CN102912629A - Preparation method of bacterial-cellulose-based generating fiber and yarn - Google Patents

Preparation method of bacterial-cellulose-based generating fiber and yarn Download PDF

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CN102912629A
CN102912629A CN2012104122210A CN201210412221A CN102912629A CN 102912629 A CN102912629 A CN 102912629A CN 2012104122210 A CN2012104122210 A CN 2012104122210A CN 201210412221 A CN201210412221 A CN 201210412221A CN 102912629 A CN102912629 A CN 102912629A
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bacteria cellulose
cellulose
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bacterial
fiber
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CN102912629B (en
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张迎晨
吴红艳
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Zhongyuan University of Technology
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Zhongyuan University of Technology
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Abstract

Disclosed is a preparation method of bacterial-cellulose-based generating fiber. The preparation method includes soaking ultrafine ribbon of bacterial cellulose into nano-ZnO sol, dipping to obtain bacterial cellulose B, and extracting for standby; placing the bacterial cellulose B into zinc amino salt solution for reacting for a certain time to form bacterial cellulose C; performing surface metallization to the bacterial cellulose C; and preparing bacterial cellulose fiber having generating performance. The prepared finished products are bacterial-cellulose-based generating fiber and yarn, which can be deeply processed by the existing spinning and weaving technology. Mechanical generating components different in scale are formed, and the bacterial-cellulose-based generating fiber and yarn are widely applied to fields, which have requirements for different sizes and powers of self-generating components, such as environment monitoring, biochips implanted into bodies, cars, buildings and military areas.

Description

The preparation method of bacteria cellulose base generating fiber and yarn
Technical field
The present invention relates to the preparation method of a kind of bacteria cellulose base generating fiber and yarn, particularly a kind of bacteria cellulose base that can be applied to miniature, high-performance electronic apparatus and the self-powered of sensor preparation method of fiber and yarn that generates electricity.
Background technology
Along with the development of economic society, electricity has been a part indispensable in the society.The present power status of China is the city short of electricity, remote without the electricity, spring and autumn paddy, summer in winter peak.Although the engineering of transferring electricity from the west to the east has been opened by country, the power loss of long distance powedr transmission and high track laying expense then make the cost of electric power go up not down.The data demonstration of China Electricity Council's issue, China's power consumption reached 4.69 trillion kilowatt hours in 2011, increased by 11.7% on a year-on-year basis.The maximum breach of power supply and demand was 3,000 ten thousand kilowatts in 2010; Meet that maximum breach is 2,500 ten thousand kilowatts during the kurtosis summer.At present, generated energy far can not satisfy the demand of economic growth.
Yet capacity of installed generator is also reducing year by year, and the newly-increased capacity of installed generator in the whole nation had surpassed 9,000 ten thousand kilowatts in 2011, but the scale that in fact effectively increases reduces.Thermoelectricity is China generating main force, yet thermoelectricity loses electric look forward to losing investment drive and the ability of making year after year, and continuously and healthily decline of thermoelectricity investment was by 2,271 hundred million yuan of 1,054 hundred million yuan of reducing to fast 2011 in 2005.The variation of weather causes occurring extremely trembling with fear, very hot weather and electric coal price lattice continue the anxiety that run at high level has also aggravated electricity consumption.Therefore, a few years from now on electric power breach will continue to enlarge certainly, estimate will reach 5,000 ten thousand kilowatts in 2012.Electric power supply is not enough to cause " hard short of electricity " phenomenon unavoidable.Moreover from far-off regions owing to landform and fund, a lot of places power restricted even also do not have and switch on.Military combat, interchange, traffic etc. during pleasure trip on foot because entrained electric weight limited and can not keep permanent, for meagrely-populated zone, the supply of power equipment also is a problem, present large-scale TRT is more complicated and big energy-consuming all, the manufacturing of small-sized electric generating apparatus, reclaims and improperly all can cause very large harm to environment.Therefore, the Technology Need that we are present, the self power generation of namely generating electricity to improve electricity usage efficient, reduces the electric power conveying process, reduces cost, instant our the needed electric energy that obtains from life.
The development of microelectronics and micro-fabrication technology makes the micro-systems such as wireless sense network and microactrator be widely used in environmental monitoring, body and is implanted into biochip, automobile, building, the key areas such as military.Along with going deep into of research, the pursuit to function of MEMS is more and more stronger, and is more and more lower to the requirement of power consumption, the research that volume and size have then been entered nanoscale.
Nanometer technology is just experiencing high speed development as the important emerge science technical field of 21 century in theory and practice.A large amount of novel nano device and materials constantly are developed, for people's life brings more facility.Simultaneously, also the clean technologies that solve energy crisis have been brought for us from microelectric technique research aspect.
Yet Nano-technology Development is to today, and large quantity research all is to concentrate on to develop high sensitivity, high performance nano-device, almost without any the research about the power-supply system of nanoscale.But the nano-sensor that is applied to the aspects such as biological national defence is urgent all the more because of the lifting of technology to the demand of this power supply.In general the power supply of these devices all is directly or indirectly to derive from battery.Sensor can ownly in the object provide power supply to oneself, thereby the miniaturization that realizes simultaneously device and power supply is the target of researcher's Recent study.
Since Curie brother finds that in quartz crystal piezo-electric effect begins, people just are devoted to mechanical energy is converted into the research of electric energy always.Conventional piezoelectric although can form potential change, can not form the Schottky barrier with unilateral conduction because of its electric property as metal, thereby can not reach this process of release that gathers of energy.Thereby piezoelectric circuit generally needs the external circuits of a complexity to finish the output of electric energy now.And conventional piezoelectric causes piezoelectric structure can not accomplish miniaturization because crystal structure is too complicated, says nothing of the high-quality piezoelectric structure of nanoscale.But enter the research category of piezoelectric fabric when metal oxides such as zinc oxide and silica after, its simple chemical composition and crystal structure bring up the easy control of its purity, size, pattern.It becomes rapidly the important materials of current piezoelectric research as the electric conductivity of metal oxide with as the power generation performance of piezoelectric excellence.
The scientist Wang Zhonglin leader's of Chinese origin of the georgia ,u.s.a Institute of Technology in 2006 scientific research group develops a kind of novel plated zinc oxide nanofiber that can produce electric energy, and at motor driving because piezo-electric effect produces electric energy; The U.S. had gone out take a kind of piezoelectric nano generator of zinc oxide nanowire as the basis with Chinese scientist's joint study in 2011, had realized on nanoscale mechanical energy being converted into electric energy.But present material can not come into operation well because of the rapid reduction mediocre and efficient under wet environment of its overall work efficient.
Summary of the invention
Order of the present invention provides the preparation method of a kind of bacteria cellulose base generating fiber and yarn.The prepared nanometer bacteria cellulose base of the present invention generating fiber and yarn can be applied to environmental monitoring, body and be implanted into biochip, automobile, building, the important field that needs the microdevice miniature self-generating source corresponding with it such as military.
For achieving the above object, the technical solution used in the present invention is as follows:
The preparation method of bacteria cellulose base generating fiber of the present invention comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10 mm ~ 100 m/ minutes speed feeding;
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar;
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; (preparation of Nano-ZnO Sol is with reference to Preparation of ZnO ultrafine powder by Sol-Gel method Chinese journal of scientific instrument 1995(1) 37-40; The journal 2009.4.113-116 of progress Industrial and Commercial University Of Chongqing of the superfine Synthesis of ZnO Nanoparticles by Sol-Gel Method of Ran De.)
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 60-100 ℃ of thermal environment, stand-by;
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is any one among Pt, Au, Cu, Al, Zn or the Ag.
The diameter of employed gripping roller is 20 ~ 3000mm in the step (1), is preferably 30 ~ 300mm.
The moisture content of the bacteria cellulose super fiber of processing through press filtration in the step (2) is between 15% ~ 50000%, and the diameter of superfine fibre is at 10 ~ 500nm, and superfine fibre length is between 200nm ~ 200mm.
Preferably between 30% ~ 3000%, the diameter of superfine fibre is preferably at 30 ~ 300nm for the moisture content of the bacteria cellulose super fiber of processing through press filtration in the step (2), and superfine fibre length is preferably between 500nm ~ 100mm.
The collosol temperature that the bacteria cellulose bar immerses in the step (3) is between 80 ~ 100 ℃, and dip time is 5 ~ 100min.
Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 80 ~ 100 ℃ of reaction temperatures, and the reaction time is 24 ~ 72 hours.
Described zinc salt is any one in zinc nitrate, zinc acetate, zinc acetylacetonate or the zinc chloride.Described amine aqueous solution is any one in hexa, urea, ammoniacal liquor, monoethanolamine, diethanol amine, the triethanolamine solution;
Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 80 ~ 100 ℃ of reaction temperatures, and the reaction time is 24 ~ 72 hours.
Step (5) coat of metal conductive processing can be that the methods such as metal steam vapour plating, vacuum sputtering, magnetron sputtering and CVD are processed.
Adopt bacteria cellulose base generating fiber spinning of the present invention to obtain bacteria cellulose base generating yarn of the present invention.
The made finished product of the present invention is bacteria cellulose base generating fiber and yarn, can carry out deep processing by existing weaving weaving technology.Can form the mechanical electrification component of different scales yardstick, be widely used in environmental monitoring, body and be implanted into biochip, automobile, building, the field that the self power generation assembly is had the different size power requirement such as military.
The specific embodiment
Embodiment 1
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10 mm ~ 100 m/ minutes speed feeding; The diameter of employed gripping roller is 20 ~ 3000mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 15% ~ 50000%, and the diameter of superfine fibre is at 10 ~ 500nm, and superfine fibre length is between 200nm ~ 200mm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 80 ~ 100 ℃, and dip time is 5 ~ 100min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 60-100 ℃ of thermal environment, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 80 ~ 100 ℃ of reaction temperatures, and the reaction time is 24 ~ 72 hours.
Described zinc salt is any one in zinc nitrate, zinc acetate, zinc acetylacetonate or the zinc chloride.Described amine aqueous solution is any one in hexa, urea, ammoniacal liquor, monoethanolamine, diethanol amine, the triethanolamine solution.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is any one among Pt, Au, Cu, Al, Zn or the Ag.Step (5) coat of metal conductive processing can be the steam plating, vacuum sputtering, and magnetron sputtering and CVD method are processed.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 50nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 2
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10 mm minutes speed feeding; The diameter of employed gripping roller is 20mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 15%, and the diameter of superfine fibre is at 500nm, and superfine fibre length is between 200mm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 80 ℃, and dip time is 100min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 60 ℃ of thermal environments, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 80 ℃ of reaction temperatures, and the reaction time is 72 hours.
Described zinc salt is zinc nitrate, and described amine aqueous solution is hexa solution.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is Pt.Step (5) coat of metal conductive processing adopts the steam electroplating method to process.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 40nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 3
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 00 m/ minute speed feeding; The diameter of employed gripping roller is 3000mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 50000%, and the diameter of superfine fibre is at 10nm, and superfine fibre length is between 200nm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 100 ℃, and dip time is 5min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in the 60-100 degree thermal environment, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 100 ℃ of reaction temperatures, and the reaction time is 24 hours.
Described zinc salt is zinc acetate, and described amine aqueous solution is urea liquid.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is Au, and coat of metal conductive processing is that the vacuum sputtering method is processed.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 35nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 4
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 50 m/ minutes speed feeding; The diameter of employed gripping roller is 1000mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 10000%, and the diameter of superfine fibre is at 300nm, and superfine fibre length is between 100mm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 95 ℃, and dip time is 80min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 80 ℃ of thermal environments, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 95 ℃ of reaction temperatures, and the reaction time is 60 hours.
Described zinc salt is zinc acetylacetonate, and described amine aqueous solution is ammonia spirit.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is Cu, and coat of metal conductive processing can be that magnetically controlled sputter method is processed.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 38nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 5
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10 m/ minutes speed feeding; The diameter of employed gripping roller is 800mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 300%, and the diameter of superfine fibre is at 100nm, and superfine fibre length is between 800nm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 85 ℃, and dip time is 30min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 70 ℃ of thermal environments, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 90 ℃ of reaction temperatures, and the reaction time is 36 hours.
Described zinc salt is zinc chloride, and described amine aqueous solution is ethanolamine solutions.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is Al, and coat of metal conductive processing adopts the CVD method to process.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 42nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 6
The preparation method of the bacteria cellulose base generating fiber of the present embodiment comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10m/ minute speed feeding; The diameter of employed gripping roller is 1200mm.
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar; The moisture content of the bacteria cellulose super fiber that the process press filtration is processed is between 20000%, and the diameter of superfine fibre is at 30nm, and superfine fibre length is between 50mm.
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by; The collosol temperature that the bacteria cellulose bar immerses is between 95 ℃, and dip time is 20min.
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 70 ℃ of thermal environments, stand-by; Amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, and zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 90 ℃ of reaction temperatures, and the reaction time is 52 hours.
Described zinc salt is zinc chloride, and described amine aqueous solution is diethanolamine solution.
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is Ag, and step (5) coat of metal conductive processing is that magnetically controlled sputter method is processed.
The bacteria cellulose base generating fiber spinning that employing obtains obtains bacteria cellulose base generating yarn of the present invention.The yarn of one section 10 centimeter length detects the current output signal of 38nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 7
With the bacteria cellulose after the bleaching, feed between the gripping roller that a pair of diameter is 20mm according to the speed of 10mm.Then puncture at a high speed, isolate and combing effect through the surperficial needle-like combing of the spiked roller acupuncture through formation such as needle-like, superhard, elastic stainless steel silk or B alloy wire polishing wheels, bacterial cellulose wet-coating is become bacteria cellulose fibre.Bacteria cellulose super fiber moisture content after treatment is 80%, and diameter is 400nm, and length is 150mm.Then the bacteria cellulose super fiber is immersed respectively zinc solution and alkaline solution that preparation is finished.Then the Nano-ZnO Sol for preparing ambient-temp-stable by blend.To immerse through the bacteria cellulose fibre that immersion liquid is processed in 80 degrees centigrade the nano zine oxide colloidal sol, process through 15 minutes immersions, form bacteria cellulose fibre B.Bacteria cellulose B is put into the zincamide salting liquid of 80 degrees centigrade of constant temperature according to the mass ratio of 1:1, react formation bacteria cellulose fibre C after 36 hours.Bacteria cellulose fibre C is carried out can obtaining bacteria cellulose base generating fiber and yarn after golden vacuum and steam plates 10 nanometered disposals.The yarn of one section 10 centimeter length detects the current output signal of 50nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 8
With the bacteria cellulose after the bleaching, feed between the gripping roller that a pair of diameter is 50mm according to the speed of 30mm.Then puncture at a high speed, isolate and combing effect through the surperficial needle-like combing of the spiked roller acupuncture through formation such as needle-like, superhard, elastic stainless steel silk or B alloy wire polishing wheels, bacterial cellulose wet-coating is become bacteria cellulose fibre.Bacteria cellulose super fiber moisture content after treatment is 68%, and diameter is 320nm, and length is 150mm.Then the bacteria cellulose super fiber is immersed respectively zinc solution and alkaline solution that preparation is finished.Then the Nano-ZnO Sol for preparing ambient-temp-stable by blend.To immerse through the bacteria cellulose fibre that immersion liquid is processed in 90 degrees centigrade the nano zine oxide colloidal sol, process through 30 minutes immersions, form bacteria cellulose fibre B.Bacteria cellulose B is put into the zincamide salting liquid of 85 degrees centigrade of constant temperature according to the mass ratio of 1:1, react formation bacteria cellulose fibre C after 48 hours.Bacteria cellulose fibre C is carried out can obtaining bacteria cellulose base generating fiber and yarn after silver-colored vacuum and steam plates 10 nanometered disposals.The yarn of one section 10 centimeter length detects the current output signal of 30nA through galvanometer under the ultrasonic oscillation disposition.
Embodiment 9
With the bacteria cellulose after the bleaching, feed between the gripping roller that a pair of diameter is 80mm according to the speed of 50mm.Then puncture at a high speed, isolate and combing effect through the surperficial needle-like combing of the spiked roller acupuncture through formation such as needle-like, superhard, elastic stainless steel silk or B alloy wire polishing wheels, bacterial cellulose wet-coating is become bacteria cellulose fibre.Bacteria cellulose super fiber moisture content after treatment is 60%, and diameter is 250nm, and length is 150mm.Then the bacteria cellulose super fiber is immersed respectively zinc solution and alkaline solution that preparation is finished.Then the Nano-ZnO Sol for preparing ambient-temp-stable by blend.To immerse through the bacteria cellulose fibre that immersion liquid is processed in 95 degrees centigrade the nano zine oxide colloidal sol, process through 40 minutes immersions, form bacteria cellulose fibre B.Bacteria cellulose B is put into the zincamide salting liquid of 90 degrees centigrade of constant temperature according to the mass ratio of 1:1, react formation bacteria cellulose fibre C after 60 hours.Bacteria cellulose fibre C is carried out can obtaining bacteria cellulose base generating fiber and yarn after the copper vacuum and steam plates 20 nanometered disposals.The yarn of one section 10 centimeter length detects the current output signal of 28nA through galvanometer under the ultrasonic oscillation disposition.

Claims (9)

1. the preparation method of bacteria cellulose base generating fiber, its special type is, comprises the steps:
(1) bacterial cellulose wet-coating behind the bleaching is placed between a pair of gripping roller, according to 10 mm ~ 100 m/ minutes speed feeding;
(2) puncture at a high speed, isolate and combing effect through licker-in surface acupuncture from the cellulose membrane of exporting between the roller, bacterial cellulose wet-coating is become bacteria cellulose fibre; Bacteria cellulose fibre is processed through the filter press press filtration, prepared bacteria cellulose superfine fibre bar;
(3) configure respectively zinc solution and alkaline solution, prepare the Nano-ZnO Sol of ambient-temp-stable by blend; Bacteria cellulose superfine fibre bar is immersed Nano-ZnO Sol, and dipping obtains bacteria cellulose B, takes out postlyophilization, and is stand-by;
(4) bacteria cellulose B is put into the amido zinc solution, reaction a period of time, form bacteria cellulose C, take out postlyophilization, then place in 60-100 ℃ of thermal environment, stand-by;
(5) bacteria cellulose C is carried out the coat of metal conductive processing of plating; Prepare the bacteria cellulose fibre with power generation performance, described metal is any one among Pt, Au, Cu, Al, Zn or the Ag.
2. the preparation method of bacteria cellulose base according to claim 1 generating fiber, its special type is: the diameter of employed gripping roller is 20 ~ 3000mm in the step (1).
3. the preparation method of bacteria cellulose base according to claim 2 generating fiber, its special type is: the diameter of employed gripping roller is 30 ~ 300mm in the step (1).
4. the preparation method of bacteria cellulose base according to claim 1 generating fiber, its special type is: the moisture content of the bacteria cellulose super fiber of processing through press filtration in the step (2) is between 15% ~ 50000%, the diameter of superfine fibre is at 10 ~ 500nm, and superfine fibre length is between 200nm ~ 200mm.
5. the preparation method of bacteria cellulose base according to claim 4 generating fiber, its special type is: the moisture content of the bacteria cellulose super fiber of processing through press filtration in the step (2) is between 30% ~ 3000%, the diameter of superfine fibre is at 30 ~ 300nm, and superfine fibre length is between 500nm ~ 100mm.
6. the preparation method of bacteria cellulose base according to claim 1 generating fiber, its special type is: the collosol temperature that the bacteria cellulose bar immerses in the step (3) is between 80 ~ 100 ℃, and dip time is 5 ~ 100min.
7. the preparation method of bacteria cellulose base according to claim 1 generating fiber, its special type is: the amido zinc solution described in the step (4) is the mixed liquor of zinc solution and amine aqueous solution, zinc ion and amine ion concentration are 0.01mol/L in the solution; Bacteria cellulose B is 1:1 with the mass ratio of the amido zinc solution of putting into, 80 ~ 100 ℃ of reaction temperatures, and the reaction time is 24 ~ 72 hours.
8. the preparation method of bacteria cellulose base according to claim 1 generating fiber, its special type is: step (5) coat of metal conductive processing can be the steam plating, vacuum sputtering, magnetron sputtering and CVD method are processed.
9. the preparation method of a bacteria cellulose base generating yarn is characterized in that: adopt bacteria cellulose base generating fiber spinning claimed in claim 1 to obtain yarn.
CN201210412221.0A 2012-10-25 2012-10-25 Preparation method of bacterial-cellulose-based generating fiber and yarn Expired - Fee Related CN102912629B (en)

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CN104201280A (en) * 2014-08-04 2014-12-10 北京科技大学 Preparation methods of nanometer piezoelectric film and nanometer composite piezoelectric generator
CN104201280B (en) * 2014-08-04 2017-01-04 北京科技大学 A kind of nanometer piezoelectric membrane and the preparation method of nano combined piezoelectric generator

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