CN102952507B - Water-based environment-friendly fine mounting glue - Google Patents
Water-based environment-friendly fine mounting glue Download PDFInfo
- Publication number
- CN102952507B CN102952507B CN201210416540.9A CN201210416540A CN102952507B CN 102952507 B CN102952507 B CN 102952507B CN 201210416540 A CN201210416540 A CN 201210416540A CN 102952507 B CN102952507 B CN 102952507B
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- initiator
- glue
- raw material
- monomer
- weight parts
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- 239000003292 glue Substances 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 239000003999 initiator Substances 0.000 claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 230000007613 environmental effect Effects 0.000 claims description 13
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 230000001681 protective effect Effects 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000004945 emulsification Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 230000037303 wrinkles Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000013538 functional additive Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a water-based environment-friendly fine mounting glue, which is composed of the following raw materials: a pre-emulsifier, a seed monomer, an dropping monomer, an initiator 1, an initiator 2 and a functional additive. The fine mounting glue produced by the invention is environment-friendly and healthy, does not have bad smell or contain harmful substances such as toluene, dimethylbenzene and heavy metals, and has the advantages of high solid content and high toughness. The mounting product hardly wrinkle or deform. In addition, the glue has fast drying speed at room temperature, high yield efficiency, good stain cleaning performance and coating performance, and initial adhesion and lasting adhesion reaching the process requirements for a hardcover gift box.
Description
Technical field
The main a kind of essence of the present invention mounts glue, particularly relates to a kind of aqueous, environmental protective essence and mounts glue.
Background technology
When making hard-cover gift box by hand, to the initial bonding strength of glue with hold viscosity and have higher requirement, the initial bonding strength had to make glue holds viscosity with long, past is when glue, employ toluene, dimethylbenzene rosin, the raw material such as SBS adopts the method for water and milk to be made, and because this technique employs toluene and dimethylbenzene, so obnoxious flavour exceeds standard, (smell is large) not environmentally.
Summary of the invention
The object of the invention is just to provide a kind of aqueous, environmental protective essence and mounts glue.
The present invention is achieved by the following technical solutions:
A kind of aqueous, environmental protective essence mounts glue, and it is made up of the raw material of following weight parts:
Pre-emulsification agent 360-400, seed monomer 40-45, dropping monomer 180-185, initiator 1 16-18, initiator 2 90-95, functional aid 18-22;
Wherein, described pre-emulsification agent is mixed by the raw material of following weight parts and forms: deionized water 300-350, sodium hydroxide 8-10; Vinylformic acid 30-35, OP-10 4-5;
Described seed monomer is mixed by following weight parts raw material and forms: vinylformic acid 1-2, Butyl acrylate 22-26, vinyl acetate between to for plastic 10-12, diacetone 0.3-0.8, polyacrylamide 0.3-0.8;
Described dropping monomer is mixed by the raw material of following weight parts and forms: vinylformic acid 5-8, Butyl acrylate 115-125, vinyl acetate between to for plastic 53-58, diacetone 1.2-1.8, polyacrylamide 1.2-1.8;
Described initiator 1 for concentration be the ammonium persulfate aqueous solution of 2.8-3%;
Described initiator 2 for concentration be the ammonium persulfate aqueous solution of 2-2.2%;
Described functional aid is mixed by the raw material of following weight parts and forms: concentration is ammonia soln 8-12, ethylene glycol 6-10, the silicone antifoam agent 1-2 of 25-28%.
Described aqueous, environmental protective essence mounts the preparation method of glue, comprises the following steps:
The pre-emulsification agent of above-mentioned weight part is joined in reactor, when raised temperature is to 75-80 DEG C gradually, adds seed monomer and the initiator 1 of above-mentioned weight part; React after 30-35 minute, control temperature is at 82-86 DEG C, and drip dropping monomer and the initiator 2 of above-mentioned weight part, time for adding is between 4-5 hour; After being added dropwise to complete, be warming up to 88-90 DEG C, insulation 1-1.5 hour, normal temperature is cooled to 45-50 DEG C, adds the functional aid of above-mentioned weight part, and mixing, obtains described aqueous, environmental protective essence and mount glue.
Advantage of the present invention is:
The essence that the present invention produces mounts glue environmental protection, good for health, without unpleasant odor, not containing toluene and the objectionable impurities such as dimethylbenzene and heavy metal, there is high solids content, high tenacity, make mounted product wrinkle resistant, not yielding, under normal temperature, rate of drying is very fast, and efficient efficiency is high, go stain keep a public place clean performance and coating performance good, the initial bonding strength of its glue and hold viscosity and all can reach the processing requirement making hard-cover gift box.
Embodiment
Embodiment 1
A kind of aqueous, environmental protective essence mounts glue, and it is made up of the raw material of following weight parts:
Pre-emulsification agent 400, seed monomer 45, dropping monomer 180, initiator 1 18, initiator 2 95, functional aid 22;
Wherein, described pre-emulsification agent is mixed by the raw material of following weight parts and forms: deionized water 350, sodium hydroxide 10; Vinylformic acid 35, OP-10 5;
Described seed monomer is mixed by following weight parts raw material and forms: vinylformic acid 1, Butyl acrylate 22-26, vinyl acetate between to for plastic 10, diacetone 0.8, polyacrylamide 0.8;
Described dropping monomer is mixed by the raw material of following weight parts and forms: vinylformic acid 5-8, Butyl acrylate 115, vinyl acetate between to for plastic 53, diacetone 1.2, polyacrylamide 1.8;
Described initiator 1 for concentration be the ammonium persulfate aqueous solution of 3%;
Described initiator 2 for concentration be the ammonium persulfate aqueous solution of 2.2%;
Described functional aid is mixed by the raw material of following weight parts and forms: concentration is ammonia soln 12, ethylene glycol 10, the silicone antifoam agent 2 of 28%.
Described aqueous, environmental protective essence mounts the preparation method of glue, comprises the following steps:
The pre-emulsification agent of above-mentioned weight part is joined in reactor, gradually during raised temperature to 80 DEG C, adds seed monomer and the initiator 1 of above-mentioned weight part; React after 35 minutes, control temperature is at 86 DEG C, and drip dropping monomer and the initiator 2 of above-mentioned weight part, time for adding is between 5 hours; After being added dropwise to complete, be warming up to 90 DEG C, be incubated 1.5 hours, normal temperature is cooled to 50 DEG C, adds the functional aid of above-mentioned weight part, and mixing, obtains described aqueous, environmental protective essence and mount glue.
Claims (2)
1. aqueous, environmental protective essence mounts a glue, it is characterized in that it is made up of the raw material of following weight parts:
Pre-emulsification agent 360-400, seed monomer 40-45, dropping monomer 180-185, initiator 1 16-18, initiator 2 90-95, functional aid 18-22;
Wherein, described pre-emulsification agent is mixed by the raw material of following weight parts and forms: deionized water 300-350, sodium hydroxide 8-10; Vinylformic acid 30-35, OP-10 4-5;
Described seed monomer is mixed by following weight parts raw material and forms: vinylformic acid 1-2, butyl acrylate 22-26, vinyl acetate between to for plastic 10-12, diacetone 0.3-0.8, polyacrylamide 0.3-0.8;
Described dropping monomer is mixed by the raw material of following weight parts and forms: vinylformic acid 5-8, butyl acrylate 115-125, vinyl acetate between to for plastic 53-58, diacetone 1.2-1.8, polyacrylamide 1.2-1.8;
Described initiator 1 for concentration be the ammonium persulfate aqueous solution of 2.8-3%;
Described initiator 2 for concentration be the ammonium persulfate aqueous solution of 2-2.2%;
Described functional aid is mixed by the raw material of following weight parts and forms: concentration is ammonia soln 8-12, ethylene glycol 6-10, the silicone antifoam agent 1-2 of 25-28%.
2. aqueous, environmental protective essence as claimed in claim 1 mounts a preparation method for glue, it is characterized in that comprising the following steps:
The pre-emulsification agent of weight part described in claim 1 is joined in reactor, when raised temperature is to 75-80 DEG C gradually, adds seed monomer and the initiator 1 of weight part described in claim 1; React after 30-35 minute, control temperature is at 82-86 DEG C, and drip dropping monomer and the initiator 2 of weight part described in claim 1, time for adding is between 4-5 hour; After being added dropwise to complete, be warming up to 88-90 DEG C, insulation 1-1.5 hour, normal temperature is cooled to 45-50 DEG C, adds the functional aid of weight part described in claim 1, and mixing, obtains described aqueous, environmental protective essence and mount glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416540.9A CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416540.9A CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102952507A CN102952507A (en) | 2013-03-06 |
| CN102952507B true CN102952507B (en) | 2014-12-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210416540.9A Active CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102952507B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216831A (en) * | 2017-07-07 | 2017-09-29 | 泗县美佳化建有限责任公司 | A kind of aggretion type aqueous, environmental protective pencil glues core rubber and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570673A (en) * | 2009-05-21 | 2009-11-04 | 上海东和胶粘剂有限公司 | KT sheet gum and preparation method thereof |
| CN101705065A (en) * | 2009-10-08 | 2010-05-12 | 广东三和化工科技有限公司 | Water-resistant white latex |
| CN102391411A (en) * | 2011-08-29 | 2012-03-28 | 华南理工大学 | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof |
-
2012
- 2012-10-27 CN CN201210416540.9A patent/CN102952507B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570673A (en) * | 2009-05-21 | 2009-11-04 | 上海东和胶粘剂有限公司 | KT sheet gum and preparation method thereof |
| CN101705065A (en) * | 2009-10-08 | 2010-05-12 | 广东三和化工科技有限公司 | Water-resistant white latex |
| CN102391411A (en) * | 2011-08-29 | 2012-03-28 | 华南理工大学 | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102952507A (en) | 2013-03-06 |
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| C14 | Grant of patent or utility model | ||
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Effective date of registration: 20201203 Address after: Group 1, Yuechi village, Xindian Town, Rudong County, Nantong City, Jiangsu Province, 226400 Patentee after: Niu Xiaoduo Address before: 234300, Anhui, Suzhou, Sixian cutting North Road North Patentee before: SI COUNTY MEIJIA CHEMICAL BUILDING Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231221 Address after: 224199 West Side of Qingdao Port Road, Dafeng Port, Dafeng District, Yancheng City, Jiangsu Province (701, 7th Floor, Jiangsu Marine Industry Research Institute) Patentee after: Yancheng Lingsheng Technology Service Co.,Ltd. Address before: Group 1, Yuechi village, Xindian Town, Rudong County, Nantong City, Jiangsu Province, 226400 Patentee before: Niu Xiaoduo |
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| TR01 | Transfer of patent right |