CN102993928A - Quick-drying type efficient anticorrosion alkyd iron red coating and preparation method thereof - Google Patents

Quick-drying type efficient anticorrosion alkyd iron red coating and preparation method thereof Download PDF

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Publication number
CN102993928A
CN102993928A CN2012105061074A CN201210506107A CN102993928A CN 102993928 A CN102993928 A CN 102993928A CN 2012105061074 A CN2012105061074 A CN 2012105061074A CN 201210506107 A CN201210506107 A CN 201210506107A CN 102993928 A CN102993928 A CN 102993928A
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China
Prior art keywords
quick
type efficient
alkyd
iron oxide
drying type
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CN2012105061074A
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Chinese (zh)
Inventor
李连才
胡胜初
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WUXI HUHUANG PAINT CO Ltd
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WUXI HUHUANG PAINT CO Ltd
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Priority to CN2012105061074A priority Critical patent/CN102993928A/en
Publication of CN102993928A publication Critical patent/CN102993928A/en
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  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a quick-drying type efficient anticorrosion alkyd iron red coating and a preparation method thereof. The quick-drying type efficient anticorrosion alkyd iron red coasting comprises the following components in percentage by weight: 15 to 50% of dry vegetable oil modified alkyd resin, 10 to 25% of butyl acetate, 0.1 to 0.5% of dispersing agent, 10 to 30% of iron oxide red, 5 to 30% of talcum powder, 0.5 to 1% of bentonite, 0.1 to 0.3% of diacetylmonoxime, and 0.5 to 1% of combination drier. The quick-drying type efficient anticorrosion alkyd iron red coating disclosed by the invention is always used as the primer to be applicable to black surfaces such as the surface of a large-scale steel structure and the surface of a bridge. The quick-drying type efficient anticorrosion alkyd iron red coating is higher in adhesive force and moisture resistance and high in back paint connection, and is specially applicable to resisting the corrosion from the atmosphere. The quick-drying type efficient anticorrosion alkyd iron red coating can be dried and delivered for use within seven days. Compared with the coating with anticorrosion effect lasting for about six months in the prior art, the quick-drying type efficient anticorrosion alkyd iron red coating disclosed by the invention has the anticorrosive effect up to two years, and the hardness reaches of level HB.

Description

A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating and preparation method thereof
Technical field
The invention belongs to chemical technology field, relate to a kind of protective system and preparation method thereof, be specifically related to a kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating and preparation method thereof.
Background technology
The protective system of prior art be by long-oil-length tetramethylolmethane, Synolac and iron oxide pigment, additive etc. through grinding and add an amount of aluminum paste, the siccative such as cobalt, manganese, lead and organic solvent are formulated.There is time of drying slow (generally needing to parch about 15-20 days), difference of hardness (F level), the technical problem such as Corrosion Protection is poor.
Summary of the invention
Slow time of drying for the existing protective system that background technology proposes, difference of hardness, the technical problem such as anticorrosion ability is poor the object of the present invention is to provide a kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating.This coating is applicable to large-scale steel structure, and generally use as priming paint the metallic surface of the black such as bridge.Has preferably sticking power, moistureproofness, good, the special erosion that can adapt to Chinese People's Anti-Japanese Military and Political College's gas of bottom surface lacquer communication property.
Another object of the present invention is to provide a kind of preparation method of quick-dry type efficient corrosion resisting alkyd iron oxide red coating.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter comprises following component by weight:
Dry vegetable oil modified alkyd resin 15% ~ 50%
N-BUTYL ACETATE 10% ~ 25%
Dispersion agent 0.1% ~ 0.5%
Red iron oxide 10% ~ 30%
Talcum powder 5% ~ 30%
Wilkinite 0.5% ~ 1%
Diacetylmonoxime 0.1% ~ 0.3%
Composite drier 0.5% ~ 1%.
Each composition weight percentage composition sum of above-mentioned quick-dry type efficient corrosion resisting alkyd iron oxide red coating is 100%.
Preferably, the weight percentage of each component is:
Dry vegetable oil modified alkyd resin 20% ~ 40%
N-BUTYL ACETATE 15% ~ 20%
Dispersion agent 0.1% ~ 0.5%
Red iron oxide 15% ~ 30%
Talcum powder 10% ~ 30%
Wilkinite 0.5% ~ 1%
Diacetylmonoxime 0.1% ~ 0.3%
Composite drier 0.5% ~ 1%.
The preparation method of above-mentioned quick-dry type efficient corrosion resisting alkyd iron oxide red coating is: be ground to fineness≤30 μ m after first dry vegetable oil modified alkyd resin, N-BUTYL ACETATE, dispersion agent, red iron oxide, talcum powder, wilkinite being mixed in proportion, then add in proportion Diacetylmonoxime and composite drier and mix.
What the present invention adopted is that adding composite drier and anti-skinning auxiliary agent (Diacetylmonoxime) are formulated with after refining dry vegetable oil modified alkyd resin and red iron oxide (rust-stabilising pigment), pigment extender (talcum powder), dispersion agent, anti-settling agent (wilkinite) and solvent (N-BUTYL ACETATE) grinding.
Beneficial effect of the present invention:
Quick-dry type efficient corrosion resisting alkyd iron oxide red coating of the present invention is applicable to large-scale steel structure, and generally use as priming paint the metallic surface of the black such as bridge.Has preferably sticking power, moistureproofness, good, the special erosion that can adapt to Chinese People's Anti-Japanese Military and Political College's gas of bottom surface lacquer communication property.This coating can be delivered for use at 7 days inner dryings.The anticorrosion ability of prior art is about six months, and this product can be brought up to Corrosion Protection 2 years, and hardness reaches the HB level.
Embodiment
Use raw material:
Dispersion agent: BYK-104S
Composite drier: V-10, Wuxi moral space chemical industry
Talcum powder: 1250 orders
N-BUTYL ACETATE, red iron oxide, wilkinite, Diacetylmonoxime are conventional commercially available prod.
The dry vegetable oil modified alkyd resin, model C Y60: Jiangsu Miki Chemical Co., Ltd.
Embodiment 1
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter is composed of the following components by weight:
Dry vegetable oil modified alkyd resin 35%
N-BUTYL ACETATE 20%
Dispersion agent 0.3%
Red iron oxide 20%
Talcum powder 23%
Wilkinite 0.7%
Diacetylmonoxime 0.2%
Composite drier 0.8%.
Preparation technology:
Be ground to fineness≤30 μ m after first dry vegetable oil modified alkyd resin, N-BUTYL ACETATE, dispersion agent, red iron oxide, talcum powder, wilkinite being mixed in proportion, then add in proportion Diacetylmonoxime and composite drier and mix.
Embodiment 2
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter is composed of the following components by weight:
Dry vegetable oil modified alkyd resin 40%
N-BUTYL ACETATE 15%
Dispersion agent 0.3%
Red iron oxide 23%
Talcum powder 20%
Wilkinite 0.8%
Diacetylmonoxime 0.2%
Composite drier 0.7%.
Preparation technology is with embodiment 1.
Embodiment 3
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter is composed of the following components by weight:
Dry vegetable oil modified alkyd resin 30%
N-BUTYL ACETATE 18%
Dispersion agent 0.5%
Red iron oxide 30%
Talcum powder 20%
Wilkinite 0.5%
Diacetylmonoxime 0.3%
Composite drier 0.7%.
Preparation technology is with embodiment 1.
Embodiment 4
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter is composed of the following components by weight:
Dry vegetable oil modified alkyd resin 20%
N-BUTYL ACETATE 20%
Dispersion agent 0.5%
Red iron oxide 28
Talcum powder 30%
Wilkinite 0.5%
Diacetylmonoxime 0.2%
Composite drier 0.8%.
Preparation technology is with embodiment 1.
Embodiment 5
A kind of quick-dry type efficient corrosion resisting alkyd iron oxide red coating, the percentage composition meter is composed of the following components by weight:
Dry vegetable oil modified alkyd resin 50%
N-BUTYL ACETATE 25%
Dispersion agent 0.4%
Red iron oxide 10%
Talcum powder 13%
Wilkinite 0.6%
Diacetylmonoxime 0.2%
Composite drier 0.8%.
Preparation technology is with embodiment 1.
Adopt the using method of the product of embodiment 1-5 preparation: directly adjusting viscosity with thinner according to the construction needs can use, thinner is dimethylbenzene, the thinner consumption is that 5 ~ 20%(is after the per 1 part dilution in the coating, and the percentage composition meter contains 5 ~ 20% dimethylbenzene by weight).The performance test results of the quick-dry type efficient corrosion resisting alkyd iron oxide red coating that embodiment 1 ~ 5 is prepared sees Table 1.
Table 1 is the result of the Performance Detection of the quick-dry type efficient corrosion resisting alkyd iron oxide red coating of embodiment 1-5 preparation
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Hardness HB HB HB HB HB
Sticking power 1 grade 1 grade 1 grade 1 grade 1 grade
Time of drying 7 days 7 days 5 days 5 days 6 days
[0094]Quick-dry type efficient corrosion resisting alkyd iron oxide red coating of the present invention is applicable to large-scale steel structure, and generally use as priming paint the metallic surface of the black such as bridge.Has preferably sticking power, moistureproofness, good, the special erosion that can adapt to Chinese People's Anti-Japanese Military and Political College's gas of bottom surface lacquer communication property.This coating can be delivered for use at 7 days inner dryings.The anticorrosion ability of prior art is about six months, and this product can be brought up to Corrosion Protection 2 years, and hardness reaches the HB level.

Claims (4)

1. quick-dry type efficient corrosion resisting alkyd iron oxide red coating is characterized in that the percentage composition meter comprises following component by weight:
Dry vegetable oil modified alkyd resin 15% ~ 50%
N-BUTYL ACETATE 10% ~ 25%
Dispersion agent 0.1% ~ 0.5%
Red iron oxide 10% ~ 30%
Talcum powder 5% ~ 30%
Wilkinite 0.5% ~ 1%
Diacetylmonoxime 0.1% ~ 0.3%
Composite drier 0.5% ~ 1%.
2. quick-dry type efficient corrosion resisting alkyd iron oxide red coating according to claim 1 is characterized in that the weight percentage of each component is:
Dry vegetable oil modified alkyd resin 20% ~ 40%
N-BUTYL ACETATE 15% ~ 20%
Dispersion agent 0.1% ~ 0.5%
Red iron oxide 15% ~ 30%
Talcum powder 10% ~ 30%
Wilkinite 0.5% ~ 1%
Diacetylmonoxime 0.1% ~ 0.3%
Composite drier 0.5% ~ 1%.
3. quick-dry type efficient corrosion resisting alkyd iron oxide red coating according to claim 1, it is characterized in that its preparation method is: be ground to fineness≤30 μ m after first dry vegetable oil modified alkyd resin, N-BUTYL ACETATE, dispersion agent, red iron oxide, talcum powder, wilkinite being mixed in proportion, then add in proportion Diacetylmonoxime and composite drier and mix.
4. quick-dry type efficient corrosion resisting alkyd iron oxide red coating claimed in claim 1, be ground to fineness≤30 μ m after it is characterized in that first dry vegetable oil modified alkyd resin, N-BUTYL ACETATE, dispersion agent, red iron oxide, talcum powder, wilkinite being mixed in proportion, then add in proportion Diacetylmonoxime and composite drier and mix.
CN2012105061074A 2012-11-30 2012-11-30 Quick-drying type efficient anticorrosion alkyd iron red coating and preparation method thereof Pending CN102993928A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525279A (en) * 2013-10-09 2014-01-22 丹阳市永生涂料有限公司 Iron oxide red antirust primer
CN103725175A (en) * 2014-01-27 2014-04-16 厦门双瑞船舶涂料有限公司 Thick film modified alkyd paint and preparation method thereof
CN104449390A (en) * 2014-11-24 2015-03-25 天长市开林化工有限公司 Quick-drying, alcohol-soluble and antirust paint and preparation method thereof
CN105038542A (en) * 2015-08-05 2015-11-11 天长市开林化工有限公司 Industrial high-performance alkyd resin coating and preparation method thereof
CN105038543A (en) * 2015-08-05 2015-11-11 天长市开林化工有限公司 Alkyd resin coating for industrial outer wall and preparation method thereof
CN105349009A (en) * 2015-12-24 2016-02-24 常熟市福达金属制件有限公司 IBC (intermediate bulk container) for food production
CN105567064A (en) * 2016-03-24 2016-05-11 叶青 Environment-friendly quick-drying dark red paint for metals
CN105860788A (en) * 2016-05-09 2016-08-17 上海漆盟化工有限公司 Environment-friendly quick-drying waterborne alkyd paint and preparation method thereof
CN107603437A (en) * 2017-09-30 2018-01-19 江苏冠军科技集团股份有限公司 A kind of high solid steel structure anti-corrosion paint and preparation method thereof
CN107629647A (en) * 2017-10-17 2018-01-26 江苏欣安新材料技术有限公司 A kind of alkyd rustproof paint and its production method
CN110028883A (en) * 2019-05-05 2019-07-19 重庆三峡油漆股份有限公司 A kind of air-drying property coating and preparation method thereof being effectively improved skinning
CN113372798A (en) * 2021-07-06 2021-09-10 安徽江锐新材料有限公司 Scratch-resistant quick-drying alkyd iron red primer and preparation process thereof
CN113652153A (en) * 2021-08-20 2021-11-16 江苏冠军科技集团股份有限公司 Oily coating composition and preparation method and application thereof
CN114231138A (en) * 2021-12-14 2022-03-25 安徽衡光新材料科技有限公司 Oily alkyd paint and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245219A (en) * 2008-02-29 2008-08-20 浙江天女集团制漆有限公司 Alkyd paint with low content of VOC and manufacture method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245219A (en) * 2008-02-29 2008-08-20 浙江天女集团制漆有限公司 Alkyd paint with low content of VOC and manufacture method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525279A (en) * 2013-10-09 2014-01-22 丹阳市永生涂料有限公司 Iron oxide red antirust primer
CN103725175B (en) * 2014-01-27 2016-08-17 厦门双瑞船舶涂料有限公司 A kind of thick-film modified alkyd paint and preparation method thereof
CN103725175A (en) * 2014-01-27 2014-04-16 厦门双瑞船舶涂料有限公司 Thick film modified alkyd paint and preparation method thereof
CN104449390A (en) * 2014-11-24 2015-03-25 天长市开林化工有限公司 Quick-drying, alcohol-soluble and antirust paint and preparation method thereof
CN105038542A (en) * 2015-08-05 2015-11-11 天长市开林化工有限公司 Industrial high-performance alkyd resin coating and preparation method thereof
CN105038543A (en) * 2015-08-05 2015-11-11 天长市开林化工有限公司 Alkyd resin coating for industrial outer wall and preparation method thereof
CN105349009A (en) * 2015-12-24 2016-02-24 常熟市福达金属制件有限公司 IBC (intermediate bulk container) for food production
CN105567064A (en) * 2016-03-24 2016-05-11 叶青 Environment-friendly quick-drying dark red paint for metals
CN105860788A (en) * 2016-05-09 2016-08-17 上海漆盟化工有限公司 Environment-friendly quick-drying waterborne alkyd paint and preparation method thereof
CN107603437A (en) * 2017-09-30 2018-01-19 江苏冠军科技集团股份有限公司 A kind of high solid steel structure anti-corrosion paint and preparation method thereof
CN107629647A (en) * 2017-10-17 2018-01-26 江苏欣安新材料技术有限公司 A kind of alkyd rustproof paint and its production method
CN110028883A (en) * 2019-05-05 2019-07-19 重庆三峡油漆股份有限公司 A kind of air-drying property coating and preparation method thereof being effectively improved skinning
CN113372798A (en) * 2021-07-06 2021-09-10 安徽江锐新材料有限公司 Scratch-resistant quick-drying alkyd iron red primer and preparation process thereof
CN113652153A (en) * 2021-08-20 2021-11-16 江苏冠军科技集团股份有限公司 Oily coating composition and preparation method and application thereof
CN114231138A (en) * 2021-12-14 2022-03-25 安徽衡光新材料科技有限公司 Oily alkyd paint and preparation method thereof

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Application publication date: 20130327