CN103013204A - Flame-retardant ultraviolet curable coating for wood - Google Patents
Flame-retardant ultraviolet curable coating for wood Download PDFInfo
- Publication number
- CN103013204A CN103013204A CN 201210281849 CN201210281849A CN103013204A CN 103013204 A CN103013204 A CN 103013204A CN 201210281849 CN201210281849 CN 201210281849 CN 201210281849 A CN201210281849 A CN 201210281849A CN 103013204 A CN103013204 A CN 103013204A
- Authority
- CN
- China
- Prior art keywords
- retardant
- acrylic resin
- flame
- nano
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a flame-retardant ultraviolet curable coating for wood, composed of 30-50% of epoxy acrylic resin, 10-20% of nano-silicon dioxide, 10-20% of hydroxyethyl acrylate phosphoric acid derivatives, 5-30% of nano-alumium hydroxide, 1-5% of oxidized soybean oil acrylic resin, 0.1-1% of KH560 and 5% of 1173 by mass. The flame-retardant ultraviolet curable coating for wood is flame-retardant, high in gloss, full, soft, wearable and high in curing speed.
Description
Technical field
The invention belongs to paint field, relate to a kind of wood coating, specifically relate to a kind of fire-retardant, wear-resisting, inferior light ultraviolet cured paint composition for timber.
Background technology
Along with UV Application of coatings scope is more and more extensive, people also more and more pay attention to the flame-retardant modified of UV coating.At present a lot of to the method for modifying flame of UV coating, mainly be to adopt the interpolation fire retardant to carry out flame-retardant modified to coating system.Wherein fire retardant mainly divides two classes, and a class is additive flame retardant; Another kind of is reactive flame retardant..Wherein reactive flame retardant mainly is the modification to prepolymer or monomer, and its mode with chemical bond is followed other component combinations, but the reactive flame retardant cost is high, and price comparison is expensive; Although and the additive flame retardant low price is very large on the impact of UV coating, the impact of wherein most importantly UV being solidified.And the poor stability of additive flame retardant in coating, be easy to separate out.Therefore researching and developing a kind of mixed type fire retardant that has simultaneously addition type and response type is highly significant.
The nitrogen based flame retardant becomes the new leading product of fire retardant in recent years, and it has flame retarding efficiency height, heat decomposition temperature advantages of higher.Such as: trimeric cyanamide, dicyanodiamide etc. are monomer-grafted and be dispersed in a kind of mixed type fire retardant in the polyether polyol, these fire retardants all are small molecules, do not participate in solidification process, move to easily the surface of coating, along with the time changes, be diffused into gradually in the environment, lost flame retardant effect, simultaneously, these fire retardants join in the UV-light coating, also do not affected solidification effect because not participating in the UV-light reaction, also increased the fragility of filming simultaneously, the flame retardant curing agent of therefore seeking development of new has great importance.
Have the characteristics of quick solidifying, environmental protection as the UV ultraviolet-curing paint, be used for gradually now timber, use as a kind of decorative paint.Yet along with the raising of fire prevention and other performance requriements, requirement has fire-retardant, wear-resisting, the coating that is used for timber of the multiple over-all properties such as inferior light.
Summary of the invention
The objective of the invention is the defective that exists for overcoming prior art, satisfy fire-retardant, wear-resisting, the multiple over-all properties requirement such as inferior light, and a kind of fire-retardant ultraviolet-curing paint for timber is provided.
In order to achieve the above object, the technical scheme that the present invention deals with problems is by utilizing Hydroxyethyl acrylate phosphoric acid derivatives and nano-aluminum hydroxide to be fire retardant matter, nano silicon be wear-resisting with regulate the glossiness material; Simultaneously, utilize soybean oil olefin(e) acid fat to be the dispersion curing material, and utilize sharp coupling agent KH560 to be the interface activator, to improve sticking power, utilize the different new ester of vinylformic acid to be defoamer and curing material, several compositions cooperatively interact, to reach the optimization purpose.Its concrete technical scheme is: a kind of fire-retardant ultraviolet-curing paint for timber is by epoxy acrylic resin, nano silicon, the Hydroxyethyl acrylate phosphoric acid derivatives, nano-aluminum hydroxide, oxidation soybean oil acrylic resin, KH560 and 1173 forms, and the mass percentage content scope of its component is:
Epoxy acrylic resin 30%～50%,
Nano silicon 10～20%,
Hydroxyethyl acrylate phosphoric acid derivatives 10～20%,
Nano-aluminum hydroxide 5～30%,
Oxidation soybean oil acrylic resin 1～5%,
KH560 0.1～1%，
1173 5%。
Wherein: described Hydroxyethyl acrylate phosphoric acid derivatives molecular structure is:
It derives from following reaction:
Its preparation method is, with phosphoric acid according to mol ratio: phosphoric acid: Hydroxyethyl acrylate=1.25:3 joins in the reactor, and temperature of reaction is controlled first 80 degree, react after 1 hour, is warmed up to 100 degree, continues to react then cool to room temperature, then discharging 4 hours.
Preparation method of the present invention is, first the liquid ingredient in the technical formula component mixed, and then adds solid ingredient and stirs, and grinds at shredder, at last packing again.
Advantage and the effect that has compared with prior art for the fire-retardant ultraviolet-curing paint of timber of the present invention is:
Technical solution of the present invention is owing to utilized Hydroxyethyl acrylate phosphoric acid derivatives and nano-aluminum hydroxide to be fire retardant matter, and nano silicon is wear-resisting and regulates the glossiness material; Utilized soybean oil olefin(e) acid fat for disperseing curing material, and utilized sharp coupling agent KH560 to be the interface activator, to improve sticking power, utilized the different new ester of vinylformic acid to be defoamer and curing material, several compositions cooperatively interact, so that the present invention has is fire-retardant, glossiness is high, full, soft, wear-resisting and fast advantage and the effect of curing speed.
Embodiment
Embodiment 1:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 30%,
Nano silicon 20%,
Phosphorous Hydroxyethyl acrylate derivative 20%,
Nano-aluminum hydroxide 22.9%,
Oxidation soybean oil acrylic resin 2%,
KH560 0.1%，
1173 5%。
Two, the preparation method is: first the liquid ingredient in the technical formula component is mixed, then add solid ingredient and stir, grind at shredder, at last packing.
Three, the technical indicator of present embodiment is: curing speed=10s, wear loss=38g/min, glossiness (20 measurement of angle)=50GU, mist shadow=13GU.
Embodiment 2:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 40%,
Nano silicon 10%,
Phosphorous acrylic acid derivative 15%,
Nano-aluminum hydroxide 28%,
Oxidation soybean oil acrylic resin 1%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=12s, and wear loss=25g/min, glossiness (20 measurement of angle)=48GU, mist shadow=25GU, fire-retardant.
Embodiment 3:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 50%,
Nano silicon 20%,
Phosphorous acrylic acid derivative 10%,
Nano-aluminum hydroxide 9%,
Oxidation soybean oil acrylic resin 5%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=10s, and wear loss=36g/min, glossiness (20 measurement of angle)=39GU, mist shadow=5GU, fire-retardant.
Embodiment 4:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 47%,
Nano silicon 20%,
Phosphorous acrylic acid derivative 20%,
Nano-aluminum hydroxide 5%,
Oxidation soybean oil acrylic resin 2%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=8s, and wear loss=30g/min, glossiness (20 measurement of angle)=54GU, mist shadow=24GU, fire-retardant.
Embodiment 5:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 45%,
Nano silicon 20%,
Phosphorous acrylic acid derivative 15%,
Nano-aluminum hydroxide 9%,
Oxidation soybean oil acrylic resin 5%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=10s, and wear loss=38g/min, glossiness (20 measurement of angle)=58GU, mist shadow=20GU, fire-retardant.
Embodiment 6:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 30%,
Nano silicon 20%,
Phosphorous acrylic acid derivative 20%,
Nano-aluminum hydroxide 19%,
Oxidation soybean oil acrylic resin 5%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=7s, and wear loss=32g/min, glossiness (20 measurement of angle)=48GU, mist shadow=15GU, fire-retardant.
Embodiment 7:
One, component content proportioning by mass percentage:
Epoxy acrylic resin 32%,
Nano silicon 10%,
Phosphorous Hydroxyethyl acrylate derivative 17%,
Nano-aluminum hydroxide oxidation 30%,
Oxidation soybean oil acrylic resin 5%,
KH560 1%，
1173 5%。
Two, the preparation method is identical with embodiment 1.
Three, the technical indicator of present embodiment is: curing speed=10s, and wear loss=38g/min, glossiness (20 measurement of angle)=58GU, mist shadow=20GU, fire-retardant.
Embodiment of the present invention only is used for the explanation technical solution of the present invention, is not limited to the present invention.
Claims (1)
1. fire-retardant ultraviolet-curing paint that is used for timber, it is characterized in that: content is 30%～50% by epoxy acrylic resin by mass percentage, nano silicon is 10～20%, the Hydroxyethyl acrylate phosphoric acid derivatives is 10～20%, nano-aluminum hydroxide is 5～30%, oxidation soybean oil acrylic resin is that 1～5%, KH560 is 0.1～1% and 1173 to be 5% to form, and wherein: described Hydroxyethyl acrylate phosphoric acid derivatives molecular structure is:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210281849 CN103013204A (en) | 2012-08-09 | 2012-08-09 | Flame-retardant ultraviolet curable coating for wood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210281849 CN103013204A (en) | 2012-08-09 | 2012-08-09 | Flame-retardant ultraviolet curable coating for wood |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103013204A true CN103013204A (en) | 2013-04-03 |
Family
ID=47962334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210281849 Pending CN103013204A (en) | 2012-08-09 | 2012-08-09 | Flame-retardant ultraviolet curable coating for wood |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103013204A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817935A (en) * | 2015-04-27 | 2015-08-05 | 苏州市鼎立包装有限公司 | Waterproof coating for surface of packaging wood case and preparation method of waterproof coating |
| CN105034107A (en) * | 2015-06-24 | 2015-11-11 | 南通亚振东方家具有限公司 | Method for preparing composite wood with hydroxide |
| CN105131673A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing flame retardant primer coating and preparation method thereof |
-
2012
- 2012-08-09 CN CN 201210281849 patent/CN103013204A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817935A (en) * | 2015-04-27 | 2015-08-05 | 苏州市鼎立包装有限公司 | Waterproof coating for surface of packaging wood case and preparation method of waterproof coating |
| CN105034107A (en) * | 2015-06-24 | 2015-11-11 | 南通亚振东方家具有限公司 | Method for preparing composite wood with hydroxide |
| CN105131673A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing flame retardant primer coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104072742B (en) | A kind of epoxide modified aqueous alkide resin and water alcohol acid amino-stoving varnish and preparation method | |
| CN101885943B (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN104804633B (en) | A kind of low-temperature quick-drying type acroleic acid polyurethane coating and preparation method thereof | |
| CN104356884A (en) | Low-temperature quick-drying water-based primer-topcoat protective paint used for elevator track and preparation method thereof | |
| CN102863874B (en) | Water-base epoxy zinc-rich priming paint and preparation method thereof | |
| CN101845263A (en) | UV (Ultraviolet) curing coatings with high weatherability | |
| CN105440821B (en) | A kind of pump valve antirust paint | |
| CN103409026B (en) | A kind of environment-friendly water-based anti-flaming dope | |
| CN101781517B (en) | Self-flame-retardant aqueous polyurethane industrial wood lacquer | |
| CN102140306A (en) | UV (Ultraviolet) laser roller coating woodware primer coat | |
| CN104559616A (en) | Corrosion-resistant acrylic paint | |
| CN104073040A (en) | UV-cured white curtaining paint and preparation method thereof | |
| CN105860629A (en) | Fireproof paint for wood | |
| CN103013204A (en) | Flame-retardant ultraviolet curable coating for wood | |
| CN102850872B (en) | A kind of steel construction heat reflection frie retardant coating of ultrathin rete and preparation method thereof | |
| CN102167920A (en) | Aqueous flame-retardant coating and preparation method thereof | |
| CN104531036B (en) | Water-based double-component spray glue | |
| CN104017427B (en) | Thermosetting powder coating additive and preparation process thereof | |
| CN103436158A (en) | Crystal water-permeability UV (Ultraviolet) matte top-coat | |
| CN105670356A (en) | Fireproof waterborne coating for steel structures | |
| CN107964345A (en) | A kind of water paint and its preparation and application method | |
| CN103740171B (en) | Utilize ultraviolet light polymerization in the colour-wash/ink of tire and preparation method | |
| CN102816506A (en) | Self-dried acrylic modified alkyd resin flame-retardant paint | |
| CN105733416A (en) | Environment-friendly ultraviolet light polymerization powder coating | |
| CN103254749B (en) | Water-based blackboard paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C05 | Deemed withdrawal (patent law before 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130403 |