CN102964803A - Method for manufacturing solar photovoltaic module junction box - Google Patents
Method for manufacturing solar photovoltaic module junction box Download PDFInfo
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- CN102964803A CN102964803A CN2012104753684A CN201210475368A CN102964803A CN 102964803 A CN102964803 A CN 102964803A CN 2012104753684 A CN2012104753684 A CN 2012104753684A CN 201210475368 A CN201210475368 A CN 201210475368A CN 102964803 A CN102964803 A CN 102964803A
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- aluminum oxide
- silicon carbide
- solar photovoltaic
- photovoltaic assembly
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Abstract
The invention relates to a material for manufacturing a solar photovoltaic module junction box. The material comprises the following components in percentage by weight: 25 to 30 percent of polyphenyl ether, 25 to 30 percent of nylon 66, 5 to 8 percent of glass fiber, 2.5 to 3.5 percent of a compatilizer, 3 to 4.5 percent of a toughening agent, 1 to 1.5 percent of an auxiliary agent, and 25 to 30 percent of a packing material which is a mixture of silicon carbide and aluminum oxide, wherein the silicon carbide and aluminum oxide particles are obtained by mixing nano-particles and micron-particles, and the weight ratio of the nano-particles to the micron-particles in each of the silicon carbide particles and the aluminum oxide particles is 1:1.
Description
Technical field
The invention belongs to polymeric material field, refer to especially a kind of material for the manufacture of the solar photovoltaic assembly terminal box.
Background technology
Existing solar photovoltaic assembly terminal box includes the electric elements in terminal block housings, cable, cable connector and the box.Electric elements in the box body have consisted essentially of the electronic components such as diode, and the environment for use of terminal box is outdoor, and the function that this just requires terminal box will have waterproof, protection against the tide and dispel the heat is to avoid causing the damage of the electric elements in the terminal box.
In order to guarantee the heat sinking function of terminal box, there is technology to propose at junction box body scatterer to be set, it is that the use of scatterer has increased the production cost of terminal box that there is defective in this technical scheme, and is unfavorable for insulation.Also technology proposes, and uses the bilayer structure of metal shell structure, and between two-layer housing vent passages is set.Adopt the design of metal shell and vent passages, although can improve to a certain extent radiating effect, metal heat absorption capacity in the sun can be offset the heat-sinking capability of metal.And can't accomplish completely waterproof and protection against the tide in junction box body Pi ventilation hole design, the life-span of the electric elements in the butted line box is influential.
Summary of the invention
The purpose of this invention is to provide a kind of material for the manufacture of the photovoltaic terminal box, described material can when guaranteeing insulation, have good heat dispersion.Therefore, do not need to provide separately heat abstractor and vent passages and effectively waterproof and protection against the tide for terminal box.
The present invention is achieved by the following technical solutions:
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes the polyphenylene oxide of 25-30% by weight percentage, the nylon 66 of 25-30%, the glass fibre of 5-8%, the compatilizer of 2.5-3.5%, the toughner of 3-4.5%, the auxiliary agent of 1-1.5%, the filler of 25-30%; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide.
The particle diameter of nano particle is the 20-50 nanometer in the particle of described silicon carbide and aluminum oxide.
The particle diameter of micron particle is the 40-200 micron in the particle of described silicon carbide and aluminum oxide.
Described aluminum oxide accounts for the weight percent 13-40% of filler.
Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer.
The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Compatilizer is selected from the PPO-g-MAH that percentage of grafting is 0.8-1.5%, and the polyphenylene oxide grafted maleic anhydride by adding compatilizer, has strengthened the interface compatibility of polyphenylene oxide and nylon 66, realizes the even mixing of each component in the synthetic plastics.
Toughner is selected from the SEBS-g-MAH that percentage of grafting is 0.8-1.5%, and the SEBS grafted maleic anhydride has improved toughness and over-all properties by doping plasticizing agent in synthetic plastics.
The beneficial effect that the present invention compares with prior art is:
By in plastics, adding silicon carbide and the aluminum oxide with good heat conductive performance, effectively realized radiating effect; And this material has good insulating property.
Embodiment
Describe by the following examples technical scheme of the present invention in detail, following embodiment only can be used for the present invention being described and can not being interpreted as to be limitation of the present invention.
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes the polyphenylene oxide of 25-30% by weight percentage, the nylon 66 of 25-30%, the glass fibre of 5-8%, the compatilizer of 2.5-3.5%, the toughner of 3-4.5%, the auxiliary agent of 1-1.5%, the filler of 25-30%; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide.
By the analysis showed that, when the particle of silicon carbide and aluminum oxide was respectively the composite grain of nano particle and micron particle, radiating effect was significantly better than the radiating effect of single particle, and the radiating effect when the weight ratio of two kinds of particles is 1: 1 is best.
The particle diameter of nano particle is the 20-50 nanometer in the particle of described silicon carbide and aluminum oxide.
The particle diameter of micron particle is the 40-200 micron in the particle of described silicon carbide and aluminum oxide.
Described aluminum oxide accounts for the weight percent 13-40% of filler.
Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer.
The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Compatilizer is selected from the PPO-g-MAH that percentage of grafting is 0.8-1.5%, and the polyphenylene oxide grafted maleic anhydride by adding compatilizer, has strengthened the interface compatibility of polyphenylene oxide and nylon 66, realizes the even mixing of each component in the synthetic plastics.
Toughner is selected from the SEBS-g-MAH that percentage of grafting is 0.8-1.5%, and the SEBS grafted maleic anhydride has improved toughness and over-all properties by doping plasticizing agent in synthetic plastics.
A kind of material preparation method of making the solar photovoltaic assembly terminal box may further comprise the steps:
At first, its composition includes by weight percentage, the polyphenylene oxide of 25-30%, and the nylon 66 of 25-30%, the compatilizer of 2.5-3.5%, the toughner of 3-4.5%, the auxiliary agent of 1-1.5%, the filler of 25-30%, described filler are the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide, and above-mentioned composition is made mixture;
Secondly, under temperature 230-250 ℃ condition, be that the screw extrusion press skill of 25-40 go out process with length-to-diameter ratio with this mixture, to extrude in the treatment step at this, the adding weight percentage is the glass fibre of 5-8%.
In the present invention, described polyphenylene oxide chemical name is called for short PPO for poly-2,6-dimethyl-Isosorbide-5-Nitrae-phenylate; The chemical name of described nylon 66 is polyhexamethylene adipamide, is called for short PA66.
Compatilizer is selected from the PPO-g-MAH that percentage of grafting is 0.8-1.5%, and the polyphenylene oxide grafted maleic anhydride by adding compatilizer, has strengthened the consistency of each component in the synthetic plastics, realizes evenly mixing.
Toughner is selected from the SEBS-g-MAH that percentage of grafting is 0.8-1.5%, and the SEBS grafted maleic anhydride has improved toughness and over-all properties by doping plasticizing agent in synthetic plastics.
Oxidation inhibitor is selected from triglycol two-3-(the 3-tertiary butyl-4 hydroxy-5-methyl base phenyl) fine, four [methyl-β-(3 of propylene, 5-di-t-butyl-4 hydroxy phenyl) propionic ester] one or more combinations in pentaerythritol ester, three (2, the 4-di-tert-butylphenol) phosphorous acid ester.
Lubricant is selected from one or both combinations in tetramethylolmethane stearate or the two stearic amides of ethyl.
Thermo-stabilizer is selected from one or both combinations in zinc oxide or the zinc sulphide.
Preparation method in various embodiments of the present invention is identical, the composition that different only is among each embodiment.
Embodiment 1
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes by weight percentage, 30% polyphenylene oxide, the glass fibre of 25% nylon 66,8%, 2.5% compatilizer, 3% toughner, 1.5% auxiliary agent, 30% filler; Described filler is the mixture of silicon carbide and aluminum oxide; Described aluminum oxide accounts for the weight percent 15% of filler; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide; Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer; The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Embodiment 2
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes by weight percentage, 25% polyphenylene oxide, the glass fibre of 30% nylon 66,8%, 2.5% compatilizer, 3% toughner, 1.5% auxiliary agent, 30% filler; Described filler is the mixture of silicon carbide and aluminum oxide; Described aluminum oxide accounts for the weight percent 20% of filler; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide; Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer; The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Embodiment 3
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes by weight percentage, 30% polyphenylene oxide, the glass fibre of 30% nylon 66,8%, 2.5% compatilizer, 3% toughner, 1.5% auxiliary agent, 25% filler; Described filler is the mixture of silicon carbide and aluminum oxide; Described aluminum oxide accounts for the weight percent 15% of filler; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide; Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer; The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Embodiment 4
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes by weight percentage, 28% polyphenylene oxide, the glass fibre of 28% nylon 66,5%, 3.5% compatilizer, 4.5% toughner, 1.0% auxiliary agent, 30% filler; Described filler is the mixture of silicon carbide and aluminum oxide; Described aluminum oxide accounts for the weight percent 15% of filler; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide; Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer; The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Embodiment 5
A kind of material of making the solar photovoltaic assembly terminal box, its composition includes by weight percentage, 28% polyphenylene oxide, the glass fibre of 28% nylon 66,8%, 3% compatilizer, 4% toughner, 1.5% auxiliary agent, 27.5% filler; Described filler is the mixture of silicon carbide and aluminum oxide; Described aluminum oxide accounts for the weight percent 15% of filler; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide; Described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer; The weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
Claims (8)
1. material of making the solar photovoltaic assembly terminal box, it is characterized in that: its composition includes by weight percentage, the polyphenylene oxide of 25-30%, the nylon 66 of 25-30%, the glass fibre of 5-8%, the compatilizer of 2.5-3.5%, the toughner of 3-4.5%, the auxiliary agent of 1-1.5%, the filler of 25-30%; Described filler is the mixture of silicon carbide and aluminum oxide; The particle of described silicon carbide and aluminum oxide is mixing of nano particle and micron particle, and the weight ratio of nano particle and micron particle is 1: 1 in the particle of described silicon carbide and aluminum oxide.
2. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: the particle diameter of nano particle is the 20-50 nanometer in the particle of described silicon carbide and aluminum oxide.
3. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: the particle diameter of micron particle is the 40-200 micron in the particle of described silicon carbide and aluminum oxide.
4. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: described aluminum oxide accounts for the weight percent 13-40% of filler.
5. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: described auxiliary agent comprises oxidation inhibitor, lubricant and thermo-stabilizer.
6. manufacturing solar photovoltaic assembly joint-box compound according to claim 5, it is characterized in that: the weight ratio of described oxidation inhibitor, lubricant and thermo-stabilizer is 1: 1: 2.
7. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: compatilizer is selected from the PPO-g-MAH that percentage of grafting is 0.8-1.5%, the polyphenylene oxide grafted maleic anhydride, by adding compatilizer, strengthen the interface compatibility of polyphenylene oxide and nylon 66, realized the even mixing of each component in the synthetic plastics.
8. manufacturing solar photovoltaic assembly joint-box compound according to claim 1, it is characterized in that: toughner is selected from the SEBS-g-MAH that percentage of grafting is 0.8-1.5%, the SEBS grafted maleic anhydride has improved toughness and over-all properties by doping plasticizing agent in synthetic plastics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012104753684A CN102964803A (en) | 2012-11-19 | 2012-11-19 | Method for manufacturing solar photovoltaic module junction box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012104753684A CN102964803A (en) | 2012-11-19 | 2012-11-19 | Method for manufacturing solar photovoltaic module junction box |
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| CN102964803A true CN102964803A (en) | 2013-03-13 |
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| CN2012104753684A Pending CN102964803A (en) | 2012-11-19 | 2012-11-19 | Method for manufacturing solar photovoltaic module junction box |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331100A (en) * | 2015-11-17 | 2016-02-17 | 安徽正华电气有限公司 | High-strength junction box with explosion-proof material added |
| CN113789043A (en) * | 2021-09-29 | 2021-12-14 | 苏州赛伍应用技术股份有限公司 | Heat-conducting junction box material and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0682084A2 (en) * | 1994-05-13 | 1995-11-15 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition |
| CN101096423A (en) * | 2007-06-22 | 2008-01-02 | 哈尔滨工业大学 | Temperature-resistant resin modified polyphenyl ester ternary alloy ultrasonic motor friction material |
| CN101875776A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | High-strength PPO/PA66 alloy material and preparation method thereof |
-
2012
- 2012-11-19 CN CN2012104753684A patent/CN102964803A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0682084A2 (en) * | 1994-05-13 | 1995-11-15 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition |
| CN101096423A (en) * | 2007-06-22 | 2008-01-02 | 哈尔滨工业大学 | Temperature-resistant resin modified polyphenyl ester ternary alloy ultrasonic motor friction material |
| CN101875776A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | High-strength PPO/PA66 alloy material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331100A (en) * | 2015-11-17 | 2016-02-17 | 安徽正华电气有限公司 | High-strength junction box with explosion-proof material added |
| CN113789043A (en) * | 2021-09-29 | 2021-12-14 | 苏州赛伍应用技术股份有限公司 | Heat-conducting junction box material and preparation method and application thereof |
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Application publication date: 20130313 |