CN103011596A - Wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force - Google Patents
Wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force Download PDFInfo
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- CN103011596A CN103011596A CN2012105490756A CN201210549075A CN103011596A CN 103011596 A CN103011596 A CN 103011596A CN 2012105490756 A CN2012105490756 A CN 2012105490756A CN 201210549075 A CN201210549075 A CN 201210549075A CN 103011596 A CN103011596 A CN 103011596A
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- porcelain enamel
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- enamel material
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Abstract
The invention relates to a porcelain enamel material, in particular to a wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force. The porcelain enamel material comprises the following components by mass percent: 20-30% of quartz, 15-25 % of mica, 15-25% of feldspar, 2-5% of calcium oxide, barium oxide or lithium oxide, 2-5% of sodium oxide, 2-5% of aluminium sesquioxide, 2-5% of boric oxide, 1-3% of cobaltous oxide, 1-3% of polyethylene wax powder and 2-5% of calcium fluoride. Preferably, the porcelain enamel material comprises the following components by mass percent: 30% of quartz, 20% of mica, 22% of feldspar, 5% of calcium oxide, barium oxide or lithium oxide, 5% of sodium oxide, 4% of aluminium sesquioxide, 4% of boric oxide, 3% of cobaltous oxide, 2% of polyethylene wax powder and 5% of calcium fluoride. The porcelain enamel material provided by the invention has good adhesive force and is wear-resistant and corrosion-resistant.
Description
Technical field
The present invention relates to a kind of frit for porcelain enamel.
Background technology
Frit for porcelain enamel be for the application of slip at the metal mold, consist of the glass state material of alkali-boron-silicate.It had both had the intrinsic physical strength of metal and processing characteristics, have again that the figure layer has corrosion-resistant, wear-resisting, heat-resisting, nontoxic and can be ornamental.It is widely used in the daily life, such as tableware, kitchen tools, wall, floor etc.
Summary of the invention
Technical problem to be solved by this invention provides the good frit for porcelain enamel of a kind of wear resistant corrosion resistant sticking power, and this frit for porcelain enamel has difficult drop-off, wear-resisting, corrosion resistant advantage.
Technical problem to be solved by this invention is achieved by the following technical programs:
The good frit for porcelain enamel of a kind of wear resistant corrosion resistant sticking power is comprised of the component of following mass percent:
Quartz 20 ~ 30%, mica 15 ~ 25%, feldspar 15 ~ 25%, calcium oxide or barium oxide or Lithium Oxide 98min 2 ~ 5%, sodium oxide 2 ~ 5%, aluminium sesquioxide 2 ~ 5%, boron oxide 2 ~ 5%, cobalt oxide 1 ~ 3%, polyethylene wax powder 1 ~ 3%, Calcium Fluoride (Fluorspan) 2 ~ 5%.
Further, each component and mass percent are preferably: quartz 30%, mica 20%, feldspar 22%, calcium oxide or barium oxide or Lithium Oxide 98min 5%, sodium oxide 5%, aluminium sesquioxide 4%, boron oxide 4%, cobalt oxide 3%, polyethylene wax powder 2%, Calcium Fluoride (Fluorspan) 5%.
The present invention has following beneficial effect:
Glaze sticking power of the present invention is good, wear-resisting, corrosion-resistant.
Embodiment
The present invention will be described in detail below in conjunction with embodiment, and embodiment only is preferred implementation of the present invention, is not limitation of the invention.
The good frit for porcelain enamel of a kind of wear resistant corrosion resistant sticking power is comprised of the component of following mass percent: quartzy 30%, mica 20%, feldspar 22%, calcium oxide or barium oxide or Lithium Oxide 98min 5%, sodium oxide 5%, aluminium sesquioxide 4%, boron oxide 4%, cobalt oxide 3%, polyethylene wax powder 2%, Calcium Fluoride (Fluorspan) 5%.
The preparation method of this frit for porcelain enamel is: each raw material fully pulverized, mixed, drop in the crucible, and fusing under 1200 degree, then cold quenching in cold water is pulled oven dry out, solidifies to get block frit.The preparation method is this area general knowledge, is not described in detail.
Above-mentioned frit for porcelain enamel is made enameling sheet take stainless steel plate as matrix, carry out the detection of tack, wear resistance, erosion resistance.
(1) adhesion test method is:
Mark the lattice (scratch depth is controlled at and guarantees film lower substrate metal exposed) of 100 1mm of being spaced apart of uniform size with sharp blade on the enameling sheet surface, the lattice that the ketone group glaze comes off is counted N1, the scotch tape that width is 24mm is sticked in the lattice zone of drawing on film, and guarantees between adhesive tape and the film that grid is arranged in conjunction with tight.Behind the 5min, with the power of a vertical face adhesive tape is uncovered, and is again added up the lattice that film comes off and count N2.Appraisal procedure is as follows: adopt centesimal system, film sticking power mark=100-(N1+N2), film sticking power mark is larger, illustrates that sticking power is better.
(2) abrasion resistance test method is:
Enameling sheet put into take out after 2h is ground in oscillating mill continuous shaking, whether the rete of observing the corner angle of enameling sheet and surface has comes off.
(3) erosion resistance testing method:
Weigh by salt-fog test, the salt-fog test method is for to place enameling sheet in the salt-mist corrosion tester, 35 the degree under with 5% sodium chloride aqueous solution splash 2h after, taking out and being placed on another temperature again is that 40 degree, relative humidity are in 80% the climatic chamber, how long the rear surface occurs unusual to observe it, time is longer, illustrates that the erosion resistance of rete is better.
Test-results is as shown in table 1.
| Film sticking power mark | Wear resistance | Erosion resistance (lab scale) |
| 100 | Corner angle and surface are all without any coming off | 240 |
As can be seen from Table 1, the board with enamel panel layer made of frit for porcelain enamel of the present invention has good sticking power, wear resistance and erosion resistance.
Claims (2)
1. the frit for porcelain enamel that wear resistant corrosion resistant sticking power is good is characterized in that, is comprised of the component of following mass percent:
Quartz 20 ~ 30%, mica 15 ~ 25%, feldspar 15 ~ 25%, calcium oxide or barium oxide or Lithium Oxide 98min 2 ~ 5%, sodium oxide 2 ~ 5%, aluminium sesquioxide 2 ~ 5%, boron oxide 2 ~ 5%, cobalt oxide 1 ~ 3%, polyethylene wax powder 1 ~ 3%, Calcium Fluoride (Fluorspan) 2 ~ 5%.
2. the good frit for porcelain enamel of wear resistant corrosion resistant sticking power according to claim 1 is characterized in that, each component and mass percent are preferably:
Quartz 30%, mica 20%, feldspar 22%, calcium oxide or barium oxide or Lithium Oxide 98min 5%, sodium oxide 5%, aluminium sesquioxide 4%, boron oxide 4%, cobalt oxide 3%, polyethylene wax powder 2%, Calcium Fluoride (Fluorspan) 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210549075.6A CN103011596B (en) | 2012-12-18 | 2012-12-18 | Wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210549075.6A CN103011596B (en) | 2012-12-18 | 2012-12-18 | Wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103011596A true CN103011596A (en) | 2013-04-03 |
| CN103011596B CN103011596B (en) | 2015-04-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210549075.6A Expired - Fee Related CN103011596B (en) | 2012-12-18 | 2012-12-18 | Wear-resistant and corrosion-resistant porcelain enamel material with good adhesive force |
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| CN (1) | CN103011596B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103723922A (en) * | 2013-12-09 | 2014-04-16 | 常熟市永达化工设备厂 | Wear-resistant corrosion-resistant enamel glaze with good adhesive force |
| CN105294171A (en) * | 2015-11-20 | 2016-02-03 | 常熟市永达化工设备厂 | Corrosion-resistant enamel glaze |
| CN106746646A (en) * | 2016-12-15 | 2017-05-31 | 宜兴市吾牛陶紫砂艺术研究院 | A kind of equal bristol glaze |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1749196A1 (en) * | 1990-05-03 | 1992-07-23 | Чебоксарское производственное объединение "Химпром" | Composition for repair glass enamel coating |
| CN102040335A (en) * | 2009-10-21 | 2011-05-04 | 哈尔滨天路搪瓷制品有限责任公司 | Coten base enamel and glazeslip thereof |
-
2012
- 2012-12-18 CN CN201210549075.6A patent/CN103011596B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1749196A1 (en) * | 1990-05-03 | 1992-07-23 | Чебоксарское производственное объединение "Химпром" | Composition for repair glass enamel coating |
| CN102040335A (en) * | 2009-10-21 | 2011-05-04 | 哈尔滨天路搪瓷制品有限责任公司 | Coten base enamel and glazeslip thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103723922A (en) * | 2013-12-09 | 2014-04-16 | 常熟市永达化工设备厂 | Wear-resistant corrosion-resistant enamel glaze with good adhesive force |
| CN105294171A (en) * | 2015-11-20 | 2016-02-03 | 常熟市永达化工设备厂 | Corrosion-resistant enamel glaze |
| CN106746646A (en) * | 2016-12-15 | 2017-05-31 | 宜兴市吾牛陶紫砂艺术研究院 | A kind of equal bristol glaze |
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| Publication number | Publication date |
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| CN103011596B (en) | 2015-04-29 |
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Granted publication date: 20150429 Termination date: 20181218 |