CN102952507A - Water-based environment-friendly fine mounting glue - Google Patents
Water-based environment-friendly fine mounting glue Download PDFInfo
- Publication number
- CN102952507A CN102952507A CN2012104165409A CN201210416540A CN102952507A CN 102952507 A CN102952507 A CN 102952507A CN 2012104165409 A CN2012104165409 A CN 2012104165409A CN 201210416540 A CN201210416540 A CN 201210416540A CN 102952507 A CN102952507 A CN 102952507A
- Authority
- CN
- China
- Prior art keywords
- initiator
- glue
- raw material
- monomer
- weight parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003292 glue Substances 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 239000003999 initiator Substances 0.000 claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 230000007613 environmental effect Effects 0.000 claims description 14
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 230000001681 protective effect Effects 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000004945 emulsification Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 230000037303 wrinkles Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000013538 functional additive Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a water-based environment-friendly fine mounting glue, which is composed of the following raw materials: a pre-emulsifier, a seed monomer, an dropping monomer, an initiator 1, an initiator 2 and a functional additive. The fine mounting glue produced by the invention is environment-friendly and healthy, does not have bad smell or contain harmful substances such as toluene, dimethylbenzene and heavy metals, and has the advantages of high solid content and high toughness. The mounting product hardly wrinkle or deform. In addition, the glue has fast drying speed at room temperature, high yield efficiency, good stain cleaning performance and coating performance, and initial adhesion and lasting adhesion reaching the process requirements for a hardcover gift box.
Description
Technical field
The main a kind of essence of the present invention is mounted glue, relates in particular to a kind of aqueous, environmental protective essence and mounts glue.
Background technology
When making hard-cover gift box by hand, to the initial bonding strength of glue with hold viscosity higher requirement is arranged, in order to make glue that the viscosity of holding of good initial bonding strength and length be arranged, past is when glue, toluene, dimethylbenzene rosin have been used, the raw materials such as SBS adopt the method for water and milk to be made, because this technique has been used toluene and dimethylbenzene, (smell is large) not environmental protection so obnoxious flavour exceeds standard.
Summary of the invention
The object of the invention just provides a kind of aqueous, environmental protective essence and mounts glue.
The present invention is achieved by the following technical solutions:
A kind of aqueous, environmental protective essence is mounted glue, and it is comprised of the raw material of following weight parts:
Pre-emulsification agent 360-400, seed monomer 40-45, dropping monomer 180-185, initiator 1 16-18, initiator 2 90-95, functional aid 18-22;
Wherein, described pre-emulsification agent is comprised of the raw material mixing of following weight parts: deionized water 300-350, sodium hydroxide 8-10; Vinylformic acid 30-35, OP-10 4-5;
Described seed monomer is mixed by the following weight parts raw material and forms: vinylformic acid 1-2, Butyl acrylate 22-26, vinyl acetate between to for plastic 10-12, diacetone 0.3-0.8, polyacrylamide 0.3-0.8;
Described dropping monomer is comprised of the raw material mixing of following weight parts: vinylformic acid 5-8, Butyl acrylate 115-125, vinyl acetate between to for plastic 53-58, diacetone 1.2-1.8, polyacrylamide 1.2-1.8;
Described initiator 1 is the ammonium persulfate aqueous solution of 2.8-3% for concentration;
Described initiator 2 is the ammonium persulfate aqueous solution of 2-2.2% for concentration;
Described functional aid is comprised of the raw material mixing of following weight parts: concentration is ammonia soln 8-12, ethylene glycol 6-10, the silicone antifoam agent 1-2 of 25-28%.
Described aqueous, environmental protective essence is mounted the preparation method of glue, may further comprise the steps:
The pre-emulsification agent of above-mentioned weight part is joined in the reactor, and the temperature that raises gradually adds seed monomer and the initiator 1 of above-mentioned weight part during to 75-80 ℃; React after 30-35 minute, the control temperature drips dropping monomer and the initiator 2 of above-mentioned weight part at 82-86 ℃, and time for adding is between 4-5 hour; After being added dropwise to complete, be warming up to 88-90 ℃, be incubated 1-1.5 hour, normal temperature is cooled to 45-50 ℃, adds the functional aid of above-mentioned weight part, mixes, and namely gets described aqueous, environmental protective essence and mounts glue.
Advantage of the present invention is:
The essence that the present invention produces is mounted glue environmental protection, good for health, without bad smell, do not contain toluene and the objectionable impuritiess such as dimethylbenzene and heavy metal, have high solids content, high tenacity, make institute's product of mounting wrinkle resistant, not yielding, rate of drying is very fast under the normal temperature, and efficient efficient is high, go keep a public place clean performance and coating performance of stain good, the initial bonding strength of its glue and hold viscosity and all can reach the processing requirement of making hard-cover gift box.
Embodiment
Embodiment 1
A kind of aqueous, environmental protective essence is mounted glue, and it is comprised of the raw material of following weight parts:
Pre-emulsification agent 400, seed monomer 45, dropping monomer 180, initiator 1 18, initiator 2 95, functional aid 22;
Wherein, described pre-emulsification agent is comprised of the raw material mixing of following weight parts: deionized water 350, sodium hydroxide 10; Vinylformic acid 35, OP-10 5;
Described seed monomer is mixed by the following weight parts raw material and forms: vinylformic acid 1, Butyl acrylate 22-26, vinyl acetate between to for plastic 10, diacetone 0.8, polyacrylamide 0.8;
Described dropping monomer is comprised of the raw material mixing of following weight parts: vinylformic acid 5-8, Butyl acrylate 115, vinyl acetate between to for plastic 53, diacetone 1.2, polyacrylamide 1.8;
Described initiator 1 is 3% ammonium persulfate aqueous solution for concentration;
Described initiator 2 is 2.2% ammonium persulfate aqueous solution for concentration;
Described functional aid is comprised of the raw material mixing of following weight parts: concentration is 28% ammonia soln 12, ethylene glycol 10, silicone antifoam agent 2.
Described aqueous, environmental protective essence is mounted the preparation method of glue, may further comprise the steps:
The pre-emulsification agent of above-mentioned weight part is joined in the reactor, during the temperature to 80 that raises gradually ℃, add seed monomer and the initiator 1 of above-mentioned weight part; React after 35 minutes, the control temperature drips dropping monomer and the initiator 2 of above-mentioned weight part at 86 ℃, and time for adding is between 5 hours; After being added dropwise to complete, be warming up to 90 ℃, be incubated 1.5 hours, normal temperature is cooled to 50 ℃, adds the functional aid of above-mentioned weight part, mixes, and namely gets described aqueous, environmental protective essence and mounts glue.
Claims (2)
1. an aqueous, environmental protective essence is mounted glue, it is characterized in that it is comprised of the raw material of following weight parts:
Pre-emulsification agent 360-400, seed monomer 40-45, dropping monomer 180-185, initiator 1 16-18, initiator 2 90-95, functional aid 18-22;
Wherein, described pre-emulsification agent is comprised of the raw material mixing of following weight parts: deionized water 300-350, sodium hydroxide 8-10; Vinylformic acid 30-35, OP-10 4-5;
Described seed monomer is mixed by the following weight parts raw material and forms: vinylformic acid 1-2, Butyl acrylate 22-26, vinyl acetate between to for plastic 10-12, diacetone 0.3-0.8, polyacrylamide 0.3-0.8;
Described dropping monomer is comprised of the raw material mixing of following weight parts: vinylformic acid 5-8, Butyl acrylate 115-125, vinyl acetate between to for plastic 53-58, diacetone 1.2-1.8, polyacrylamide 1.2-1.8;
Described initiator 1 is the ammonium persulfate aqueous solution of 2.8-3% for concentration;
Described initiator 2 is the ammonium persulfate aqueous solution of 2-2.2% for concentration;
Described functional aid is comprised of the raw material mixing of following weight parts: concentration is ammonia soln 8-12, ethylene glycol 6-10, the silicone antifoam agent 1-2 of 25-28%.
2. preparation method that aqueous, environmental protective essence as claimed in claim 1 is mounted glue is characterized in that may further comprise the steps:
The pre-emulsification agent of above-mentioned weight part is joined in the reactor, and the temperature that raises gradually adds seed monomer and the initiator 1 of above-mentioned weight part during to 75-80 ℃; React after 30-35 minute, the control temperature drips dropping monomer and the initiator 2 of above-mentioned weight part at 82-86 ℃, and time for adding is between 4-5 hour; After being added dropwise to complete, be warming up to 88-90 ℃, be incubated 1-1.5 hour, normal temperature is cooled to 45-50 ℃, adds the functional aid of above-mentioned weight part, mixes, and namely gets described aqueous, environmental protective essence and mounts glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416540.9A CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416540.9A CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102952507A true CN102952507A (en) | 2013-03-06 |
| CN102952507B CN102952507B (en) | 2014-12-24 |
Family
ID=47761908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210416540.9A Active CN102952507B (en) | 2012-10-27 | 2012-10-27 | Water-based environment-friendly fine mounting glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102952507B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216831A (en) * | 2017-07-07 | 2017-09-29 | 泗县美佳化建有限责任公司 | A kind of aggretion type aqueous, environmental protective pencil glues core rubber and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570673A (en) * | 2009-05-21 | 2009-11-04 | 上海东和胶粘剂有限公司 | KT sheet gum and preparation method thereof |
| CN101705065A (en) * | 2009-10-08 | 2010-05-12 | 广东三和化工科技有限公司 | Water-resistant white latex |
| CN102391411A (en) * | 2011-08-29 | 2012-03-28 | 华南理工大学 | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof |
-
2012
- 2012-10-27 CN CN201210416540.9A patent/CN102952507B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570673A (en) * | 2009-05-21 | 2009-11-04 | 上海东和胶粘剂有限公司 | KT sheet gum and preparation method thereof |
| CN101705065A (en) * | 2009-10-08 | 2010-05-12 | 广东三和化工科技有限公司 | Water-resistant white latex |
| CN102391411A (en) * | 2011-08-29 | 2012-03-28 | 华南理工大学 | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216831A (en) * | 2017-07-07 | 2017-09-29 | 泗县美佳化建有限责任公司 | A kind of aggretion type aqueous, environmental protective pencil glues core rubber and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102952507B (en) | 2014-12-24 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201203 Address after: Group 1, Yuechi village, Xindian Town, Rudong County, Nantong City, Jiangsu Province, 226400 Patentee after: Niu Xiaoduo Address before: 234300, Anhui, Suzhou, Sixian cutting North Road North Patentee before: SI COUNTY MEIJIA CHEMICAL BUILDING Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231221 Address after: 224199 West Side of Qingdao Port Road, Dafeng Port, Dafeng District, Yancheng City, Jiangsu Province (701, 7th Floor, Jiangsu Marine Industry Research Institute) Patentee after: Yancheng Lingsheng Technology Service Co.,Ltd. Address before: Group 1, Yuechi village, Xindian Town, Rudong County, Nantong City, Jiangsu Province, 226400 Patentee before: Niu Xiaoduo |
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| TR01 | Transfer of patent right |