CN103013356B - Low-temperature-resistant binding agent for packaging material - Google Patents
Low-temperature-resistant binding agent for packaging material Download PDFInfo
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- CN103013356B CN103013356B CN2012105345358A CN201210534535A CN103013356B CN 103013356 B CN103013356 B CN 103013356B CN 2012105345358 A CN2012105345358 A CN 2012105345358A CN 201210534535 A CN201210534535 A CN 201210534535A CN 103013356 B CN103013356 B CN 103013356B
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- 239000011230 binding agent Substances 0.000 title claims abstract description 29
- 239000005022 packaging material Substances 0.000 title abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- -1 isophthalic acid ester Chemical class 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 6
- IANQTJSKSUMEQM-UHFFFAOYSA-N Benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims description 6
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 claims description 6
- 230000003712 anti-aging Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 229920000459 Nitrile rubber Polymers 0.000 claims description 4
- 101700029265 TPPD Proteins 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl N,N-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N 2-hydroxyethyl 2-methylacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 3
- XENVCRGQTABGKY-ZHACJKMWSA-N Chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims description 3
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N Distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 3
- KTWOOEGAPBSYNW-UHFFFAOYSA-N Ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000001264 neutralization Effects 0.000 claims description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000010074 rubber mixing Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 235000012222 talc Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 239000000084 colloidal system Substances 0.000 abstract description 2
- 239000003292 glue Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000000704 physical effect Effects 0.000 abstract description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- 230000002708 enhancing Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 2
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
Abstract
The invention discloses a low-temperature-resistant binding agent for a packaging material. The low-temperature-resistant binding agent comprises a component A and a component B. The low-temperature-resistant binding agent disclosed by the invention has the advantages of reasonable formula design, easiness in obtainment of raw materials, simple production process, easiness in matching with equipment, stable quality of a product and strong binding power, and can improve physical properties, medium resistance, storage stability and the like in comparison with a traditional binding agent, effectively reduce the damages to the binding agent caused by water molecules by adding treated plant ash, greatly improve the water resistance of the binding agent, enable the binding agent to have great quick-drying property due to the decline in hydrophilicity of glue, increase the stickiness of the binding agent by adding modified PVC (polyvinyl chloride) resin, improve the fluidity of colloid and further enhance the binding performance of the product.
Description
Technical field
The present invention relates generally to a kind of binding agent, relates in particular to a kind of low temperature resistant wrapping material binding agent.
Background technology
The packaging binding agent is produce on the basis of packaging industry fast development and develop, the performance of packaging binding agent, quality have directly affected packing effect and quality, current wrapping binding agent ubiquity thermotolerance is poor, winter hardiness is not good, the shortcomings such as package stability is poor, medium-resistance is poor, in order to overcome these shortcomings of traditional binding agent, invent a kind of new, high performance binding agent and all seem particularly important for daily life, prodution and development.
Summary of the invention
The object of the invention is exactly in order to make up the defect of prior art, and a kind of low temperature resistant wrapping material binding agent is provided.
The present invention is achieved by the following technical solutions:
A kind of low temperature resistant wrapping material binding agent, it is comprised of first and second liang of components:
Described first component is comprised of the raw material of following weight parts:
Chloroprene rubber CR121 80-85, paracril N41 20-25, vinylbenzene 120-130, dimethylbenzene 100-105, ethyl acetate 60-70, acrylate 18-20, ethylene glycol 10-13, isophthalic acid ester 8-10, silica powder 8-10, Zinic stearas 3-4, magnesium oxide 2-3, plant ash 2-3, coumarone 3-4, epoxy soybean oil 3.5-4, sec.-propyl distearyl acyl-oxygen base Aluminate 1-2, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, TM monex TM1-2, anti-aging agent TPPD0.8-1, antioxidant MB 1-1.5, oxidation inhibitor DSTP1-2,
The preparation method of described first component comprises the following steps:
(1) first use the plant ash 3-4h of the above-mentioned weight part of 10-15% salt acid soak, deionized water wash is clean, soak 3-4h with the 10-12% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add the fatty alcohol-polyoxyethylene ether that is equivalent to above-mentioned plant ash weight 2-3%, the paregal O of 1-2%, the phthalic ester of 2-3%, the talcum powder of 3-5%, high speed 1200-1500r/min stirs 1-2h, dry, pulverizing grinds to form ultrafine powder and gets final product;
(2) the chloroprene rubber CR121 of above-mentioned weight part is placed on rubber mixing machine, roll spacing 0.6-1mm, the roller temperature is 30-38 ℃, plasticate 25-30 time, then strengthen roll spacing to 8-12mm, refine after 4-6 minute, the coumarone, epoxy soybean oil, sec.-propyl distearyl acyl-oxygen base Aluminate, Zinic stearas, magnesium oxide, antioxidant MB, anti-aging agent TPPD, the N-2-(aminoethyl that add successively above-mentioned weight part)-3-aminopropyl trimethoxysilane, the plant ash of above-mentioned processing, oxidation inhibitor DSTP, all add rear thin-pass 10-12 time, section;
(3) each raw material of the section of above-mentioned chloroprene rubber CR121 and all the other is mixed and adds in reactor, stir 5-6 hour to all dissolving under 50-60 ℃, be cooled to normal temperature, finally add the ethylene glycol of above-mentioned weight part, stir and obtain described first component;
Described component B is comprised of the raw material of following weight parts:
Modified PVC resin 18-25, chlorohydrin rubber T55 10-15, dimethylbenzene 30-40, barium stearate 2-4, aluminium powder 2-3,3-aminopropyl trimethoxysilane 1-2, hydroxyethyl methylacrylate 1-2, ferrocene 1-2, pentanoic 0.8-1;
Described modified PVC resin is comprised of the raw material of following weight parts:
PVC resin SG-5 20-25, stearic acid 1-1.5, chlorinatedpolyethylene 2-2.5, active CaCO
30.8-1;
The PVC resin SG-5 of above-mentioned weight part, stearic acid, chlorinatedpolyethylene are mixed, add in high-speed mixer, the mixing machine stirring velocity is risen at a high speed by low speed, when the mixture temperature rises to 100 ℃ gradually, add the active CaCO of above-mentioned weight part
3, stir after 1-2 minute discharging cooling, be cooled to 40-50 ℃, make the modified PVC resin;
Each raw material of above-mentioned weight part is mixed, under 100-120 ℃, react 1-2h, be cooled to normal temperature, obtain described component B;
First and second liang of components obtained above are mixed, be heated to 130-140 ℃, stirring reaction 1h, obtain described binding agent.
Advantage of the present invention is:
Formulating of recipe of the present invention is reasonable, raw material is easy to get, production technique is simple, coordinative composition of equipments is easy, constant product quality, cohesive force is strong, physicals, medium-resistance, package stabilities etc. all increase than conventional binders, by adding the plant ash after processing, effectively reduce the destruction of water molecules to binding agent, make the water resisting property of binding agent improve a lot, hydrophilicity decline due to glue, make it there is the characteristic of good quick-drying, by adding the modified PVC resin, increased the viscosity of binding agent, improved the mobility of colloid, further strengthened the adhesiveproperties of product.
Embodiment
Embodiment 1
A kind of low temperature resistant wrapping material binding agent, it is comprised of first and second liang of components:
Described first component is comprised of the raw material of following weight parts (kilogram):
Chloroprene rubber CR121 85, paracril N41 25, vinylbenzene 130, dimethylbenzene 105, ethyl acetate 70, acrylate 20, ethylene glycol 10-13, isophthalic acid ester 10, silica powder 10, Zinic stearas 4, magnesium oxide 3, plant ash 3, coumarone 3-4, epoxy soybean oil 2, sec.-propyl distearyl acyl-oxygen base Aluminate 2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2, TM monex TM2, anti-aging agent TPPD0.8, antioxidant MB 1.5, oxidation inhibitor DSTP2;
The preparation method of described first component comprises the following steps:
(1) first use the plant ash 4h of the above-mentioned weight part of 15% salt acid soak, deionized water wash is clean, soak 4h with 12% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add the fatty alcohol-polyoxyethylene ether that is equivalent to above-mentioned plant ash weight 3%, 2% paregal O, 3% phthalic ester, 5% talcum powder, high speed 1500r/min stirs 2h, dry, pulverizing grinds to form ultrafine powder and gets final product;
(2) the chloroprene rubber CR121 of above-mentioned weight part is placed on rubber mixing machine, roll spacing 0.6mm, the roller temperature is 38 ℃, plasticate 30 times, then strengthen roll spacing to 12mm, refine after 4-6 minute, the coumarone 3-4, epoxy soybean oil, sec.-propyl distearyl acyl-oxygen base Aluminate, Zinic stearas, magnesium oxide, antioxidant MB, anti-aging agent TPPD, the N-2-(aminoethyl that add successively above-mentioned weight part)-3-aminopropyl trimethoxysilane, the plant ash of above-mentioned processing, oxidation inhibitor DSTP, all add rear thin-pass 12 times, section;
(3) section of above-mentioned chloroprene rubber CR121, paracril N41, vinylbenzene, dimethylbenzene, ethyl acetate, acrylate, TM monex TM, isophthalic acid ester, silica powder are mixed and adds in reactor, stir 6 hours to all dissolving under 60 ℃, be cooled to normal temperature, the ethylene glycol that finally adds above-mentioned weight part, stir and obtain described first component;
Described component B is comprised of the raw material of following weight parts:
Modified PVC resin 18-25, chlorohydrin rubber T55 15, dimethylbenzene 40, barium stearate 4, aluminium powder 3,3-aminopropyl trimethoxysilane 2, hydroxyethyl methylacrylate 2, ferrocene 2, pentanoic 0.8;
Described modified PVC resin is comprised of the raw material of following weight parts:
PVC resin SG-5 25, stearic acid 1.5, chlorinatedpolyethylene 2.5, active CaCO
30.8;
The PVC resin SG-5 of above-mentioned weight part, stearic acid, chlorinatedpolyethylene are mixed, add in high-speed mixer, the mixing machine stirring velocity is risen at a high speed by low speed, when the mixture temperature rises to 100 ℃ gradually, add the active CaCO of above-mentioned weight part
3, stir after 1 minute discharging cooling, be cooled to 50 ℃, make the modified PVC resin;
Each raw material of above-mentioned weight part is mixed, under 120 ℃, react 2h, be cooled to normal temperature, obtain described component B;
First and second liang of components obtained above are mixed, be heated to 130-140 ℃, stirring reaction 1h, obtain described binding agent.
Performance test:
Tensile strength (MPa): 45
Flexural strength (MPa): 64
Compressive strength (MPa): 86
Tensile strength (MPa): 37
Medium-resistance: (the shearing resistance conservation rate % soak 3 days in 90 ℃ of solution after): 0
#Diesel oil 98.8, distilled water 99.8;
Lower temperature resistance :-32 ℃ are not freezed in lower 7 days;
Weather resistance: indoor use 10-20, outdoor 3-5;
Use the carton of binding agent of the present invention to duck in drink, within 48 hours, do not come unstuck, after the carton drying, good bonding, mass conservation.
Claims (1)
1. a low temperature resistant wrapping material binding agent is characterized in that it is comprised of first and second liang of components:
Described first component is comprised of the raw material of following weight parts:
Chloroprene rubber CR121 80-85, paracril N41 20-25, vinylbenzene 120-130, dimethylbenzene 100-105, ethyl acetate 60-70, acrylate 18-20, ethylene glycol 10-13, isophthalic acid ester 8-10, silica powder 8-10, Zinic stearas 3-4, magnesium oxide 2-3, plant ash 2-3, coumarone 3-4, epoxy soybean oil 3.5-4, sec.-propyl distearyl acyl-oxygen base Aluminate 1-2, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, TM monex TM1-2, anti-aging agent TPPD 0.8-1, antioxidant MB 1-1.5, oxidation inhibitor DSTP1-1.5,
The preparation method of described first component comprises the following steps:
(1) first use the plant ash 3-4h of the above-mentioned weight part of 10-15% salt acid soak, deionized water wash is clean, soak 3-4h with the 10-12% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add the fatty alcohol-polyoxyethylene ether that is equivalent to above-mentioned plant ash weight 2-3%, the paregal O of 1-2%, the phthalic ester of 2-3%, the talcum powder of 3-5%, high speed 1200-1500r/min stirs 1-2h, dry, pulverizing grinds to form ultrafine powder and gets final product;
(2) the chloroprene rubber CR121 of above-mentioned weight part is placed on rubber mixing machine, roll spacing 0.6-1mm, the roller temperature is 30-38 ℃, plasticate 25-30 time, then strengthen roll spacing to 8-12mm, refine after 4-6 minute, the coumarone, epoxy soybean oil, sec.-propyl distearyl acyl-oxygen base Aluminate, Zinic stearas, magnesium oxide, antioxidant MB, anti-aging agent TPPD, the N-2-(aminoethyl that add successively above-mentioned weight part)-3-aminopropyl trimethoxysilane, the plant ash of above-mentioned processing, oxidation inhibitor DSTP, all add rear thin-pass 10-12 time, section;
(3) each raw material of the section of above-mentioned chloroprene rubber CR121 and all the other is mixed and adds in reactor, stir 5-6 hour to all dissolving under 50-60 ℃, be cooled to normal temperature, finally add the ethylene glycol of above-mentioned weight part, stir and obtain described first component;
Described component B is comprised of the raw material of following weight parts:
Modified PVC resin 18-25, chlorohydrin rubber T55 10-15, dimethylbenzene 30-40, barium stearate 2-4, aluminium powder 2-3,3-aminopropyl trimethoxysilane 1-2, hydroxyethyl methylacrylate 1-2, ferrocene 1-2, pentanoic 0.8-1;
Described modified PVC resin is comprised of the raw material of following weight parts:
PVC resin SG-5 20-25, stearic acid 1-1.5, chlorinatedpolyethylene 2-2.5, active CaCO
30.8-1;
The PVC resin SG-5 of above-mentioned weight part, stearic acid, chlorinatedpolyethylene are mixed, add in high-speed mixer, the mixing machine stirring velocity is risen at a high speed by low speed, when the mixture temperature rises to 100 ℃ gradually, add the active CaCO of above-mentioned weight part
3, stir after 1-2 minute discharging cooling, be cooled to 40-50 ℃, make the modified PVC resin;
Each raw material of above-mentioned weight part is mixed, under 100-120 ℃, react 1-2h, be cooled to normal temperature, obtain described component B;
First and second liang of components obtained above are mixed, be heated to 130-140 ℃, stirring reaction 1h, obtain described binding agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105345358A CN103013356B (en) | 2012-12-12 | 2012-12-12 | Low-temperature-resistant binding agent for packaging material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105345358A CN103013356B (en) | 2012-12-12 | 2012-12-12 | Low-temperature-resistant binding agent for packaging material |
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| Publication Number | Publication Date |
|---|---|
| CN103013356A CN103013356A (en) | 2013-04-03 |
| CN103013356B true CN103013356B (en) | 2013-12-04 |
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ID=47962485
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| CN2012105345358A Expired - Fee Related CN103013356B (en) | 2012-12-12 | 2012-12-12 | Low-temperature-resistant binding agent for packaging material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103265916A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive for packaging containing silicon carbide whiskers and preparation method thereof |
| CN103265913A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing calcined clay for packaging and preparation method thereof |
| CN104277719B (en) * | 2014-10-31 | 2015-12-30 | 浙江红高梁木业有限公司 | A kind of preparation method of freeze proof timber floor tackiness agent |
| CN106967362B (en) * | 2017-03-23 | 2019-07-26 | 深圳市朗迈新材料科技有限公司 | A kind of low temperature resistant asphalt waterproofing paint and preparation method thereof |
| CN109181580A (en) * | 2018-08-17 | 2019-01-11 | 安徽瑞腾塑业有限公司 | A kind of PVC processing adhesive |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3746606A (en) * | 1971-06-17 | 1973-07-17 | Ncr | Off-line process for laminating magnetic tape to tab stock |
| JPH06271817A (en) * | 1993-03-23 | 1994-09-27 | Three Bond Co Ltd | Alpha-cyanoacrylate-based adhesive composition and its production |
| WO2011016479A1 (en) * | 2009-08-05 | 2011-02-10 | 日本ゼオン株式会社 | Nitrile rubber composition, crosslinked nitrile rubber composition, crosslinked rubber material, and method for producing nitrile rubber composition |
| CN102744238B (en) * | 2012-07-14 | 2015-12-09 | 南京工业大学 | A kind of method of biomass power plant plant ash comprehensive utilization |
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