CN102121212A - Method for producing marble art paper - Google Patents

Method for producing marble art paper Download PDF

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Publication number
CN102121212A
CN102121212A CN 201010576456 CN201010576456A CN102121212A CN 102121212 A CN102121212 A CN 102121212A CN 201010576456 CN201010576456 CN 201010576456 CN 201010576456 A CN201010576456 A CN 201010576456A CN 102121212 A CN102121212 A CN 102121212A
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paper
slurry
dyestuff
liquid
dyeing
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CN102121212B (en
Inventor
丛永宁
周大仕
宋桂芳
于彦凤
李甲年
单秋萍
张黎敏
李早柏
岳剑霞
唐晓东
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SHANDONG KAILI SPECIAL PAPER CO Ltd
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SHANDONG KAILI SPECIAL PAPER CO Ltd
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Abstract

The invention relates to a method for producing marble art paper, comprising the following steps: selecting 20% of softwood pulp and 80% of bleached eucalyptus pulp, controlling the beating degree of the pulps within 34-35 DEG SR, the screening concentration of the pulps at 0.9-1.0%, the quantification of paper at 95 g/m<2>. And the surface absorption weight at 20-30 g/m<2>; and dyeing the paper twice, wherein during the first dyeing, a dye is added to a paper machine flow which is conveyed to a high tank, and the liquid dye is directly added to the high tank to be mixed with the pulps, and during the second dyeing, at an initial phase of dehydration and screening of the pulp flow, the dye is sprayed onto a paper machine screen part through a spraying device, and natural and soft simulated cloud patterns or marble patterns are formed through shaking the paper machine screen part and naturally dispersing the dye so as to obtain the marble art paper. The marble art paper has the advantages of easiness in production, reliable production process, high operability, soft paper surface color, abundant colors and cloud pattern effects. The marble art paper is mainly applied to package of special products, book cover, high-order offices and the like.

Description

A kind of preparation method of marble art paper
Technical field
The present invention relates to a kind of manufacture craft of artistic paper, specifically a kind of preparation method of marble art paper.
Background technology
We know that paper technology normally forms fibrous raw material through pulling an oar, prepare burden, manufacturing paper with pulp, and the performance of paper is with regard to the kind of paper and purposes and decide, and its raw material configuration of the paper of different cultivars performance, manufacture method, technology are different.The paper grades hundreds of is individual at present, and only packaging group accounts for 37% of overall package material with paper, and paper develops into conglomerate, many kinds, multipurposes such as package paper steadily with paper from information.Present domestic packing and decorating are with most of paperboard or coated board, the boxboard etc. of adopting of paper, and are of low grade, of poor quality, do not possess anti-counterfeiting performance and artistic performance, and it is total that the paper technology that is adopted belongs to industry.Existing paper, common paper and common speciality paper incompatibility expensive goods packing are decorated and are needed, and lack artistry.Existing artistic paper is to add different lines again by different colours to realize, in general be a kind of color on the surface of a piece of paper, two kinds of colors occur and then be realizing that by paper being carried out embossing when certain moisture just part in compression darkens.At present, a kind of marble art paper is arranged on the market, it is the general name of imitative cloud line and reason bag art paper.But do not see up to now, the report of relevant marble art paper production technology.The bibliographical information that when the paper machine is produced, does not also have to occur simultaneously on a piece of paper two kinds of colors.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned the deficiencies in the prior art, provide a kind of processing and fabricating easy, production technology is reliable, strong operability, two kinds of colors appear on a piece of paper simultaneously, the paper surface color is soft, has imitative cloud line and reason bag effect, the preparation method of the marble art paper of chromaticness Ganfeng richness.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of preparation method of marble art paper, select 20% needle slurry for use, 80% broad-leaved slurry, slurry pulping adopts the mode of mixing making beating, 34-35 ° of SR of control slurry pulping beating degree, approach flow concentration 0.9-1.0%, the quantitative 95g/m of paper 2, the surface absorbs weight 20-30g/m 2, it is characterized in that: described paper carries out twice dyeing in two stages, and header box is sent at paper machine stream in the implantation site that adds of a dye, and liquid dyes directly add header box and mix with slurry, and slurry forms single background color; Secondary dyeing is at the slurry stream slurry online dehydration initial stage, dyestuff is sprayed on the web part of paper machine by flusher, the drop dyestuff that sprays mixes with the background color of preceding once dyeing formation on the web part of paper machine pulp layer, by the shake of web part of paper machine and spreading naturally of dyestuff, paper forms soft imitative cloud line of nature or reason bag color, and, obtain marble art paper after shaping and drying batches finished product.
The said once liquid dyes of dyeing of the present invention are respectively that liquid is directly yellow, liquid is directly red, liquid is directly black or their compound.
It is the slurry stream slurry online initial stage that the said secondary dye of the present invention adds the implantation site, web part of paper machine 0.5-1.0m place, dyestuff adding mode is sprayed for the paper view picture, each dropping liquid that sprays formation drips dyestuff and contacts with the paper pulp layer, and along with the operation and the shaking of paper machine, to depth and diffusion on every side,, form soft imitative cloud line of nature or reason bag color with the background color stack of once dyeing.
The said secondary dyestuff of the present invention is that liquid is directly yellow, liquid is directly red or their compound.
The present invention is because paper carries out twice dyeing in two stages, obtains that nature is soft, the marble art paper of the depth and variform imitative cloud line or reason bag.Against existing technologies, processing and fabricating of the present invention is easy, and production technology is reliable, strong operability, and the paper surface color is soft and have abundant chromaticness sense and cloud line or a reason bag effect.Be mainly used in the packing of extraordinary product, the front cover of books, high-grade office etc., good artistic feeling and aesthetic feeling are arranged.Product does not have brightening agent class additive, belongs to the myopia prevention paper of a class environment-friendly type, the long-time use, but effectively preventing eye fatigue.
The specific embodiment
The present invention is further described below in conjunction with embodiment.
The preparation method of a kind of marble art of the present invention paper is selected 20% needle slurry for use, 80% broad-leaved slurry, and slurry pulping adopts the mode of mixing making beating, 34-35 ° of SR of control slurry pulping beating degree, approach flow concentration 0.9-1.0%, the quantitative 95g/m of paper 2, the surface absorbs weight 20-30g/m 2Online dehydration, the shaping and drying of paper pulp and to batch finished product same as the prior art, for example shaping and drying can be that filled cloth slurry back adopts heated-air drying, far-infrared ray drying and sealing drying to carry out polynary shaping and drying etc.Specifically repeat no more.
Paper of the present invention carries out twice dyeing in two stages, and the header box place is sent at paper machine stream in the implantation site that adds of a dye, and dyestuff adopts liquid dyes directly to add header box, mixes with slurry, and the paper slurry forms the background color of single look.Once Ran Se liquid dyes can be respectively that liquid is directly yellow, liquid is directly red, liquid is directly black or their compound.Secondary dyeing is at the slurry stream slurry online dehydration initial stage, dyestuff is sprayed on the web part of paper machine by flusher, the drop dyestuff that sprays mixes with the background color of preceding once dyeing formation on the web part of paper machine pulp layer, by the shake of web part of paper machine and spreading naturally of dyestuff, in the paper pulp layer, form soft imitative cloud line of nature or reason bag color, and, obtain marble art paper after shaping and drying batches finished product.
It is that the paper machine slurry flowing box export pulp is just surfed the Net the initial stage that the said secondary dyestuff of the present invention adds the implantation site, web part of paper machine 0.5-1.0m place, the adding mode drips for the paper view picture sprays, to be that the directly yellow and liquid of liquid is direct red etc. mix in blending bin the secondary dyestuff by a certain percentage, mix after a flusher, be sprayed onto the surface of pulp layer as high-pressure nozzle, the secondary dyestuff contacted with pulp layer at the online initial stage, operation along with the paper machine, the secondary dyestuff is the distributions with the multiple spot drop on the pulp layer surface, each drips dyestuff along with the direction of paper machine operation is carried out longitudinal diffusion, simultaneously along with horizontal proliferation is carried out in the shaking of paper machine, the secondary dyestuff superposes with the background color of a dyestuff in the process of diffusion, forms difformity, soft naturally imitative cloud line or manage the bag decorative pattern.The secondary dyestuff is different with diffusion because of the amount of drop, and the shade that secondary dyestuff and paper pulp contact point extend the outer edge place with diffusion forms difference, thereby forms a kind of decorative pattern of natural gradual change look.Along with the dehydration after the paper pulp online, the secondary dyestuff permeates in the depth of pulp layer, and what make paper also forms color and the corresponding decorative pattern that nature spreads by wire side, obtains marble art paper at last.
Embodiment 1: a kind of preparation method of marble art paper, the wet end furnish of selecting for use is Canadian Kai Lipu softwood pulp 20%, sunshine gloomy rich hardwood pulp 80%, slurry pulping adopts the mode of mixing making beating, 34 ° of SR of control slurry pulping beating degree, approach flow concentration 0.9-1.0%, the surface absorbs weight 20-30g/m 2, top sizing: the AKD consumption is 1.0% (the relative oven dry stock mass ratio of AKD stoste).The paper machine production speed of a motor vehicle: 50m/min.Substance: 95g/m 2
Described paper carries out twice dyeing in two stages, and the header box place is sent at paper machine stream in the implantation site that adds of a dye, and dyestuff adopts liquid dyes directly to add header box, mixes with slurry, and the paper slurry forms the background color of single look.A dye consumption: the yellow 602ppm of Clariant liquid dyes (the relative oven dry stock quality of liquid dyes stoste, below identical), the red 88ppm of Clariant liquid dyes, the Clariant liquid dyes are deceived 143ppm.The flow that dyestuff is controlled various colorants with measuring pump during paper production measures, add by the header box place, mix in header box with slurry, a dyestuff obtains full and uniform mixing with slurry behind screen centrifuge, and head box is sprayed onto online slurry and is uniform pale yellow color.Secondary dyeing is dewatered the initial stage at wet end, web part of paper machine 0.5-1.0m place, and secondary dye consumption: the yellow 433ppm of Clariant liquid dyes, the Clariant liquid dyes are deceived 315ppm.Secondary dyestuff ratio proportioning on request mixes, and mentions the dyestuff holding vessel with pump, and holding vessel has overfall, is sprayed onto the surface of pulp layer by shower nozzle.The sprinkling flow of secondary dyestuff is undertaken by the liquid level of control dyestuff accumulator tank.Flow velocity and dyestuff that the height of liquid level directly influences dyestuff distribute in the sprinkling of paper surface.Adjust the height of dyestuff holding vessel liquid level and the position of shower nozzle according to paper machine speed and change in color.The concrete dyestuff liquid level 95mm that adjusts, shower nozzle is from the high 72mm of wire side.The secondary dyestuff carries out on web part of paper machine 0.5-1.0m with the form of spraying, the drop dyestuff that sprays and the paper background color that forms of going forward once to dye mixes, by the shake and dyestuff the diffuseing to form different, the soft naturally imitative cloud line of the depth naturally or managing the bag decorative pattern in pulp layer of web part of paper machine.Then shaping and drying and batch finished product obtains marble art paper.
Embodiment 2: a kind of preparation method of marble art paper, the wet end furnish of selecting for use is Canadian Kai Lipu softwood pulp 20%, sunshine gloomy rich hardwood pulp 80%, slurry pulping adopts the mode of mixing making beating, 35 ° of SR of control slurry pulping beating degree, approach flow concentration 1.0%, the surface absorbs weight 20-25g/m 2, top sizing: the AKD consumption is 1.0% (the relative oven dry stock mass ratio of AKD stoste).The paper machine production speed of a motor vehicle: 50m/min.Substance: 95g/m 2
Described paper carries out twice dyeing in two stages, and the header box place is sent at paper machine stream in the implantation site that adds of a dye, and dyestuff adopts liquid dyes directly to add header box, mixes with slurry, and the paper slurry forms the background color of single look.Dye consumption: the yellow 25ppm of Clariant liquid dyes (the relative oven dry stock quality of liquid dyes stoste, below identical), the red 30ppm of Clariant liquid dyes.The flow that dyestuff is controlled various colorants with measuring pump during paper production measures, add by the header box place, mix in header box with slurry, a dyestuff obtains full and uniform mixing with slurry behind screen centrifuge, and head box is sprayed onto online slurry and is uniform light pink color.Secondary dyeing is dewatered the initial stage at wet end, web part of paper machine 0.5-1.0m place, secondary dye consumption: the yellow 240ppm of Clariant liquid dyes, the red 650ppm of Clariant liquid dyes.Secondary dyestuff ratio proportioning on request mixes, and mentions the dyestuff holding vessel with pump, and holding vessel has overfall, is sprayed onto the surface of pulp layer by shower nozzle.The sprinkling flow of secondary dyestuff is undertaken by the liquid level of control dyestuff accumulator tank.Concrete dyestuff liquid level 95mm, shower nozzle is from the high 70mm of wire side.The secondary dyestuff carries out on web part of paper machine 0.5-1.0m with the form of spraying, the drop dyestuff that sprays and the paper background color that forms of going forward once to dye mixes, by the shake and dyestuff the diffuseing to form different, the soft naturally imitative cloud line of the depth naturally or managing the bag decorative pattern in pulp layer of web part of paper machine.Then shaping and drying and batch finished product obtains marble art paper.

Claims (4)

1. the preparation method of a marble art paper is selected 20% needle slurry for use, 80% broad-leaved slurry, and slurry pulping adopts the mode of mixing making beating, 34-35 ° of SR of control slurry pulping beating degree, approach flow concentration 0.9-1.0%, the quantitative 95g/m of paper 2, the surface absorbs weight 20-30g/m 2, it is characterized in that: described paper carries out twice dyeing in two stages, and header box is sent at paper machine stream in the implantation site that adds of a dye, and liquid dyes directly add header box and mix with slurry, and slurry forms single background color; Secondary dyeing is at the slurry stream slurry online dehydration initial stage, dyestuff is sprayed on the web part of paper machine by flusher, the drop dyestuff that sprays mixes with the background color of preceding once dyeing formation on the web part of paper machine pulp layer, by the shake of web part of paper machine and spreading naturally of dyestuff, paper forms soft imitative cloud line of nature or reason bag color, and, obtain marble art paper after shaping and drying batches finished product.
2. the preparation method of marble art paper according to claim 1 is characterized in that: the said once liquid dyes of dyeing are that liquid is directly yellow, liquid is directly red, liquid is directly black or their compound.
3. the preparation method of marble art paper according to claim 1, it is characterized in that: it is the slurry stream slurry online initial stage that said secondary dye adds the implantation site, web part of paper machine 0.5-1.0m place, dyestuff adding mode is sprayed for the paper view picture, each dropping liquid that spray to form drips dyestuff and contacts with the paper pulp layer, and along with the operation and the shaking of paper machine, to depth with spread on every side, with the background color stack of once dyeing, form soft imitative cloud line of nature or reason bag color.
4. the preparation method of marble art paper according to claim 1 is characterized in that: said secondary dyestuff is that liquid is directly yellow, liquid is directly red or their compound.
CN 201010576456 2010-11-25 2010-11-25 Method for producing marble art paper Active CN102121212B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102517996A (en) * 2011-12-30 2012-06-27 珠海经济特区红塔仁恒纸业有限公司 Hue adjusting process for high-whiteness coating white cardboard
CN102609577A (en) * 2012-01-20 2012-07-25 天津大学 Computer simulation method of paper marbling image
CN102660886A (en) * 2012-05-29 2012-09-12 山东凯丽特种纸股份有限公司 Production method of snowflake art paper
CN103031777A (en) * 2012-12-31 2013-04-10 镇江大东纸业有限公司 Making method of color card paper
CN105133427A (en) * 2015-09-01 2015-12-09 安庆市新宜纸业有限公司 Paper dyeing technology
CN111188224A (en) * 2020-01-03 2020-05-22 山东太阳纸业股份有限公司 Myopia-preventing paper and preparation method thereof
CN115369689A (en) * 2022-08-17 2022-11-22 山鹰国际控股股份公司 Papermaking pre-dyeing process

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US5716498A (en) * 1996-04-12 1998-02-10 Witco Corporation Process for softening paper in manufacture
CN1276843A (en) * 1997-10-25 2000-12-13 阿尔若威金斯精细纸品有限公司 Production for mottled paper

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102517996A (en) * 2011-12-30 2012-06-27 珠海经济特区红塔仁恒纸业有限公司 Hue adjusting process for high-whiteness coating white cardboard
CN102517996B (en) * 2011-12-30 2014-12-10 珠海经济特区红塔仁恒纸业有限公司 Hue adjusting process for high-whiteness coating white cardboard
CN102609577A (en) * 2012-01-20 2012-07-25 天津大学 Computer simulation method of paper marbling image
CN102609577B (en) * 2012-01-20 2014-07-02 天津大学 Computer simulation method of paper marbling image
CN102660886A (en) * 2012-05-29 2012-09-12 山东凯丽特种纸股份有限公司 Production method of snowflake art paper
CN102660886B (en) * 2012-05-29 2014-02-12 山东凯丽特种纸股份有限公司 Production method of snowflake art paper
CN103031777A (en) * 2012-12-31 2013-04-10 镇江大东纸业有限公司 Making method of color card paper
CN103031777B (en) * 2012-12-31 2016-03-30 镇江大东纸业有限公司 The production method of colored paperboard
CN105133427A (en) * 2015-09-01 2015-12-09 安庆市新宜纸业有限公司 Paper dyeing technology
CN111188224A (en) * 2020-01-03 2020-05-22 山东太阳纸业股份有限公司 Myopia-preventing paper and preparation method thereof
CN111188224B (en) * 2020-01-03 2023-01-17 山东太阳纸业股份有限公司 Myopia-preventing paper and preparation method thereof
CN115369689A (en) * 2022-08-17 2022-11-22 山鹰国际控股股份公司 Papermaking pre-dyeing process

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