CN102971071B - 保护固体吸附剂的方法和受保护的固体吸附剂 - Google Patents

保护固体吸附剂的方法和受保护的固体吸附剂 Download PDF

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Publication number
CN102971071B
CN102971071B CN201180015767.6A CN201180015767A CN102971071B CN 102971071 B CN102971071 B CN 102971071B CN 201180015767 A CN201180015767 A CN 201180015767A CN 102971071 B CN102971071 B CN 102971071B
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heating
solid
surface layer
cooling
zeolite
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CN102971071A (zh
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穆赫辛·S·耶加内
布彭德尔·S·米尼亚斯
赵苏芳
塔米德·I·米赞
理查德·W·弗林
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ExxonMobil Technology and Engineering Co
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ExxonMobil Research and Engineering Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B01J20/28019—Spherical, ellipsoidal or cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3289—Coatings involving more than one layer of same or different nature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3291—Characterised by the shape of the carrier, the coating or the obtained coated product
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
    • F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Sorption Type Refrigeration Machines (AREA)
CN201180015767.6A 2010-03-25 2011-03-24 保护固体吸附剂的方法和受保护的固体吸附剂 Active CN102971071B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US31747110P 2010-03-25 2010-03-25
US61/317,471 2010-03-25
PCT/US2011/029758 WO2011119808A1 (en) 2010-03-25 2011-03-24 Method of protecting a solid adsorbent and a protected solid adsorbent

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CN102971071A CN102971071A (zh) 2013-03-13
CN102971071B true CN102971071B (zh) 2015-09-02

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US (2) US8500887B2 (https=)
EP (1) EP2550096B1 (https=)
JP (1) JP2013523424A (https=)
CN (1) CN102971071B (https=)
CA (1) CA2792488A1 (https=)
SG (1) SG183863A1 (https=)
WO (1) WO2011119808A1 (https=)

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US8425674B2 (en) 2008-10-24 2013-04-23 Exxonmobil Research And Engineering Company System using unutilized heat for cooling and/or power generation
US8555642B2 (en) * 2010-03-09 2013-10-15 Exxonmobil Research And Engineering Company Methods of utilizing waste heat for creating a pressurized working fluid
US8747694B2 (en) * 2010-06-17 2014-06-10 General Electric Company Carbon dioxide absorbent and method of using the same
DE102012014335A1 (de) * 2012-07-19 2014-01-23 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Dispersion, Verfahren zur Beschichtung von Gegenstädenmit dieser Dispersion und Verwendung der Dispersion
US20140165455A1 (en) * 2012-12-19 2014-06-19 Seyed Dastgheib Carbon-hydrocarbon gas composite fuels
KR101823622B1 (ko) 2014-04-02 2018-01-31 한국에너지기술연구원 수분안정성이 개선된 이산화탄소 흡수제 및 그 제조방법
CN104556119B (zh) * 2015-01-28 2016-05-11 西安科技大学 一种采用煤泥制备13x型分子筛的方法
EP3352885B1 (en) 2015-09-25 2022-11-02 ExxonMobil Technology and Engineering Company Cyclic thermal swing adsorption with direct heat transfer using a heat transfer fluid
CN106925235B (zh) * 2017-03-27 2019-10-08 东北大学 一种可高效分离湿气中co2的吸附剂及其制备方法
JPWO2018179089A1 (ja) * 2017-03-28 2020-01-30 日立化成株式会社 吸着剤、反応容器、二酸化炭素除去装置及び二酸化炭素除去システム
JP7360477B2 (ja) 2019-05-24 2023-10-12 インテグリス・インコーポレーテッド 有機金属蒸気を吸着する方法およびシステム
WO2021029979A1 (en) * 2019-08-14 2021-02-18 Exxonmobil Research And Engineering Company Increasing hydrothermal stability of an adsorbent comprising a small pore zeolite in a swing adsorption process
JP7482497B2 (ja) * 2019-11-11 2024-05-14 日本ゼトック株式会社 セラミックス多孔質体及びその製造方法
JP7713700B2 (ja) * 2020-08-21 2025-07-28 日本ゼトック株式会社 選択的油分分離除去剤及びその製造方法、油分の選択的分離除去方法、並びにセラミックス多孔質体
US20230302393A1 (en) * 2022-03-25 2023-09-28 Xiwang Qi System and method for direct air capture of carbon dioxide utilizing a microwave desorption technique
KR102891021B1 (ko) * 2022-11-08 2025-12-01 서울대학교산학협력단 질소산화물 제거용 촉매 및 그 제조 방법
CN116328743B (zh) * 2023-05-11 2024-05-07 北京工业大学 一种在斜发沸石表面原位生长微晶的复合材料制备方法
DE102023117330A1 (de) * 2023-06-30 2025-01-02 Volkswagen Aktiengesellschaft Verfahren zur Verbesserung der CO2:H2O-Selektivität von Zeolithen
DE102025102086A1 (de) 2024-10-14 2026-04-16 Bemeka Technologie-Transfer Gmbh Wiederverwertbare, umweltverträgliche Materialien für die Sequestrierung von Kohlendioxid durch Mineralisierung, Verfahren zu ihrer Herstellung und ihre Verwendung

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US8814986B2 (en) 2014-08-26
US20130288883A1 (en) 2013-10-31
SG183863A1 (en) 2012-10-30
JP2013523424A (ja) 2013-06-17
WO2011119808A1 (en) 2011-09-29
CN102971071A (zh) 2013-03-13
US20110232493A1 (en) 2011-09-29
EP2550096A1 (en) 2013-01-30
CA2792488A1 (en) 2011-09-29
US8500887B2 (en) 2013-08-06
EP2550096B1 (en) 2018-06-06

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