CN101205275A - Alcohol water-soluble resin and method for making same - Google Patents

Alcohol water-soluble resin and method for making same Download PDF

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CN101205275A
CN101205275A CN 200610022517 CN200610022517A CN101205275A CN 101205275 A CN101205275 A CN 101205275A CN 200610022517 CN200610022517 CN 200610022517 CN 200610022517 A CN200610022517 A CN 200610022517A CN 101205275 A CN101205275 A CN 101205275A
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alcohol
resin
soluble resin
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water
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CN100473670C (en
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邹文俊
邹明国
钟文军
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钟文军
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Abstract

The invention provides an alcohol water-soluble resin and a preparation method thereof. The alcohol water-soluble resin can be dissolved in the mixed solvent of alcohol and water and the polymerization raw materials of the alcohol water-soluble resin mainly consit of the vinyl acetate monomers, and simultaneously the methacrylate monomers, the acylid acids and other hydrophilic functional monomers are added into the raw materials so as to ensure that the performance of the resin can meet the requirements for particular use. The invention also provides an alcohol water-soluble ink, compound adhesive, antiseptic varnish for printing, gloss varnish for woodware, decorative coatings for plastic surface and hair colorants that are prepared by adotping resin and the preparation methods thereof.

Description

一种醇水溶性树脂及其制备方法 An alcohol-soluble resin and preparation method

所属技术领域 Those of skill

苯发明涉及一种醇水溶性共聚树脂,具体地说是涉及一种在制备醇水溶性油墨、 涂料、塑料复合粘合剂等醇水溶性精细化工产品时作为主要原料的醇水溶性树脂, 及其制备方法。 Benzene invention relates to a water-soluble alcohol copolymer resin, particularly to an alcohol A water-soluble resin when preparing an alcohol soluble ink, paint, adhesive and the like an alcohol-soluble plastic composite fine chemical products as the main raw material, and methods for their preparation. 技术背景 technical background

树脂是生产油墨、胶粘剂、涂料等精细化工产品的主要原料,树脂决定了这些产品的性能、成本以及在使用过程中用何种溶剂稀释;目前,生产上述产品的大多数树脂均以苯类、酮类溶剂稀释,这些溶剂不仅严重污染环境,且由于是石油提炼物,随着石油价格的上涨,成本大幅升髙;由于成本与环保的压力,市场上出现了多种体系的以醇类、酯类作溶剂的树脂,其中本发明申请人在另一发明申请《一种醇溶性树脂及其制备方法》(申请号200510021271.6)中,描述了一种以醋酸乙烯为主要原料生产醇溶性树脂的工艺和原料配方,但无论是酯类、醇类,虽然其毒性较苯类、兩类低,但仍然属于有机溶剂的范围,因此,开发既能满足使用要求,又能部分或以全部以水作为溶剂的树脂,即醇水溶性树脂或水溶性树脂,尽量减少有机溶剂用量,成为树脂行业追求 Is the main raw material resin inks, adhesives, paint and other chemical products, the resin determine the performance of these products, as well as the cost of which is diluted with a solvent in use; present, the production of these products are most resin benzene, ketone solvent dilution, these solvents not only seriously pollute the environment, and because the material is petroleum refining, as oil prices rise, the cost rose sharply Gao; because of cost and environmental pressures, a variety of systems on the market in alcohol, as a solvent-based resin, wherein the applicant of the present invention in another application the invention "an alcohol-soluble resin and preparation method" (application No. 200510021271.6), there is described a vinyl acetate as a main raw material alcohol resin formulation process and raw materials, but both esters, alcohols, although its toxicity than benzene, two kinds of low, but still within the scope of the organic solvent, thus, can satisfy the requirements of the development, but also part or all of the water as the resin solution, i.e., an alcohol-soluble resin or a water-soluble resin to minimize the amount of organic solvent, the resin to become the industry seek 目标之一。 One of the goals. 目前未见与本发明相类似的配方或工艺生产醇水溶性树脂的相关报道。 Currently no reports with the present invention similar to the water-soluble resin formulation or production process of an alcohol.

发明内容 SUMMARY

本发明的目的在于提供一种醇水溶性树脂,即能在醇与水的混合物中溶解的树脂;本发明的另一目的是提供该树脂的制备方法和用途。 Object of the present invention to provide an alcohol-soluble resin that can be dissolved in a mixture of alcohol and water in the resin; a further object of the present invention to provide a preparation process and use of the resin.

本发明提供的醇水溶性树脂,是由下列重量配比的原料制备而成-醋酸乙烯50—70% 丙烯酸酯或/和甲基丙烯酸酯4一20% 丙烯酸1-5% 亲水性官能团单体16—30% The present invention provides an alcohol-soluble resin is prepared from the following raw materials weight ratio of from - 50 to 70% vinyl acetate or an acrylate / methacrylate and 4 to 20% acrylic acid 5% of hydrophilic functional groups single body 16-30%

加入原料总重量0.1 % _0.9%的偶氮二异丁晴和/或过氧化苯甲酰作为弓I发剂,在醇类或醇水混合溶剂中聚合即得。 0.1% by weight of the total feed was added _0.9% of azobisisobutyronitrile Qinghe / or benzoyl peroxide as initiator I bow, in an alcohol or alcohol-water polymerization mixed solvent to obtain.

所述亲水性官能团单体为丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸羟乙酯、 甲基丙烯酸羟丙酯、丙烯酰胺、甲基丙烯酰胺、羟甲基丙烯酰胺、羟甲基甲基丙烯酰胺中的一种或几种; The hydrophilic functional group monomer is hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, acrylamide, methacrylamide, methylol acrylamide, methylol one or more methyl acrylamide;

本发明提供的制备醇水溶性树脂的方法,包括如下步骤: The method of preparing the alcohol-soluble resin of the present invention is provided, comprising the steps of:

a、 按下列配比称取原料: a, according to the following formulation weighed raw materials:

甲组分: 醋酸乙烯10 — 25% Group A: vinyl acetate 10--25%

丙烯酸酯或/和甲基丙烯酸酯1-10% 加入醇类溶剂或醇水混合溶剂,溶剂的量为上述醋酸乙烯和丙烯酸酯或/ 和甲基丙烯酸酯总重量的10 — 35%。 1-10% acrylic and / or methacrylic esters is added an alcoholic solvent or a mixed solvent of alcohol-water, amount of the solvent is above 10 acrylate or vinyl acetate and the total weight / methacrylate and - 35%.

乙组分: 醋酸乙烯25-60% Part B: 25-60% vinyl acetate

丙烯酸酯或/和甲基丙烯酸酯3—10% 丙烯酸1_5% 亲水性官能团单体16-30% 另加入原料总重量0. l—0.9%的引发剂 Acrylate and / or methacrylate and 3-10% acrylate 1_5% hydrophilic functional group was added another monomer 16-30% by weight of the total feed 0. l-0.9% initiator

b、 将甲组分加入反应釜中,搅拌,升温至回流温度; B, the Group A points added to the kettle, stirred, warmed to reflux temperature;

c、 在4.5—6小时内向反应釜中滴加乙组分; c, over a period of 4.5-6 hours reaction kettle was added dropwise Part B;

d、 c步骤完成后,控制物料温度在70—85'C之间继续反应2小时; d, after completion of step c, the reaction was continued at the temperature control of the material between 70-85'C 2 hours;

e、 根据产品的浓度要求加入醇类和水混合溶剂稀释,边搅拌边降温,釜内的物料温度降至50'C以下时出料,即得所需浓度的醇水溶性树脂。 When the material E, an alcohol, and water was added diluting solvent depending on the concentration of the product required, cooling with stirring, the temperature of the material in the autoclave down to 50'C or less, to obtain the desired concentration of the alcohol-soluble resin.

本发明生产的树脂,在保证树脂使用性能的前提下,使树脂具有在醇类与水的混合溶剂中溶解的特点,由于在溶剂中加入一定量的水,直接减少了有机溶剂的用量,从而有效降低了生产树脂的溶剂成本和树脂的使用成本。 The resins produced according to the present invention, under the precondition to ensure performance of the resin, the resin has dissolved in a mixed solvent of alcohol and water feature, since a certain amount of water in the solvent, directly reduce the amount of organic solvent, thereby effectively reduces the cost of production cost of the resin and the resin of the solvent.

以下是生产醇水溶性树脂和生产醇溶性树脂的溶剂成本比较, 即按照本发明实施例1方法生产200公斤醇水溶性树脂与按照已公开的专利文献方法(专利申请号200510021271. 6)生产200公斤醇溶性树脂的溶剂组成及溶剂成本比较: Below is a comparison of production cost alcohol solvent-soluble resin and an alcohol-soluble resin is produced, i.e. according to the embodiment of the present invention, the production method of Example 1 200 kg alcohol and water-soluble resin produced has 200 according to the method disclosed in Patent Document (Patent Application No. 200510021271.6) kg of solvent composition and a solvent alcohol resin cost comparison:

<table>table see original document page 4</column></row> <table> <Table> table see original document page 4 </ column> </ row> <table>

从上表比较可知,生产200公斤醇水溶性树脂与生产200公斤醇溶性树脂比较,溶剂成本减少了276.5元,即溶剂成本减少约32%。 From the table are compared, the production of an alcohol-soluble resin and 200 kg 200 kg Production Comparative alcohol-soluble resin, a solvent to reduce the cost of 276.5 yuan, i.e., cost reduction of about 32% solvent.

本发明还提供了醇水溶性树脂在制备油墨、塑料复合粘合剂,木器上光漆、纸印刷上光油和塑料表面装饰漆、毛发着色剂中的用途。 The present invention further provides a water-soluble resin an alcohol in preparation of the ink, plastic composite adhesive, wood polish, decorative paint varnish and plastic surfaces, use hair colorant in the printed paper.

下面通过具体实施例的方式对本发明做进一步详述,但不应理解为是对本发明保护范围的限制,凡基于上述技术思想,利用本领域普通技术知识和惯用手段所做的修改、替换、变更均属于本发明的范围。 What follows is by way of specific embodiments of the present invention in further detail, but should not be construed as limiting the scope of the present invention, where the basis of the technical idea, use edits of ordinary skill and knowledge usual means, substitutions and changes They are within the scope of the present invention. 具体实施方式 Detailed ways

实施例1本发明醇水溶性树脂的制备 Preparation of an alcohol-soluble resin according to the invention embodiment

设备:本发明所需设备为:配有搅拌器的反应釜、回流冷凝器、不锈钢滴加罐、 加热及温控器。 Equipment: The equipment required for the invention: a reaction vessel equipped with a stirrer, reflux condenser, dropping tanks of stainless steel, heating and temperature control.

① .将醋酸乙烯20公斤、丙烯酸乙酯5公斤作为甲组分,另加溶剂无水乙醇IO公斤作为稀释剂一起加入反应釜中,升温并搅拌。 ①. The vinyl acetate 20 kg, 5 kg of ethyl acrylate as Group A, additional solvent ethanol as a diluent was added along with IO kg kettle, heated and stirred.

② .将醋酸乙烯45公斤、丙烯酸乙酯2,5公斤、丙烯酸甲酯2.5公斤、甲基丙烯酸甲酯4公斤、丙烯酸5公斤、丙烯酰胺10公斤、丙烯酸羟丙酯6公斤、偶氮二异丁晴0.9公斤作为乙组分加入滴加罐内。 ②. The 45 kg of vinyl acetate, 2.5 kg of ethyl acrylate, 2.5 kg of methyl acrylate, methyl methacrylate, 4 kg, 5 kg of acrylic acid, acrylamide 10 kg, 6 kg hydroxypropyl acrylate, azobis iso NBR 0.9 kg as Part B to join dropping tank. 待釜内物料温度升至回流温度时,在5 小时内滴入釜内。 When the autoclave until the temperature was raised to reflux temperature, the kettle was added dropwise over 5 hours.

保温反应2小时后向釜内加入95%工业酒精70公斤,去离子水20公斤, 并冷却降温后出料,即得固含量为50%的树脂200.7公斤。 After incubation for 2 hours of reaction the autoclave was added to 70 kg of 95% industrial alcohol, 20 kg of deionized water, and cooled after cooling the material, i.e., a solids content of 200.7 kg of 50% resin.

实施例1所述配方制成的树脂最宜用于生产凹版塑料表印油墨。 The resin formulation described in Example 1 most suitable for producing plastic gravure surface printing ink. 实施例2本发明醇水溶性树脂的制备按下列配比称取原料: Preparation of 2-ol water-soluble resin according to embodiments of the invention the following formulation weighed raw materials:

甲组分: 醋酸乙烯25公斤 Group A: vinyl acetate 25 kg

丙烯酸甲酯1公斤 1 kg of methyl acrylate

甲基丙烯酸甲酯7公斤 7 kg of methyl methacrylate

另加15公斤无水乙醇作稀释剂乙组分: 醋酸乙烯35公斤 Plus 15 kg of anhydrous ethanol as a diluent Part B: vinyl acetate 35 kg

丙烯酸甲酯2公斤 Acrylate 2 kg

甲基丙烯酸甲酯8公斤 8 kg of methyl methacrylate

丙烯酸3公斤 Acrylic 3 kg

丙烯酸羟丙酯15公斤 15 kg of hydroxypropyl acrylate

丙烯酰胺4公斤 Acrylamide 4 kg

过氧化苯甲酰0.6公斤 Benzoyl peroxide 0.6 kg

另备无离子水15公斤、95%工业酒精75公斤作稀释剂,制备方法同实施例l, 得固含量为50%的树脂200. 7公斤。 Another Preparation of deionized water 15 kg, 75 kg of 95% industrial alcohol as diluent, prepared in Example l with the embodiment, a solids content of 50% resin 200.7 kilograms. 实施例2所述配方制成的树脂最宜用作生产耐热、耐蒸煮凹版塑料复合油墨。 The resin formulation described in Example 2 is appropriate for the production of the most heat-resistant retort plastic gravure composite ink.

实施例3本发明醇水溶性树脂的制备按下列配比称取原料: Preparation of 3-ol water-soluble resin according to embodiments of the invention the following formulation weighed raw materials:

甲组分: 醋酸乙烯15公斤 Group A: vinyl acetate 15 kg

丙烯酸甲酯5公斤 5 kg of methyl acrylate

另加10公斤无水乙醇和2公斤无离子水作稀释剂乙组分: 醋酸乙烯50公斤 Plus 10 kg of absolute ethanol and 2 kg of deionized water is used as diluent Part B: vinyl acetate 50 kg

丙烯酸甲酯10公斤 10 kg of methyl acrylate

丙烯酸2公斤丙烯酰胺10公斤 2 kg of acrylic acid acrylamide 10 kg

丙烯酸羟乙酯8公斤 Acrylate 8 kg

偶氮二异丁晴0.8公斤 Azobisisobutyronitrile clear 0.8 kg

另备无离子水18公斤、95%工业酒精70公斤作稀释剂,制备方法同实施例l, 得固含量为50%的树脂200. 7公斤。 Another Preparation of deionized water 18 kg, 70 kg of 95% industrial alcohol as diluent, prepared in Example l with the embodiment, a solids content of 50% resin 200.7 kilograms.

实施例3所述配方制成的树脂适宜于用作生产普通凹版塑料复合油墨。 Embodiment 3 The resin formulation suitable for the production of ordinary Examples plastic gravure composite ink. 实施例4本发明醇水溶性树脂的制备按下列配比称取原料: Preparation of 4-ol according to the invention the water soluble resin according to the following formulation embodiments weighed raw materials:

甲组分: 醋酸乙烯10公斤 Group A: vinyl acetate 10 kg

丙烯酸丁酯5公斤 5 kg of butyl acrylate

另加10公斤无水乙醇和2公斤无离子水作稀释剂乙组分: 醋酸乙烯55公斤 Plus 10 kg of absolute ethanol and 2 kg of deionized water is used as diluent Part B: vinyl acetate 55 kg

丙烯酸丁酯8公斤 8 kg of butyl acrylate

丙烯酸5公斤 Acrylic acid 5 kg

丙烯酰胺5公斤 Acrylamide 5 kg

丙烯酸羟乙酯12公斤 12 kg of hydroxyethyl acrylate

偶氮二异丁晴0.7公斤 Azobisisobutyronitrile clear 0.7 kg

另备95%工业酒精78公斤、无离子水10公斤作稀释剂,制备方法同实施例l, 得固含量为50。 Preparation Another 78 kg of 95% industrial alcohol, 10 kg deionized water as a diluent, prepared in Example l with the embodiment, a solids content of 50. /。 /. 的树脂200. 9公斤。 Resin 200.9 kilograms.

实施例4所述配方制成的树脂就是固含量为50%的塑料复合胶粘剂。 The resin formulation described in Example 4 is 50% of the solid content of plastic composite adhesive. 实施例5本发明醇水溶性油墨的制备 Water-soluble ink of the invention ol 5 cases embodiment

用本发明树脂生产醇水溶性油墨的配方如下(重量比): With the present invention for producing an alcohol-soluble ink resin of the following formula (weight ratio):

由实施例l、 2或3制备的树脂溶液(固含量50%) 35 钛百粉35 Example l by the embodiment, the resin solution prepared in 2 or 3 (50% solids) 35 35 Titanium one hundred powder

腊粉0.2 0.2 wax powder

无离子水6 — 9 Deionized water 6--9

工业酒精21—24 Industrial alcohol 21-24

用本发明树脂生产醇水溶性油墨的工艺如下: With the present invention for producing an alcohol-soluble ink resin of the following process:

将上述原料放入容器内,高速搅拌20分钟让其充分混合分散均匀,再经砂磨机研磨,研磨时保持物料温度不高于40'C,研磨至细度为15微米以下即成。 The raw material into the container, a high speed stirring for 20 minutes allowed to fully mixed and dispersed uniformly, and then by sand mill, maintaining the batch temperature during polishing is not higher than 40'C, ground to a fineness of 15 micrometers or less Serve. 实施例6本发明醇水溶性树脂的制备按下列配比称取原料: 6-ol was prepared according to the invention the water soluble resin according to the following formulation embodiments weighed raw materials:

甲组分: 醋酸乙烯25公斤 Group A: vinyl acetate 25 kg

丙烯酸甲酯4公斤 4 kg of methyl acrylate

另加10公斤无水乙醇作稀释剂乙组分: 醋酸乙烯35公斤 Plus 10 kg of anhydrous ethanol as a diluent Part B: vinyl acetate 35 kg

丙烯酸甲酯5公斤甲基丙烯酸甲酯4公斤丙烯酸3公斤 5 kg methyl methacrylate methacrylate acrylate, 3 kg 4 kg

丙烯酸羟丙酯16公斤 16 kg of hydroxypropyl acrylate

甲基丙烯酰胺8公斤 Methacrylamide 8 kg

过氧化苯甲酰0.5公斤 0.5 kg benzoyl peroxide

另备无离子水10公斤、95%工业酒精80公斤作稀释剂,制备方法同实施例l, 得固含量为50%的树脂200.8公斤。 Another Preparation of deionized water 10 kg, 80 kg of 95% industrial alcohol as diluent, prepared in Example l with the embodiment, a solids content of 200.8 kg of 50% resin.

实施例6所述配方制成的树脂宜作木器上光漆、纸印刷上光油和塑料表面装饰漆。 The resin formulation described in Example 6 should be polish wood, paper and plastic surfaces printed decorative paint coatings.

实施例7本发明生产木器上光漆的制备 Preparation 7 Production of the present embodiment polish wood

用本发明树脂生产木器上光漆的配方如下(重量比)- With the present invention for producing wood polish formulation as a resin (weight ratio) -

由实施例6制备的树脂溶液(固含量50%) 45 The resin solution prepared in Example 6 (50% solids) 45

硝化棉醇溶液(70%) 20 Nitrocellulose alcohol solution (70%) 20

二丁酯3 Dibutyl 3

醋酸乙酯12 Ethyl acetate 12

丁醇5 Butanol 5

95%工业乙醇12 95% industrial ethanol 12

无离子水3 用生产本发明木器上光漆的工艺如下: 3 with deionized water wood polish production process of the present invention is as follows:

将上述原料放入容器内,搅拌10分钟让其充分混合分散均匀,再经过滤即成。 The raw material into the container, stirred for 10 minutes, to be mixed and dispersed sufficiently uniformly, then filtered Serve. 实施例8本发明纸印刷上光油的制备 Preparation of Varnish paper printing invention embodiment 8

本实施例生产纸印刷上光油的配方如下(重量比): Varnish Formulation Examples of the present embodiment for producing paper printed as follows (weight ratio):

由实施例6制备的树脂溶液(固含量50%) 40 The resin solution prepared in Example 6 (50% solids) 40

醇溶松香液(固含量20%) 35 Rosin alcohol solution (solids content 20%) 35

气相二氧化硅3 Fumed silica 3

无离子水2 Deionized water 2

95%工业乙醇20 本实施例工艺如下: 95% industrial ethyl alcohol, the process embodiment 20 is as follows:

将上述原料放入容器内,高速搅拌30分钟让其充分混合分散均匀,再经过滤即成。 The raw material into the container, a high speed stirring for 30 minutes allowed to fully mixed and dispersed uniformly, and then filtered Serve.

实施例9本发明醇水溶性塑料表面装饰漆制备 Preparation of the alcohol-soluble plastic surface decorative paint Example 9 This invention embodiment

用本发明树脂生产塑料表面装饰漆的配方如下(重量比): 由实施例6制备的树脂溶液(固含量50%) 45 With the present invention for producing the plastic surface and decorative coating resin formulation as follows (weight ratio): resin solution prepared in Example 6 (50% solids) 45

颜料20 Pigment 20

流平剂0.3 Leveling agent 0.3

防沉剂1 Anti-settling agent 1

无水乙醇10 Ethanol 10

无离子水2 Deionized water 2

95%工业乙醇21 95% industrial ethanol 21

用本发明树脂生产塑料表面装饰漆的工艺如下: With the present invention is the production of plastic resin surface and decorative coating process is as follows:

将上述原料放入容器内,髙速搅拌10分钟让其充分混合分散均匀,再经过砂磨机研磨至细度小于15微米即成。 The raw material into the container, stirred for 10 minutes, to Gao speed sufficiently mixed and dispersed uniformly, and then through the sand mill to a fineness of less than 15 microns Serve. 实施例IO本发明醇水溶性毛发着色剂制备 Example IO Preparation of the alcohol-soluble hair colorant of the present invention embodiment

用本发明树脂生产醇水溶性毛发着色剂的配方如下(重量比): 由实施例12制备的树脂溶液(固含量50% ) 40 With the present invention for producing alcohol-soluble hair colorant formulation as the resin (weight ratio): resin solution prepared in Example 12 (50% solids) 40

色料10 Pigment 10

蒸馏水15 Distilled water 15

95%工业乙醇15 95% industrial ethanol 15

香料0.05 Perfume 0.05

用本发明树脂生产醇水溶性毛发着色剂的工艺如下: 将上述原料放入容器内,高速搅拌10分钟让其充分混合分散均匀即成。 With the production process of the present invention, the resin is an alcohol-soluble hair colorant as follows: the raw material into the container, a high speed stirred for 10 minutes allowed to fully mixed and dispersed evenly Serve.

Claims (6)

1. 一种醇水溶性树脂,其特征在于:它是由下列重量配比的原料制备而成: 醋酸乙烯50-70% 丙烯酸酯或/和甲基丙烯酸酯4-20% 丙烯酸1-5% 亲水性官能团单体16-30% 加上原料总重量0.1-0.9%的引发剂,在醇类或醇水混合溶剂中聚合即得。 An alcohol-soluble resin, characterized in that: it is prepared from the following raw material from weight proportion: 50-70% vinyl acetate or an acrylate / methacrylate and 4-20% acrylate 1-5% hydrophilic functional group plus the total monomer 16-30% by weight of 0.1-0.9% of the initiator feed, the polymerization solvent to obtain an alcohol in an alcohol or water.
2、 根据权利要求2所述的醇水溶性树脂,其特征在于:所述亲水性官能团单体为丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸羟乙酯、甲基丙烯酸羟丙酯、丙烯酰胺、甲基丙烯酰胺、羟甲基丙烯酰胺、羟甲基甲基丙烯酰胺中的一种或几种;所述引发剂为偶氮二异丁晴和/或过氧化苯甲酰。 2, an alcohol-soluble resin according to claim 2, wherein: said hydrophilic functional group monomer is hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate , acrylamide, methacrylamide, methylol acrylamide, methylol acrylamide is one or more; the initiator is azobisisobutyronitrile Qinghe / or benzoyl peroxide.
3、 制备权利要求2所述的醇水溶性树脂的方法,其特征在于:a、 按下列配比称取原料:甲组分: 醋酸乙烯10—25%丙烯酸酯或/和甲基丙烯酸酯1-10% 加入醇类溶剂,溶剂的量为上述醋酸乙烯和丙烯酸酯或/和甲基丙烯酸酯总重量的10—35%;乙组分: 醋酸乙烯25-60%丙烯酸酯或/和甲基丙烯酸酯3—10% 丙烯酸1一5% 亲水性官能团单体16—30% 另加入原料总重量0. l—O. 9%的引发剂b、 将甲组分加入反应釜中,搅拌,升温至回流温度;c、 在4.5—6小时内向反应釜中滴加乙组分;d、 c歩骤完成后,控制物料温度在70—85iC之间继续反应2小时;e、 根据产品的浓度要求加入醇类和水的混合溶剂稀释,边搅拌边降温,釜内的物料温度降至50℃以下时出料,即得所需浓度的醇水溶性油墨树脂。 3, an alcohol-soluble resin prepared according to claim 2, wherein: a, raw materials weighed according to the following formulation: Group A: 10 to 25% vinyl acetate or an acrylate / methacrylate and 1 -10% of the amount added to an alcohol solvent, the solvent is the above vinyl acetate and acrylic and / or 10-35% of the total weight of the methacrylate; Part B: 25-60% vinyl acetate or an acrylate / methyl and 3-10% acrylic acrylate 1 to 5% of hydrophilic functional monomer 16-30% of the total weight of the feedstock and add another 0. l-O. 9% of initiator B, group a will be divided into a reactor and stirred, warmed to reflux temperature; C, the reaction kettle over a period of 4.5-6 h Part B was added dropwise; the d, c ho step is completed, the reaction was continued in the temperature control of the material between 70-85iC 2 hours; E, depending on the concentration of the product when added to the material requirements and diluted with a mixed solvent of alcohols water cooling with stirring, the temperature of the material in the autoclave drops below 50 ℃, i.e., to obtain the desired alcohol concentration in the water-soluble ink resin.
4、 权利要求l一4任一项所述的醇水溶性树脂在制备塑料复合粘合剂、油墨、 纸印刷上光油、木器上光漆、塑料表面装饰涂料、毛发着色剂中的用途。 4, as claimed in any one of claims l-4 alcohol use water-soluble resin varnish, polish wood, decorative plastic surface coatings, hair coloring agent in the preparation of plastic composite adhesive, ink, paper printing requirements.
5、 一种塑料复合粘合剂,其特征在于:它是由权利要求l一3任一项所述的醇水溶性树脂制备而成。 5. A plastic composite adhesive, characterized in that: it is a preparation according to any one of claims 3 alcohol formed by the water-soluble resin as claimed in claim l.
6、 一种油墨,其特征在于:它是由权利要求1一4任一项所述的醇水溶性树脂, 加上颜料、溶剂和助剂组成。 6. An ink, characterized in that: it is an alcohol-soluble resin according to any one of claims 1 a 4, together with pigments, solvents and additives.
CN 200610022517 2006-12-18 2006-12-18 Alcohol water-soluble resin and method for making the same CN100473670C (en)

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CN101899236A (en) * 2009-06-01 2010-12-01 钟文军 High-temperature digestion resistant ink and preparation method thereof
CN102010631A (en) * 2009-10-29 2011-04-13 成都市新津托展油墨有限公司 Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof
CN102153971A (en) * 2011-01-25 2011-08-17 北京高盟新材料股份有限公司 Waterborne aluminium foil adhesive and preparation method thereof
CN102443319A (en) * 2011-10-24 2012-05-09 北京高盟新材料股份有限公司 Alcohol water-soluble amino modified vinyl acetate-acrylic system ink connecting material and preparation method thereof
CN101818033B (en) 2010-01-22 2012-07-25 北京高盟新材料股份有限公司 Alcohol-soluble composite film adhesive and preparation method thereof
CN103755861A (en) * 2014-01-09 2014-04-30 杭州拜善晟生物科技有限公司 Carbomer and preparation method thereof
CN104031203A (en) * 2014-06-17 2014-09-10 常熟国和新材料有限公司 Alcohol-soluble modified acrylate resin and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN101899236A (en) * 2009-06-01 2010-12-01 钟文军 High-temperature digestion resistant ink and preparation method thereof
CN102010631A (en) * 2009-10-29 2011-04-13 成都市新津托展油墨有限公司 Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof
CN102010631B (en) 2009-10-29 2013-03-13 成都市新津托展油墨有限公司 Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof
CN101818033B (en) 2010-01-22 2012-07-25 北京高盟新材料股份有限公司 Alcohol-soluble composite film adhesive and preparation method thereof
CN102153971A (en) * 2011-01-25 2011-08-17 北京高盟新材料股份有限公司 Waterborne aluminium foil adhesive and preparation method thereof
CN102153971B (en) 2011-01-25 2013-02-27 北京高盟新材料股份有限公司 The aqueous adhesive foil and preparation method
CN102443319A (en) * 2011-10-24 2012-05-09 北京高盟新材料股份有限公司 Alcohol water-soluble amino modified vinyl acetate-acrylic system ink connecting material and preparation method thereof
CN102443319B (en) 2011-10-24 2014-04-02 北京高盟新材料股份有限公司 Alcohol water-soluble amino modified vinyl acetate-acrylic system ink connecting material and preparation method thereof
US9315064B2 (en) 2012-02-20 2016-04-19 Avery Dennison Corporation Multilayer film for multi-purpose inkjet systems
CN103755861A (en) * 2014-01-09 2014-04-30 杭州拜善晟生物科技有限公司 Carbomer and preparation method thereof
CN104031203A (en) * 2014-06-17 2014-09-10 常熟国和新材料有限公司 Alcohol-soluble modified acrylate resin and preparation method thereof
CN105970735A (en) * 2016-05-18 2016-09-28 太仓市好心情印务有限公司 Varnishing process of specially shaped paper printed matter

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