CN102978415A - Oscillating type lead smelting and slag removing device - Google Patents
Oscillating type lead smelting and slag removing device Download PDFInfo
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- CN102978415A CN102978415A CN2012105239880A CN201210523988A CN102978415A CN 102978415 A CN102978415 A CN 102978415A CN 2012105239880 A CN2012105239880 A CN 2012105239880A CN 201210523988 A CN201210523988 A CN 201210523988A CN 102978415 A CN102978415 A CN 102978415A
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- removal tank
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Abstract
The invention discloses an oscillating type lead smelting and slag removing device which comprises a supporting frame arranged above a lead smelting boiler, a slag removing box hinged with the supporting frame, a chain rake mechanism arranged inside the slag removing box, and a driving mechanism which is arranged on the supporting frame and is used for driving the slag removing box to oscillate, wherein a slag inlet extending into the lead smelting boiler and a slag outlet for discharging slag are respectively formed at two ends of the bottom of the slag removing box; and the input end and the output end of the chain rake mechanism respectively corresponds to the slag inlet and the slag outlet of the slag removing box. The oscillating type lead smelting and slag removing device can automatically remove slag during lead smelting; the labor intensity of workers is reduced; a working environment is improved; and the oscillating type lead smelting and slag removing device is simple in structure and convenient to operate.
Description
Technical field
The present invention relates to the molten lead technical field, be specifically related to a kind of swing type molten lead deslagging device.
Background technology
Lead is the human a kind of metal that early extract, and is the softest heavy metal, also is one of metal of density maximum, and plumbous ductility is good, and easy and other metals are made alloy.Lead alloy is in a large number for the manufacture of pole plate, lead pipe and the stereotype of lead acid cell.
In lead acid cell production field, more domestic enterprises with recovery of scrap lead after again melting, the casting lead pig is used for the processing of battery grid and pole plate etc.
For example, application number is that 201210036232.3 Chinese invention patent application has been announced a kind of plumbous method that reclaims from the scrap lead battery, comprises and will comprise plumbous waste and the citric acid fermentation broth hybrid reaction of PbSO4, PbO2, PbO and Pb, with the generation lead citrate; Separation of citric acid is plumbous from the aqueous solution, lead citrate is converted into lead or plumbous oxide again.
Application number is that 201010119502.6 Chinese invention patent discloses a kind of process for recycling waste lead batteries.This process using vacuum technique reclaims waste lead accumulator, comprises vacuum melting, vacuum reducing and vacuum thermal cracking three parts.Waste lead accumulator is after broken apart, and grid adopts the method for vacuum melting to obtain lead pig; After the lead plaster process desulfurization conversion processing, make pelletizing and under vacuum condition, obtain metallic lead with the charcoal reduction; Plastic waste obtains pyrolysis oil and pyrolysis gas by vacuum thermal cracking.Plumbous electrolytic recovery generally gets lead bullion through the preliminary fire refining decopper(ing), and lead bullion obtains electricity again behind electrorefining plumbous.Lead bullion adopts market pot to carry out the decopper(ing) refining, and to impurity such as the harmful copper of electrolysis, tin, the plumbous liquid after the decopper(ing) removal of impurities pumps in the casting equipment by plumbous pump, carries out lead ingot in casting equipment in the removal lead bullion.
In the molten lead process, in market pot under the stirring action of whipping appts, impurity can float over plumbous liquid surface and form one deck scum silica frost, before the casting lead pig, need in market pot, these scum silica frost be pulled out, prevent that these lead skims from entering in the lead pig, affect further refining, increase difficulty and the cost of subsequent purification technique.
For example application number is that 201020582911.7 Chinese utility model patent discloses a kind of automatic submerged slag conveyer, comprise device for dragging dregs, this device for dragging dregs places on the kitchen sink of lead pan by suspension bracket, described device for dragging dregs comprises base, be positioned at the top assembling on device for dragging dregs top, be located at the bottom assembling of device for dragging dregs bottom: be equipped with sprocket wheel in the assembling of described top and the bottom assembling, the sprocket wheel of this top assembling passes through an actuator drives: the sprocket wheel of described top assembling links to each other by flight chain with the sprocket wheel of bottom assembling, be provided with on this flight chain and scrape hopper, described flight chain below is provided with chute, and the afterbody of chute is provided with slag notch.
Traditional deslagging method adopts and drags for slag pan, manually pulls out in market pot, and workman's intensity is large, work under bad environment, operation inconvenience.
Summary of the invention
The invention provides a kind of swing type molten lead deslagging device, realized the automatization that removes the gred in the molten lead process alleviating workman's labour intensity, improve Working environment, and simple in structure, easy to operate.
A kind of swing type molten lead deslagging device comprises:
Bracing frame is erected at the top of market pot; Slag removal tank, hinged with support frame as described above, the two ends of the bottom of this slag removal tank have respectively stretches into entering cinder notch and being used for the slag notch of deslagging in the market pot; Chain harrow mechanism is installed in the inside of described slag removal tank, the input terminus of this chain harrow mechanism and output terminal respectively corresponding described slag removal tank enter cinder notch and slag notch; Driving mechanism is installed on the support frame as described above, is used for driving described slag removal tank and swings.
Slag removal tank is installed in the top of market pot by bracing frame, and the cinder notch that enters of slag removal tank stretches in the market pot, starts chain harrow mechanism, and chain harrow mechanism harrows the lead skim in the market pot in the slag removal tank, is discharged by slag notch.Driving mechanism drives slag removal tank and swings, and reconciles the angle of inclination of slag removal tank, stretches into the degree of depth with the cinder notch that enters of reconciling slag removal tank in market pot.
As preferably, described driving mechanism is screw body or pulley mechanism.
The driving mechanism that drives described slag removal tank swing can be screw body, and described screw body comprises:
Be hinged on the overturning seat on the support frame as described above; The screw mandrel that the top of one end and described slag removal tank is hinged, the other end of this screw mandrel runs through described overturning seat; Be installed in the first drive-motor on the described overturning seat, the gear drive screw mandrel that matches by with described screw mandrel is taken out in the output of this first drive-motor.
The first drive-motor drives screw mandrel and moves up and down, and regulates the angle of inclination of slag removal tank, thereby regulates the degree of depth that cinder notch one end is positioned at market pot that enters of slag removal tank.
The driving mechanism that drives described slag removal tank swing can also be pulley mechanism, and described pulley mechanism comprises:
Be installed in respectively the interior bottom of support frame as described above and two fixed pulleys at top; Be installed in the second drive-motor on the bracing frame; Around the home on two fixed pulleys and an end and the second drive-motor is connected, the other end is connected with slag removal tank travel rope.
As preferably, the cinder notch position that enters of described slag removal tank is provided with slag-guiding plate.Slag-guiding plate is set entering cinder notch, during chain harrow mechanism rake slag, easier the entering in the slag removal tank of scum silica frost in the market pot.
As preferably, support frame as described above is case structure, is located at the outside of described slag removal tank; The top of support frame as described above is with exhaust outlet; One side of support frame as described above is with blast orifice.
Case structure can be located at its inner slag removal tank by protective guard, and the pollution substance that can reduce simultaneously in the market pot volatilizees in ambient air; In the slag removal, in the body structure of bracing frame, blast air, the pollution impurity in the volatilization inlet body is extracted out by exhaust outlet.
As preferably, the top of described slag removal tank is with access hole, and this access hole position is with hermatic door.At slag removal tank access hole is set, convenient maintenance to inner chain harrow mechanism.
As preferably, described chain harrow mechanism comprises:
Chain harrow drive shaft and the driven shaft of switching on slag removal tank; The chain harrow on described chain harrow drive shaft and driven shaft around the home; Outstanding the 3rd drive-motor of establishing, the output shaft of the 3rd drive-motor connects described chain harrow drive shaft by step-down gear; Be fixed on the swing arm on the housing of described the 3rd drive-motor; Be used for stopping the elastic component of described swing arm motion, the two ends of this elastic component are the described swing arm of butt and slag removal tank respectively; Be fixed on the described slag removal tank, for the sensing element of the housing motion of responding to described the 3rd drive-motor, the stopping signal of described the 3rd drive-motor is from this sensing element.
When chain harrow breaks down, when the chain harrow drive shaft was stuck, the torsion buffering system started, the touching sensing element, and sensing element is transferred to the 3rd drive-motor with stopping signal, the 3rd drive-motor auto stop, protection chain harrow drive shaft is not twisted off.
As preferably, described sensing element is travel switch.
As preferably, the housing of described the 3rd drive-motor is provided be used to the frizzen that triggers described sensing element.
When chain harrow breaks down; when the chain harrow drive shaft was stuck, because reactive force, swing arm can swing to the direction with chain harrow drive shaft turns opposite direction; be fixed on the frizzen touching sensing element on the housing, sensing element is about to stopping signal and sends to the 3rd drive-motor.Elastic component limits the limit position that swing arm swings.
As preferably, described elastic component is stage clip.
More preferably, described support is provided with tail rod, and described compression spring sleeve is located on this tail rod.
More preferably, be fixed with mount pad on the described support, described tail rod is fixed on this mount pad, and the two ends of described stage clip are the described swing arm of butt and mount pad respectively.The installation that mount pad makes things convenient for elastic component is set.
More preferably, described swing arm is provided be used to the through hole that passes tail rod.This through hole makes things convenient for the installation of tail rod on swing arm.
More preferably, be provided with two relative limit locating dowels of position between described swing arm and the mount pad.Two limit locating dowel assistant spring spares carry out spacing to the swing limit position of swing arm.
More preferably, be provided with auxiliary stage clip between described swing arm and the mount pad, the two ends of this auxiliary stage clip are set in respectively on described two limit locating dowels.Should can assist elastic component to the return of swing arm by auxiliary stage clip.
For the chain harrow mechanism that is installed in the slag removal tank, in order to make things convenient for the adjusting of chain harrow mechanism rate of tension, as preferably, the outer wall of described slag removal tank is provided with the chain harrow strainer.
More preferably, described chain harrow strainer comprises: be fixed on the mounting plate on the slag removal tank outer wall; The slide of fixing with described driven shaft and being slidingly matched with described mounting plate; And the drive unit that drives the slide slip.
Slide slides at mounting plate, regulates the position of driven shaft, to regulate the rate of tension of chain harrow mechanism.
Beneficial effect of the present invention:
Traditional deslagging method adopts and drags for slag pan, manually pulls out in market pot, and workman's intensity is large, work under bad environment, operation inconvenience.
Bracing frame of the present invention is erected on the market pot, slag removal tank is hinged on the bracing frame, and the chain harrow mechanism in the slag removal tank rotates, and the scum silica frost in the market pot is harrowed in the slag removal tank from entering cinder notch, the slag notch place that reaches slag removal tank discharges scum silica frost, and whole slag removal carries out automatically.Screw body or pulley mechanism drive the slag removal tank upset, regulate the angle of inclination of slag removal tank, to adapt to the plumbous liquid degree of depth in the market pot, increase the practicality of device.
Description of drawings
Fig. 1 is the structural representation of a kind of use state of swing type molten lead deslagging device (entering cinder notch stretches in the market pot) of the embodiment of the invention 1.
Fig. 2 is the structural representation of the another kind of use state of the swing type molten lead deslagging device of the embodiment of the invention 1 (entering cinder notch leaves in the market pot).
Fig. 3 is the structural representation of the swing type molten lead deslagging device of the embodiment of the invention 2.
Fig. 4 is the structural scheme of mechanism of slag removal tank of the present invention and chain harrow mechanism part.
Fig. 5 is the frizzen of chain harrow of the present invention mechanism and the sensing element structural representation when disconnecting.
Fig. 6 is the structural representation of the frizzen of chain harrow of the present invention mechanism when contacting with sensing element.
Structural representation when Fig. 7 is the hermatic door sealing of access hole of the present invention place.
Fig. 8 is the structural representation of check man of the present invention when locating hermatic door and opening.
Embodiment
Shown in Fig. 1, Fig. 2, Fig. 4~8, a kind of swing type molten lead deslagging device comprises the chain harrow mechanism 10 in bracing frame 1, slag removal tank 8, the slag removal tank 8 and the screw body that drives slag removal tank 10 upsets.
An end is installed chain harrow drive shaft 1011 (slag notch 7 one ends) on slag removal tank 8, the other end is installed driven shaft 1013 (entering cinder notch 9 one ends), the outer wall that a wherein end of chain harrow drive shaft 1011 runs through slag removal tank 8 extends to the outside of slag removal tank 8, chain harrow 1002 is around the home on chain harrow drive shaft 1011 and driven shaft, and the input terminus of chain harrow 1002 and output terminal are respectively to entering cinder notch 9 and slag notch 7.
At the outer wall of slag removal tank 8 one the 3rd drive-motor 1001 that suspends, the output shaft of the 3rd drive-motor 1001 connects the end that chain harrow drive shaft 1011 runs through slag removal tank 8 by step-down gear, outer cup at the 3rd drive-motor 1001 and step-down gear is established housing 1003, in housing 1,003 one side outer walls (side relative with chain harrow 1002) fixed installation along the outward extending swing arm 1005 of horizontal plane.
On the outer wall of slag removal tank 8 and be positioned at swing arm 1005 below fix a mount pad 1008, the mounting plate face of mount pad 1008 stretches out and is parallel to each other with swing arm 1005 along horizontal plane, a through hole is set on the swing arm 1005, a tail rod 1004 is fixed with the mounting plate face of mount pad 1008 after running through this through hole, the end that this tail rod 1004 runs through swing arm 1005 is screw rod, a sheathed fitting nut on the part above this screw rod runs through swing arm 1005.
Between swing arm 1005 and mount pad 1008 elastic component 1012 is set, in the present embodiment, this elastic component 1012 is stage clip, and stage clip is located on the tail rod 1004, upper end butt swing arm 1005, the end face of lower end butt mount pad 1008.
At the bottom surface of swing arm 1005 and two relative limit locating dowels 1007 of end face setting position of mount pad 1008, sheathed auxiliary stage clip 1006 on these two limit locating dowels 1007.
On the slag removal tank 8 and below being positioned at housing 1003 sensing element 1010 is being installed; in the present embodiment; this sensing element 1010 is travel switch; fix a frizzen 1009 that triggers sensing element 1010 in the bottom of housing 1003; extend to sensing element 1010 places the end of frizzen 1009; when chain harrow mechanism 10 normally moves; disconnect between this frizzen 1009 and the sensing element 1010; when chain harrow mechanism 10 breaks down when causing chain harrow drive shaft 1011 stuck; swing arm 1005 because of and chain harrow drive shaft 1011 between reactive force swing; to lower compression stage clip and auxiliary stage clip 1006; frizzen 1009 is contacted with sensing element 1010; trigger sensing element 1010, sensing element 1010 sends to the 3rd drive-motor 1001, the three drive-motor 1001 auto stops with stopping signal.
The input terminus of chain harrow mechanism 10 is with to enter cinder notch 9 positions corresponding, output terminal is corresponding with slag notch 7 positions, driving chain harrow drive shaft 1011 by the 3rd drive-motor 1001 rotates, drive chain harrow 1002 transmissions, chain harrow 1002 is discharged enter the slag notch 7 that cinder notch 9 harrow to slag removal tank 8 of the scum silica frost in the market pot 12 from slag removal tank 8 by slag notch 7.
At the hinged overturning seat 3 in bracing frame 1 one sides (side of mounting rod is set) top, this overturning seat 3 and thread fit are with it run through in one rhizoid bar, 4 upper ends, it is hinged that bottom and slag removal tank 8 are positioned at the top of bracing frame 1 outer part, the first drive-motor 5 of a driving screw mandrel 4 also is set on bracing frame 1, and the gear drive screw mandrel 3 that matches by with screw mandrel 4 is taken out in the output of this first drive-motor 5.
Overturning seat 3, screw mandrel 4 and the first drive-motor 5 consist of screw body, and the first drive-motor 5 drives screw mandrel 4 and moves up and down, and regulates the angle of inclination of slag removal tank 8, thereby adjusting slag removal tank 8 stretches into the degree of depth in the market pot 12.
Outer wall at slag removal tank 8 arranges chain harrow strainer 6, the setting position of this chain harrow strainer 6 is corresponding with the driven shaft 1013 in the slag removal tank 8, the slide 602 that this chain harrow strainer 6 comprises the mounting plate 601 that is fixed on the slag removal tank 8, be slidingly matched with this mounting plate 601 and drive the drive unit 601 that this slide 602 slides, this drive unit 603 can adopt prior art, it for example can be the screw rod with the nut seat thread fit, one end of screw rod and slide 602 are fixing, the other end runs through nut seat, and the driven shaft 1013 in the slag removal tank 8 is fixed on the slide 602.
On slag removal tank 8, also be provided with access hole 22, the setting position of this access hole 22 is positioned at the top of slag removal tank 8, at these access hole 22 places hermatic door 23 is set, the structural representation that access hole 22 and hermatic door 23 cooperatively interact as shown in Figure 7 and Figure 8, one side and hermatic door 23 1 sides of access hole 22 are hinged, the opposite side kinge-joint knot component 24 of access hole 22, this buckling piece 24 are a screw rod and are set on a nut on the screw rod that hermatic door 23 is provided with the hole clipping that matches with this screw rod.
When on the closure during hermatic door 23, screw rod is snapped in the hole clipping of hermatic door 23, tighten the nut on the screw rod, as shown in Figure 7, make hermatic door 23 sealings; When needs were opened hermatic door 23, the turn nut shifted out hermatic door 23 with screw rod, and hermatic door 23 is opened, as shown in Figure 8.
Use-pattern of the present invention is as follows:
Reconciled the angle of inclination of slag removal tank 8 by screw body, make the scum silica frost place that is positioned at market pot 12 into cinder notch 9, start the chain harrow mechanism 10 in the slag removal tank 8, chain harrow mechanism 10 harrows the scum silica frost in the market pot 12 to slag notch 7 places from entering cinder notch 9 continuously, is discharged by slag notch 7.
Slagging-off blasts air by blast orifice 13 simultaneously in bracing frame 1, then discharged by exhaust outlet 2.
When the chain harrow of the interior chain harrow of slag removal tank 8 mechanism 10 is lax, regulate the rate of tension of chain harrow mechanisms 10 by chain harrow strainer 6.
When chain harrow mechanism 10 normally moves, disconnect between frizzen 1009 and the sensing element 1010, as shown in Figure 5; When chain harrow mechanism 10 breaks down; when chain harrow drive shaft 1011 is stuck; swing arm 1005 is to lower swing compressing stage clip and auxiliary stage clip 1006; drive housing 1003 and tilt, the frizzen 1009 contact induction elements 1010 of housing 1003 bottoms, as shown in Figure 6; frizzen 1009 triggers sensing element 1010; sensing element 1010 sends to the 3rd drive-motor 1001, the three drive-motor 1001 auto stops with stopping signal, and protection chain harrow drive shaft 1011 is not twisted off.
After the 3rd drive-motor 1001 is shut down, elastic component 1012 and auxiliary stage clip 7 collaborative 1005 returns of swing arm that make, frizzen 1009 disconnects with sensing element 1010.
Such as 3, shown in Fig. 4~8, a kind of swing type molten lead deslagging device, the driving mechanism of driving slag removal tank 8 upsets of present embodiment is different as different from Example 1, adopts pulley mechanism to drive the swing of slag removal tank 8 in the present embodiment.
Pulley mechanism is installed in slag removal tank 8 and brings between the inwall of a side sidewall of cinder notch 9 and supporting rack 1, and pulley mechanism comprises two fixed pulleys and the travel rope 19 on two fixed pulleys around the home in the second drive-motor 15 of being installed on bracing frame 1 sidewall, the bracing frame 1.
Enter cinder notch 9 corresponding side sidewalls at bracing frame 1 and slag removal tank 8 and fixedly mount second drive-motor 15 and two fixed pulleys (the first fixed pulley 18 and the second fixed pulley 21), the output shaft of the second drive-motor 15 extends into bracing frame 1 inside, along vertically to the toothed rack 16 that is slidingly installed, output shaft is provided with the gear meshing with this tooth bar 16 on the inwall of bracing frame 1.
The first fixed pulley 18 is fixedly mounted on the bottom in the bracing frame 1, the second fixed pulley 21 is fixedly mounted on the end face inwall in the bracing frame 1, the first fixed pulley 18 and the second fixed pulley 21 be the certain distance in interval in the horizontal direction, and the top side wall that sets into cinder notch 9 one sides at slag removal tank 8 is fixed an engaging lug 20.
The second drive-motor 15 outputting powers, the tooth bar 16 on the gear on the output shaft and the bracing frame 1 cooperatively interacts, and tooth bar 16 is vertically slided, thus pulling travel rope 19 slides at two fixed pulleys, regulates the angle of inclination of slag removal tank 8.
The mode of operation of present embodiment is with embodiment 1, and difference is that the type of drive of slag removal tank 8 upsets is different.Drive pulling travel rope 19, thereby the angle of inclination of adjusting slag removal tank 8 in the present embodiment by the second drive-motor 15.
The above only is better implementation example of the present invention, is not limited to the present invention, and is all within the present invention spirit and principle, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. a swing type molten lead deslagging device is characterized in that, comprising:
Bracing frame is erected at the top of market pot; Slag removal tank, hinged with support frame as described above, the two ends of the bottom of this slag removal tank have respectively stretches into entering cinder notch and being used for the slag notch of deslagging in the market pot; Chain harrow mechanism is installed in the inside of described slag removal tank, the input terminus of this chain harrow mechanism and output terminal respectively corresponding described slag removal tank enter cinder notch and slag notch; Driving mechanism is installed on the support frame as described above, is used for driving described slag removal tank and swings.
2. swing type molten lead deslagging device according to claim 1 is characterized in that, described driving mechanism is screw body or pulley mechanism.
3. swing type molten lead deslagging device according to claim 2 is characterized in that described screw body comprises:
Be hinged on the overturning seat on the support frame as described above;
The screw mandrel that the top of one end and described slag removal tank is hinged, the other end of this screw mandrel runs through described overturning seat;
Be installed in the first drive-motor on the described overturning seat, the gear drive screw mandrel that matches by with described screw mandrel is taken out in the output of this first drive-motor.
4. swing type molten lead deslagging device according to claim 2 is characterized in that described pulley mechanism comprises:
Be installed in respectively the interior bottom of support frame as described above and two fixed pulleys at top;
Be installed in the second drive-motor on the bracing frame; Around the home on two fixed pulleys and an end and the second drive-motor is connected, the other end is connected with slag removal tank travel rope.
5. according to claim 3 or 4 described swing type molten lead deslagging devices, it is characterized in that the cinder notch position that enters of described slag removal tank is provided with slag-guiding plate.
6. according to claim 3 or 4 described swing type molten lead deslagging devices, it is characterized in that support frame as described above is case structure, be located at the outside of described slag removal tank; The top of support frame as described above is with exhaust outlet; One side of support frame as described above is with blast orifice.
7. according to claim 3 or 4 described swing type molten lead deslagging devices, it is characterized in that the top of described slag removal tank is with access hole, this access hole position is with hermatic door.
8. according to claim 3 or 4 described swing type molten lead deslagging devices, it is characterized in that described chain harrow mechanism comprises:
Chain harrow drive shaft and the driven shaft of switching on slag removal tank;
The chain harrow on described chain harrow drive shaft and driven shaft around the home;
Outstanding the 3rd drive-motor of establishing, the output shaft of the 3rd drive-motor connects described chain harrow drive shaft by step-down gear;
Be fixed on the swing arm on the housing of described the 3rd drive-motor;
Be used for stopping the elastic component of described swing arm motion, the two ends of this elastic component are the described swing arm of butt and slag removal tank respectively;
Be fixed on the described slag removal tank, for the sensing element of the housing motion of responding to described the 3rd drive-motor, the stopping signal of described the 3rd drive-motor is from this sensing element.
9. swing type molten lead deslagging device according to claim 8 is characterized in that the outer wall of described slag removal tank is provided with the chain harrow strainer.
10. swing type molten lead deslagging device according to claim 9 is characterized in that, described chain harrow strainer comprises:
Be fixed on the mounting plate on the slag removal tank outer wall;
The slide of fixing with described driven shaft and being slidingly matched with described mounting plate;
And the drive unit that drives the slide slip.
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CN107838409A (en) * | 2017-11-15 | 2018-03-27 | 广西塔锡科技有限公司 | A kind of removing dross casting mechanism |
CN115849038A (en) * | 2022-12-30 | 2023-03-28 | 浙江天能电源材料有限公司 | Reciprocating type waste lead plaster distributing and quantitative feeding device and method |
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CN115849038B (en) * | 2022-12-30 | 2023-10-03 | 浙江天能电源材料有限公司 | Reciprocating type waste lead plaster distribution quantitative feeding device and method |
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Denomination of invention: A swinging lead melting slag removal device Effective date of registration: 20230905 Granted publication date: 20131204 Pledgee: Agricultural Bank of China Limited by Share Ltd. Changxing County branch Pledgor: ZHEJIANG TIANNENG POWER SOURCE MATERIAL Co.,Ltd. Registration number: Y2023980055316 |
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