CN102993352A - Tank truck quick-drying primer and acrylic resin for same - Google Patents
Tank truck quick-drying primer and acrylic resin for same Download PDFInfo
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- CN102993352A CN102993352A CN2012105060620A CN201210506062A CN102993352A CN 102993352 A CN102993352 A CN 102993352A CN 2012105060620 A CN2012105060620 A CN 2012105060620A CN 201210506062 A CN201210506062 A CN 201210506062A CN 102993352 A CN102993352 A CN 102993352A
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Abstract
The invention discloses an acrylic resin quick-drying primer for a tank truck and a preparation method of the primer. The acrylic resin quick-drying primer comprises the following components in parts by weight: 1000-1400 parts of backing material A component, 2130-2865 parts of mixed monomer B component, 75-145 parts of supplementary C component and 1000-1400 parts of dilution D component, wherein the backing material A component consists of xylene; the mixed monomer B component comprises the following materials: methyl methacrylate, crylic acid, butyl acrylate, hydroxyethyl acrylate, phenyl ethylene, iso-octyl acrylate and TBPB (tert butylperoxy benzoate) initiator; the supplementary C component comprises TBPB and xylene; and the dilution D component is toluene. The acrylic resin quick-drying primer for a tank truck is quickly dried, is solvent-resistant, has good comprehensive performances, and meets the special requirement of continuously coating the tank truck; and the preparation method of the primer is simple and easily implemented.
Description
Technical field
The invention belongs to the synthetic resins field, be specifically related to a kind of tank wagon quick-drying primer with acrylic resin and tank wagon quick-drying primer.
Background technology
Tank wagon is a kind of large-scale storage facilities, because equipment is relatively large, can not enter the drying room forced drying behind the paint spraying, can only be the normal temperature seasoning.And all be that the continuous spray operation is that first spray base is followed again spray paint, general about 30 minutes of the time spent of spraying sprays one and is then spraying next from the end to the face.Usually using these several series products on the market now: 1: thermoplastic acrylic resin is made bottom paint resin, its feature is fast drying, can satisfy the needs of continuous spray, but end phenomenon occurs stinging owing to the anti-solvent of priming paint missionary society when spray paint, surface effect is too poor; 2: hydroxyl acrylic resin is made bottom paint resin, if there is time enough crosslinked, the over-all properties of paint can be very good, but it is too slow that shortcoming is surface drying, usually need 20 ~ 30 minutes ability surface dryings, end phenomenon when spray paint, also can occur stinging, can not satisfy the needs of continuous spray operation.
Because all there are various problems in existing acrylic resin, is difficult to reach the requirement of tank wagon continuous spray.Need to develop a kind of both quick-dryings for this phenomenon, solvent-proof acrylic resin product reaches the particular requirement of tank wagon spraying again.
Summary of the invention
The object of the invention is to the technical problem for the background technology proposition, a kind of tank wagon quick-drying primer acrylic resin is provided.The present invention researches and develops the characteristics that a kind of marginal product had both had the thermoplastic acrylic resin quick-drying in conjunction with the characteristics of thermoplastic acrylic resin and hydroxyl acrylic resin, has again the anti-solvent of hydroxyl acrylic resin, the characteristics of good combination property.Thereby satisfy the requirement of tank wagon continuous spray.
Another object of the present invention is to provide a kind of tank wagon quick-drying primer.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of tank wagon quick-drying primer acrylic resin, by weight, described acrylic resin comprises following component: 1000 ~ 1400 parts of hearth layer A components, 2130 ~ 2865 parts of mix monomer B components, add C component 75 ~ 145 and latting drown D component 1000 ~ 1400;
Wherein, the raw material of described hearth layer A component is dimethylbenzene;
Mix monomer B component is comprised of following raw material: 5 ~ 15 parts of 50 ~ 90 parts of 820 ~ 1025 parts of methyl methacrylates, 5 ~ 25 parts in vinylformic acid, 500 ~ 700 parts of butyl acrylates, 150 ~ 210 parts of Hydroxyethyl acrylates, 600 ~ 800 parts of vinylbenzene, Isooctyl acrylate monomer and TBPB initiators;
Adding the C component is comprised of 70 ~ 130 parts of 5 ~ 15 parts of TBPB and dimethylbenzene;
The raw material of latting drown D component is toluene.
Preferably, described acrylic resin comprises following component: 1100 ~ 1300 parts of hearth layer A components, 2344 ~ 2656 parts of mix monomer B components, add 1100 ~ 1300 parts of 100 ~ 120 parts of C components and latting drown D components;
Mix monomer B component is comprised of following raw material: 8 ~ 12 parts of 64 ~ 76 parts of 875 ~ 975 parts of methyl methacrylates, 12 ~ 18 parts in vinylformic acid, 560 ~ 640 parts of butyl acrylates, 165 ~ 195 parts of Hydroxyethyl acrylates, 660 ~ 740 parts of vinylbenzene, Isooctyl acrylate monomer and TBPB initiators;
Adding the C component is comprised of 92 ~ 108 parts of 8 ~ 12 parts of TBPB and dimethylbenzene.
Further preferred, described acrylic resin comprises following component: 1200 parts of hearth layer A components, 2500 parts of mix monomer B components, add 1200 parts of 110 parts of C components and latting drown D components;
Mix monomer B component is comprised of following raw material: 10 parts of 925 parts of methyl methacrylates, 15 parts in vinylformic acid, 600 parts of butyl acrylates, 180 parts of Hydroxyethyl acrylates, 700 parts of vinylbenzene, 70 parts of Isooctyl acrylate monomers and TBPB initiators;
Adding the C component is comprised of 100 parts of 10 parts of TBPB and dimethylbenzene.
Above-mentioned tank wagon quick-drying primer may further comprise the steps with the preparation method of acrylic resin:
1) takes by weighing in proportion methyl methacrylate, vinylformic acid, butyl acrylate, Hydroxyethyl acrylate, vinylbenzene, Isooctyl acrylate monomer and TBPB initiator and mix, make mix monomer B component;
2) taking by weighing in proportion TBPB and dimethylbenzene makes and adds the C component;
3) hearth layer A component is dropped into reactor, then reactor is warming up to 130 ~ 140 ℃, drip mix monomer B component, dropwise rear insulation 2 ~ 4 hours, will add the C component and drip half and also be incubated 0.5 ~ 1.5 hour, then drip residue and add the C component, be incubated 2 ~ 4 hours, drip again latting drown D component and stir, be cooled to below 80 ℃, filter packing.
A kind of tank wagon quick-drying primer, the percentage composition meter comprises following component: acrylic resin 38 ~ 48% claimed in claim 1, pigment 6 ~ 10%, cellulose acetate butyrate 2 ~ 4%, silicone antifoam agent 0.05 ~ 1%, flow agent 0.1 ~ 1%, anti-settling agent 0.5 ~ 2%, mixed solvent 35 ~ 46% and solidifying agent 2 ~ 6% by weight.
Comprise dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE in the described mixed solvent.The usage ratio of dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE affects the volatilization ratio of mixed solvent, the speed of surface drying; Can adjust as required, the weight ratio of dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE is preferably 5:2:3.
Pigment can be adjusted according to client's needs, can select metallic pigment, substitutes such as pigment such as aluminium silver powder, titanium dioxide or medium chrome yellow medium yellows.
Cellulose acetate butyrate mainly has been that pigment is directed in prescription, accelerates drying varniss, eliminates the paint film shrinkage cavity, improves solvent release, improves the hardness that colo(u)rant dispersion is arranged effect, improved coating.
Flow agent can be selected as required, is preferably EFKA-3777 or the flow agent of the same type with EFKA-3777.
Beneficial effect of the present invention:
Adopt the acrylic resin of the present invention's preparation as the tank wagon quick-drying primer of base-material preparation, both quick-dryings, anti-solvent again, good combination property can satisfy the particular requirement of tank wagon continuous spray.Preparation method's technique of this acrylic resin and priming paint is simple, easy handling.
Embodiment
Use raw material:
Pigment: aluminium silver powder, titanium dioxide or medium chrome yellow medium yellow.
Cellulose acetate butyrate (CAB-551-0.5S)
Flow agent: EFKA-3777
Anti-settling agent: 201-P(solid content 10%), the modest company of Taiwan moral, chemical ingredients: polyethylene wax, solvent: dimethylbenzene/Virahol
Mixed solvent: dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are mixed with by the weight ratio of 5:2:3.
Silicone antifoam agent: BYK-141, German Bi Ke chemistry BYK auxiliary agent can be used for universal industrial coating
Solidifying agent: N-3390, the tripolymer product of the HDI of German Bayer company.
Embodiment 1
A kind of tank wagon quick-drying primer acrylic resin comprises following component: hearth layer A component 1200 Kg, mix monomer B component 2500 Kg, add C component 110 Kg and latting drown D component 1200 Kg; Wherein:
Hearth layer A component is dimethylbenzene;
Mix monomer B component is comprised of following raw material: methyl methacrylate 925 Kg, vinylformic acid 15 Kg, butyl acrylate 600 Kg, Hydroxyethyl acrylate 180 Kg, vinylbenzene 700 Kg, Isooctyl acrylate monomer 70 Kg and TBPB initiator 10 Kg; Mix monomer B component adds up to quality 2500 Kg;
Adding the C component is comprised of TBPB 10 Kg and dimethylbenzene 100 Kg;
Latting drown D component is toluene.
Production method is as follows:
1) takes by weighing in proportion methyl methacrylate, vinylformic acid, butyl acrylate, Hydroxyethyl acrylate, vinylbenzene, Isooctyl acrylate monomer and TBPB initiator and mix, make mix monomer B component;
2) taking by weighing in proportion TBPB and dimethylbenzene makes and adds the C component;
3) hearth layer A component is dropped into reactor, then reactor is warming up to 135 ± 2 ℃ under condition of normal pressure, drips mix monomer B component, after evenly dropwising in 3 hours, be incubated 3 hours, to add the C component and drip half (55Kg) and be incubated 1 hour, and then drip residue and add C component (55Kg), be incubated 3 hours, dripping latting drown D component stirs again, be cooled to below 80 ℃ after middle control fine setting touches the mark, filter packing.
Embodiment 2
A kind of tank wagon quick-drying primer acrylic resin comprises following component: hearth layer A component 1100 Kg, mix monomer B component 2344 Kg, add C component 100Kg and latting drown D component 1100 Kg; Wherein:
Hearth layer A component is dimethylbenzene;
Mix monomer B component is comprised of following raw material: methyl methacrylate 875 Kg, vinylformic acid 12 Kg, butyl acrylate 560 Kg, Hydroxyethyl acrylate 165Kg, vinylbenzene 660 Kg, Isooctyl acrylate monomer 64 Kg and TBPB initiator 8 Kg; Mix monomer B component adds up to quality 2344 Kg;
Adding the C component is comprised of TBPB 8Kg and dimethylbenzene 92 Kg;
Latting drown D component is toluene.
Production method is as follows:
1) takes by weighing in proportion methyl methacrylate, vinylformic acid, butyl acrylate, Hydroxyethyl acrylate, vinylbenzene, Isooctyl acrylate monomer and TBPB initiator and mix, make mix monomer B component;
2) taking by weighing in proportion TBPB and dimethylbenzene makes and adds the C component;
3) hearth layer A component is dropped into reactor, then reactor is warming up to 135 ± 2 ℃ under condition of normal pressure, drips mix monomer B component, after evenly dropwising in 3 hours, be incubated 3 hours, to add the C component and drip half (50Kg) and be incubated 1 hour, and then drip residue and add C component (50Kg), be incubated 3 hours, after dripping again latting drown D component and stirring, be cooled to below 80 ℃, filter, packing.
Embodiment 3
A kind of tank wagon quick-drying primer acrylic resin comprises following component: hearth layer A component 1300 Kg, mix monomer B component 2656 Kg, add C component 120 Kg and latting drown D component 1300Kg; Wherein:
Hearth layer A component is dimethylbenzene;
Mix monomer B component is comprised of following raw material: methyl methacrylate 975Kg, vinylformic acid 18 Kg, butyl acrylate 640 Kg, Hydroxyethyl acrylate 195Kg, vinylbenzene 740 Kg, Isooctyl acrylate monomer 76 Kg and TBPB initiator 12 Kg; Mix monomer B component adds up to quality 2656 Kg;
Adding the C component is comprised of TBPB 12 Kg and dimethylbenzene 108Kg;
Latting drown D component is toluene.
Production method is as follows:
1) takes by weighing in proportion methyl methacrylate, vinylformic acid, butyl acrylate, Hydroxyethyl acrylate, vinylbenzene, Isooctyl acrylate monomer and TBPB initiator and mix, make mix monomer B component;
2) taking by weighing in proportion TBPB and dimethylbenzene makes and adds the C component;
3) hearth layer A component is dropped into reactor, then reactor is warming up to 135 ± 2 ℃ under condition of normal pressure, drips mix monomer B component, after evenly dropwising in 3 hours, be incubated 3 hours, to add the C component and drip half (55Kg) and be incubated 1 hour, and then drip residue and add C component (55Kg), be incubated 3 hours, dripping latting drown D component stirs again, be cooled to below 80 ℃ after middle control fine setting touches the mark, filter packing.
Embodiment 4 preparation tank wagon quick-drying primers
The acrylic resin 43% of embodiment 1 preparation, aluminium silver powder 8%, CAB-551-0.5s 3%, BYK-141 0.1%, EFKA-3777 0.3%, 10% the anti-settling slurry 1% of 201-P, mixed solvent 40.6% and N-3390 4%.
Preparation technology: in proportion the acrylic resin of embodiment 1 preparation, aluminium silver powder, CAB-551-0.5s, BYK-141, EFKA-3777,10% the anti-settling slurry of 201-P, mixed solvent and N-3390 are mixed, namely make the tank wagon quick-drying primer.
Embodiment 5 preparation tank wagon quick-drying primers
The acrylic resin 39% of embodiment 1 preparation, aluminium silver powder 9%, CAB-551-0.5s 4%, BYK-141 0.3%, EFKA-3777 0.2%, 10% the anti-settling slurry 1% of 201-P, mixed solvent 41.5% and N-3390 5%.
Preparation technology: in proportion the acrylic resin of embodiment 1 preparation, aluminium silver powder, CAB-551-0.5s, BYK-141, EFKA-3777,10% the anti-settling slurry of 201-P, mixed solvent and N-3390 are mixed, namely make the tank wagon quick-drying primer.
Embodiment 6 preparation tank wagon quick-drying primers
The acrylic resin 47% of embodiment 1 preparation, aluminium silver powder 7%, CAB-551-0.5s 3%, BYK-141 0.3%, EFKA-3777 0.2%, 10% the anti-settling slurry 1% of 201-P, mixed solvent 38.5% and N-3390 3%.
Preparation technology: in proportion the acrylic resin of embodiment 1 preparation, aluminium silver powder, CAB-551-0.5s, BYK-141, EFKA-3777,10% the anti-settling slurry of 201-P, mixed solvent and N-3390 are mixed, namely make the tank wagon quick-drying primer.
Comparative example 1
Solid content is 50% thermoplastic acrylic resin 50%, aluminium silver powder 8%, CAB-551-0.5s 3%, BYK-141 0.1%, EFKA-3777 0.3%, 10% the anti-settling slurry 1% of 201P and mixed solvent 37.6%.
Preparation technology: be that 50% thermoplastic acrylic resin, aluminium silver powder, CAB-551-0.5s, BYK-141, EFKA-3777,10% the anti-settling slurry of 201P and mixed solvent mix in proportion with solid content, namely make tank wagon priming paint.
Comparative example 2
Solid content is 50% hydroxyl acrylic resin 38%, aluminium silver powder 8%, CAB-551-0.5s 3%, BYK-141 0.1%, EFKA-3777 0.3%, 10% the anti-settling slurry 1% of 201-P, mixed solvent 43.6% and N-3390 7%.
Preparation technology: be that 50% hydroxyl acrylic resin, aluminium silver powder, CAB-551-0.5s, BYK-141, EFKA-3777,10% the anti-settling slurry of 201-P, mixed solvent and N-3390 mix in proportion with solid content, namely make tank wagon priming paint.
Embodiment 4 ~ 6 sees Table 1 with the performance test results of the priming paint of comparative example 1 ~ 2 preparation.Contrast priming paint 1: thermoplastic acrylic resin, contrast priming paint 2: hydroxyl acrylic resin
The performance test results of the priming paint of table 1 embodiment 4 ~ 6 and comparative example 1 ~ 2 preparation
The result shows: it is superior that the tank wagon quick-drying primer of embodiment 4-6 preparation and existing thermoplastic acrylic resin priming paint and hydroxyl acrylic resin priming paint are compared over-all properties, both quick-dryings, anti-solvent again, good combination property can satisfy the particular requirement of tank wagon continuous spray.
Claims (7)
1. tank wagon quick-drying primer acrylic resin, it is characterized in that by weight described acrylic resin comprises following component: 1000 ~ 1400 parts of hearth layer A components, 2130 ~ 2865 parts of mix monomer B components, add C component 75 ~ 145 and latting drown D component 1000 ~ 1400;
The raw material of wherein said hearth layer A component is dimethylbenzene;
Mix monomer B component is comprised of following raw material: 5 ~ 15 parts of 50 ~ 90 parts of 820 ~ 1025 parts of methyl methacrylates, 5 ~ 25 parts in vinylformic acid, 500 ~ 700 parts of butyl acrylates, 150 ~ 210 parts of Hydroxyethyl acrylates, 600 ~ 800 parts of vinylbenzene, Isooctyl acrylate monomer and TBPB initiators;
Adding the C component is comprised of 70 ~ 130 parts of 5 ~ 15 parts of TBPB and dimethylbenzene;
The raw material of latting drown D component is toluene.
2. tank wagon quick-drying primer acrylic resin according to claim 1 is characterized in that described acrylic resin comprises following component: 1100 ~ 1300 parts of hearth layer A components, 2344 ~ 2656 parts of mix monomer B components, add 1100 ~ 1300 parts of 100 ~ 120 parts of C components and latting drown D components;
Mix monomer B component is comprised of following raw material: 8 ~ 12 parts of 64 ~ 76 parts of 875 ~ 975 parts of methyl methacrylates, 12 ~ 18 parts in vinylformic acid, 560 ~ 640 parts of butyl acrylates, 165 ~ 195 parts of Hydroxyethyl acrylates, 660 ~ 740 parts of vinylbenzene, Isooctyl acrylate monomer and TBPB initiators;
Adding the C component is comprised of 92 ~ 108 parts of 8 ~ 12 parts of TBPB and dimethylbenzene.
3. tank wagon quick-drying primer acrylic resin according to claim 1 and 2 is characterized in that described acrylic resin comprises following component: 1200 parts of hearth layer A components, 2500 parts of mix monomer B components, add 1200 parts of 110 parts of C components and latting drown D components;
Mix monomer B component is comprised of following raw material: 10 parts of 925 parts of methyl methacrylates, 15 parts in vinylformic acid, 600 parts of butyl acrylates, 180 parts of Hydroxyethyl acrylates, 700 parts of vinylbenzene, 70 parts of Isooctyl acrylate monomers and TBPB initiators;
Adding the C component is comprised of 100 parts of 10 parts of TBPB and dimethylbenzene.
4. according to claim 1,2 or 3 described tank wagon quick-drying primer acrylic resins, it is characterized in that its preparation method may further comprise the steps:
1) takes by weighing in proportion methyl methacrylate, vinylformic acid, butyl acrylate, Hydroxyethyl acrylate, vinylbenzene, Isooctyl acrylate monomer and TBPB initiator and mix, make mix monomer B component;
2) taking by weighing in proportion TBPB and dimethylbenzene makes and adds the C component;
3) hearth layer A component is dropped into reactor, then reactor is warming up to 130 ~ 140 ℃, drip mix monomer B component, dropwise rear insulation 2 ~ 4 hours, will add the C component and drip half and also be incubated 0.5 ~ 1.5 hour, then drip residue and add the C component, be incubated 2 ~ 4 hours, drip again latting drown D component and stir, be cooled to below 80 ℃, filter packing.
5. tank wagon quick-drying primer, it is characterized in that by weight percentage composition meter, comprise following component: acrylic resin 38 ~ 48% claimed in claim 1, pigment 6 ~ 10%, cellulose acetate butyrate 2 ~ 4%, silicone antifoam agent 0.05 ~ 1%, flow agent 0.1 ~ 1%, anti-settling agent 0.5 ~ 2%, mixed solvent 35 ~ 46% and solidifying agent 2 ~ 6%.
6. tank wagon quick-drying primer according to claim 5 is characterized in that comprising in the described mixed solvent dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE.
7. tank wagon quick-drying primer according to claim 6, the weight ratio that it is characterized in that described dimethylbenzene, 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE is 5:2:3.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210506062.0A CN102993352B (en) | 2012-11-30 | 2012-11-30 | Tank truck quick-drying primer and acrylic resin for same |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210506062.0A CN102993352B (en) | 2012-11-30 | 2012-11-30 | Tank truck quick-drying primer and acrylic resin for same |
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| CN102993352A true CN102993352A (en) | 2013-03-27 |
| CN102993352B CN102993352B (en) | 2014-10-22 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923251A (en) * | 2014-04-28 | 2014-07-16 | 无锡德贝尔光电材料有限公司 | Quick drying acrylate polymer and preparation method thereof |
| CN116082905A (en) * | 2023-02-01 | 2023-05-09 | 岚图汽车科技有限公司 | Method for improving paint mist of solvent type acrylic acid system and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153691A (en) * | 2011-04-19 | 2011-08-17 | 广东同步化工股份有限公司 | Hydroxy acrylic resin for ultra-fast dry automobile varnish and preparation method thereof |
| CN102206309A (en) * | 2011-04-18 | 2011-10-05 | 广东同步化工股份有限公司 | Thermosetting acrylic resin for electrogilding oil and preparation method thereof |
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2012
- 2012-11-30 CN CN201210506062.0A patent/CN102993352B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206309A (en) * | 2011-04-18 | 2011-10-05 | 广东同步化工股份有限公司 | Thermosetting acrylic resin for electrogilding oil and preparation method thereof |
| CN102153691A (en) * | 2011-04-19 | 2011-08-17 | 广东同步化工股份有限公司 | Hydroxy acrylic resin for ultra-fast dry automobile varnish and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923251A (en) * | 2014-04-28 | 2014-07-16 | 无锡德贝尔光电材料有限公司 | Quick drying acrylate polymer and preparation method thereof |
| CN103923251B (en) * | 2014-04-28 | 2016-07-06 | 无锡德贝尔光电材料有限公司 | A kind of quick-dry type acrylate polymer and preparation method thereof |
| CN116082905A (en) * | 2023-02-01 | 2023-05-09 | 岚图汽车科技有限公司 | Method for improving paint mist of solvent type acrylic acid system and application |
| CN116082905B (en) * | 2023-02-01 | 2024-03-12 | 岚图汽车科技有限公司 | Method for improving paint mist of solvent type acrylic acid system and application |
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Address after: No.888, Huhuang Avenue, Fangqiao Town Industrial Zone, Yixing City, Wuxi City, Jiangsu Province Patentee after: Huhuang New Material Technology Group Co.,Ltd. Address before: No.888, Huhuang Avenue, Fangqiao Town Industrial Zone, Yixing City, Wuxi City, Jiangsu Province Patentee before: WUXI HUHUANG PAINT Co.,Ltd. |
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