CN102936127A - Light hollow ceramsite and production method thereof - Google Patents

Light hollow ceramsite and production method thereof Download PDF

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Publication number
CN102936127A
CN102936127A CN201210462747XA CN201210462747A CN102936127A CN 102936127 A CN102936127 A CN 102936127A CN 201210462747X A CN201210462747X A CN 201210462747XA CN 201210462747 A CN201210462747 A CN 201210462747A CN 102936127 A CN102936127 A CN 102936127A
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greenwave
polyphenyl foam
foam particle
hollow haydite
haydite
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CN102936127B (en
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雷团结
樊传刚
唐世敏
李亚辉
金仁才
刘磊彬
钱元弟
盛海涛
王孝平
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China MCC17 Group Co Ltd
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Maanshan MCC 17 Engineering Science and Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention provides a light hollow ceramsite and a production method thereof and belongs to the technical field of artificial lightweight aggregate processing. The light hollow ceramsite is made of a ceramic forming material and a template material, wherein the ceramic forming material is composed of waste paper papermaking dry sludge, fly ash and clay, and the template material is composed of polyphenyl foam particles. The obtained light hollow ceramsite is spherical or similar to a sphere in appearance, a middle cavity is spherical or similar to a sphere, and the middle cavity is separated from the outside through a ceramic structure with wall thickness to be 0.5-2.5mm. According to the light hollow ceramsite, barrel pressure strength is 33MPa, stacking bulk weight is 300-500kg/m<3> and particle size is 5-20mm, and therefore the light hollow ceramsite can be used for preparing high performance light aggregate concrete or suspended bio-film ceramic filter materials used for sewage treatment.

Description

A kind of light hollow haydite and preparation method thereof
Technical field
The invention belongs to the artificial lightweight aggregate processing technique field, be specifically related to a kind of light hollow haydite and preparation method thereof.
Background technology
Now widely used artificial lightweight aggregate mainly is sintering-expanded haydite, it is to utilize clay, shale or flyash etc. can burn swollen raw material to add water stirring, balling-up that tradition is made sintering-expanded haydite, utilization can be burnt the characteristic that swollen raw material at high temperature expands, in high temperature rotary kiln through expanded and form spheroid or the ball column of porous, be exactly sintering-expanded haydite after the cooling, they are the shapes such as irregular inferior circle shape, inferior water caltrop shape more.The raw material of producing sintering-expanded haydite must be to burn swollen raw material, and this raw material is few at nature, therefore generally need to improve its expansion characteristics with additive, because the material performance difference such as clay, shale are larger, even same batch of material performance also there are differences, and the use of additive had both increased the swollen effect of burning after the production cost of sintering-expanded haydite is difficult to stable the adding, quality product is made a big impact, and this method had also greatly been wasted land resources.The swollen performance of basic not burning also can't expand to make the lightweight sintering-expanded haydite even add additive after the batching such as some regional clay, shale, and this is so that there is the limitation on the raw material in the manufacturing of sintering-expanded haydite.Moreover the production process of sintering-expanded haydite is at high temperature expanded and form the spheroid of porous, and energy consumption is high, cost is large, and it is low to obtain the intensity of sintering-expanded haydite; In addition, guarantee product performance and product size by material performance, be difficult to control on the technique, only have to burn and sieve to control product size after swollen, what general particle diameter was large is haydite, and what particle diameter was little is pottery sand.In order to address this problem, development hollow haydite is imperative, Chinese patent CN 200510041886.5 provides a kind of preparation method of hollow haydite, by extruding first the hollow circular tube base substrate with extrusion method, and then cut into segment, and in pan-pelletizer, be molded into irregular hollow haydite base substrate, in high-temperature calcination equipment, burn out again at last the hollow haydite.Propose similar method among the Chinese patent CN 91110948.X " shaft kiln cement raw material hollow forming equipment and technique " and also can prepare the irregular hollow haydite of profile, when these haydites prepare light concrete as light-weight aggregate, at first be shaped as irregular, easily produce stress concentration when forming concrete structure, secondly, irregular haydite generation space resistance is larger during stirring, haydite is easily destroyed, concrete easily stirs inhomogeneous, moreover, the aforesaid method moulding is not easy to form the hollow haydite of cavity sealing, and the water ash mass ratio when causing preparing light aggregate concrete is not easy control.In view of above situation the present invention proposes a kind of hollow haydite and preparation method thereof, prepared hollow haydite is that sphere or the class of internal cavities sealing is spherical, and can carry out on a large scale, at low cost the production of hollow ceramic product.
Summary of the invention
To the purpose of this invention is to provide a kind of profile be spherical or near-spherical, middle light hollow haydite for enclosed cavity and preparation method thereof.
A kind of light hollow haydite provided by the present invention is by becoming ceramic material and mould material to form; Described one-tenth ceramic material is by regenerated papermaking dewatered sludge, flyash and Clay composition, described regenerated papermaking dewatered sludge, flyash, clay three's mass percent is respectively: regenerated papermaking dewatered sludge: 30 ~ 40%, flyash: 40 ~ 50%, clay: 10 ~ 20%, the particle diameter £ 0.08mm of described one-tenth ceramic material; Described mould material is the polyphenyl foam particle, and described polyphenyl foam particle is spherical or near-spherical, and the particle diameter of described polyphenyl foam particle is 3 ~ 15mm.
The preparation method of a kind of light hollow haydite provided by the present invention, concrete steps are as follows:
(1) described one-tenth ceramic material is prepared burden according to described ratio, then fully mix, mixing time 10 ~ 30min makes into the greenwave material;
(2) described mould material polyphenyl foam particle surface is infiltrated or the liquid film of the polyvinyl alcohol solution of the cmc soln of spraying one deck mass concentration 1 ~ 2.5% or one deck mass concentration 1 ~ 2.5%, obtain the mould material polyphenyl foam particle after the surface treatment;
(3) the one-tenth greenwave material that the described step of part (1) is obtained carries out fluidization to be processed, obtain fluidised one-tenth greenwave material, mould material polyphenyl foam particle after the surface treatment that described step (2) is obtained joins in the fluidised one-tenth greenwave material, make described mould material polyphenyl foam particle surface be stained with the one-tenth greenwave bed of material of a layer thickness 0.1 ~ 0.5mm, obtain the surface and be stained with the mould material polyphenyl foam particle that one deck becomes the greenwave material;
(4) the one-tenth greenwave material feeding pan-pelletizer that described step (1) is obtained, then the surface that the described step of feeding (3) obtains in described pan-pelletizer Sloped rotating process is stained with the mould material polyphenyl foam particle that one deck becomes the greenwave material, simultaneously the powder granule in the described pan-pelletizer is squirted, squirting used liquid is the cmc soln of water or mass concentration 0.5 ~ 2.5% or the polyvinyl alcohol solution of mass concentration 0.5 ~ 2.5%; Obtain the hollow haydite raw material ball that particle diameter is 6 ~ 21mm by this step process;
(5) the hollow haydite raw material ball that step (5) is obtained takes out afterwards dry 1 ~ 5min under 50-100 ℃ temperature, then dried hollow haydite raw material ball feeding rotary kiln or shaft kiln are burnt till, the top temperature scope of burning till is 1100 ℃ ~ 1200 ℃, park 10 ~ 30min in top temperature, then cool to room temperature obtains described light hollow haydite.
Resulting light hollow haydite profile is spherical or near-spherical, and middle cavity also is spherical or near-spherical, and middle cavity is separated by the ceramic structure of one deck wall thickness 0.5 ~ 2.5mm with extraneous; The cylindrical compress strength 33MPa of this light hollow haydite, accumulation unit weight is 300 ~ 500kg/m 3, the particle diameter of this light hollow haydite is 5 ~ 20mm, can be used in the preparation Performance of High-Performance Lightweight Aggregate Concrete or as the suspended biological film ceramic filter material in the sewage disposal.
The present invention has following technical characterstic and advantage:
1, be compared with existing technology, the present invention can prepare the hollow haydite of spherical or near-spherical on a large scale, and haydite is not only light but also have high mechanical strength, is more suitable for the artificial lightweight aggregate as Performance of High-Performance Lightweight Aggregate Concrete;
2, be compared with existing technology, it is trade waste more than 80% that hollow haydite of the present invention adopts in the pottery raw material, so production cost is lower, and resources circulation and cultivated land protection action effect are obvious;
3, be compared with existing technology, spherical hollow haydite of the present invention, has larger specific surface area, therefore also be suitable as the suspended biological film ceramic filter material in the sewage disposal, the hollow haydite out-of-shape that other technologies obtain, banking process is not easy to form stable suspended biological film ceramic filter material bed;
4, be compared with existing technology, the template raw material that hollow haydite of the present invention adopts is granular polystyrene, can obtain with waste and old polyphenyl foam plate is broken, therefore can solve the white pollution problems that waste and old polyphenyl foam difficult degradation brings, granular polystyrene makes hollow haydite base substrate have enough physical strengths as template in addition, satisfy hollow haydite base substrate in accumulation, conveying, indeformable, the not damaged mechanical property requirement of drying course, improved the product serviceability rate of hollow haydite;
5, be compared with existing technology, regenerated papermaking mud and mould material granular polystyrene that hollow haydite of the present invention adopts into ceramic material also can substitute a part of fuel, make the Energy Intensity Reduction of haydite sintering process.
Embodiment
Embodiment 1: hollow haydite of the present invention, and employed raw material has two portions, becomes ceramic material and mould material, and becoming ceramic material is regenerated papermaking mud (doing), flyash, clay, and three's respectively massfraction is: regenerated papermaking mud 40%; Flyash 40%; The particle diameter £ 0.08mm of 20%, three kind of raw material of clay, mould material is the polyphenyl foam particle.
Hollow haydite of the present invention, described mould material polyphenyl foam particle is spherical, near-spherical, particle diameter is in 5 ~ 20mm scope.
Hollow haydite of the present invention, finished product profile are spherical or near-spherical, and middle cavity also is spherical, and middle cavity is separated by the ceramic structure of one deck wall thickness 0.5 ~ 2.5mm with extraneous.
Hollow haydite of the present invention, its preparation process is divided into following steps:
(1) first the one-tenth ceramic material of hollow haydite is prepared burden according to described ratio, then fully mix, mixing time 30min becomes described one-tenth greenwave material;
(2) mould material polyphenyl foam particle surface is infiltrated or the cmc soln liquid film of spraying one deck mass concentration 1%;
(3) the polyphenyl foam particle after step (2) surface treatment is complete adds fluidised step (1) and obtains in the greenwave material environment, makes the polyphenyl foam particle surface be stained with the thick one-tenth greenwave bed of material of a layer thickness 0.1mm;
(4) the one-tenth greenwave material feeding pan-pelletizer that step (1) is obtained, then in pan-pelletizer Sloped rotating process, feed the surface that step (3) obtains and be stained with the granular polystyrene that one deck becomes the greenwave material, simultaneously the powder granule in the pan-pelletizer is squirted, the liquid that squirts is water;
(5) after being taken out, the hollow haydite raw material ball that reaches granularity requirements in the pan-pelletizer carries out drying, dry temperature is below 100 ℃, then dried hollow haydite raw material ball feeding rotary kiln or shaft kiln are burnt till, the top temperature of burning till is 1100 ℃, park 30min in top temperature, then cool to room temperature obtains described hollow haydite, the cylindrical compress strength 3.5MPa of hollow haydite, and the accumulation unit weight of hollow haydite is 300kg/m 3, can be used for preparing Performance of High-Performance Lightweight Aggregate Concrete or as the suspended biological ceramic filter material in the sewage disposal.
Embodiment 2: hollow haydite of the present invention, and employed raw material has two portions, becomes ceramic material and mould material, and becoming ceramic material is regenerated papermaking mud (doing), flyash, clay, and three's respectively massfraction is: regenerated papermaking mud 30%; Flyash 50%; The particle diameter £ 0.08mm of 20%, three kind of raw material of clay, mould material is the polyphenyl foam particle.
Hollow haydite of the present invention, described mould material polyphenyl foam particle is spherical, near-spherical, particle diameter is in 5 ~ 20mm scope.
Hollow haydite of the present invention, finished product profile are spherical or near-spherical, and middle cavity also is spherical, and middle cavity is separated by the ceramic structure of one deck wall thickness 0.5 ~ 2.5mm with extraneous.
Hollow haydite of the present invention, its preparation process is divided into following steps:
(1) first the one-tenth ceramic material of hollow haydite is prepared burden according to described ratio, then fully mix, mixing time 20min becomes described one-tenth greenwave material;
(2) mould material polyphenyl foam particle surface is infiltrated or the cmc soln liquid film of spraying one deck mass concentration 1.5%;
(3) the polyphenyl foam particle after step (2) surface treatment is complete adds fluidised step (1) and obtains in the greenwave material environment, makes the polyphenyl foam particle surface be stained with the thick one-tenth greenwave bed of material of a layer thickness 0.1mm;
(4) the one-tenth greenwave material feeding pan-pelletizer that step (1) is obtained, then in pan-pelletizer Sloped rotating process, feed the granular polystyrene that surface that step (3) obtains is stained with one deck greenwave material, simultaneously its surface is squirted, the liquid that squirts is the cmc soln of mass concentration 1%;
(5) after being taken out, the hollow haydite raw material ball that reaches granularity requirements in the pan-pelletizer carries out drying, dry temperature is below 100 ℃, then dried hollow haydite raw material ball feeding rotary kiln or shaft kiln are burnt till, the top temperature of burning till is 1150 ℃, park 15min in top temperature, then cool to room temperature obtains described hollow haydite, the cylindrical compress strength 5MPa of hollow haydite, and the accumulation unit weight of hollow haydite is 400kg/m 3, can be used for preparing Performance of High-Performance Lightweight Aggregate Concrete or as the suspended biological ceramic filter material in the sewage disposal.
Embodiment 3: hollow haydite of the present invention, and employed raw material has two portions, becomes ceramic material and mould material, and becoming ceramic material is regenerated papermaking mud (doing), flyash, clay, and three's respectively massfraction is: regenerated papermaking mud 30%; Flyash 50%; The particle diameter £ 0.08mm of 20%, three kind of raw material of clay, mould material is the polyphenyl foam particle.
Hollow haydite of the present invention, described mould material polyphenyl foam particle is spherical, near-spherical, particle diameter is in 5 ~ 20mm scope.
Hollow haydite of the present invention, finished product profile are spherical or near-spherical, and middle cavity also is spherical, and middle cavity is separated by the ceramic structure of one deck wall thickness 0.5 ~ 2.5mm with extraneous.
Hollow haydite of the present invention, its preparation process is divided into following steps:
(1) first the one-tenth ceramic material of hollow haydite is prepared burden according to described ratio, then fully mix, mixing time 20min becomes described one-tenth greenwave material;
(2) mould material polyphenyl foam particle surface is infiltrated or the polyvinyl alcohol solution liquid film of spraying one deck mass concentration 2.5%;
(3) the polyphenyl foam particle after step (2) surface treatment is complete adds fluidised step (1) and obtains in the greenwave material environment, makes the polyphenyl foam particle surface be stained with the thick one-tenth greenwave bed of material of a layer thickness 0.1mm;
(4) the one-tenth greenwave material feeding pan-pelletizer that step (1) is obtained, then in pan-pelletizer Sloped rotating process, feed the surface that step (3) obtains and be stained with the granular polystyrene that one deck becomes the greenwave material, simultaneously its surface is squirted, the liquid that squirts is the polyvinyl alcohol solution of mass concentration 2.5%;
(5) after being taken out, the hollow haydite raw material ball that reaches granularity requirements in the pan-pelletizer carries out drying, dry temperature is below 100 ℃, then dried hollow haydite raw material ball feeding rotary kiln or shaft kiln are burnt till, the top temperature of burning till is 1200 ℃, park 10min in top temperature, then cool to room temperature obtains described hollow haydite, the cylindrical compress strength 7.5MPa of hollow haydite, and the accumulation unit weight of hollow haydite is 500kg/m 3, can be used for preparing Performance of High-Performance Lightweight Aggregate Concrete or as the suspended biological ceramic filter material in the sewage disposal.

Claims (2)

1. a light hollow haydite is characterized in that described light hollow haydite is by becoming ceramic material and mould material to form; Described one-tenth ceramic material is by regenerated papermaking dewatered sludge, flyash and Clay composition, described regenerated papermaking dewatered sludge, flyash, clay three's mass percent is respectively: regenerated papermaking dewatered sludge: 30 ~ 40%, flyash: 40 ~ 50%, clay: 10 ~ 20%, the particle diameter £ 0.08mm of described one-tenth ceramic material; Described mould material is the polyphenyl foam particle, and described polyphenyl foam particle is spherical or near-spherical, and the particle diameter of described polyphenyl foam particle is 3 ~ 15mm.
2. a kind of preparation method of light hollow haydite as claimed in claim 1 is characterized in that described preparation method's concrete steps are as follows:
(1) described one-tenth ceramic material is prepared burden according to described ratio, then fully mix, mixing time 10 ~ 30min makes into the greenwave material;
(2) described mould material polyphenyl foam particle surface is infiltrated or the liquid film of the polyvinyl alcohol solution of the cmc soln of spraying one deck mass concentration 1 ~ 2.5% or one deck mass concentration 1 ~ 2.5%, obtain the mould material polyphenyl foam particle after the surface treatment;
(3) the one-tenth greenwave material that the described step of part (1) is obtained carries out fluidization to be processed, obtain fluidised one-tenth greenwave material, mould material polyphenyl foam particle after the surface treatment that described step (2) is obtained joins in the fluidised one-tenth greenwave material, make described mould material polyphenyl foam particle surface be stained with the one-tenth greenwave bed of material of a layer thickness 0.1 ~ 0.5mm, obtain the surface and be stained with the mould material polyphenyl foam particle that one deck becomes the greenwave material;
(4) the one-tenth greenwave material feeding pan-pelletizer that described step (1) is obtained, then the surface that the described step of feeding (3) obtains in described pan-pelletizer Sloped rotating process is stained with the mould material polyphenyl foam particle that one deck becomes the greenwave material, simultaneously the powder granule in the described pan-pelletizer is squirted, squirting used liquid is the cmc soln of water or mass concentration 0.5 ~ 2.5% or the polyvinyl alcohol solution of mass concentration 0.5 ~ 2.5%; Obtain the hollow haydite raw material ball that particle diameter is 6 ~ 21mm by this step process;
(5) it is dry under 50-100 ℃ temperature after the hollow haydite raw material ball that step (5) is obtained takes out, 1 ~ 5min, then dried hollow haydite raw material ball feeding rotary kiln or shaft kiln are burnt till, the top temperature scope of burning till is 1100 ℃ ~ 1200 ℃, park 10 ~ 30min in top temperature, then cool to room temperature obtains described light hollow haydite.
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105439619A (en) * 2016-01-06 2016-03-30 山东理工大学 Method of utilizing waste wood particles to produce light-weight ceramsite balls
CN106630715A (en) * 2016-12-30 2017-05-10 东莞深圳清华大学研究院创新中心 Method for preparing ceramsite by using flyash of circulating fluidized bed and paper mill sludge
CN108147690A (en) * 2017-12-11 2018-06-12 吴刚 A kind of preparation method of concrete Desert Sand
CN108341437A (en) * 2018-01-24 2018-07-31 广州市环境保护工程设计院有限公司 A kind of biology gaseous-waste holdup system
CN108424096A (en) * 2018-04-03 2018-08-21 东南大学 A kind of medium temperature calcining is low close high than strong ground polymers lightweight aggregate and preparation method thereof
CN108423837A (en) * 2018-01-24 2018-08-21 广州市环境保护工程设计院有限公司 A kind of filler improving biological gaseous-waste holdup system percolation effect
CN108863432A (en) * 2018-07-10 2018-11-23 黄河三角洲京博化工研究院有限公司 A kind of hollow haydite of solid waste and preparation method thereof
CN109650932A (en) * 2019-01-28 2019-04-19 重庆市都梁实业有限公司 Recycling sludge intelligently disposes tower and disposing technique
CN110759745A (en) * 2018-07-27 2020-02-07 广东清大同科环保技术有限公司 High-strength cavity ceramsite and preparation method thereof
CN110835240A (en) * 2018-08-17 2020-02-25 中国科学院过程工程研究所 Fly ash ceramsite and preparation method thereof
CN111018384A (en) * 2019-12-13 2020-04-17 西安建筑科技大学 Hollow ceramsite and preparation method thereof
CN112552021A (en) * 2020-12-09 2021-03-26 河南强耐新材股份有限公司 Fly ash ceramsite and preparation method thereof
CN115108812A (en) * 2022-07-20 2022-09-27 湖南工学院 Method for regulating and controlling ceramsite structural characteristics and mechanical strength, pomegranate-like structure light-weight high-strength ceramsite and preparation method thereof
CN115124364A (en) * 2022-07-04 2022-09-30 湖南工学院 Light high-strength ceramsite based on solid waste and preparation method thereof
CN115716723A (en) * 2022-11-08 2023-02-28 苏州市宏宇环境科技股份有限公司 Sludge ceramsite reinforced concrete self-insulation building block and preparation method thereof
CN115974525A (en) * 2023-01-12 2023-04-18 重庆聚源塑料股份有限公司 Light ceramsite and preparation method and application thereof

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CN1733651A (en) * 2005-03-25 2006-02-15 兰州理工大学 Sintering haydite preparation method
CN101386524A (en) * 2008-10-28 2009-03-18 安徽工业大学 Method for preparing porcelain granule from waste paper-making sludge
CN101519316A (en) * 2009-04-15 2009-09-02 北京师范大学 Novel foam zeolite granule and preparation method thereof

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CN1733651A (en) * 2005-03-25 2006-02-15 兰州理工大学 Sintering haydite preparation method
CN101386524A (en) * 2008-10-28 2009-03-18 安徽工业大学 Method for preparing porcelain granule from waste paper-making sludge
CN101519316A (en) * 2009-04-15 2009-09-02 北京师范大学 Novel foam zeolite granule and preparation method thereof

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105439619A (en) * 2016-01-06 2016-03-30 山东理工大学 Method of utilizing waste wood particles to produce light-weight ceramsite balls
CN106630715B (en) * 2016-12-30 2019-01-08 广东清大同科环保技术有限公司 A method of haydite is prepared using circulating fluid bed coal ash and paper mill sludge
CN106630715A (en) * 2016-12-30 2017-05-10 东莞深圳清华大学研究院创新中心 Method for preparing ceramsite by using flyash of circulating fluidized bed and paper mill sludge
CN108147690A (en) * 2017-12-11 2018-06-12 吴刚 A kind of preparation method of concrete Desert Sand
CN108341437A (en) * 2018-01-24 2018-07-31 广州市环境保护工程设计院有限公司 A kind of biology gaseous-waste holdup system
CN108423837A (en) * 2018-01-24 2018-08-21 广州市环境保护工程设计院有限公司 A kind of filler improving biological gaseous-waste holdup system percolation effect
CN108424096A (en) * 2018-04-03 2018-08-21 东南大学 A kind of medium temperature calcining is low close high than strong ground polymers lightweight aggregate and preparation method thereof
CN108863432A (en) * 2018-07-10 2018-11-23 黄河三角洲京博化工研究院有限公司 A kind of hollow haydite of solid waste and preparation method thereof
CN108863432B (en) * 2018-07-10 2022-06-03 山东京泰再生资源有限公司 Solid waste hollow ceramsite and preparation method thereof
CN110759745A (en) * 2018-07-27 2020-02-07 广东清大同科环保技术有限公司 High-strength cavity ceramsite and preparation method thereof
CN110759745B (en) * 2018-07-27 2022-02-15 广东清大同科环保技术有限公司 High-strength cavity ceramsite and preparation method thereof
CN110835240A (en) * 2018-08-17 2020-02-25 中国科学院过程工程研究所 Fly ash ceramsite and preparation method thereof
CN109650932A (en) * 2019-01-28 2019-04-19 重庆市都梁实业有限公司 Recycling sludge intelligently disposes tower and disposing technique
CN111018384A (en) * 2019-12-13 2020-04-17 西安建筑科技大学 Hollow ceramsite and preparation method thereof
CN112552021A (en) * 2020-12-09 2021-03-26 河南强耐新材股份有限公司 Fly ash ceramsite and preparation method thereof
CN112552021B (en) * 2020-12-09 2023-03-24 河南强耐新材股份有限公司 Fly ash ceramsite and preparation method thereof
CN115124364A (en) * 2022-07-04 2022-09-30 湖南工学院 Light high-strength ceramsite based on solid waste and preparation method thereof
CN115124364B (en) * 2022-07-04 2023-10-10 湖南工学院 Lightweight high-strength ceramsite based on solid waste and preparation method thereof
CN115108812A (en) * 2022-07-20 2022-09-27 湖南工学院 Method for regulating and controlling ceramsite structural characteristics and mechanical strength, pomegranate-like structure light-weight high-strength ceramsite and preparation method thereof
CN115108812B (en) * 2022-07-20 2023-08-01 湖南工学院 Method for regulating and controlling structural characteristics and mechanical strength of ceramsite, lightweight high-strength ceramsite with pomegranate-like structure and preparation method of lightweight high-strength ceramsite
CN115716723A (en) * 2022-11-08 2023-02-28 苏州市宏宇环境科技股份有限公司 Sludge ceramsite reinforced concrete self-insulation building block and preparation method thereof
CN115716723B (en) * 2022-11-08 2023-11-14 苏州市宏宇环境科技股份有限公司 Sludge ceramsite reinforced concrete self-heat-preservation building block and preparation method thereof
CN115974525A (en) * 2023-01-12 2023-04-18 重庆聚源塑料股份有限公司 Light ceramsite and preparation method and application thereof
CN115974525B (en) * 2023-01-12 2023-10-27 重庆聚源塑料股份有限公司 Light ceramsite and preparation method and application thereof

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