CN103254749B - Water-based blackboard paint - Google Patents

Water-based blackboard paint Download PDF

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Publication number
CN103254749B
CN103254749B CN201310149701.7A CN201310149701A CN103254749B CN 103254749 B CN103254749 B CN 103254749B CN 201310149701 A CN201310149701 A CN 201310149701A CN 103254749 B CN103254749 B CN 103254749B
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parts
agent
water
paint
good
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CN103254749A (en
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陈利平
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JINGNING SHE AUTONOMOUS COUNTY FULIDA WOODEN CRAFT CO Ltd
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JINGNING SHE AUTONOMOUS COUNTY FULIDA WOODEN CRAFT CO Ltd
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Abstract

The invention relates to water-based blackboard paint. The water-based blackboard paint is proportioned by the following substances: water, an assistant, a film forming substance, pigment and filler, a macromolecule dispersion agent, inorganic pigment, polymerized powder, a thermal stabilizer, an adhesive force promoter, a viscosity adjusting solvent, a cross-linking agent, cellulose, an anti-foaming agent, a flatting agent, a wetting agent, a paint anticorrosion agent, a surfactant, an anti-blushing agent, a thickening agent and an alkali. The water-based blackboard paint has the beneficial effects of no toxicity, no pollution, difficulty in burning, good thermal stability, convenience in storage and transportation, energy conservation, environmental protection and no pungent smell, and has high crosslink density, good solvent resistance, good chemicals resistances, good temperature changing resistance, good after-back resistance, good scratching resistance, good weather resistance, difficulty in color changing and good attaching effect after forming a paint film.

Description

A kind of water-based blackboard paint
Technical field
The invention belongs to a kind of coating, especially a kind of water-based blackboard paint.
Background technology
Along with the steady-state growth of world economy, the consumers demand of water-based chalkboard paint and toy product day by day expands.The water-based chalkboard paint maximum as the whole world and toy production base, China has the market share of international water-based chalkboard paint and toy product more than 70%, water-based chalkboard paint and toy industry are bearing export market depression, the dual-pressure that production cost and technical threshold improve, meanwhile, based on health, environmental protection, the original intention of safety and economy Sustainable development, countries in the world or area establish strict control test and regulation, and constantly upgraded, refinement, the contentious matter that industry causes rises one after another, the sanction of relevant laws and regulations is also increasingly severe, the particularly restriction of VOC, to manufacturers, importor and retailer bring huge challenge, now, water-based chalkboard paint and toy coating arise.
At present, the woodenware chalkboard paint that market uses and toy coating major part are based on pyroxylin(e)finish, part is water-based, PU, because pyroxylin(e)finish has the advantage of himself: fast drying, easy construction, limit without duration of service, cheap etc., but pyroxylin(e)finish also has the shortcoming of self: admittedly divide low, fullness ratio is poor, solvent resistant, chemical species difference etc., environmental pollution is greatly its main shortcoming, because it is solvent based coating, the mainly film forming by solvent evaporates, therefore, pyroxylin(e)finish eventually can replace by other environment-friendly type coating, and water-based chalkboard paint and toy coating have nontoxic, pollution-free, difficult combustion, storage convenient transportation, the advantage such as energy-conservation, and along with various countries' environmental protection law, regulation perfects gradually, it is trend of the times that water-borne coatings substitutes traditional solvent-borne coating, also the important development direction of following coating will be become.
Summary of the invention
The present invention is directed to the shortcoming of above-mentioned prior art, a kind of water-based blackboard paint is provided, woodenware chalkboard paint conventional in the market can be replaced, and there is the advantage not available for woodenware chalkboard paint.
The present invention solves the technical scheme that its technical problem adopts:
A kind of water-based blackboard paint, it carries out proportioning according to the mass fraction of following material: 100 parts ~ 140 parts, water, auxiliary agent 40 parts ~ 60 parts, filmogen 60 parts ~ 90 parts, color stuffing 40 parts ~ 70 parts, macromolecule dispersing agent 20 parts ~ 35 parts, inorganic pigment 10 parts ~ 15 parts, aggretion type powder 15 parts ~ 30 parts, thermo-stabilizer 10 parts ~ 30 parts, adhesion promoter 20 parts ~ 30 parts, viscosity adjustment solvent 5 parts ~ 10 parts, linking agent 20 parts ~ 40 parts, Mierocrystalline cellulose 10 parts ~ 20 parts, defoamer 10 parts ~ 20 parts, flow agent 8 parts ~ 15 parts, wetting agent 9 parts ~ 18 parts, coating antiseptic 12 parts ~ 24 parts, 4 parts ~ 8 parts, tensio-active agent, non-blushing thinner 9 parts ~ 16 parts, thickening material 10 parts ~ 15 parts, 4 parts ~ 8 parts, alkali.
As preferably, above-mentioned water-based blackboard paint, it carries out proportioning according to the mass fraction of following material: the adjustment of 120 parts, water, auxiliary agent 50 parts, filmogen 80 parts, color stuffing 60 parts, macromolecule dispersing agent 28, inorganic pigment 13 parts, aggretion type powder 18 parts, thermo-stabilizer 20 parts, adhesion promoter 25 parts, viscosity solvent 8 parts, linking agent 24 parts, Mierocrystalline cellulose 16 parts, defoamer 16 parts, flow agent 14 parts, wetting agent 15 parts, coating antiseptic 20 parts, 6 parts, tensio-active agent, non-blushing thinner 12 parts, thickening material 12 parts, 7 parts, alkali.
Filmogen is aqueous polyurethane dispersion.
Aggretion type powder is carbon black.
Adopt aqueous polyurethane dispersion as filmogen, form that film cross-linking density after film is high, solvent resistant, chemicals-resistant, temp. variation resistant, anti-ly to after-tack, the effect of weathering resistance is better, is particularly useful for colored paint.Linking agent for improving cross-linking density, thus improves paint film property, and the hydrophilic radical generation crosslinking reaction in linking agent and coating, improves cross-linking density, thus improve the performances such as hardness, solvent resistant, water tolerance, chemical resistant properties, sticking power.
The effect that the present invention is useful is: water-based blackboard paint of the present invention, nontoxic pollution-free, nonflammable, Heat stability is good, stores convenient transportation, energy-conserving and environment-protective, there is no irritating smell, form that cross-linking density after film is high, solvent resistant, chemicals-resistant, temp. variation resistant, anti-ly to after-tack, the effect of anti scuffing, weathering resistance is better, after forming film, light fastness is good, not easy to change, adhesion effect is good.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment one:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 130 parts, water, auxiliary agent 45 parts, filmogen 90 parts, color stuffing 60 parts, macromolecule dispersing agent 35 parts, inorganic pigment 15 parts, aggretion type powder 30 parts, thermo-stabilizer 18 parts, adhesion promoter 280 parts, viscosity solvent 9 parts, linking agent 36 parts, Mierocrystalline cellulose 16 parts, defoamer 15 parts, flow agent 12 parts, wetting agent 16 parts, coating antiseptic 18 parts, 6 parts, tensio-active agent, non-blushing thinner 14 parts, thickening material 13 parts, 7 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Embodiment two:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 110 parts, water, auxiliary agent 46 parts, filmogen 70 parts, color stuffing 45 parts, macromolecule dispersing agent 20 parts, inorganic pigment 14 parts, aggretion type powder 28 parts, thermo-stabilizer 28 parts, adhesion promoter 25 parts, viscosity solvent 9 parts, linking agent 30 parts, Mierocrystalline cellulose 15 parts, defoamer 15 parts, flow agent 12 parts, wetting agent 16 parts, coating antiseptic 22 parts, 6 parts, tensio-active agent, non-blushing thinner 14 parts, thickening material 14 parts, 6 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Embodiment three:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 135 parts, water, auxiliary agent 55 parts, filmogen 78 parts, color stuffing 60 parts, macromolecule dispersing agent 32 parts, inorganic pigment 14 parts, aggretion type powder 18 parts, thermo-stabilizer 22 parts, adhesion promoter 26 parts, viscosity solvent 8 parts, linking agent 30 parts, Mierocrystalline cellulose 18 parts, defoamer 15 parts, flow agent 12 parts, wetting agent 16 parts, coating antiseptic 22 parts, 6 parts, tensio-active agent, non-blushing thinner 15 parts, thickening material 12 parts, 5 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Embodiment four:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 128 parts, water, auxiliary agent 55 parts, filmogen 76 parts, color stuffing 66 parts, macromolecule dispersing agent 30 parts, inorganic pigment 14 parts, aggretion type powder 20 parts, thermo-stabilizer 28 parts, adhesion promoter 25 parts, viscosity solvent 9 parts, linking agent 30 parts, Mierocrystalline cellulose 14 parts, defoamer 17 parts, flow agent 14 parts, wetting agent 18 parts, coating antiseptic 20 parts, 6 parts, tensio-active agent, non-blushing thinner 14 parts, thickening material 12 parts, 4 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Embodiment five:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 138 parts, water, auxiliary agent 48 parts, filmogen 68 parts, color stuffing 66 parts, macromolecule dispersing agent 32 parts, inorganic pigment 13 parts, aggretion type powder 19 parts, thermo-stabilizer 28 parts, adhesion promoter 28 parts, viscosity solvent 8 parts, linking agent 26 parts, Mierocrystalline cellulose 16 parts, defoamer 18 parts, flow agent 14 parts, wetting agent 16 parts, coating antiseptic 20 parts, 7 parts, tensio-active agent, non-blushing thinner 12 parts, thickening material 12 parts, 7 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Embodiment six:
The water-based blackboard paint of the present embodiment, it carries out proportioning according to the mass fraction of following material:
The adjustment of 132 parts, water, auxiliary agent 46 parts, filmogen 88 parts, color stuffing 68 parts, macromolecule dispersing agent 30 parts, inorganic pigment 13 parts, aggretion type powder 28 parts, thermo-stabilizer 28 parts, adhesion promoter 28 parts, viscosity solvent 6 parts, linking agent 30 parts, Mierocrystalline cellulose 15 parts, defoamer 15 parts, flow agent 14 parts, wetting agent 16 parts, coating antiseptic 22 parts, 6 parts, tensio-active agent, non-blushing thinner 15 parts, thickening material 12 parts, 6 parts, alkali.
The preparation method of above-mentioned water-based blackboard paint is: by water, auxiliary agent adds in dispersion cylinder, after stirring, add color stuffing, macromolecule dispersing agent carries out blending dispersion, add filmogen again and be thoroughly mixed to form mixture, add inorganic pigment successively in the mixture, aggretion type powder, thermo-stabilizer, adhesion promoter, linking agent, Mierocrystalline cellulose, flow agent, wetting agent, coating antiseptic, tensio-active agent, non-blushing thinner, alkali fully mixes, add defoamer again, viscosity adjustment solvent, thickening material fully mixes, again the final mixture of gained is tested, mixture through gained is after the assay was approved water-based blackboard paint.
Linking agent is used for linking agent for improving cross-linking density, thus improves paint film property, and the hydrophilic radical generation crosslinking reaction in linking agent and coating, improves cross-linking density, thus improve the performances such as hardness, solvent resistant, water tolerance, chemical resistant properties, sticking power.
Macromolecule dispersing agent adopts impact resistant polystyrene, and macromolecule dispersing agent for promoting that pressed powder is scattered in liquid, thus improves the hardness performance of water-based blackboard paint.
Inorganic pigment adopts colour black, and inorganic pigment can protect the color of water-based blackboard paint.
Aggretion type powder adopts Degussa carbon black FW200, and after water-based blackboard paint can be made to form paint film, light fastness is good, not easy to change.
Thermo-stabilizer adopts hot polymerization vinylchlorid, and thermo-stabilizer, for improving the thermostability of water-based blackboard paint, is convenient to store transport.
Adhesion promoter adopts solvent type resin, and adhesion promoter forms the adhesion property after film for improving water-based blackboard paint.
Viscosity adjustment solvent adopts resene solvent, and viscosity adjustment solvent is for improving the solvent resistance of water-based blackboard paint.
Coating antiseptic adopts benzimidazole ester class, and coating antiseptic is used for preventing the mouldy corrosion of coating, improves the work-ing life of water-based blackboard paint.
Tensio-active agent adopts quaternary ammonium compound, and tensio-active agent, for increasing the surfactivity of water-based blackboard paint, is convenient to the use of water-based blackboard paint.
Non-blushing thinner adopts esters solvent, and non-blushing thinner is used for preventing water-based blackboard paint from making moist, and improves the work-ing life of water-based blackboard paint.
Alkali is for reducing the irritating smell of water-based blackboard paint.
Other materials adopt common chalkboard paint starting material to meet service requirements.
In above-mentioned six embodiments, water-based blackboard paint is made according to the manufacture craft of reinforced, dispersion, toning, tune viscosity, detection, filtration, the water-based blackboard paint prepared is carried out sample making, warm air drying is adopted to carry out forced drying to model, carry out Performance Detection to the paint film formed after completing, detected result is as follows:
Can draw from detected result, water-based blackboard paint of the present invention, form that cross-linking density after film is high, solvent resistant, chemicals-resistant, temp. variation resistant, anti-ly to after-tack, the effect of anti scuffing, weathering resistance is better, after forming film, light fastness is good, not easy to change, adhesion effect is good.
The model getting 100 parts of water-based blackboard paint making of the present invention carries out hardness, solvent resistant, chemicals-resistant, temp. variation resistant, resist and after-tack, anti scuffing, weathering resistance, photostabilization, tack, the detection of thermostability, 98 increment plate hardness are qualified, 96 increment plate solvent resistances are qualified, 98 increment plate chemical resistant propertiess are qualified, 99 increment plate temp. variation resistants are qualified, 97 parts of anti-performances of after-tacking are qualified, 98 increment plate anti scuffing performances are qualified, 99 increment plate weather resistances are qualified, 96 increment plate light fastness are qualified, 99 increment plate adhesion properties are qualified, 98 increment plate thermostabilitys are qualified, comprehensively draw, the total pass rate of water-based blackboard paint performance of the present invention is 97.9%, result of use is good.
Although the present invention is described by reference to preferred embodiment, those skilled in the art should understand, and in the scope of claims, can do the various change in form and details.

Claims (2)

1. a water-based blackboard paint, it is characterized in that, it carries out proportioning according to the mass fraction of following material: 100 parts ~ 140 parts, water, auxiliary agent 40 parts ~ 60 parts, aqueous polyurethane dispersion 60 parts ~ 90 parts, color stuffing 40 parts ~ 70 parts, macromolecule dispersing agent 20 parts ~ 35 parts, inorganic pigment 10 parts ~ 15 parts, carbon black 15 parts ~ 30 parts, thermo-stabilizer 10 parts ~ 30 parts, adhesion promoter 20 parts ~ 30 parts, viscosity adjustment solvent 5 parts ~ 10 parts, linking agent 20 parts ~ 40 parts, Mierocrystalline cellulose 10 parts ~ 20 parts, defoamer 10 parts ~ 20 parts, flow agent 8 parts ~ 15 parts, wetting agent 9 parts ~ 18 parts, coating antiseptic 12 parts ~ 24 parts, 4 parts ~ 8 parts, tensio-active agent, non-blushing thinner 9 parts ~ 16 parts, thickening material 10 parts ~ 15 parts, 4 parts ~ 8 parts, alkali.
2. water-based blackboard paint according to claim 1, it is characterized in that, it carries out proportioning according to the mass fraction of following material: 120 parts, water, auxiliary agent 50 parts, aqueous polyurethane dispersion 80 parts, color stuffing 60 parts, macromolecule dispersing agent 28 parts, inorganic pigment 13 parts, carbon black 18 parts, thermo-stabilizer 20 parts, adhesion promoter 25 parts, viscosity adjustment solvent 8 parts, linking agent 24 parts, Mierocrystalline cellulose 16 parts, defoamer 16 parts, flow agent 14 parts, wetting agent 15 parts, coating antiseptic 20 parts, 6 parts, tensio-active agent, non-blushing thinner 12 parts, thickening material 12 parts, 7 parts, alkali.
CN201310149701.7A 2013-04-26 2013-04-26 Water-based blackboard paint Active CN103254749B (en)

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Publication number Priority date Publication date Assignee Title
CN107129711A (en) * 2017-07-03 2017-09-05 四川马可视觉网络科技有限公司 Anti- tarnishing poster paint
CN107141987A (en) * 2017-07-03 2017-09-08 四川马可视觉网络科技有限公司 Anti- tarnishing smell poster paint
CN111393917A (en) * 2020-04-22 2020-07-10 厦门锦德兴工贸有限公司 Water-based paint and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1477162A (en) * 2003-06-27 2004-02-25 辉 陈 Preparation method of blackboard paint
CN101712843A (en) * 2009-12-29 2010-05-26 谢立华 Color paste for environment-friendly blackboard coating and preparation method of special maintenance coating for environment-friendly blackboard

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5334833A (en) * 1976-09-13 1978-03-31 Suzuka Toryo Paint for blackboard and like

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1477162A (en) * 2003-06-27 2004-02-25 辉 陈 Preparation method of blackboard paint
CN101712843A (en) * 2009-12-29 2010-05-26 谢立华 Color paste for environment-friendly blackboard coating and preparation method of special maintenance coating for environment-friendly blackboard

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Denomination of invention: A water-based blackboard paint coating

Effective date of registration: 20231017

Granted publication date: 20150715

Pledgee: Jingning She Autonomous County Branch of China Postal Savings Bank Co.,Ltd.

Pledgor: JINGNING FULIDA WOODEN CRAFT CO.,LTD.

Registration number: Y2023980061365