet end drainage and formation, passes through front drying again, top sizing, rear drying, then enter the press polish operation, add dyestuff at the top sizing place, make colored paperboard and become paper finally by batching.
At curling front follow-on test paper look, use toning software to adjust the flow of each measuring pump according to the data of three primary color theory and survey, thereby change each dye dosage of header box place, realize the Automatic Control of paper look.
Present embodiment adds batch dyeing (dye dosage: Turquoise R-Z 1809ppm/ oven dry stock, Red 2B-Z 50ppm/ oven dry stock, Yellow S-Z 61ppm/ oven dry stock) production method with traditional dyestuff at dosing chamber to be compared, and the total consumption of dyestuff can reduce about 11%; Becoming paper paper look L*, a* and b* value is 84.12 ,-13.38 and-9.85, the paper look can be strict controlled in L* value 84.01 ± 0.5, a* value-13.26 ± 0.3, the b * value-9.91 ± 0.3; Positive and negative value of chromatism △ E is 0.13, much smaller than standard value 1.5; This colour paperboard is bright in luster, form and aspect stable, and its combination property reaches client's instructions for use.
Embodiment 2: paper look L*, a* and b* value are 68.56 ,-12.34 and-19.15, and quantitative 80gsm manufactures paper with pulp
The production method of colored paperboard uses common fourdrinier wire wire multi-cylinder paper machine to produce, and the technological process of production is making beating, with slurry, manufacture paper with pulp, starching, drying, top sizing, press polish are made into paper with rewinding.Colored paperboard is take bleached sulphate pin, hardwood pulp as main raw material(s), take chemical assistant dyestuff, cationic starch, AKD (alkyl ketene dimer), calcium carbonate, color-fixing agent and preservative as auxiliary raw material.Concrete technology is as follows:
(1) wet end furnish: bleached sulphate softwood pulp adapted 10%, BRATSK 90%;
(2) dyestuff uses:
Dosing chamber adds dyestuff Turquoise R-Z 7000ppm/ oven dry stock (accounting for the total consumption 66% of this dyestuff),
Top sizing is added in and keeps relatively poor Turquoise R-Z 1500ppm/ oven dry stock (account for the total consumption of this dyestuff 14%) in the slurry,
Add at last the about 2099ppm/ oven dry stock of Turquoise R-Z, the about 577ppm/ oven dry stock of Red 2B-Z, Yellow S-Z about the 222ppm/ oven dry stock carries out automatic color regulating at the header box place.
(3) other auxiliary materials:
Calcium carbonate consumption 18%/oven dry stock,
Color-fixing agent consumption 0.4%/oven dry stock,
Cationic starch, AKD and preservative be routinely consumption interpolation then.
When production is carried out, softwood pulp and hardwood pulp are disperseed through hydrabrusher successively, through kowtowing front stock tank, making beating is stored in kowtows rear stock tank, according to proportioning softwood pulp and hardwood pulp being put into dosing chamber mixes, add successively cationic starch and dyestuff, the mixed slurry that configures is sent into the transfer stock tank successively, paper machine stock tank, header box, in header box, add successively AKD and dyestuff, slurry arrives the 1# fan pump through header box, add calcium carbonate at 1# fan pump entrance, through arriving the 2# fan pump behind the scummer, add color-fixing agent at 2# fan pump entrance, slurry enters pressurized screen, add preservative before pressurized screen, slurry enters press section through flow box and wet end drainage and formation, passes through front drying again, top sizing, rear drying, then enter the press polish operation, add dyestuff at the top sizing place, make colored paperboard and become paper finally by batching.
At curling front follow-on test paper look, use toning software to adjust the flow of each measuring pump according to the data of three primary color theory and survey, thereby change each dye dosage of header box place, realize the Automatic Control of paper look.
Present embodiment adds batch dyeing (dye dosage: Turquoise R-Z 12354ppm/ oven dry stock, Red 2B-Z 691ppm/ oven dry stock, Yellow S-Z 364ppm/ oven dry stock) production method with traditional dyestuff at dosing chamber to be compared, and the total consumption of dyestuff can reduce about 15%; Becoming paper paper look L*, a* and b* value is 68.75 ,-12.26 and-19.28, the paper look can be strict controlled in L* value 68.56 ± 0.5, a* value-12.34 ± 0.3, the b * value-19.15 ± 0.3; Positive and negative value of chromatism △ E is 0.39, much smaller than standard value 1.5; This colour paperboard is bright in luster, form and aspect stable, and its combination property reaches client's instructions for use.