CN102911555B - Method for producing water-soluble ink for carton printing with abandoned offset printing ink - Google Patents
Method for producing water-soluble ink for carton printing with abandoned offset printing ink Download PDFInfo
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- CN102911555B CN102911555B CN 201210420957 CN201210420957A CN102911555B CN 102911555 B CN102911555 B CN 102911555B CN 201210420957 CN201210420957 CN 201210420957 CN 201210420957 A CN201210420957 A CN 201210420957A CN 102911555 B CN102911555 B CN 102911555B
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Abstract
The invention discloses a method for producing water-soluble ink for carton printing with abandoned offset printing ink. The method comprises the steps of mixing the abandoned offset printing ink and printing ink cleaning agent according to the mass ratio of 1:(4-6) for dilution; heating the diluted printing ink to 60 DEG C, placing the printing ink into a decolorizing filter for deoiling and decolorizing, and separating a pigment and a solvent; and taking the separated pigment and solvent as major raw materials for producing the water-soluble ink for the carton printing and adding other raw materials to produce the water-soluble ink for the carton printing according to a production formula of the water-soluble ink for the carton printing. According to the method, the abandoned offset printing ink is subjected to solvent dilution, heating, filtering, deoiling, decolorizing and other processes, and relevant materials are added to an extractive to produce the water-soluble ink meeting carton printing requirements, so that the environment is not polluted, the environmental protection is facilitated, and the production cost of the water-soluble ink is lowered.
Description
Technical field
The present invention relates to printing and use black production field, more specifically say a kind of and utilize discarded flexographic ink to produce the method for cardboard box printing with water-soluble China ink.
Background technology
Pigment in flexographic ink is water-fast, these granules of pigments are very tiny, adsorptive power is very strong, wherein also contain the heavy metal element such as lead, chromium, cadmium, mercury that human body is there is to certain toxicity, discarded flexographic ink is to environment, and how processing discarded flexographic ink becomes the printing industry problem demanding prompt solution, if can will discard the flexographic ink recycling, both can reduce production costs, can solve again the problem of environmental pollution.
Summary of the invention
The purpose of this invention is to provide a kind of method of discarded flexographic ink production cardboard box printing with water-soluble China ink of utilizing, be intended to solve problem of environmental pollution by the recycling of discarded flexographic ink, reduce production costs simultaneously.
The objective of the invention is to be achieved by the following technical programs, a kind of method of discarded flexographic ink production cardboard box printing with water-soluble China ink of utilizing, is characterized in that, comprises the following steps:
The first step, will discard flexographic ink and detergent for ink 1:(4～6 in mass ratio) the mixed dilution;
Second step, be heated to 60 degree by the printing ink after above-mentioned dilution, puts into the de-oiling decolorizing filter and carry out de-oiling, decolouring, isolates pigment and solvent;
The 3rd step, using isolated pigment and solvent as producing the main raw material of cardboard box printing with water-soluble China ink, add other raw material production according to cardboard box printing with the production formula of water-soluble China ink and go out carton printing water dissolubility China ink.
Adopt isolated mineral black and solvent production cardboard box printing with the proportion by weight of water-soluble tusche to be:
Isolated solvent 60-70 part, 10 parts of isolated mineral blacks, carbon black 8-12 part, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to carbon black below particle diameter 15um;
Second step, mix the carbon black powder after grinding and isolated solvent, isolated mineral black, the agent of pH value stabilization, drying retardant with rear fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour.
Adopt isolated red and solvent production cardboard box printing with the proportion by weight of water-soluble bright red China ink to be:
Isolated solvent 60-70 part, 3 parts of isolated reds, 12 parts of reds, bright red 3 parts of Li Suer, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, by red and bright red being ground to below particle diameter 15um of vertical element that;
Second step, just the red after the grinding and the vertical element bright red mixed powder of that and isolated solvent, isolated red, the agent of pH value stabilization, drying retardant fully stir 40 minutes after mixing;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour.
Adopt isolated phthalocyanine and solvent production cardboard box printing with the proportion by weight of water-soluble dark green China ink to be:
Isolated solvent 60-70 part solvent, 3 parts of isolated phthalocyanines, 12 parts of phthalocyanine greens, 7 parts of diarylide yellows, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to phthalocyanine green and diarylide yellow below particle diameter 15um;
Second step, the phthalocyanine green after grinding and the mixed powder of diarylide yellow and isolated solvent, isolated phthalocyanine, the agent of pH value stabilization, drying retardant is mixed after fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour.
Adopt isolated blue pigment and solvent production cardboard box printing with the proportion by weight of water-soluble dark blue China ink to be:
Isolated solvent 60-70 part solvent, 3 parts of isolated blue pigment, 8 parts of Phthalocyanine Blue BGS, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to Phthalocyanine Blue BGS below particle diameter 15um;
Second step, mix the Phthalocyanine Blue BGS powder after grinding and isolated solvent, isolated blue pigment, the agent of pH value stabilization, drying retardant with rear fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour.
Beneficial effect: the present invention utilizes discarded flexographic ink to process by solvent cut, heating, filtration, de-oiling, the operation such as discolor; add associated materials with extract and make the water-soluble China ink that meets the cardboard box printing service requirements; not to environment; be conducive to environment protection, reduce the production cost of water-soluble China ink simultaneously.
Embodiment
A kind of method of discarded flexographic ink production cardboard box printing with water-soluble China ink of utilizing provided by the invention comprises the following steps:
The first step, will discard the flexographic ink analytical study, according to its main component, press discarded flexographic ink and detergent for ink mass ratio 1:(4～6) the mixed dilution, to reach the service requirements of the water-soluble China ink of cardboard box printing;
Second step, be heated to 60 degree by the printing ink after above-mentioned dilution, puts into the de-oiling decolorizing filter and carry out de-oiling, decolouring, isolates pigment and solvent;
The 3rd step, using isolated pigment and solvent as producing the main raw material of cardboard box printing with water-soluble China ink, add other raw material production according to cardboard box printing with the production formula of water-soluble China ink and go out carton printing water dissolubility China ink.
Tusche: isolated solvent 60-70 part, 10 parts of isolated mineral blacks, carbon black 8-12 part, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water.
Bright red China ink: isolated solvent 60-70 part solvent, 3 parts of isolated reds, 12 parts of reds, bright red 3 parts of Li Suer, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water.
Dark green China ink: isolated solvent 60-70 part solvent, 3 parts of isolated phthalocyanines, 12 parts of phthalocyanine greens, 7 parts of diarylide yellows, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water.
Deep blue China ink: isolated solvent 60-70 part solvent, 3 parts of isolated blue pigment, 8 parts of Phthalocyanine Blue BGS, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water.
Specific embodiments
Embodiment mono-:
The production of the water-soluble China ink of black
Get the raw materials ready: 65 kilograms of isolated solvents, 10 kilograms, 10 kilograms carbon blacks of isolated mineral black, 6 kilograms of emulsifying agents, 2 kilograms of pH value stabilization agent, 2 kilograms of drying retardants, 1 kilogram of defoamer, 2 kilograms of thinners, 1 kilogram of ionized water, 300 liter capacity cylinder a bites, one, stirrer, one of shredder;
The first step is poured 10 kilograms of carbon blacks into shredder and is ground, and is ground to fineness and reaches below 15um;
Second step is poured 2 kilograms of 65 kilograms of isolated solvents, 10 kilograms, 10 kilograms carbon black powders of isolated mineral black, 2 kilograms of pH value stabilization agent, drying retardant in cylinder into and is fully stirred 40 minutes;
The 3rd step is poured 1 kilogram of 6 kilograms of emulsifying agent, 1 kilogram of defoamer, 2 kilograms of thinners, ionized water sequentially in cylinder and is fully stirred after 1 hour and can use.
Embodiment bis-:
The production of bright red water-soluble China ink
Get the raw materials ready: 70 kilograms of isolated solvents, 3 kilograms of isolated reds, 12 kilograms of reds, bright red 6 kilograms of Li Suer, 5 kilograms of emulsifying agents, 2 kilograms of pH value stabilization agent, 2 kilograms of drying retardants, 1 kilogram of defoamer, 2 kilograms of thinners, 1 kilogram of ionized water, 300 liter capacity cylinder a bites, one, stirrer, one of shredder;
The first step is poured bright red 6 kilograms of 12 kilograms of reds, Li Suer respectively into shredder and is ground, and is ground to fineness and reaches below 15um;
Second step is poured 70 kilograms of isolated solvents, 3 kilograms of isolated reds, 12 kilograms of reds, 3 kilograms of emulsifying agents, 2 kilograms of pH value stabilization agent, 2 kilograms of parts of drying retardant in cylinder into and is fully stirred 30 minutes;
The 3rd step will be found 1 kilogram of your bright red 6 kilogram, 2 kilograms of emulsifying agents, 1 kilogram of defoamer, 2 kilograms of thinners, ionized water of element and pour into sequentially in cylinder and fully stir after 1 hour and can use.
Embodiment tri-:
The production of dark green water-soluble China ink
Get the raw materials ready: 60 kilograms of isolated solvents, 3 kilograms of isolated phthalocyanines, 13 kilograms of phthalocyanine greens, 7 kilograms of diarylide yellows, 6 kilograms of emulsifying agents, 2 kilograms of pH value stabilization agent, 3 kilograms of parts of drying retardant, 1.5 kilograms of defoamers, 2 kilograms of thinners, 1 kilogram of ionized water, 300 liter capacity cylinder a bites, one, stirrer, one of shredder;
The first step is poured respectively 7 kilograms of 13 kilograms of phthalocyanine greens, diarylide yellow into shredder and is ground, and is ground to fineness and reaches below 15um;
Second step is poured 60 kilograms of isolated solvents, 3 kilograms of isolated phthalocyanines, 13 kilograms of phthalocyanine greens, 2 kilograms of pH value stabilization agent, 2 kilograms of parts of drying retardant in cylinder into and is fully stirred 40 minutes;
The 3rd step is poured 1 kilogram of 7 kilograms of diarylide yellow, 6 kilograms of emulsifying agents, 1 kilogram of defoamer, 2 kilograms of thinners, ionized water sequentially in cylinder and is fully stirred after 1 hour and can use.
Embodiment tetra-: deep blue
Get the raw materials ready: 65 kilograms of isolated solvents, 3 kilograms of isolated blue pigment, 8 kilograms of phthalocyanine blues, 4 kilograms, fuchsin, 6 kilograms of emulsifying agents, 2 kilograms of pH value stabilization agent, 3 kilograms of parts of drying retardant, 1.5 kilograms of defoamers, 2 kilograms of thinners, 1 kilogram of ionized water, 300 liter capacity cylinder a bites, one, stirrer, one of shredder;
The first step is poured respectively 4 kilograms of 8 kilograms of phthalocyanine blues, fuchsin into shredder and is ground, and is ground to fineness and reaches below 15um;
Second step is poured 2 kilograms of 65 kilograms of isolated solvents, 3 kilograms of isolated blue pigment, 8 kilograms of phthalocyanine blues, 4 kilograms, fuchsin, 2 kilograms of pH value stabilization agent, drying retardant in cylinder into and is fully stirred 40 minutes;
The 3rd step is poured 1 kilogram of 6 kilograms of emulsifying agent, 1 kilogram of defoamer, 2 kilograms of thinners, ionized water sequentially in cylinder and is fully stirred after 1 hour and can use.
The above, be only preferred embodiment of the present invention, not the present invention done to any pro forma restriction; Any those of ordinary skill in the art, do not breaking away from technical solution of the present invention scope situation, all can utilize method and the technology contents of above-mentioned announcement to make many possible changes and modification to technical solution of the present invention, or be revised as the equivalent embodiment of equivalent variations.Therefore, every content that does not break away from technical solution of the present invention, according to technical spirit of the present invention to any simple modification made for any of the above embodiments, be equal to replacements, equivalence changes and modify, all still belong in the scope that technical solution of the present invention protects.
Claims (1)
1. one kind is utilized discarded flexographic ink to produce the method for cardboard box printing with water-soluble China ink, it is characterized in that, comprises the following steps:
The first step, will discard flexographic ink and detergent for ink 1:(4～6 in mass ratio) the mixed dilution;
Second step, be heated to 60 degree by the printing ink after above-mentioned dilution, puts into the de-oiling decolorizing filter and carry out de-oiling, decolouring, isolates pigment and solvent;
The 3rd step, using isolated pigment and solvent as producing the main raw material of cardboard box printing with water-soluble China ink, add other raw material production according to cardboard box printing with the production formula of water-soluble China ink and go out carton printing water dissolubility China ink;
Adopt isolated mineral black and solvent production cardboard box printing with the proportion by weight of water-soluble tusche to be:
Isolated solvent 60-70 part, 10 parts of isolated mineral blacks, carbon black 8-12 part, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to carbon black below particle diameter 15um;
Second step, mix the carbon black powder after grinding and isolated solvent, isolated mineral black, the agent of pH value stabilization, drying retardant with rear fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour;
Adopt isolated red and solvent production cardboard box printing with the proportion by weight of water-soluble bright red China ink to be:
Isolated solvent 60-70 part, 3 parts of isolated reds, 12 parts of reds, bright red 3 parts of Li Suer, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, by red and bright red being ground to below particle diameter 15um of vertical element that;
Second step, just the red after the grinding and the vertical element bright red mixed powder of that and isolated solvent, isolated red, the agent of pH value stabilization, drying retardant fully stir 40 minutes after mixing;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour;
Adopt isolated phthalocyanine and solvent production cardboard box printing with the proportion by weight of water-soluble dark green China ink to be:
Isolated solvent 60-70 part solvent, 3 parts of isolated phthalocyanines, 12 parts of phthalocyanine greens, 7 parts of diarylide yellows, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to phthalocyanine green and diarylide yellow below particle diameter 15um;
Second step, the phthalocyanine green after grinding and the mixed powder of diarylide yellow and isolated solvent, isolated phthalocyanine, the agent of pH value stabilization, drying retardant is mixed after fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour;
Adopt isolated blue pigment and solvent production cardboard box printing with the proportion by weight of water-soluble dark blue China ink to be:
Isolated solvent 60-70 part solvent, 3 parts of isolated blue pigment, 8 parts of phthalocyanine blues, 10 parts of emulsifying agents, 2 parts of pH value stabilization agent, 3 parts of drying retardants, 1 part of defoamer, 2 parts of thinners, 1 part of ionized water;
The preparation method comprises the following steps:
The first step, be ground to Phthalocyanine Blue BGS below particle diameter 15um;
Second step, mix the Phthalocyanine Blue BGS powder after grinding and isolated solvent, isolated blue pigment, the agent of pH value stabilization, drying retardant with rear fully stirring 40 minutes;
The 3rd step, join emulsifying agent, defoamer, thinner, ionized water sequentially in above-mentioned mixed liquid and fully and stir 1 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210420957 CN102911555B (en) | 2012-10-30 | 2012-10-30 | Method for producing water-soluble ink for carton printing with abandoned offset printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210420957 CN102911555B (en) | 2012-10-30 | 2012-10-30 | Method for producing water-soluble ink for carton printing with abandoned offset printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102911555A CN102911555A (en) | 2013-02-06 |
| CN102911555B true CN102911555B (en) | 2013-12-25 |
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| CN 201210420957 Expired - Fee Related CN102911555B (en) | 2012-10-30 | 2012-10-30 | Method for producing water-soluble ink for carton printing with abandoned offset printing ink |
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| CN107352704A (en) * | 2017-08-18 | 2017-11-17 | 沈瑞忠 | A kind of printing ink wastewater recycling device |
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| US5779909A (en) * | 1995-10-13 | 1998-07-14 | Sony Corporation | Method for recovering binder resin from ink ribbon, method for recovering dye from ink ribbon, apparatus for recovering ink according to said method, and method for producing recycled ink |
| CN1179989A (en) * | 1996-08-30 | 1998-04-29 | 江汉石油学院 | Regeneration treating method for gravure printing ink waste liquid |
| JP2006170801A (en) * | 2004-12-15 | 2006-06-29 | Seiko Epson Corp | Method of analyzing color material composition |
| CN101100822B (en) * | 2007-07-04 | 2010-05-26 | 中国科学院长春应用化学研究所 | Method for deinking and decoloring office waste paper by using ion liquid |
| CN101246349B (en) * | 2008-03-19 | 2011-07-06 | 东莞惠能办公耗材有限公司 | Wasted ink powder classification method and reclaiming utilization method after specification |
| CN101649134B (en) * | 2009-09-18 | 2011-09-07 | 广州市恒远彩印有限公司 | Waste-ink renewable ink and preparation method thereof |
| CN102058991B (en) * | 2009-11-13 | 2014-08-20 | 车磊 | Solvent recovery method and device for organic solvent-containing dye and coating waste |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Lianmei Inventor before: Chai Jiannan Inventor before: Jiang Yunnong Inventor before: Yuan Hongliang |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170612 Address after: 266000 Shandong Province, Qingdao city Huangdao District tiejue road 367 Patentee after: Qingdao New Century Paper Co., Ltd. Address before: Anhui province Bengbu City Yuhui District 233010 Hing Road No. 1639 Patentee before: Bengbu Biyoute Package Printing Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131225 Termination date: 20181030 |