CN102921196B - Device for defoaming liquid - Google Patents
Device for defoaming liquid Download PDFInfo
- Publication number
- CN102921196B CN102921196B CN201210442377.3A CN201210442377A CN102921196B CN 102921196 B CN102921196 B CN 102921196B CN 201210442377 A CN201210442377 A CN 201210442377A CN 102921196 B CN102921196 B CN 102921196B
- Authority
- CN
- China
- Prior art keywords
- tower
- defoaming
- liquid
- liquid storage
- pipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 92
- 238000003860 storage Methods 0.000 claims abstract description 40
- 230000000694 effects Effects 0.000 abstract description 10
- 238000007599 discharging Methods 0.000 abstract 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 36
- 229910000019 calcium carbonate Inorganic materials 0.000 description 19
- 239000006260 foam Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 14
- 239000013530 defoamer Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000010720 hydraulic oil Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 241000197194 Bulla Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000002836 Ipomoea tricolor Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 208000002352 blister Diseases 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Degasification And Air Bubble Elimination (AREA)
Abstract
The invention discloses a device for defoaming a liquid. The device comprises a liquid storage tower, a defoaming tower, a charging pipe and a discharging pipe. The defoaming tower is arranged inside the liquid storage tower, the charging pipe is arranged on the same axis of the liquid storage tower and the defoaming tower, the discharging pipe is arranged at the bottom of the liquid storage tower or the side face of the lower section of the liquid storage tower, an overflow pipe is arranged, valves B are arranged on the discharging pipe and the overflow pipe respectively, and the discharging pipe and the overflow pipe are connected with an external liquid tank. More than three rows of overflow holes with apertures in a range of phi 1-4mm are evenly arranged on the periphery of the wall of the lower section of the defoaming tower, and the total area of overflow holes is larger than the sectional area of the charging pipe. The position of one end of the charging pipe, which is arranged inside the defoaming tower, is 5-20cm higher than that of the highest row of overflow holes of the defoaming tower, a flow meter and a valve A are arranged at a liquid inlet end of the charging pipe, and the charging pipe is connected with a circulating pump. The device is simple in structure, easy to operate, low in investment, good in liquid defoaming effect, applicable to defoaming of liquids of high viscosity and low viscosity and good in economical benefit.
Description
Technical field
The invention belongs to chemical machinery technical field, relate to a kind of physical defoaming device, especially a kind of device for liquid froth breaking.
Background technology
In the process of preparing nano-calcium carbonate, in order to obtain good dispersiveness, conventionally need to add surfactant to be coated processing.But common surfactant is again typical foaming agent, can in slurries, generate a large amount of foams, follow-up technological operation has been caused to serious impact.Exactly these slurries are carried out to defoaming treatment and address this problem unique approach.
Thermodynamic argument is thought: the foam that neat liquid produces can only of short duration existence of short time, and is dissolved with the liquid of impurity, but has to strengthen the tendency of bubbling, and makes foam become lasting and stablize.Foam be gas as discontinuous phase (spherical) dispersion in liquid, and gas occupied most of volume, between bubble, only isolated by very thin liquid film.In the time that two bubbles that vary in size contact, because the pressure of vesicle inside is large, through the contact action of certain hour, gas moves to bulla by liquid film, is finally merged into a larger bubble.Once and foam forms, due to low with respect to liquid system of density, rise to gradually liquid level under the effect of buoyancy.In the time that the formation speed of bubble is greater than the speed that bubble breaks, will pile up, finally form foam, and passing in time and increasing, thereby harm formed.
In froth breaking process, generally mainly contain two kinds of froth breaking modes, one is chemical froth breaking, adds defoamer froth breaking, one is physical defoaming, uses mechanical defoaming device, or two kinds of froth breaking modes are also used.Adding defoamer is a kind of now widely used method, and it is in material, to add a certain amount of applicable defoamer, has changed material table surface tension, reduces or has suppressed foaming, thereby reaching froth breaking object.Defoamer is expensive, uses defoamer not only to expend fund, and can affect performance or the polluted product of product, and this method cost-effective rate is low.Use mechanical defoaming device can get rid of the pollution to product, can utilize continuously, particularly some simple and easy froth breakers, consume energy low, can reach the effect of low-cost high-efficiency.
At present, fermentation, pulping and paper-making, hydraulic oil, sewage disposal and some food as the industry such as soya-bean milk, honey in, mostly can use froth breaker.Old-fashioned froth breaker is generally furnished with agitator, motor etc., and compression chamber that uses froth breaking oar or High Rotation Speed etc. smashes foam more, generally all needs the very high-power good defoaming effect that just can play.And in actual production process, its defoaming effectiveness is lower, so be eliminated gradually.The froth breaker simple, energy consumption is low, effective is only the optimal selection that enterprise enhances productivity.Chinese utility model patent ZL 200620095219.5, CN 202054838U disclose respectively " a kind of flying saucer type centrifugal defoamer " and " a kind of defoaming device " applies to fermentation industry, and its operating load is little, defoaming effectiveness is high.How effectively Chinese invention patent CN 102442708A provides a kind of froth breaker of wastewater treatment, no matter character and state and the stacked situation froth breaking of bubble.Chinese invention patent CN 102410285A has introduced one can prevent that high-volume hydraulic oil from producing bubble while getting back to fuel tank, reduces the super-high flow return-oil defoamer of oil contamination.These froth breakers are easier than old-fashioned froth breaker froth breaking mode, and defoaming effectiveness is high.But these froth breaker structures are comparatively complicated, manufacturing process's difficulty, invests higher.
So far, by consulting data of literatures, we not yet find a froth breaker that can effectively be applied to nano-calcium carbonate industry.In order to address this problem, the invention provides a kind of defoaming device for calcium carbonate industry.
Summary of the invention
Object of the present invention: comparatively complicated at present existing defoaming equipment structure, manufacturing process's difficulty, invests higher shortcoming, and a kind of simple device for liquid froth breaking is provided.
Technical scheme of the present invention is:
Utilizing foam is the solution-air non-individual body that liquid film that one deck is very thin surrounds gas, foam on liquid level is conventionally by the organic principle in liquid, be that surfactant maintains its stability, and if any liquid that contains surfactant does not contact with air, the principle that just can not bubble.And utilize the energy of introducing at gas-liquid contact face as far as possible little, effectively suppress the principle of the generation of foam.Method of the present invention adopts in fluid transport process, reduces the contact of liquid-to-air as far as possible, reduces as much as possible the impact energy of introducing when liquid flows into gas-liquid contact face simultaneously, suppresses to greatest extent the generation of foam.
In order to realize the above-mentioned defoaming effect of mentioning, the technical solution used in the present invention is:
For a device for liquid froth breaking, comprise liquid storage tower, defoaming tower, feed pipe and discharge nozzle are set, it is characterized in that: defoaming tower is located in liquid storage tower, on the same axle center of liquid storage tower and defoaming tower, feed pipe is set; Described discharge nozzle is located at the bottom of liquid storage tower or the side of hypomere, and effective control valve is set, and discharge nozzle and/or overflow pipe arrange respectively valve and be connected with outer liquid pool.
Above-described defoaming tower surrounding on the wall of middle hypomere evenly arranges spillway hole, and the aperture of spillway hole is Φ 1-4mm, and more than spillway hole arranges three rows, the gross area of spillway hole is greater than the sectional area of feed pipe.
Arranging than the highest row's of defoaming tower the high 5-20cm of spillway hole of the tip position of above-described feed pipe in defoaming tower, feed pipe arranges flowmeter and valve A in feed liquor one end, and is connected with circulating pump.
Arranging than the high 2-10cm of liquid storage liquid level of the tip position of above-described overflow pipe in liquid storage tower.
This device is applicable to viscosity greatly and the little liquid froth breaking of viscosity.
Beneficial effect of the present invention is:
1, it is Φ 1-4mm spillway hole that defoaming tower surrounding on the wall of middle hypomere that this device arranges evenly arranges aperture, and liquid storage tower, defoaming tower, feed pipe are arranged on same axle center, forms the liquid fluid system of sealing, and liquid foam can effectively disappear.
2, this apparatus structure is simple, processing ease, and small investment, liquid defoaming effect is good, is applicable to viscosity greatly and the little liquid froth breaking of viscosity, has good economic benefit.
Brief description of the drawings
Fig. 1: be the schematic diagram of this defoaming device.
In figure, identify: 1-liquid storage tower; 2-defoaming tower; 3-feed pipe; 4-froth breaking liquid level; 5-overflow water; 6-spillway hole; 7-liquid storage liquid level; 8-flowmeter; 9-valve A; 10-valve B; 11-discharge nozzle; 12-overflow pipe.
Specific embodiment
Describe particular content of the present invention in detail below in conjunction with the drawings and specific embodiments.
Embodiment 1
As shown in Figure 1, this defoaming device arranges liquid storage tower 1, defoaming tower 2, feed pipe 3 and discharge nozzle 11.Defoaming tower 2 is located in liquid storage tower 1, on the same axle center of liquid storage tower 1 and defoaming tower 2, feed pipe 3 is set, discharge nozzle 11 is located at the bottom of liquid storage tower 1 or the side of hypomere, and overflow pipe 12 is set, discharge nozzle 11 and overflow pipe 12 arrange respectively valve B10, and are connected with outer liquid pool.It is Φ 2mm spillway hole 6 that described defoaming tower 2 surrounding on the wall of middle hypomere evenly arranges aperture, and spillway hole 6 arranges 5 rows, and the gross area of spillway hole 6 is greater than the sectional area of feed pipe 3.The tip position of feed pipe 3 in defoaming tower 2 an overflowing water hole 6 high 5cm higher than defoaming tower 2 be set, feed pipe 3 arranges flowmeter 8 and valve A9 in feed liquor one end, and is connected with circulating pump.Arranging than the high 10cm of liquid storage liquid level 7 of the tip position of overflow pipe 12 in liquid storage tower 1.
In the time that calcium carbonate serosity froth breaking uses, by circulating pump, the calcium carbonate serosity after surface treatment is passed into from feed pipe 3, control feed rate is 3m simultaneously
3/ h.Calcium carbonate serosity flows in porous defoaming tower 2 fast.In the time that inlet amount is consistent with load, the froth breaking liquid level 4 in defoaming tower 2 maintains a fixing level height.Now, foam forms on the contact-making surface of liquid-to-air, can not have foam lower than the calcium carbonate serosity inside of this contact-making surface, and can flow in liquid storage tower 1 along the slow overflow formation of defoaming tower wall overflow water 5 by spillway hole 6.In this process, the impact that calcium carbonate serosity causes the liquid storage liquid level 7 of liquid storage tower 1 is very little, substantially can not produce foam, and in the process gliding at calcium carbonate serosity, the liquid between the effect bubble of gravity is separated out, and makes bubble and fluid separation applications.As time goes on, the liquid storage liquid level 7 of liquid storage tower 1 also can constantly raise, and, in the time transmitting slurries, does not contact with air lower than the spillway hole 6 of outer liquid level 7, has further avoided the formation of foam.In this process, open the valve B10 that discharge nozzle 11 and overflow pipe 12 arrange respectively, froth breaking calcium carbonate serosity is sent into outer liquid pool.Control feed liquor amount and liquid outlet quantity and equate, by this method, effectively reached the effect of calcium carbonate serosity froth breaking.
Embodiment 2
As shown in Figure 1, this defoaming device arranges liquid storage tower 1, defoaming tower 2, feed pipe 3 and discharge nozzle 11.Defoaming tower 2 is located in liquid storage tower 1, on the same axle center of liquid storage tower 1 and defoaming tower 2, feed pipe 3 is set, and discharge nozzle 11 is located at the bottom of liquid storage tower 1 or the side of hypomere, and discharge nozzle 11 arranges valve B10, and is connected with outer liquid pool.It is Φ 4mm spillway hole 6 that described defoaming tower 2 surrounding on the wall of middle hypomere evenly arranges aperture, and spillway hole 6 arranges 7 rows, and the gross area of spillway hole 6 is greater than the sectional area of feed pipe 3.The tip position of feed pipe 3 in defoaming tower 2 an overflowing water hole 6 high 10cm higher than defoaming tower 2 be set, feed pipe 3 arranges flowmeter 8 and valve A9 in feed liquor one end, and is connected with circulating pump.
In the time that calcium carbonate serosity froth breaking uses, by circulating pump, the calcium carbonate serosity after surface treatment is passed into from feed pipe 3, control feed rate is 5m simultaneously
3/ h.Calcium carbonate serosity flows in porous defoaming tower 2 fast.In the time that inlet amount is consistent with load, the froth breaking liquid level 4 in defoaming tower 2 maintains a fixing level height.Now, foam forms on the contact-making surface of liquid-to-air, can not have foam lower than the calcium carbonate serosity inside of this contact-making surface, and can flow in liquid storage tower 1 along the slow overflow formation of defoaming tower wall overflow water 5 by spillway hole 6.In this process, the impact that calcium carbonate serosity causes the liquid storage liquid level 7 of liquid storage tower 1 is very little, substantially can not produce foam, and in the process gliding at calcium carbonate serosity, the liquid between the effect bubble of gravity is separated out, and makes bubble and fluid separation applications.As time goes on, the liquid storage liquid level 7 of liquid storage tower 1 also can constantly raise, and, in the time transmitting slurries, does not contact with air lower than the spillway hole 6 of outer liquid level 7, has further avoided the formation of foam.The valve B10 that opens discharge nozzle 11 in this process, sends froth breaking calcium carbonate serosity into outer liquid pool.Control feed liquor amount and liquid outlet quantity and equate, by this method, effectively reached the effect of calcium carbonate serosity froth breaking.
Claims (1)
1. the device for liquid froth breaking, comprise liquid storage tower (1), defoaming tower (2), feed pipe (3) and discharge nozzle (11) are set, it is characterized in that: defoaming tower (2) is located in liquid storage tower (1), on the same axle center of liquid storage tower (1) and defoaming tower (2), feed pipe (3) is set; Described discharge nozzle (11) is located at the bottom of liquid storage tower (1) or the side of hypomere, and effective control valve is set, and discharge nozzle (11) and/or overflow pipe (12) arrange respectively valve and be connected with outer liquid pool;
Arranging than the highest row's of defoaming tower (2) the high 5-20cm of spillway hole (6) of the tip position of described feed pipe (3) in defoaming tower (2), feed pipe (3) arranges flowmeter (8) and valve A(9 in feed liquor one end), and be connected with circulating pump;
Described defoaming tower (2) surrounding on the wall of middle hypomere evenly arranges spillway hole (6), and the aperture of spillway hole (6) is Φ 1-4mm, and more than spillway hole (6) arranges three rows, the gross area of spillway hole (6) is greater than the sectional area of feed pipe (3);
Arranging than the high 2-10cm of liquid storage liquid level (7) of the tip position of described overflow pipe (12) in liquid storage tower (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210442377.3A CN102921196B (en) | 2012-11-08 | 2012-11-08 | Device for defoaming liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210442377.3A CN102921196B (en) | 2012-11-08 | 2012-11-08 | Device for defoaming liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102921196A CN102921196A (en) | 2013-02-13 |
| CN102921196B true CN102921196B (en) | 2014-11-26 |
Family
ID=47636207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210442377.3A Active CN102921196B (en) | 2012-11-08 | 2012-11-08 | Device for defoaming liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102921196B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105944405B (en) * | 2016-06-27 | 2018-02-09 | 江苏宝钢精密钢丝有限公司 | Liquid return tank defoaming device |
| CN109513238B (en) * | 2017-09-18 | 2021-04-02 | 中石化广州工程有限公司 | Three-cylinder type air eliminator |
| CN108771887A (en) * | 2018-07-27 | 2018-11-09 | 江苏凤谷节能科技有限公司 | A kind of mechanical defoaming device of balance system |
| CN112999702B (en) * | 2021-03-25 | 2022-11-18 | 绵阳世诺科技有限公司 | Continuous gravity film centrifugal discharge disc and application |
| CN114405072A (en) * | 2021-12-31 | 2022-04-29 | 至微半导体(上海)有限公司 | Spraying system suitable for chemical etching is used |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN203043639U (en) * | 2012-11-08 | 2013-07-10 | 广西华纳新材料科技有限公司 | Device for liquid defoaming |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56115604A (en) * | 1980-02-20 | 1981-09-10 | Hitachi Ltd | Defoaming machine |
| JP3051495B2 (en) * | 1991-05-13 | 2000-06-12 | テルモ株式会社 | Defoaming device and blood reservoir |
-
2012
- 2012-11-08 CN CN201210442377.3A patent/CN102921196B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN203043639U (en) * | 2012-11-08 | 2013-07-10 | 广西华纳新材料科技有限公司 | Device for liquid defoaming |
Non-Patent Citations (2)
| Title |
|---|
| JP昭56-115604A 1981.09.10 * |
| JP特开平4-336076A 1992.11.24 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102921196A (en) | 2013-02-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102921196B (en) | Device for defoaming liquid | |
| CN203043639U (en) | Device for liquid defoaming | |
| CN202482129U (en) | Water gas stripping device | |
| US9707534B2 (en) | Antibubble generator and preparation method | |
| CN104591417A (en) | Preparation method and preparation equipment of hydrogen-rich water | |
| CN106186179A (en) | A kind of organic water based on Hydrodynamic cavitation pollutes degeneration system | |
| CN203700023U (en) | Novel anaerobic granular sludge fluidized bed reactor | |
| CN201857392U (en) | Mechanical defoaming device and fermentation tank provided with same | |
| CN101618896B (en) | Current ejector aerated water preparation device | |
| CN201199753Y (en) | Defoaming apparatus | |
| CN212865428U (en) | Defoaming device for papermaking white water | |
| CN203281079U (en) | Vacuum degasifier | |
| CN206692397U (en) | A kind of device for being advantageous to improve indissoluble gases solubility | |
| JP2017209662A (en) | Water treatment system and water treatment method | |
| CN203346114U (en) | Air-liquid mixing and reacting device | |
| CN106629958B (en) | Closed continuous high-pressure gas dissolving device and method | |
| CN210145856U (en) | High-concentration nanoscale bubble generating device | |
| CN109078514B (en) | Micro-nano bubble generating device only by means of pressure of water supply pipe network | |
| CN102863039A (en) | Multi-bubble hybrid system for pressurizing dissolved air floatation | |
| CN201895885U (en) | Liquid discharging control device of tank | |
| CN203700129U (en) | Energy saving type sludge lifting equipment | |
| CN207079021U (en) | Coal chemical industry multi-effect evaporation system | |
| CN205241395U (en) | A tankage for oil -field brine is handled | |
| CN203768064U (en) | Foam separator used for produced water pretreatment | |
| CN205035110U (en) | Utilize device of anti - bubble preparation microbubble |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhu Yong Inventor after: Wang Quanguang Inventor after: Yan Gancai Inventor after: Long Xiaoe Inventor after: Wei Guanwen Inventor before: Zhu Yong Inventor before: Wang Quanguang Inventor before: Yan Caigan Inventor before: Long Xiaoe Inventor before: Wei Guanwen |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHU YONG WANG QUANGUANG YAN CAIGAN LONG XIAOE WEI GUANWEN TO: ZHU YONG WANG QUANGUANG YAN GANCAI LONG XIAOE WEI GUANWEN |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Device for defoaming liquid Effective date of registration: 20150826 Granted publication date: 20141126 Pledgee: Bank of Communications Ltd the Guangxi Zhuang Autonomous Region branch Pledgor: Guangxi Huana New Materials Science & Technology Co., Ltd. Registration number: 2015990000720 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190322 Granted publication date: 20141126 Pledgee: Bank of Communications Ltd the Guangxi Zhuang Autonomous Region branch Pledgor: Guangxi Huana New Materials Science & Technology Co., Ltd. Registration number: 2015990000720 |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 530103 No.29, Ganwei street, Ganwei Town, Wuming District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Guangxi Warner New Material Co.,Ltd. Address before: 530103 No.29, Ganwei street, Ganwei Town, Wuming County, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: GUANGXI HUANA NEW MATERIALS TECHNOLOGY Co.,Ltd. |