CN1030228C - Multifunction, waterless scrubbing dirt emulsion and its preparing method - Google Patents
Multifunction, waterless scrubbing dirt emulsion and its preparing method Download PDFInfo
- Publication number
- CN1030228C CN1030228C CN 91110600 CN91110600A CN1030228C CN 1030228 C CN1030228 C CN 1030228C CN 91110600 CN91110600 CN 91110600 CN 91110600 A CN91110600 A CN 91110600A CN 1030228 C CN1030228 C CN 1030228C
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- emulsion
- scrubbing
- scrubbing dirt
- dirt emulsion
- waterless
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Abstract
The present invention relates to a neutral, multifunctional, waterless scrubbing dirt emulsion of high stability, low cost and high efficiency and a preparing method thereof. The scrubbing dirt emulsion is mainly composed of an anionic and non-ionic surface active agent, a macromolecule film former, a lubricant, an emollient, an abrasive, a preservative, etc. The present invention has the advantages of noninflammability, no poison, fragrance and no skin stimulation and has the action of sterilization and detumescence. The scrubbing dirt emulsion can remove various kinds of dirt on the human body in one or two minutes without using water, such as lubricating grease, engine oil, animal and vegetable oil, petroleum, coating, printing ink, black carbon, graphite, etc. The scrubbing dirt emulsion can remove oil stain on cloth, but the color of cloth can not be changed. Moreover, the scrubbing dirt emulsion has the action of dust prevention. The use amount of the scrubbing dirt emulsion at each time is only from 0.5 to 2 ml, and the price is equivalent to that of soap. The scrubbing dirt emulsion is especially suitable for workers of factories, mines and oil fields, outing drivers and travelers.
Description
The present invention relates to a kind of washings, particularly relate to a kind of water that do not need, once rubbing clean neutral degreasing washing composition-Multifunction, waterless scrubbing dirt emulsion and preparation method thereof with the hands.
Contact lubricated oil, machine oil, oil, coating, printing ink, carbon black, graphite etc. are the driver and the workman of pollution substance easily, and a common difficult problem is all arranged, and Here it is washes one's hands, difficulty washes one's face.Not being dry breach often, is exactly residual dirt in the long-term lines of the hand.Soap unonly, and because alkalescence is big, commonly used have stimulation to skin, and washing effect is poorer under the hard water condition; Quite a lot of with the washing powder effect, but need to dissolve with hot water, inconvenience is because of alkalescence is harmful to skin by force; It is more excellent to wash the agent clean effect by liquid, but cost is higher, and foam is many, essential big water gaging flushing, and the sticking puckery discomfort of skin feel; Wash with gasoline, kerosene, not only waste raw material, and inflammable dangerous, also can cause the skin degreaser drying; With chlorocarbon solvent washs such as zellons, toxicity is bigger; Immediate development be equipped with the hand cleaner of auxiliary material preparation with anion surfactant, deodorized kerosine, trolamine, clean effect is fair, but foam is many, still needs the water flushing or uses the dry goods wiping.
Under the no water source situation of people's operation in the open air or travelling, the both hands greasy dirt wants to work on, drives or has a dinner, and is badly in need of a kind of efficient water-free hand cleaner, and is more urgent at severe winter.
In 1986, day disclosure is speciallyyed permit clear 61-233099 and has been disclosed a kind of anhydrous washing composition, form by tensio-active agent, paraffin, water soluble polymer, silicone oil etc., it is said that degreasing result is better, and there is stranding to fall from clear effect, weak point is that cost is higher, and stability is not good enough, long contain demixing phenomenon.
The purpose of this invention is to provide a kind of low cost, high stable, efficiently, the multi-functional waterless scrubbing dirt emulsion of skin irritation not, remove for multiple industry workman and field work personnel that greasy dirt uses on health and the clothing.
The present invention realizes by following proposal: the significant percentage of constituent is:
Anion surfactant 1-6%
Nonionogenic tenside 1.5-5%
Aqueous solution macromolecule filming thing 3-10%
Slipping agent 0.4-4%
Abrasive 3-15%
Softener 0.2-5%
Sanitas 0.01-0.1%
Essence 0.1-0.4%
Water surplus
With water-soluble polymer film forming matter, slipping agent and gauge water, under 50-100 rev/min of stirring, in strap clamp cover reactor, be heated to 70-95 ℃, kept 20 minutes, and added negatively charged ion and nonionogenic tenside, softener, sanitas, abrasive then successively, when treating that temperature is reduced to 40-45 ℃, add essence, mixing, natural then deaeration 4 hours, can.
Anion surfactant is the major ingredient of dissolving dirt among the present invention, selects linear alkyl benzene sulphonate for use, pH value 7-9, anti-hard water, the good decontamination of tool, moistening, penetrating power.Nonionogenic tenside should have decontamination, emulsification dual-use function concurrently among the present invention, and because of preparing oil/water emulsion, the HLB value should be higher, and emulsion could be stablized.The present invention selects the alkylphenol polyoxyethylene class:
R-
-O-(CH
2-CH
2-O) n-H, R is C in the formula
9H
19, n can be best with n=10 from 8-15, the HLB value is 13.3, pH value 5-7, the good decontamination of tool, emulsification, wetting, anti-static electrification.The water-soluble polymer film forming matter is the major ingredient of adsorbed oil dirt among the present invention, and certain film-forming properties and toughness should be arranged, and is the micelle shape through rubbing, together comes off with dirt.Select partial alcoholysis polyvinyl alcohol (PVA) and Xylo-Mucine (CMC) for use.The slipping agent effect is to make emulsion keep certain slipperiness among the present invention, makes micelle be easy to take off from skin, selects dimethyl silicone oil, and it has lubricious, froth breaking, skin care, sterilizing function.Abrasive effect of the present invention is to increase frictional resistance, and the dirt that infiltrates in the skin texture is deviate from when rubbing, strengthens and cleans effect.Can select calcium mineral for use, consumption is 3-15%, and consumption frictional force very little is little, and dirt takes off unclean; Can make the emulsion denseness strengthen inconvenient rubbing when too many.The softener effect is for keeping skin surface to avoid dehydration, do not have dry sense of discomfort, and should have the coupler effect concurrently, making emulsion more stable among the present invention.Select polyvalent alcohol such as glycerol.Sanitas effect of the present invention is that the assurance emulsion is never degenerated when long storage, selects cloth sieve bohr (2-bromo-2 nitros-1, ammediol) for use, is broad-spectrum antibacterial agent, and is efficient, 1/10th of the only suitable nipagin esters of consumption.The adding of essence can make the pure and fresh frankness of people, and is optional to essence such as the less jasmine of skin irritation, rose, tinkling of pieces of jade orchid, Gui Xiang.
Product of the present invention is that oil/water type white emulsion, no inflammable, noxious solvent and bases mix.PH value 6.8, non-foam has aromatic odour.Emulsion-stabilizing, through 40 ℃ and-10 ℃ high low temperature tests, emulsion is not stratified.Product of the present invention carries out the rabbit acute skin irritation test through relevant department inside, smeared 5-120 minute and pathology section examination, non-stimulated to skin, carry out tame lagophthalmos acute irritation test again, eye drip 30 minutes, the eye conjunctiva, iris, the equal vacuum response of cornea, and splashed into the family expenses soap solution 30 minutes, family's lagophthalmos conjunctiva is congested, proves that product of the present invention is also lower than soap to eye irritation.
Product of the present invention, over one hundred routine application test through inside, can be under without the regimen condition, one, rub multiple pollutents such as the gear oil on the body of being castrated, yellow drier oil, machine oil, soya-bean oil, oil, coating, printing ink, carbon black, graphite in two minutes with the hands, effect obviously is better than soap, washing powder and other type washings.With after not only health to stain part clean incomparable, and skin softness, comfortable, no dry sensation, sterilization detumescence effect in addition.This product is double to remove greasy dirt on the clothing, and constant color and luster does not damage fiber, and has anti-electrostatic to reduce dust-absorbing function.Each consumption only needs the 0.5-2 milliliter, and price and soap are suitable.
Technology of the present invention is simple, and abundant raw material is easy to get, and the no three wastes produce in the production, and end-use is extensive, and economic benefit is outstanding.
Embodiment 1
PVA 5Kg
CMC 2Kg
Dimethyl silicone oil 1Kg
Water 56Kg
Above-mentioned each material is stirred in stainless steel or lass lining strap clamp cover reactor, progressively is heated to 80-95 ℃, kept 20 minutes, add successively:
Sodium dodecylbenzene sulfonate 2.1Kg
Polyoxyethylene nonylphenol ether (n=10) 2.5Kg
Glycerol 0.5Kg
Cloth sieve bohr 0.03Kg
Calcic breeze 10Kg
Water 20.77Kg
Be cooled to 40-45 ℃, add cream jasmin france 0.1Kg, stir evenly, emitting product is white fragrant emulsion, room temperature deaeration, packing after 4 hours.
Embodiment 2
CMC 5Kg
Dimethyl silicone oil 2Kg
Water 59Kg
Material loading mixed and be heated to 70-85 ℃, kept 20 minutes, successively adding:
Sodium dodecylbenzene sulfonate 2.5Kg
Polyoxyethylene nonylphenol ether (n=8) 2.5Kg
Glycerol 1.5Kg
Cloth sieve bohr 0.02Kg
Calcic breeze 4Kg
Water 23.28Kg
Be cooled to 40-45 ℃, add nine rare essence 0.1Kg.
Claims (2)
1, a kind of washing composition, particularly remove on the human body heavy dirty smeary Multifunction, waterless scrubbing dirt emulsion, it is characterized in that percentage meter by weight contains the Sodium dodecylbenzene sulfonate of 1-6%, the polyoxyethylene number of 1.5-5% is the polyoxyethylene nonylphenol ether of 8-15, partial alcoholysis polyvinyl alcohol or the Xylo-Mucine of 3-10%, the dimethyl silicone oil of 0.4-4%, the glycerol of 0.2-5%, the calcic breeze of 3-15%, 2-bromo-2 nitros-1 of 0.01-0.1%, ammediol, the essence of 0.1-0.4%, surplus is a water.
2, the preparation method of the Multifunction, waterless scrubbing dirt emulsion of claim 1, it is characterized in that earlier partial alcoholysis polyvinyl alcohol or Xylo-Mucine, dimethyl silicone oil and suitable quantity of water, under 50-100 rev/min of stirring, give heat to 70-95 ℃, kept 20 minutes, add Sodium dodecylbenzene sulfonate then successively, polyoxyethylene nonylphenol ether, glycerol, 2-bromo-2 nitros-1, ammediol, calcic breeze add excess water again, stir and are cooled to 40-45 ℃, add essence at last, can after natural deaeration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91110600 CN1030228C (en) | 1991-11-05 | 1991-11-05 | Multifunction, waterless scrubbing dirt emulsion and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91110600 CN1030228C (en) | 1991-11-05 | 1991-11-05 | Multifunction, waterless scrubbing dirt emulsion and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1072207A CN1072207A (en) | 1993-05-19 |
| CN1030228C true CN1030228C (en) | 1995-11-08 |
Family
ID=4910177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91110600 Expired - Fee Related CN1030228C (en) | 1991-11-05 | 1991-11-05 | Multifunction, waterless scrubbing dirt emulsion and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1030228C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003902552A0 (en) * | 2003-05-21 | 2003-06-12 | Novapharm Research (Australia) Pty Ltd | Biofilm growth prevention |
| CN101602985B (en) * | 2008-06-10 | 2011-04-27 | 财团法人工业技术研究院 | Composition for removing dirtymark and use method thereof |
| CN103805369A (en) * | 2014-03-04 | 2014-05-21 | 东莞市常晋凹版模具有限公司 | Copper-plated layer washing degreaser applied in electroplating industry |
-
1991
- 1991-11-05 CN CN 91110600 patent/CN1030228C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1072207A (en) | 1993-05-19 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |