CN102965206B - Engine carbon deposition cleaning agent and preparation method thereof - Google Patents
Engine carbon deposition cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN102965206B CN102965206B CN201210450428.7A CN201210450428A CN102965206B CN 102965206 B CN102965206 B CN 102965206B CN 201210450428 A CN201210450428 A CN 201210450428A CN 102965206 B CN102965206 B CN 102965206B
- Authority
- CN
- China
- Prior art keywords
- parts
- engine
- out system
- clean
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 25
- 239000012459 cleaning agent Substances 0.000 title abstract description 6
- 230000008021 deposition Effects 0.000 title abstract description 4
- 238000002360 preparation method Methods 0.000 title description 2
- -1 polyoxypropylene methyl ether Polymers 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 abstract description 5
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000011086 high cleaning Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
- 238000009826 distribution Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002283 diesel fuel Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910021385 hard carbon Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- MJJJJEUEZVGFLW-UHFFFAOYSA-N 2-dodecyl-2-sulfobutanedioic acid Chemical compound CCCCCCCCCCCCC(S(O)(=O)=O)(C(O)=O)CC(O)=O MJJJJEUEZVGFLW-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 208000028804 PERCHING syndrome Diseases 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- 101000976899 Homo sapiens Mitogen-activated protein kinase 15 Proteins 0.000 description 1
- 102000043136 MAP kinase family Human genes 0.000 description 1
- 108091054455 MAP kinase family Proteins 0.000 description 1
- 102100023483 Mitogen-activated protein kinase 15 Human genes 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- MHKKFFHWMKEBDW-UHFFFAOYSA-N dimethyl 2,5-dioxocyclohexane-1,4-dicarboxylate Chemical compound COC(=O)C1CC(=O)C(C(=O)OC)CC1=O MHKKFFHWMKEBDW-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000004533 oil dispersion Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 229910021384 soft carbon Inorganic materials 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to the technical field of engine cleaning agents, and particularly relates to an engine carbon deposition cleaning agent. The engine carbon deposition cleaning agent is composed of the following components in parts by weight: 5-20 parts of surfactant, 5-10 parts of penetrant, 5-15 parts of dispersant, 5-20 parts of emulsifier and 35-80 parts of organic solvent. The cleaning agent has the advantages of high cleaning efficiency, high safety and practicability, environment friendliness and the like.
Description
Technical field
The present invention relates to engine cleansing agent technical field, particularly relate to one and be applied to carbon on engine clean-out system.
Background technology
The fuel oil of engine chamber and air mixed afterfire, due to factors such as atomizing effects, the smog part produced after burning is discharged, and another part forms that carbon distribution is attached to be amassed on the object that temperature is lower as near swirler and nozzle, generates soft carbon distribution; When being deposited on high temp objects as some high-temperature zone wall of combustion chamber flame drum, formed hard carbon distribution by coking.The hard carbon distribution of combustion chamber is petroleum coke substantially, is to be formed by liquid phase fuel pyrolytic cracking pyrolytic deposition, and matter hard being difficult to removes.Hard carbon distribution often becomes the source of corrosion of combustion chamber with a small amount of sulfide.Conventional carbon cleaning method first uses apparatus as bamboo chip, and thick soot particles wiped off by steel disc, or blows large surperficial carbon deposit particle off by the method for blast.Soak with aviation kerosene, cleaning, then uses detergent washing greasy dirt, finally also cleans with a large amount of water again.Such carbon distribution method easily causes physical abuse to part, reduces work-ing life, and aero oil and water resource waste are comparatively large, and pollute the environment.
Real-life automobile maintenance industry needs the carbon distribution often removing fuel engines, and the method for existing decarbonizing is mainly scalped with perching knife after soaking carbon distribution with diesel oil, gasoline again, so both bothersome have the damage easily causing perching knife to engine part, also worry diesel oil in addition, disaster hidden-trouble that gasoline causes and dangerous, and it is also larger to environment with the greasy dirt that diesel oil, gasoline carbon remover are remaining, diesel oil, gasoline also not recoverable, had so not only been unfavorable for environmental protection but also not cost-saving.
The patent No. be 93118502.5 patent discloses one " self cleaning agent for IC engine oil pipes ".It mainly contains butanols, peregal, oleic acid, thanomin, ammoniacal liquor, kerosene, machine oil, glycol ether, water through mixing together.Then join in oil fuel and be made into mixing oil, run within the engine by such mixing oil and burn.This clean-out system reaches the object of removing grease, rust staining and carbon distribution to a certain extent, but containing ammoniacal liquor in formula, can cause corrosion to engine.
Application number be 200410051231.1 application discloses one " fuel engines carbon cleaning liquid ".It is mainly made up of potassium pyrophosphate, trisodium phosphate, sodium hydroxide, sodium carbonate, Starso, tensio-active agent, water.This clean-out system reaches the object of carbon remover to a certain extent, but this clean-out system emits by greasy dirt is become greasy filth, so just require that the engine compartment time must clean, otherwise greasy filth can block engine.At present, research and develop a large amount of carbon on engine clean-out systems, but most of clean-out system all exists has burn into a certain degree easily to block the shortcomings such as engine to engine part, develop a kind of there is high-efficiency cleaning, can reuse, carbon on engine clean-out system that environmental pollution is little just seems particularly necessary.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, the carbon on engine clean-out system that a class is new is provided, the advantages such as this clean-out system has high-efficiency cleaning, cost is low, environmental pollution is little, can reuse.
Carbon on engine clean-out system technical scheme of the present invention is be made up of following component by weight:
Tensio-active agent 5-20 part, permeate agent 5-10 part, dispersion agent 5-15 part, emulsifying agent 5-20 part, organic solvent is 35-80 part.
Tensio-active agent is any one in lauryl sulfosuccinic acid monoester disodium, fatty alcohol-polyoxyethylene ether (3) sulfosuccinic acid monoesters disodium MES, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters disodium DMSS, single Tryfac 5573 MAP, Monododecylphosphate potassium MAPK, alcohol ether phosphate (AEO3, AEO9 phosphoric acid ester), lauryl alcohol phosphoric acid ester potassium (MAEPK), fatty alcohol-polyoxyethylene ether (EO=3) ammonium sulfate (AESA).
Described permeate agent is any one in sulfated castor oil, alkyl sodium sulfonate, alkyl sulfuric ester sodium, secondary alkyl sulphate sodium, a-sodium olefin sulfonate, sodium alkyl naphthalene sulfonate, succsinic acid alkyl ester sulfonate sodium, Igepon T, thionamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
Described dispersion agent is any one in sulphonated oil, alkyl or long chain base benzene sulfonic acid sodium salt, alkyl polyoxyethylene ether, sodium lignosulfonate, naphthalene sulfonic acidformaldehyde condensation product, oleoyl polyamine group carboxylate salt.
Described emulsifying agent is polyethenoxy ether class or polyoxypropylene ethers.
Described organic solvent is any one in ethanol, benzene, toluene, acetone, methylene dichloride, ethyl acetate.
By the emulsifiers dissolve of the permeate agent of the tensio-active agent of 5-20 part, 5-10 part, 5-20 part in the organic solvent of 35-80 part, stirring and dissolving is integrated in a kettle., be warmed up to 20-40 DEG C, add the dispersion agent of 5-15 part while stirring, temperature control is at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains engine cleansing agent.Beneficial effect of the present invention is:
(1) efficient: owing to the addition of tensio-active agent, permeate agent, dispersion agent, thus make clean-out system of the present invention can penetrate into quickly and efficiently carbon on engine inside and with carbon distribution effect, thus play the effect of cleaning.There is cleaning speed fast, effective, thoroughly can remove the advantage of combustion-chamber deposit.
(2) security: traditional clean-out system generally all with the addition of highly basic, and the present invention has abandoned adding of strong alkaline substance, so corrosion-free to engine components, to human-body safety.
(3) suitability: clean-out system of the present invention, owing to the addition of a large amount of dispersion agents, makes carbon distribution to lump, can be distributed in organic solvent, directly can be discharged to external engine, and need not disassemble engine can operate.
embodiment:
In order to understand technical scheme of the present invention better, be described in detail further below by way of specific embodiment.
embodiment 1:
Take lauryl sulfosuccinic acid monoester disodium 5 parts, sulfated castor oil 5 parts, polyoxyethylene methyl ether 5 parts joins in the toluene of 80 parts, be warmed up to 20-40 DEG C, add 5 parts of sulphonated oil dispersion agents while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system A.
embodiment 2:
Take Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters disodium DMSS15 part, a mono-sodium olefin sulfonate 10 parts, polyoxyethylene methyl ether 5 parts joins in the acetone of 70 parts, be warmed up to 20-40 DEG C, add 5 parts of sulphonated oils while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system B.
embodiment 3:
Take Monododecylphosphate potassium MAPK15 part, sodium alkyl naphthalene sulfonate 10 parts, polyoxypropylene methyl ether 5 parts joins in the ethanol of 65 parts, be warmed up to 20-40 DEG C, add 5 parts of sulphonated oils while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system C.
embodiment 4:
Take 15 parts, lauryl alcohol phosphoric acid ester potassium (MAEPK), a-sodium olefin sulfonate 10 parts, polyoxypropylene methyl ether 5 parts joins in the ethyl acetate of 65 parts, be warmed up to 20-40 DEG C, add 5 parts of sodium lignosulfonates while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system D.
embodiment 5:
Take 15 parts, fat polyoxyethylenated alcohol (EO=3) ammonium sulfate (AESA), a-sodium olefin sulfonate 10 parts, polyoxypropylene methyl ether 5 parts joins in the methylene dichloride of 65 parts, be warmed up to 20-40 DEG C, add 5 parts of sodium lignosulfonates while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system E.
embodiment 6:
Take 15 parts, fat polyoxyethylenated alcohol (EO=3) ammonium sulfate (AESA), Seconary Alkane Sulphonate Sodium 10 parts, polyoxypropylene ether 5 parts joins in the ethyl acetate of 65 parts, be warmed up to 20-40 DEG C, add 5 parts of sodium lignosulfonates while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains clean-out system G.
testing example:
Take 5g carbon on engine clean-out system A, B, C, D, E, F, G respectively join traveling 150,000 kilometers and in unwashed Audi A6 engine, test the cleaning performance of clean-out system, as shown in table 1.
Table 1
Result shows: it is fast that A-G clean-out system all has cleaning speed, effective, thoroughly can remove combustion-chamber deposit, reduces oil consumption, reduces the function of noxious gas emission.
Claims (1)
1. a carbon on engine clean-out system, is characterized in that, is prepared from as follows by following component by weight:
Take 15 parts, Monododecylphosphate potassium, sodium alkyl naphthalene sulfonate 10 parts, polyoxypropylene methyl ether 5 parts joins in the ethanol of 65 parts, be warmed up to 20-40 DEG C, add 5 parts of sulphonated oils while stirring, temperature control at 20-50 DEG C, isothermal reaction 30-100min, make it be separated into uniform liquid, namely abundant dissolving obtains carbon on engine clean-out system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210450428.7A CN102965206B (en) | 2012-11-13 | 2012-11-13 | Engine carbon deposition cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210450428.7A CN102965206B (en) | 2012-11-13 | 2012-11-13 | Engine carbon deposition cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102965206A CN102965206A (en) | 2013-03-13 |
| CN102965206B true CN102965206B (en) | 2015-03-25 |
Family
ID=47795642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210450428.7A Active CN102965206B (en) | 2012-11-13 | 2012-11-13 | Engine carbon deposition cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102965206B (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396901B (en) * | 2013-07-31 | 2014-12-17 | 肇庆欧迪斯实业有限公司 | Foam type throttle cleaning aerosol |
| CN104745320A (en) * | 2013-12-25 | 2015-07-01 | 安徽明讯新材料科技有限公司 | Environment-friendly type water-based cleaning compound |
| CN103805370A (en) * | 2014-02-20 | 2014-05-21 | 苏州龙腾万里化工科技有限公司 | Glass detergent formula |
| CN103882504B (en) * | 2014-04-11 | 2016-03-23 | 武汉一枝花油脂化工有限公司 | A kind of grease-removing agent of silicate |
| CN104479895A (en) * | 2014-11-24 | 2015-04-01 | 成都顺发消洗科技有限公司 | Glass antifogging detergent |
| CN107033984A (en) * | 2015-07-14 | 2017-08-11 | 连柏全 | Desulphurization denitration combustion energy-saving combustion adjuvant |
| US10077417B2 (en) * | 2015-09-18 | 2018-09-18 | Ashland Licensing And Intellectual Property, Llc | Cleaning composition comprising an alkyl hydroxybutyrate and method of cleaning air intake valve deposits |
| CN105670829A (en) * | 2016-03-28 | 2016-06-15 | 无锡锡能锅炉有限公司 | Cleaning agent for pollutants on inner walls of biomass boilers |
| CN105755480B (en) * | 2016-05-17 | 2018-06-19 | 江苏筑磊电子科技有限公司 | Efficient acidic cleaner |
| CN105969545A (en) * | 2016-05-27 | 2016-09-28 | 北京科宇泰技术开发有限公司 | Aircraft engine cleansing agent and preparing method thereof |
| CN106085673A (en) * | 2016-06-30 | 2016-11-09 | 蓝星沈阳轻工机械设计研究所 | A kind of eco-friendly car engine interior abluent |
| CN106190619A (en) * | 2016-07-14 | 2016-12-07 | 天津市澳路浦润滑科技股份有限公司 | A kind of aerial motor spare part carbon deposit aqueous cleaning agent |
| CN106281743B (en) * | 2016-07-15 | 2023-04-07 | 广东利源节能减排技术研究所有限公司 | Automobile engine and three-way catalyst cleaning fluid |
| CN106398884A (en) * | 2016-08-31 | 2017-02-15 | 江苏可兰素汽车环保科技有限公司 | Preparation method of diesel engine DOC/POC cleaning regeneration agent |
| CN106800987A (en) * | 2017-01-04 | 2017-06-06 | 卢文哲 | A kind of tyre glue-jetting automatic assembly line special purpose detergent |
| CN107022419A (en) * | 2017-03-31 | 2017-08-08 | 北京联飞翔科技股份有限公司 | A kind of engine cleansing agent and preparation method thereof |
| CN106939248B (en) * | 2017-04-11 | 2019-12-10 | 佛山市云系科技有限公司 | Water-based carbon deposit cleaning composition for automobile |
| CN107033986A (en) * | 2017-04-27 | 2017-08-11 | 山东英可利化工有限公司 | Conduction oil carbon remover and sweep-out method |
| CN107828546B (en) * | 2017-11-01 | 2020-12-08 | 安徽安凯汽车股份有限公司 | Environment-friendly passenger car engine cleaning agent and preparation process thereof |
| CN108004067A (en) * | 2017-12-19 | 2018-05-08 | 山东联星能源集团有限公司 | The military aircraft engine cleaner special and preparation method of a kind of performance efficiency |
| CN110684583B (en) * | 2018-07-06 | 2021-12-14 | 中国石油化工股份有限公司 | Engine interior cleaning agent and preparation method and application thereof |
| CN110283670B (en) * | 2019-07-15 | 2021-06-15 | 云系科技(广东)有限公司 | Special carbon deposition cleaning agent for three-way catalyst for direct injection engine |
| CN110467966A (en) * | 2019-08-07 | 2019-11-19 | 安徽海德化工科技有限公司 | One vegetable oil desulphurization plant desulfurizing agent and preparation method thereof |
| CN112342093A (en) * | 2019-08-09 | 2021-02-09 | 南风化工集团股份有限公司 | Water-based environment-friendly carbon deposition cleaning agent |
| CN111826239A (en) * | 2020-07-15 | 2020-10-27 | 北京神彩泛亚科技有限公司 | Formula and preparation method of combustion chamber cleaning and maintenance agent |
| CN114133952A (en) * | 2020-09-08 | 2022-03-04 | 北京赛福贝特能源技术服务有限公司 | Ammonium salt dispersant for refinery fractionation device, preparation method and application thereof |
| CN112354963A (en) * | 2020-10-13 | 2021-02-12 | 南通锐深环保科技有限公司 | Structured packing degreasing process |
| CN112251297B (en) * | 2020-11-09 | 2021-09-21 | 3M中国有限公司 | Engine carbon deposit cleaning composition, method for preparing engine carbon deposit cleaning composition and method for cleaning engine carbon deposit |
| CN113249155B (en) * | 2021-03-23 | 2022-11-22 | 河南精良新能源科技有限公司 | Cleaning dispersant for fuel oil and preparation method thereof |
| CN113355172B (en) * | 2021-06-08 | 2022-09-16 | 深圳市能效能汽车服务信息有限公司 | Cleaning fluid composition for carbon deposition in fuel automobile engine and cleaning method |
| CN113930296A (en) * | 2021-11-22 | 2022-01-14 | 江苏瑞安汽车实业有限公司 | Neutral combustion chamber cleaning agent and preparation method thereof |
| CN115044419B (en) * | 2022-07-01 | 2023-12-01 | 武汉沃德汇通汽车服务有限公司 | Engine carbon deposit cleaning agent and preparation method thereof |
| CN115975746A (en) * | 2022-12-29 | 2023-04-18 | 陕西瑞益隆科环保科技有限公司 | Scale inhibitor for coking plant equipment and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162630A (en) * | 1996-04-16 | 1997-10-22 | 北京中咨能海咨询公司 | Carbon deposit cleaning agent for gas water heater |
| CN1597896A (en) * | 2004-08-25 | 2005-03-23 | 山东恒冠塑胶有限公司 | Cleaning agent for strong adhesion stain and its application |
| CN1729284A (en) * | 2002-10-21 | 2006-02-01 | 联合能源公司 | Cleaning compositions for oil-gas wells, well lines, casings, equipment, storage tanks, etc., and method of use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1003244B (en) * | 1986-10-15 | 1989-02-08 | 章文陆 | Decurbidizing agent of solvent-emulsion type and aq. type |
| JP2002080888A (en) * | 2000-07-03 | 2002-03-22 | Sanyo Chem Ind Ltd | Anionic surfactant and detergent |
-
2012
- 2012-11-13 CN CN201210450428.7A patent/CN102965206B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162630A (en) * | 1996-04-16 | 1997-10-22 | 北京中咨能海咨询公司 | Carbon deposit cleaning agent for gas water heater |
| CN1729284A (en) * | 2002-10-21 | 2006-02-01 | 联合能源公司 | Cleaning compositions for oil-gas wells, well lines, casings, equipment, storage tanks, etc., and method of use |
| CN1597896A (en) * | 2004-08-25 | 2005-03-23 | 山东恒冠塑胶有限公司 | Cleaning agent for strong adhesion stain and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102965206A (en) | 2013-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102965206B (en) | Engine carbon deposition cleaning agent and preparation method thereof | |
| CN101760345B (en) | Deposited carbon cleaning agent for internal-combustion engine | |
| CN102808191B (en) | Biological decarburizing cleaning agent | |
| CN102732900B (en) | Automobile combustion chamber carbon deposition aqueous removing agent and preparation method thereof | |
| CN107057898A (en) | A kind of aerial fog type cleaning agent for automotive engine throttle | |
| CN102242020B (en) | Cleaning agent for rotary machine used for conveying blast furnace gas and coke oven gas | |
| CN102618396A (en) | Mechanical equipment cleaning liquid | |
| CN107287047A (en) | A kind of aqueous cleaning agent of gas-air passage | |
| CN103666818B (en) | A kind of carbon on engine clean-out system and preparation method thereof | |
| CN102453623A (en) | Range hood cleaning agent | |
| CN104342327A (en) | Oil-stain cleaning agent as well as preparation method and use method thereof | |
| CN101602969A (en) | Fuel system carbon deposit undisassembly abluent of diesel engine | |
| CN109439363A (en) | A kind of peace and quiet water removal protective agent of ethanol petrol and its preparation method and application | |
| CN100402704C (en) | Degreasing agent for removing aviation pipe surface oil dirt | |
| CN101928625A (en) | Novel engine fuel additive | |
| CN109913277A (en) | A kind of high-energy methanol diesel-oil constituent | |
| CN112143582A (en) | Micro-emulsion type anti-corrosion cleaning agent for carbon deposition of parts of aircraft engine | |
| CN108795516A (en) | A kind of in-cylinder direct-jet cleaning agent and preparation method thereof | |
| CN113430071A (en) | Carbon deposit cleaning composition for engine of fuel engine and use method | |
| CN104877831B (en) | A kind of automobile engine automobile carbon deposition cleaning agent free of demolition | |
| CN104388199A (en) | Specific decarbonizer for interior of engine | |
| EP3512929A1 (en) | Cleaning composition and testing method for air intake valve deposits | |
| ul Haq et al. | Macroscopic spray behavior in pressurized chamber alongside thermal performance of quaternary castor biodiesel with butanol and 1-butoxybutane | |
| CN106281752A (en) | A kind of automobile carbon deposition scavenger specially | |
| CN103184460A (en) | Preparation method for cleaning agent for high-temperature carbon deposit in combustion chamber of all- aluminium engine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhang Chengru Inventor before: Zhang Chengru Inventor before: Cheng Xiuli Inventor before: Zhang Yi |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHANG CHENGRU CHENG XIULI ZHANG YI TO: ZHANG CHENGRU |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160308 Address after: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee after: Xinghuo Sci. & Tech. Research Inst., Jinan Dev. Zone Address before: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee before: Shandong Taide New Energy Co., Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20180502 Address after: 276600 West Huaihailu Road section of Junan County, Linyi, Shandong Patentee after: Linyi Shinengde Environmental Protection Fuel Chemical Co.,Ltd. Address before: 250100 2 north section of Qilihe Road, Licheng District, Ji'nan, Shandong Patentee before: Xinghuo Sci. & Tech. Research Inst., Jinan Dev. Zone |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200717 Address after: Room 401, unit 2, building 11, No.2, Qilihe Road, Licheng District, Jinan City, Shandong Province 250100 Patentee after: SHANDONG XINGHUO INTELLECTUAL PROPERTY SERVICE Co.,Ltd. Address before: 276600 west section of Junan County, Linyi City, Shandong Province, Huaihailu Road Patentee before: LINYI SHINENGDE ENVIRONMENTAL PROTECTION FUEL CHEMICAL Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20211122 Address after: Room 608, 6 / F, Zhongxing business enterprise development center, Pingshang Town, Lingang Economic Development Zone, Linyi City, Shandong Province Patentee after: Linyi Xinghuo Intellectual Property Service Co.,Ltd. Address before: Room 401, unit 2, building 11, No.2, Qilihe Road, Licheng District, Jinan City, Shandong Province 250100 Patentee before: SHANDONG XINGHUO INTELLECTUAL PROPERTY SERVICE CO.,LTD. |