CN102965936A - Nano waterproof, oil-proof and antifouling finishing liquid - Google Patents
Nano waterproof, oil-proof and antifouling finishing liquid Download PDFInfo
- Publication number
- CN102965936A CN102965936A CN2012104348823A CN201210434882A CN102965936A CN 102965936 A CN102965936 A CN 102965936A CN 2012104348823 A CN2012104348823 A CN 2012104348823A CN 201210434882 A CN201210434882 A CN 201210434882A CN 102965936 A CN102965936 A CN 102965936A
- Authority
- CN
- China
- Prior art keywords
- nano
- proof
- ceramic powder
- powder dispersion
- dispersion liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides nano waterproof, oil-proof and antifouling finishing liquid which comprises a waterproof, oil-proof and antifouling fluorine-containing finishing agent and nano ceramic powder dispersion liquid. According to the invention, fabric has an excellent nano waterproof, oil-proof and antifouling function; after multiple times of washing, the nano waterproof, oil-proof and antifouling effect of the fabric is maintained well; moreover, the color fastness is high, and the air permeability and moisture permeability of the fabric are perfect; and after the finishing, the breaking strength of the fabric is not obviously reduced.
Description
Technical field
The present invention relates to field of printing and dyeing, be specifically related to a kind of nano water-proof, grease proofing, soil resistant finish liquid.
Background technology
Existing textiles adopts conventional fluorine-contained finishing agent to carry out waterproof, grease proofing, antifouling (being called for short " three is anti-") arrangement, and three anti-weak effects are repeatedly poorer after the washing, and has the three-prevention finishing problems such as the breathable moisture permeability of fabric is poor later, COLOR FASTNESS is poor.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of nano water-proof, grease proofing, soil resistant finish liquid, not only can make fabric have very good nano water-proof, grease proofing, anti-pollution function, and fabric is through after repeatedly washing, it is fine that three anti-effects still keep, and every COLOR FASTNESS is high, the fabric air-permeability water vapour permeability is good, and fabric strength is after through arrangement, and it is not clearly that its fracture strength descends.
For solving above-mentioned existing technical problem, the present invention adopts following scheme: a kind of nano water-proof, grease proofing, soil resistant finish liquid, comprise for waterproof, grease proofing, antifouling fluorine-contained finishing agent, and also comprise the nano-ceramic powder dispersion liquid.
As preferably, described nano-ceramic powder dispersion liquid comprises deionization, Al
2O
3, dispersant, Al in every 100ml deionized water
2O
3Amount be that the amount of 5-15g, dispersant is 1.2 ~ 2.4ml, the pH value of described nano-ceramic powder dispersion liquid is 8-9.
As preferably, Al in the deionized water of every 100ml
2O
3Amount be that the amount of 10g, dispersant is 2ml, the pH value of described nano-ceramic powder dispersion liquid is 8.5.
As preferably, described nano-ceramic powder dispersion liquid preparation process is: first with Al
2O
3Be dissolved in the deionized water, then splash into dispersant, and then splashing into ammoniacal liquor, to regulate pH value be 8 ~ 9, carries out at last the ultrasonic wave processing again.
As preferably, also comprise crosslinking agent, bleeding agent, citric acid, fluorine-contained finishing agent 30 ~ 60g, nano-ceramic powder dispersion liquid 30 ~ 60g, crosslinking agent 5 ~ 15g, bleeding agent 0.5 ~ 2.5g, citric acid 0.5 ~ 2.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.
Beneficial effect:
A kind of nano water-proof, grease proofing, soil resistant finish liquid that the present invention adopts technique scheme to provide, not only can make fabric have very good nano water-proof, grease proofing, anti-pollution function, and fabric is through after repeatedly washing, it is fine that three anti-effects still keep, and every COLOR FASTNESS is high, the fabric air-permeability water vapour permeability is good, and fabric strength is after through arrangement, and it is not clearly that its fracture strength descends.
The specific embodiment
Embodiment one:
A kind of nano water-proof, grease proofing, soil resistant finish liquid comprise for waterproof, grease proofing, antifouling fluorine-contained finishing agent, also comprise the nano-ceramic powder dispersion liquid.Described nano-ceramic powder dispersion liquid comprises deionization, Al
2O
3, dispersant, Al in every 100ml deionized water
2O
3Amount be that the amount of 5-15g, dispersant is 1.2 ~ 2.4ml, the pH value of described nano-ceramic powder dispersion liquid is 8-9.Al in the deionized water of every 100ml
2O
3Amount be that the amount of 10g, dispersant is 2ml, the pH value of described nano-ceramic powder dispersion liquid is 8.5.Described nano-ceramic powder dispersion liquid preparation process is: first with Al
2O
3Be dissolved in the deionized water, then splash into dispersant, and then splashing into ammoniacal liquor, to regulate pH value be 8 ~ 9, carries out at last the ultrasonic wave processing again.Also comprise crosslinking agent, bleeding agent, citric acid, fluorine-contained finishing agent 30 ~ 60g, nano-ceramic powder dispersion liquid 30 ~ 60g, crosslinking agent 5 ~ 15g, bleeding agent 0.5 ~ 2.5g, citric acid 0.5 ~ 2.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.Fluorine-contained finishing agent 40g, nano-ceramic powder dispersion liquid 40g, crosslinking agent 10g, bleeding agent 1.5g, citric acid 1.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.
Embodiment two:
Be with the difference of embodiment one: Al in the deionized water of every 100ml
2O
3Amount be that the amount of 5g, dispersant is 1.2ml, the pH value of described nano-ceramic powder dispersion liquid is 8.
Embodiment three:
Be with the difference of embodiment one: Al in the deionized water of every 100ml
2O
3Amount be that the amount of 15g, dispersant is 2.4ml, the pH value of described nano-ceramic powder dispersion liquid is 9.
Embodiment four:
Be with the difference of embodiment one: fluorine-contained finishing agent 30g, nano-ceramic powder dispersion liquid 30g, crosslinking agent 5g, bleeding agent 0.5g, citric acid 0.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.
Embodiment five:
Be with the difference of embodiment one: fluorine-contained finishing agent 60g, nano-ceramic powder dispersion liquid 60g, crosslinking agent 15g, bleeding agent 2.5g, citric acid 2.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.
Among the present invention the nano-ceramic powder dispersion liquid in particle the phenomenons such as sedimentation are not arranged, dispersion stabilization is good especially, the nano-ceramic powder dispersion liquid that makes is uniform and stable, properties is good, have preferably dependability.Particle in the nano-ceramic powder dispersion liquid has minimum particle diameter (average grain diameter can reach 120nm following), large specific area and high chemical property, can make composition densification, the homogenising of material.
The Organic fluoride finishing agent that is used for waterproof, grease proofing, soil resistant finish when fluorine-contained finishing agent is existing various printing and dyeing arrangement among the present invention, the preferred Teflon ZSR of fluorine-contained finishing agent finishing agent; The amount of nano-ceramic powder dispersion liquid is preferably 40g.
Because the particle itself in the nano-ceramic powder dispersion liquid has certain electric conductivity, can reduce the electric charge of fiber surface, thereby reduce dirt by the chance of the Electrostatic Absorption between electric charge to the fiber, fabric panel pads processing or heat treatment in having added the nanometer three-prevention finishing liquid of nano-ceramic powder dispersion liquid after, the fiber surface of fabric panel can generate the superpower water of refusing of having of stability and durability, refuse oil, the nanometer level polymer of anti-pollution function characteristic, make the fabric after processing have " lotus leaf " effect, the characteristics such as gas permeability that both kept former fabric, the functional characteristic that has again extraordinary water, oil and soil repellent strengthens the fabric anti-fouling effect.
Claims (5)
1. a nano water-proof, grease proofing, soil resistant finish liquid comprise for waterproof, grease proofing, antifouling fluorine-contained finishing agent, it is characterized in that: also comprise the nano-ceramic powder dispersion liquid.
2. a kind of nano water-proof according to claim 1, grease proofing, soil resistant finish liquid, it is characterized in that: described nano-ceramic powder dispersion liquid comprises deionization, Al
2O
3, dispersant, Al in every 100ml deionized water
2O
3Amount be that the amount of 5-15g, dispersant is 1.2 ~ 2.4ml, the pH value of described nano-ceramic powder dispersion liquid is 8-9.
3. a kind of nano water-proof according to claim 2, grease proofing, soil resistant finish liquid is characterized in that: Al in the deionized water of every 100ml
2O
3Amount be that the amount of 10g, dispersant is 2ml, the pH value of described nano-ceramic powder dispersion liquid is 8.5.
4. according to claim 2 or 3 described a kind of nano water-proofs, grease proofing, soil resistant finish liquid, it is characterized in that: described nano-ceramic powder dispersion liquid preparation process is: first with Al
2O
3Be dissolved in the deionized water, then splash into dispersant, and then splashing into ammoniacal liquor, to regulate pH value be 8 ~ 9, carries out at last the ultrasonic wave processing again.
5. a kind of nano water-proof according to claim 1, grease proofing, soil resistant finish liquid, it is characterized in that: also comprise crosslinking agent, bleeding agent, citric acid, fluorine-contained finishing agent 30 ~ 60g, nano-ceramic powder dispersion liquid 30 ~ 60g, crosslinking agent 5 ~ 15g, bleeding agent 0.5 ~ 2.5g, citric acid 0.5 ~ 2.5g in every liter of nano water-proof, grease proofing, the soil resistant finish liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104348823A CN102965936A (en) | 2012-11-02 | 2012-11-02 | Nano waterproof, oil-proof and antifouling finishing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104348823A CN102965936A (en) | 2012-11-02 | 2012-11-02 | Nano waterproof, oil-proof and antifouling finishing liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102965936A true CN102965936A (en) | 2013-03-13 |
Family
ID=47796352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104348823A Pending CN102965936A (en) | 2012-11-02 | 2012-11-02 | Nano waterproof, oil-proof and antifouling finishing liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102965936A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361979A (en) * | 2013-05-21 | 2013-10-23 | 如皋市协和印染有限公司 | Method for increasing washing durability of three-proof or waterproof fabric |
| CN104153095A (en) * | 2014-07-31 | 2014-11-19 | 江苏新晨化纤股份有限公司 | Waterproof, oil-proof, soil-resistant and anti-pilling nanometer fabric and method for manufacturing same |
| CN104342933A (en) * | 2014-11-28 | 2015-02-11 | 周正英 | Polyester fabric finishing agent with oilproof and waterproof functions function |
| CN106319727A (en) * | 2016-08-19 | 2017-01-11 | 南京中脉科技发展有限公司 | Antibacterial and allergy-free textile fabric and preparation process for same |
| CN114193846A (en) * | 2021-12-22 | 2022-03-18 | 席梦思床褥家具（苏州）有限公司 | Composite fiber fabric with far infrared function and preparation method thereof |
| CN114274607A (en) * | 2021-12-22 | 2022-04-05 | 席梦思床褥家具（苏州）有限公司 | Knitted fabric with sweat-absorbing, antibacterial and deodorizing functions and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687514A (en) * | 2005-04-07 | 2005-10-26 | 上海交通大学 | Water, oil and soil repellent tablecloth |
| CN1886481A (en) * | 2003-11-24 | 2006-12-27 | 3M创新有限公司 | Fluorochemical composition for rendering substrates oil and/or water repellent |
| CN101086138A (en) * | 2007-06-12 | 2007-12-12 | 东华大学 | Organic and inorganic composite self-cleaning finishing agent and its uses |
| CN101715499A (en) * | 2007-04-17 | 2010-05-26 | 海克原料股份公司 | Water-, oil-, and dirt-repellent finishes on fibers and textile fabrics |
-
2012
- 2012-11-02 CN CN2012104348823A patent/CN102965936A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1886481A (en) * | 2003-11-24 | 2006-12-27 | 3M创新有限公司 | Fluorochemical composition for rendering substrates oil and/or water repellent |
| CN1687514A (en) * | 2005-04-07 | 2005-10-26 | 上海交通大学 | Water, oil and soil repellent tablecloth |
| CN101715499A (en) * | 2007-04-17 | 2010-05-26 | 海克原料股份公司 | Water-, oil-, and dirt-repellent finishes on fibers and textile fabrics |
| CN101086138A (en) * | 2007-06-12 | 2007-12-12 | 东华大学 | Organic and inorganic composite self-cleaning finishing agent and its uses |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361979A (en) * | 2013-05-21 | 2013-10-23 | 如皋市协和印染有限公司 | Method for increasing washing durability of three-proof or waterproof fabric |
| CN104153095A (en) * | 2014-07-31 | 2014-11-19 | 江苏新晨化纤股份有限公司 | Waterproof, oil-proof, soil-resistant and anti-pilling nanometer fabric and method for manufacturing same |
| CN104342933A (en) * | 2014-11-28 | 2015-02-11 | 周正英 | Polyester fabric finishing agent with oilproof and waterproof functions function |
| CN106319727A (en) * | 2016-08-19 | 2017-01-11 | 南京中脉科技发展有限公司 | Antibacterial and allergy-free textile fabric and preparation process for same |
| CN114193846A (en) * | 2021-12-22 | 2022-03-18 | 席梦思床褥家具（苏州）有限公司 | Composite fiber fabric with far infrared function and preparation method thereof |
| CN114274607A (en) * | 2021-12-22 | 2022-04-05 | 席梦思床褥家具（苏州）有限公司 | Knitted fabric with sweat-absorbing, antibacterial and deodorizing functions and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102965936A (en) | Nano waterproof, oil-proof and antifouling finishing liquid | |
| Duan et al. | Superhydrophobic and antibacterial wood enabled by polydopamine-assisted decoration of copper nanoparticles | |
| CN105542221B (en) | A kind of wear-resisting super-hydrophobic super-oleophylic polyurethane sponge, preparation method and its application in grease continuously separates | |
| CN102978901A (en) | Preparation technology of water, oil and pollution resistant texture fabric | |
| US6699827B2 (en) | Method for manufacturing an active component of surfactant, surfactant and a method for using the surfactant | |
| CN107629613B (en) | Nano aerogel heat-insulation waterproof coating and preparation method thereof | |
| CN104530851A (en) | Multifunctional surface treating agent and use method thereof | |
| CN108946793B (en) | Near-infrared and mid-infrared plasmon resonance nano material, preparation method and application thereof in antibacterial and antimycotic aspects | |
| MX2010011004A (en) | Foam manipulation compositions containing fine particles. | |
| CN101161916A (en) | Nano protective liquid for weaving and preparation method thereof | |
| CN104293065A (en) | Nano self-cleaning coating and preparation method thereof | |
| CN106110901A (en) | A kind of antibacterial antifouling oil-water separation material and preparation method thereof | |
| CN104805520A (en) | Preparation method of viscose fiber containing apocynum venetum extract | |
| CN104140743A (en) | Functional anti-static wall surface paint and preparation method thereof | |
| CN103468068A (en) | Aqueous elastic fluorocarbon building coating covering large cracks, and preparation method and application thereof | |
| Shabbir et al. | Engineered nanomaterials: scope in today’s textile industry | |
| CN109207968A (en) | A kind of preparation method that special wettable surfaces are copper-based | |
| CN102277736B (en) | Highly-alkaliproof mercerizing and infiltrating refining agent | |
| CN109371679A (en) | A kind of preparation method of easy stain release type fabric water-refusing oil-refusing finishing agent | |
| JP2017141441A (en) | Composite particle, white pigment dispersion and ink composition for inkjet | |
| Han et al. | One-step fabrication of OTS modified superhydrophobic cotton fabric and its efficient oil-water separation application | |
| CN104497725A (en) | Preparation methods of superhydrophobic polystyrene (PS)/ZnO composite sol and composite coating | |
| CN105219239B (en) | A kind of aqueous antirust paint and preparation method thereof | |
| CN104592811B (en) | A kind of environmental protection black ink | |
| CN106833197A (en) | A kind of water paint with water proofing property |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130313 |