CN102978727A - Processing method of durable-type antibacterial deodorizing fiber fabric - Google Patents
Processing method of durable-type antibacterial deodorizing fiber fabric Download PDFInfo
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- CN102978727A CN102978727A CN 201110261719 CN201110261719A CN102978727A CN 102978727 A CN102978727 A CN 102978727A CN 201110261719 CN201110261719 CN 201110261719 CN 201110261719 A CN201110261719 A CN 201110261719A CN 102978727 A CN102978727 A CN 102978727A
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Abstract
The invention relates to a processing method of durable-type antibacterial deodorizing fiber fabric. According to the invention, a nano-scale inorganic antibacterial agent is added into high-polymer powder according to a weight percentage of 3-30%; the mixture is well mixed; and an antibacterial master batch is formed with a screw granulation technology. The antibacterial master batch is mixed with a high polymer according to a proportion of 0.3-10%; the mixture is subjected to spinning; fabric is obtained by spinning and weaving; and the fabric is subjected to antibacterial agent post-treatment. With the method provided by the invention, the processed fiber fabric has the advantages of good antibacterial effect, and high durability. The fiber fabric processed with the method provided by the invention can be widely applied in footwear, clothing, bedding, and the like.
Description
Technical field
The present invention relates to a kind of processing method of permanent seal cooling antibacterial and deodouring fabric, the method is that the nanometer grade inorganic antibacterial agent is joined in the high polymer powder, mix and make antibacterial matrices, form fabric through spinning after weaving, again through making good anti-bacterial effect, antibacterial and deodouring fabric that persistence is strong after the antiseptic arrangement processing.
Background technology
In prior art, antiseptic has inorganic, organic and natural three major types minute.Antimicrobial technology is divided into rear arrangement processing and precursor improvement processing method.Rear finishing technique comprises following several types: 1, take reaction resin as medium with the antiseptic heat fixation to fiber surface, antiseptic is antibacterial action from the fiber surface stripping.2, antiseptic absorption is fixed to fiber surface, antiseptic is antibacterial action from the fiber surface stripping.3, utilize methoxyl group in the silicon-type season money salt and the light base on the fiber surface to take off liquor-saturated reaction, antiseptic is fixed on the fiber, the active part of antiseptic shows antibacterial action under state that fiber surface firmly is combined.4, with coating machine metal is sprayed onto fiber surface and makes it to be fixed on the fiber, antiseptic is antibacterial action from the fiber surface stripping.Precursor improvement processing method comprises following several types: (l) spinning solution spinning in organic solvent of nylon or acrylonitrile condensate and antiseptic mixing, then heat is steamed and is processed, and the antiseptic composition of the antiseptic on the fiber surface and part stripping shows antibacterial action.(2) suppress deviating from and make it and disperseing of copper in the manufacture process of regenerated fiber in fiber, the antiseptic composition of the antiseptic on the fiber surface and part stripping shows antibacterial action.The material of above method processing all has certain antibacterial action, but that common shortcoming is anti-microbial property is not lasting, and fabric antibacterial effect after washing repeatedly descends or fully loss.Given this, need to propose a kind of processing method of permanent seal cooling antibacterial and deodouring fabric.
Summary of the invention
The object of the present invention is to provide a kind of processing method of permanent seal cooling antibacterial and deodouring fabric, the method is that the nanometer grade inorganic antibacterial agent is joined in the high polymer powder, mix and make antibacterial matrices, form fabric through spinning after weaving, again through making good anti-bacterial effect, antibacterial and deodouring fabric that persistence is strong after the antiseptic arrangement processing.The object of the present invention is achieved like this: a kind of processing method of permanent seal cooling antibacterial and deodouring fabric, its procedure of processing is: a, by the freezing equipment take liquid nitrogen as refrigerant the spinning-grade high polymer material is carried out subzero treatment, treatment temperature is one 30 ℃～one 100 ℃, then use disintegrating apparatus to carry out pulverization process, obtain 80 1 500 purpose spinning-grade high polymer powder: b, weight ratio by 3 %, one 30 % joins the nanometer grade inorganic antibacterial agent in the described spinning-grade high polymer powder, use usual manner to mix the formation composite powder, this composite powder is made antibacterial matrices by Granulation Equipments; C, by 0. the weight ratio of 3 %, one 10 % is mixed described antibacterial matrices with high polymer material, then make anti-bacterial fibre by an one-tenth equipment; D, described anti-bacterial fibre weaved through spinning make antibiotic fabric, use at last antiseptic that described antibiotic fabric is carried out rear arrangement processing.Compared with the prior art the present invention has that technique is simple, cost is low, and the fabric of processing has lasting antibiosis and deodorization effects, the significant advantage of economic benefit and social benefit.
The processing method of a kind of permanent seal cooling antibacterial and deodouring of optimum implementation of the present invention fabric, its procedure of processing is: a, by the freezing equipment take liquid nitrogen as refrigerant to spinning-grade poly terephthalic acid second two liquor-saturated vinegar section carry out subzero treatment, treatment temperature is one 30 ℃～one 60 ℃, then use disintegrating apparatus to carry out pulverization process, obtain 80 1 100 purpose spinning-grade high polymer powder; B, by the weight ratio of 15 % nanometer grade inorganic antibacterial agent silver oxide is joined in the described spinning-grade high polymer powder, use usual manner to mix the formation composite powder, this composite powder is made antibacterial matrices by Granulation Equipments; C, the heavy inner ratio of pressing l % mix described antibacterial matrices with the two liquor-saturated vinegar sections of poly terephthalic acid second, then by becoming an equipment to make anti-bacterial fibre; D, the anti-bacterial fibre be confused weaved through spinning make antibiotic fabric, use at last season hinge salt antiseptic that described antibiotic fabric is carried out rear arrangement processing.The fabric anti-bacterial effect of processing.Above-mentioned antibiotic fabric carries out rear arrangement processing.In the present embodiment, described spinning-grade high polymer material can select that the spinning-grade polyethylene terephthalate is cruel, the poly terephthalic acid propylene glycol is cruel, polybutylene terephthalate is cruel, poly-phthalein amine, polyacrylonitrile, a kind of in the polypropylene material.In the present embodiment, colloid admixture, the silica supports, cupric ammine complex, silica, the antibiotic property potter's clay that carry silver that described nanometer grade inorganic antibacterial agent can select that crystallinity silicic acid aluminium, copper compound, antibacterial zeolite, phosphoric acid mistake, silver oxide, zinc oxide, silver zeolite, metallic copper, silver chlorate, phosphoric acid are admired, zinc oxide, oxidation are admired, contain a kind of in the hydrophilic amino organosilicon material.In the present embodiment, described antiseptic can be selected amino two sugar, 1 in hungry salt of organic system antiseptic phenols, season, amphoteric surfactant, symmetrical hexichol arteries and veins class, alcohols, cruel class, sulphur phthalein amine, two flesh class, amino acids, the natural system, 8 one press olein, shitosan, through basic propyl group shitosan, a kind of in cupric cellulose, poly-second phthalein Glucosamine, the tropolone material.The mode of in the present embodiment, described antibiotic fabric being carried out rear arrangement processing is impregnation method, spray pattern, coating way, dip a kind of in the mode.
Claims (5)
1. the processing method of a permanent seal cooling antibacterial and deodouring fabric, it is characterized in that: a, by the freezing equipment take liquid nitrogen as refrigerant spinning-grade merchant polymers material is carried out subzero treatment, treatment temperature is one 30 ℃～one 100 ℃, then use disintegrating apparatus to carry out pulverization process, obtain 80 1 500 purpose spinning-grade high polymer powder; B, by the weight ratio of 3 %, one 30 % the nanometer grade inorganic antibacterial agent is joined in the described spinning-grade high polymer powder, use usual manner to mix the formation composite powder, this composite powder is made antibacterial matrices by Granulation Equipments; C, by 0. the weight ratio of 3 %, one 10 % is mixed described antibacterial matrices with high polymer material, then make anti-bacterial fibre by an one-tenth equipment; D, described anti-bacterial fibre weaved through spinning make antibiotic fabric, use at last antiseptic that described antibiotic fabric is carried out rear arrangement processing.
2. 2, the processing method of described antibacterial and deodouring fabric according to claim 1, it is characterized in that: described spinning-grade high polymer material is that spinning-grade poly terephthalic acid second two liquor-saturated vinegar, poly terephthalic acid propylene glycol are cruel, polybutylene terephthalate cruel, a kind of in the poly-phthalein amine, polyacrylonitrile, polypropylene material.
3.3, according to the processing method of the described antibacterial and deodouring fabric of claim l, it is characterized in that: colloid admixture, the silica supports, cupric ammine complex, silica, the antibiotic property potter's clay that carry silver that described nanometer grade inorganic antibacterial agent is that crystallinity silicic acid aluminium, copper compound, antibacterial zeolite, phosphoric acid mistake, silver oxide, zinc oxide, silver zeolite, metallic copper, silver chlorate, phosphoric acid are admired, zinc oxide, oxidation are admired, contain a kind of in the hydrophilic amino organosilicon material.
4. 4, according to the processing method of the described antibacterial and deodouring fabric of claim l, it is characterized in that: to be organic system antiseptic phenols, season take amino two sugar, 1 in class, alcohols, cruel class, sulphur phthalein amine, two flesh class, amino acids, the natural system by salt, amphoteric surfactant, symmetrical hexichol with described antiseptic, 8 one press olein, shitosan, light basic propyl group shitosan, a kind of in cupric cellulose, poly-second phthalein Glucosamine, the tropolone material.
5. 5, according to the processing method of the described antibacterial and deodouring fabric of claim l, it is characterized in that: the mode that described antibiotic fabric is carried out rear arrangement processing is proofing mode, spray pattern, coating way, pad a kind of in the mode.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110261719 CN102978727A (en) | 2011-09-06 | 2011-09-06 | Processing method of durable-type antibacterial deodorizing fiber fabric |
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| CN 201110261719 CN102978727A (en) | 2011-09-06 | 2011-09-06 | Processing method of durable-type antibacterial deodorizing fiber fabric |
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| CN102978727A true CN102978727A (en) | 2013-03-20 |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103590233A (en) * | 2013-11-01 | 2014-02-19 | 东华大学 | Method for interfacial modification of carbon fiber by cryogenic treatment |
| CN103832040A (en) * | 2014-03-18 | 2014-06-04 | 安踏（中国）有限公司 | Antibiosis deodorizing plus material and forming method as well as composite antibiosis deodorizing material |
| CN103981591A (en) * | 2014-05-16 | 2014-08-13 | 湖州珠力纳米材料科技开发有限公司 | Copper-modified antibacterial polyester fiber and preparation method thereof |
| CN104389038A (en) * | 2014-11-04 | 2015-03-04 | 佛山市优特医疗科技有限公司 | Antibacterial fiber as well as product and preparation method thereof |
| CN105386290A (en) * | 2015-12-16 | 2016-03-09 | 湖南科技大学 | Preparation method of collagen fiber/silver chloride hybrid material |
| CN105500791A (en) * | 2015-12-29 | 2016-04-20 | 苏州鑫茂无纺材料有限公司 | Antibacterial compound non-woven fabric |
| CN105603638A (en) * | 2015-12-29 | 2016-05-25 | 苏州鑫茂无纺材料有限公司 | Medical non-woven fabric |
| CN106400527A (en) * | 2015-08-03 | 2017-02-15 | 上海亚都塑料有限公司 | Antimicrobial braided fabric |
| CN106435917A (en) * | 2016-12-07 | 2017-02-22 | 江南大学 | Polyester-cotton composite fabric with antibacterial and impermeable functions and preparation method thereof |
| CN106592230A (en) * | 2016-12-12 | 2017-04-26 | 苏州度博迈医疗科技有限公司 | Preparation method for high surface potential mediated antibacterial biocompatible fabric |
| CN110004507A (en) * | 2018-01-04 | 2019-07-12 | 康豪奈米应用材料有限公司 | The manufacturing method of copper antibacterial matrices |
| CN112779785A (en) * | 2020-12-30 | 2021-05-11 | 江门市德山复合材料科技有限公司 | Composite functional surfactant and application thereof |
| CN113500832A (en) * | 2021-05-12 | 2021-10-15 | 浩阳环境股份有限公司 | Anti-clogging three-dimensional composite drainage net |
| CN117468115A (en) * | 2023-12-26 | 2024-01-30 | 潍坊维尼新材料有限公司 | Deodorizing composite functional nylon fiber and preparation method thereof |
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2011
- 2011-09-06 CN CN 201110261719 patent/CN102978727A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103590233B (en) * | 2013-11-01 | 2015-10-28 | 东华大学 | A kind of subzero treatment carries out the method for interface modification to carbon fiber |
| CN103590233A (en) * | 2013-11-01 | 2014-02-19 | 东华大学 | Method for interfacial modification of carbon fiber by cryogenic treatment |
| CN103832040B (en) * | 2014-03-18 | 2017-01-04 | 安踏（中国）有限公司 | A kind of antibacterial and deodorizing fabric and forming method, a kind of composite antibacterial smelly eliminating material |
| CN103832040A (en) * | 2014-03-18 | 2014-06-04 | 安踏（中国）有限公司 | Antibiosis deodorizing plus material and forming method as well as composite antibiosis deodorizing material |
| CN103981591A (en) * | 2014-05-16 | 2014-08-13 | 湖州珠力纳米材料科技开发有限公司 | Copper-modified antibacterial polyester fiber and preparation method thereof |
| CN103981591B (en) * | 2014-05-16 | 2016-01-20 | 湖州珠力纳米材料科技开发有限公司 | Antibacterial polyester fibre of a kind of copper modification and preparation method thereof |
| CN104389038A (en) * | 2014-11-04 | 2015-03-04 | 佛山市优特医疗科技有限公司 | Antibacterial fiber as well as product and preparation method thereof |
| CN106400527A (en) * | 2015-08-03 | 2017-02-15 | 上海亚都塑料有限公司 | Antimicrobial braided fabric |
| CN105386290A (en) * | 2015-12-16 | 2016-03-09 | 湖南科技大学 | Preparation method of collagen fiber/silver chloride hybrid material |
| CN105603638A (en) * | 2015-12-29 | 2016-05-25 | 苏州鑫茂无纺材料有限公司 | Medical non-woven fabric |
| CN105500791A (en) * | 2015-12-29 | 2016-04-20 | 苏州鑫茂无纺材料有限公司 | Antibacterial compound non-woven fabric |
| CN106435917A (en) * | 2016-12-07 | 2017-02-22 | 江南大学 | Polyester-cotton composite fabric with antibacterial and impermeable functions and preparation method thereof |
| CN106592230A (en) * | 2016-12-12 | 2017-04-26 | 苏州度博迈医疗科技有限公司 | Preparation method for high surface potential mediated antibacterial biocompatible fabric |
| CN106592230B (en) * | 2016-12-12 | 2019-09-13 | 苏州度博迈医疗科技有限公司 | A kind of preparation method for the antibacterial biological biocompatible fabric that high surface potential mediates |
| CN110004507A (en) * | 2018-01-04 | 2019-07-12 | 康豪奈米应用材料有限公司 | The manufacturing method of copper antibacterial matrices |
| CN112779785A (en) * | 2020-12-30 | 2021-05-11 | 江门市德山复合材料科技有限公司 | Composite functional surfactant and application thereof |
| CN113500832A (en) * | 2021-05-12 | 2021-10-15 | 浩阳环境股份有限公司 | Anti-clogging three-dimensional composite drainage net |
| CN117468115A (en) * | 2023-12-26 | 2024-01-30 | 潍坊维尼新材料有限公司 | Deodorizing composite functional nylon fiber and preparation method thereof |
| CN117468115B (en) * | 2023-12-26 | 2024-03-26 | 潍坊维尼新材料有限公司 | Deodorizing composite functional nylon fiber and preparation method thereof |
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Application publication date: 20130320 |