CN103031496B - Cast steel roller and fabrication technology thereof - Google Patents
Cast steel roller and fabrication technology thereof Download PDFInfo
- Publication number
- CN103031496B CN103031496B CN201310000392.7A CN201310000392A CN103031496B CN 103031496 B CN103031496 B CN 103031496B CN 201310000392 A CN201310000392 A CN 201310000392A CN 103031496 B CN103031496 B CN 103031496B
- Authority
- CN
- China
- Prior art keywords
- alloy
- core
- roll
- cast steel
- molten
- Prior art date
Links
- 229910001208 Crucible steel Inorganic materials 0.000 title claims abstract description 14
- 238000005516 engineering processes Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 229910045601 alloys Inorganic materials 0.000 claims abstract description 37
- 239000000956 alloys Substances 0.000 claims abstract description 37
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000011514 iron Substances 0.000 claims abstract description 15
- 239000011572 manganese Substances 0.000 claims abstract description 8
- 239000000126 substances Substances 0.000 claims abstract description 8
- 239000010410 layers Substances 0.000 claims abstract description 7
- 239000010955 niobium Substances 0.000 claims abstract description 5
- 239000011651 chromium Substances 0.000 claims abstract description 4
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- 239000010950 nickel Substances 0.000 claims abstract description 4
- 241001081830 Degeneriaceae Species 0.000 claims description 27
- 229910000831 Steel Inorganic materials 0.000 claims description 19
- 239000010959 steel Substances 0.000 claims description 19
- 239000000463 materials Substances 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 238000000034 methods Methods 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 238000007670 refining Methods 0.000 claims description 9
- 238000005496 tempering Methods 0.000 claims description 9
- 238000002360 preparation methods Methods 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 7
- 239000000203 mixtures Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 238000010791 quenching Methods 0.000 claims description 6
- 230000000171 quenching Effects 0.000 claims description 6
- 239000002893 slag Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 4
- 229910000967 As alloys Inorganic materials 0.000 claims description 3
- 210000003491 Skin Anatomy 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound 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Abstract
Description
Technical field
The invention belongs to Steel Rolling roll technology field, be specifically related to a kind of cast steel roll and preparation technology thereof.
Background technology
Along with developing rapidly of Iron And Steel Industry, the production capacity of the current hot rolled strip mill of China has reached more than 300,000,000 ton, roll is a large amount of vitals that consume during steel rolling is produced, therefore the quality of roll quality not only affects the surface quality of stocking, but also affect the operating rate of milling train, directly restricting the economic benefit of enterprise.At present state-of-the-art on roll material is high-speed steel roll, and itself and conventional rapid steel class formula are different, and it exists following shortcoming:
1. working conditions is harsher, and roller temperature control slightly mistake will be peeled off even explosion, causes rolling accident, and user is had to inconvenience more;
2. manufacturing process elaborate, product rejection rate is high, and breaker roll manufacturer cost pressure is too large;
3. the high and practical steel transportation amount of cost is not significantly improved, and to using and all bad acceptance of supplier, the quality objection of generation and commercial dispute are also many.
4. consumables cost is higher, consumes alloy resource too much.
Summary of the invention
Technical problem to be solved by this invention is for above-mentioned the deficiencies in the prior art, a kind of cast steel roll and preparation technology thereof are provided, make roll meet Composition Design rationally, casting and thermal treatment process maturation, the requirement such as production cost is lower, product rejection rate is low and anti-accident ability is strong.
The technical solution adopted in the present invention is: a kind of cast steel roll, comprise alloy outer and core, and the chemical component weight percentage ratio of described alloy outer is: C 1.50-2.20%, Si≤0.060%, Mn 0.40-1.20%, P≤0.030%, S≤0.025%, Cr 3.00-8.00%, Ni 0.00-1.50%, Mo 2.00-8.00%, V 2.00-9.00%, W 0.00-3.00%, Nb 0.00-0.85%, Al 0.00-1.20%, surplus is Fe;
The chemical component weight percentage ratio of described core is: C 2.8-3.4%, Si 1.8-2.6%, Mn 0.3-0.6%, P≤0.08%, S≤0.03%, Mg 0.04-0.06%.
As preferably, adopt centrifugal casting technique by integral two kinds of different metallic substance consolutes, first alloy skin, core composition carries out accurate combo and carries out respectively intermediate frequency furnace melting, work as alloy outer, the concrete composition of core is in the time of stokehold spectral detection and the specific requirement of accurate adjustment conformance with standard technique, by alloy outer, core is distinguished refining, , when reaching when setting requires, alloy outer melting taps, increase foreign material simultaneously, refining slag filtration treatment operation, the molten steel of tapping is poured in the whizzer casting mold of high speed rotating, the pouring temperature of alloy outer molten steel is 1430-1460 DEG C, when lower machine horse back after alloy outer molten steel solidification carry out vertical group of case, to rinsing cast core molten iron in it, the pouring temperature of core molten iron is 1410-1450 DEG C, thereby make the complete metallurgical melting of alloy outer and core, junction does not have carbon segregation and shrinkage defect substantially.
As preferably, described foreign material filtration treatment operation refers to and in the time that slagging-off is tapped a blast furnace, adopts the heat-resistance stainless steel silk screen of restriction order number to carry out filtration treatment to iron liquid, filters impurity and ensure the molten quality of inside and outside two-layer metallurgical junction syzygies with refining slag.
As preferably, first test and roughing for the blank roll after cooling forming, after completing, anneal, quenching and tempering heat treatment: annealing is that roll is heated to 900-980 DEG C, then carry out stove cold; Quenching be with the heat-up rate of≤30 DEG C/h be warmed up to >=600 DEG C after, again heat-up rate is promoted to≤40 DEG C/h, roll is heated to 950-1100 DEG C, and by the insulation of insulation specified time, and then make roll cooling fast by mode air-cooled or spraying, when be cooled to 350~300 DEG C to carry out temper later; Tempering temperature is 500-680 DEG C, and times of tempering is at least three times, make alloy outer hardness reach 80HSD more than, paralympic obtaining melts fully and changes.
Beneficial effect of the present invention is: the present invention adopts alloy outer and the core of mentioned component, its wear resistance and good toughness, anti-accident ability are strong, long service life, avoid rolling accident, complete metallurgical binding between alloy outer and core, reduced the element proportional quantity that disadvantageous effect is larger in practicality simultaneously, reduce production cost, improved working conditions simultaneously; Casting of the present invention and thermal treatment process, utilize material " secondary hardening characteristic " to ensure rolling use properties, and reduce the meticulous and complexity of production technique, reduces condemnation factor.
Brief description of the drawings
Fig. 1 is technical process for casting figure of the present invention;
Fig. 2 is heat treatment cycle curve figure of the present invention.
Embodiment
Below in conjunction with the accompanying drawings and the specific embodiments the present invention is described in further detail.
Embodiment mono-: a kind of cast steel roll, comprise alloy outer and core, the chemical component weight percentage ratio of described alloy outer is: C 1.50-2.20%, Si≤0.060%, Mn 0.40-1.20%, P≤0.030%, S≤0.025%, Cr 3.00-8.00%, Ni 0.00-1.50%, Mo 2.00-8.00%, V 2.00-9.00%, W 0.00-3.00%, Nb 0.00-0.85%, Al 0.00-1.20%, surplus is Fe;
The chemical component weight percentage ratio of described core is: C 2.8-3.4%, Si 1.8-2.6%, Mn 0.3-0.6%, P≤0.08%, S≤0.03%, Mg 0.04-0.06%.
Key of the present invention is to have reduced the proportional quantity of the element that disadvantageous effect is larger in practicality, proportional quantity by Si is reduced to :≤0.060%, the proportional quantity of W is reduced to: 0.00-3.00%, the proportional quantity of Nb is reduced to: 0.00-0.85%, the proportional quantity of Al is reduced to: 0.00-1.20%, the roll of the present embodiment is reduced costs and improve working conditions, performance and rapid steel are same or similar simultaneously, ensure its purposes and effect.
The preparation technology of cast steel roll of the present invention is: as shown in Figure 1, adopt centrifugal casting technique by integral two kinds of different metallic substance consolutes, first alloy skin, core composition carries out accurate combo and carries out respectively intermediate frequency furnace melting, work as alloy outer, the concrete composition of core is in the time of stokehold spectral detection and the specific requirement of accurate adjustment conformance with standard technique, by alloy outer, core is distinguished refining, , when reaching when setting requires, alloy outer melting taps, increase foreign material simultaneously, refining slag filtration treatment operation, the molten steel of tapping is poured in the whizzer casting mold of high speed rotating, the pouring temperature of alloy outer molten steel is 1430-1460 DEG C, when lower machine horse back after alloy outer molten steel solidification carry out vertical group of case, to rinsing cast core molten iron in it, the pouring temperature of core molten iron is 1410-1450 DEG C, thereby make the abundant metallurgical melting of alloy outer and core, junction does not have carbon segregation and shrinkage defect substantially.Increase foreign material filtration treatment operation and refer to and in the time that slagging-off is tapped a blast furnace, adopt the heat-resistance stainless steel silk screen of restriction order number to carry out filtration treatment to iron liquid, filter impurity and ensure the molten quality of inside and outside two-layer metallurgical junction syzygies with refining slag.
As shown in Figure 2, first test and roughing for the blank roll after cooling forming, after completing, anneal, quenching and tempering heat treatment, thermal treatment process is round-the-clock to be checked every 30 minutes, heating, soaking time and temperature are finely tuned according to product specification and user's operating mode: annealing is that roll is heated to 900-980 DEG C, then carry out stove cold; Quenching be with the heat-up rate of≤30 DEG C/h be warmed up to >=600 DEG C after, again heat-up rate is promoted to≤40 DEG C/h, roll is heated to 950-1100 DEG C, and by the insulation of insulation specified time, then make roll cooling fast by mode air-cooled or spraying, when being cooled to carry out temper after 300-350 DEG C; Tempering temperature is 500-680 DEG C, times of tempering is revised according to hardness that product requires and paralympic amount detection controlling valu (ferrite detector), it is at least three times, make alloy outer hardness reach 80HSD more than, paralympic obtaining melts fully and changes.
The present invention adopts alloy outer and the core of mentioned component, its wear resistance and good toughness, anti-accident ability are strong, long service life, avoid rolling accident, complete metallurgical binding between alloy outer and core, reduced the element proportional quantity that disadvantageous effect is larger in practicality simultaneously, reduce production cost, improved working conditions simultaneously; Casting of the present invention and thermal treatment process, utilize material " secondary hardening characteristic " to ensure rolling use properties, and reduce the meticulous and complexity of production technique, reduces degree of scrapping.
The present invention transforms equipment for Heating Processing simultaneously, and its content comprises:
1, increase blowing/spraying machine;
2, change into Sweet natural gas by electric energy;
3, change preventing deformation base plate;
4, heat treated article bearing changes heat resisting iron material.
Utilize the cast steel roll of formula of the present invention and preparation technology's exploitation also to there is following beneficial effect:
1. properties is except red hardness is slightly on the low side, and other index is all higher than former rapid steel series products, and overall steel transportation amount improves approximately 13.3%;
2. material newly developed is approximately lower by 32.4% than former rapid steel material material cost, and alloy resource consumes less, meets national resources conservation policy;
3. the product process-cycle falls 8.7% than rapid steel product, and output is than former rapid steel product high approximately 5.6%;
4. the principle that cost is low, performance meets well market " inexpensive ", supply falls short of demand for current Europe user.
The above, be only preferred embodiment of the present invention, therefore can not limit scope of the invention process with this, the equivalence of doing according to the present patent application the scope of the claims and description changes and modifies, and all should still remain within the scope of the patent.
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CN100369681C (en) * | 2006-04-30 | 2008-02-20 | 郑州航空工业管理学院 | Compound high speed steel roll and its making process |
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